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GB1183564A - An Ion Catalyst for the Manufacture of Bisphenols - Google Patents

An Ion Catalyst for the Manufacture of Bisphenols

Info

Publication number
GB1183564A
GB1183564A GB2574468A GB2574468A GB1183564A GB 1183564 A GB1183564 A GB 1183564A GB 2574468 A GB2574468 A GB 2574468A GB 2574468 A GB2574468 A GB 2574468A GB 1183564 A GB1183564 A GB 1183564A
Authority
GB
United Kingdom
Prior art keywords
butylphenol
phenol
ketone
bisphenols
manufacture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2574468A
Inventor
Boyd Wayne Mcnutt
Benny Bryan Gammill
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Priority to GB2574468A priority Critical patent/GB1183564A/en
Publication of GB1183564A publication Critical patent/GB1183564A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B01J31/10—Ion-exchange resins sulfonated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/20—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B01J2231/341—1,2-additions, e.g. aldol or Knoevenagel condensations
    • B01J2231/347—1,2-additions, e.g. aldol or Knoevenagel condensations via cationic intermediates, e.g. bisphenol A type processes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,183,564. Bisphenols. DOW CHEMICAL CO. 29 May, 1968, No. 25744/68. Heading C2C. [Also in Division C3P] A process is disclosed for the manufacture of a bis-phenol by the catalytic condensation of a phenol with a ketone wherein the catalyst employed is a modified water-insoluble cationexchange resin containing a plurality of sulphonic acid groups, some of which have been converted to alkyl mercaptoamine sulphonic acid salt groups by partial neutralization of the resin with an alkyl mercaptoamine. A preferred catalyst is a sulphonated styrene-divinylbenzene copolymer modified by partial neutralization with 2-mercaptoethylamine. The preparation of bisphenol A is described. Other suitable starting materials are phenol, o- and m-cresol, o- and m-chlorophenol, o-bromophenol, o-sec.- butylphenol, o t - butylphenol, 2,6 - dibromophenol, 2,6 - di - t - butylphenol, 6 - chloro - o - cresol and o-phenylphenol, acetone, methylethyl ketone, methylisobutyl ketone, acetophenone, cyclohexanone and 1,3-dichloroacetone.
GB2574468A 1968-05-29 1968-05-29 An Ion Catalyst for the Manufacture of Bisphenols Expired GB1183564A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2574468A GB1183564A (en) 1968-05-29 1968-05-29 An Ion Catalyst for the Manufacture of Bisphenols

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2574468A GB1183564A (en) 1968-05-29 1968-05-29 An Ion Catalyst for the Manufacture of Bisphenols

Publications (1)

Publication Number Publication Date
GB1183564A true GB1183564A (en) 1970-03-11

Family

ID=10232576

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2574468A Expired GB1183564A (en) 1968-05-29 1968-05-29 An Ion Catalyst for the Manufacture of Bisphenols

Country Status (1)

Country Link
GB (1) GB1183564A (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2722683A1 (en) * 1976-05-21 1977-12-01 Shell Int Research CATALYST AND ITS USE
US4191843A (en) 1977-11-09 1980-03-04 Shell Oil Company Preparation of bisphenols
EP0045959A1 (en) * 1980-08-07 1982-02-17 Mitsubishi Kasei Corporation Process for preparing bisphenols
EP0171758A2 (en) * 1984-08-13 1986-02-19 The Dow Chemical Company A process for preparing partially strong-acid cation-exchange resins in acid form
EP0268318A1 (en) * 1986-10-30 1988-05-25 Shell Internationale Researchmaatschappij B.V. Process and catalyst for production of a bisphenol
EP0305774A1 (en) * 1987-08-19 1989-03-08 Bayer Ag Ion exchange resin modified by thiazolines
US5414151A (en) * 1994-05-02 1995-05-09 General Electric Company Method for making bisphenol
US5428075A (en) * 1994-05-02 1995-06-27 General Electric Company Method for regenerating a sulfonated aromatic organic polymeric ion-exchange resin bed having deactivated aminoorganomercaptan groups with phenol
WO1996012560A1 (en) * 1994-10-25 1996-05-02 China Petro-Chemical Corporation An ion exchange resin catalyst for the synthesis of bisphends and its preparation
US5631338A (en) * 1994-07-21 1997-05-20 Mitsui Toatsu Chemicals, Inc. Process for preparing bisphenol A
WO2005075396A1 (en) * 2004-02-05 2005-08-18 Bayer Materialscience Ag Production of bisphenol a with a reduced isomer formation
WO2017099674A2 (en) 2015-12-09 2017-06-15 Ptt Global Chemical Public Company Limited Ion exchange resin for producing bisphenol, and a method for producing bisphenol using said ion exchange resin

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2722683A1 (en) * 1976-05-21 1977-12-01 Shell Int Research CATALYST AND ITS USE
US4191843A (en) 1977-11-09 1980-03-04 Shell Oil Company Preparation of bisphenols
EP0045959A1 (en) * 1980-08-07 1982-02-17 Mitsubishi Kasei Corporation Process for preparing bisphenols
US4423252A (en) * 1980-08-07 1983-12-27 Mitsubishi Chemical Industries Limited Process for preparing bisphenols
EP0171758A2 (en) * 1984-08-13 1986-02-19 The Dow Chemical Company A process for preparing partially strong-acid cation-exchange resins in acid form
EP0171758A3 (en) * 1984-08-13 1988-11-09 The Dow Chemical Company A process for preparing partially strong-acid cation-exca process for preparing partially strong-acid cation-exchange resins in acid form hange resins in acid form
EP0268318A1 (en) * 1986-10-30 1988-05-25 Shell Internationale Researchmaatschappij B.V. Process and catalyst for production of a bisphenol
US4912263A (en) * 1987-08-19 1990-03-27 Bayer Aktiengesellschaft Ionic exchangers modified with thiazolines
EP0305774A1 (en) * 1987-08-19 1989-03-08 Bayer Ag Ion exchange resin modified by thiazolines
US5414151A (en) * 1994-05-02 1995-05-09 General Electric Company Method for making bisphenol
US5428075A (en) * 1994-05-02 1995-06-27 General Electric Company Method for regenerating a sulfonated aromatic organic polymeric ion-exchange resin bed having deactivated aminoorganomercaptan groups with phenol
EP0680943A1 (en) * 1994-05-02 1995-11-08 General Electric Company Method for making bisphenol
US5631338A (en) * 1994-07-21 1997-05-20 Mitsui Toatsu Chemicals, Inc. Process for preparing bisphenol A
WO1996012560A1 (en) * 1994-10-25 1996-05-02 China Petro-Chemical Corporation An ion exchange resin catalyst for the synthesis of bisphends and its preparation
CN1038395C (en) * 1994-10-25 1998-05-20 中国石油化工总公司 Ion exchange resin catalyzer for synthesising bisphenol and preparation thereof
WO2005075396A1 (en) * 2004-02-05 2005-08-18 Bayer Materialscience Ag Production of bisphenol a with a reduced isomer formation
WO2017099674A2 (en) 2015-12-09 2017-06-15 Ptt Global Chemical Public Company Limited Ion exchange resin for producing bisphenol, and a method for producing bisphenol using said ion exchange resin
EP3386634A4 (en) * 2015-12-09 2019-08-28 PTT Global Chemical Public Company Limited ION EXCHANGE RESIN FOR THE PRODUCTION OF BISPHENOL, AND PROCESS FOR PRODUCING BISPHENOL USING THE SAME ION EXCHANGE RESIN

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years