GB1248128A - Preparation of transparent and thermostable copolymers - Google Patents
Preparation of transparent and thermostable copolymersInfo
- Publication number
- GB1248128A GB1248128A GB1561869A GB1561869A GB1248128A GB 1248128 A GB1248128 A GB 1248128A GB 1561869 A GB1561869 A GB 1561869A GB 1561869 A GB1561869 A GB 1561869A GB 1248128 A GB1248128 A GB 1248128A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- copolymers
- azodiisobutyronitrile
- methylpentene
- march
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title abstract 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 2
- -1 vinyl halide Chemical class 0.000 abstract 2
- 229920002554 vinyl polymer Polymers 0.000 abstract 2
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 abstract 1
- HDIFHQMREAYYJW-FMIVXFBMSA-N 2,3-dihydroxypropyl (e)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C\CCCCCCCC(=O)OCC(O)CO HDIFHQMREAYYJW-FMIVXFBMSA-N 0.000 abstract 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 1
- JMMZCWZIJXAGKW-UHFFFAOYSA-N 2-methylpent-2-ene Chemical compound CCC=C(C)C JMMZCWZIJXAGKW-UHFFFAOYSA-N 0.000 abstract 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 abstract 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 abstract 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000872 buffer Substances 0.000 abstract 1
- 229910052793 cadmium Inorganic materials 0.000 abstract 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000000314 lubricant Substances 0.000 abstract 1
- 125000005395 methacrylic acid group Chemical group 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 1
- 239000011118 polyvinyl acetate Substances 0.000 abstract 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 239000000375 suspending agent Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 229920001567 vinyl ester resin Polymers 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/02—Monomers containing chlorine
- C08F214/04—Monomers containing two carbon atoms
- C08F214/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1,248,128. Copolymers. STAMICARBON N.V. 25 March, 1969 [28 March, 1968], No. 15618/69. Heading C3P. Transparent, thermostable copolymers are prepared by copolymerizing 4-methylpentene-1 and a vinyl halide at a pressure below 600 atmospheres. The vinyl halide may be vinyl chloride, bromide or fluoride and minor proportions of other monomers, e.g. vinylidene chloride, vinyl esters, acrylic and methacrylic compounds, vinyl ethers, styrene, vinyl pyridine, allyl compounds and maleic and fumaric esters, may also be present. Polymerization may be effected in bulk, solution, suspension or dispersion in the presence of peroxy, azo and redox catalysts, dispersing and suspending agents, and buffers. Fillers, plasticizers and other polymers may be incorporated and the products made into bottles, sheets and films. Examples describe the copolymerization of vinyl chloride and methylpentene in aqueous media in the presence of hydrolysed polyvinyl acetate and (1 to 4, 7 and 8) di-(t.-butyl-4-cyclohexyl) percarbonate and azodiisobutyronitrile (5, 6 and 9) azodiisobutyronitrile and (11) lauryl peroxide. The products are compounded with organotin and organic cadmium/barium stabilizers and glycerylmonoricinoleate as lubricant.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL6804333A NL6804333A (en) | 1968-03-28 | 1968-03-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1248128A true GB1248128A (en) | 1971-09-29 |
Family
ID=19803160
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1561869A Expired GB1248128A (en) | 1968-03-28 | 1969-03-25 | Preparation of transparent and thermostable copolymers |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE730566A (en) |
| DE (1) | DE1916052A1 (en) |
| FR (1) | FR2004967A1 (en) |
| GB (1) | GB1248128A (en) |
| NL (1) | NL6804333A (en) |
| SE (1) | SE355585B (en) |
-
1968
- 1968-03-28 NL NL6804333A patent/NL6804333A/xx unknown
-
1969
- 1969-03-25 GB GB1561869A patent/GB1248128A/en not_active Expired
- 1969-03-27 BE BE730566D patent/BE730566A/xx unknown
- 1969-03-28 DE DE19691916052 patent/DE1916052A1/en active Pending
- 1969-03-28 SE SE447269A patent/SE355585B/xx unknown
- 1969-03-28 FR FR6909302A patent/FR2004967A1/fr not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| BE730566A (en) | 1969-09-29 |
| SE355585B (en) | 1973-04-30 |
| FR2004967A1 (en) | 1969-12-05 |
| DE1916052A1 (en) | 1969-10-02 |
| NL6804333A (en) | 1969-09-30 |
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