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GB1163502A - Method for activating cycloaliphatic polyamines as curing agents for reaction with epoxide compounds - Google Patents

Method for activating cycloaliphatic polyamines as curing agents for reaction with epoxide compounds

Info

Publication number
GB1163502A
GB1163502A GB98868A GB98868A GB1163502A GB 1163502 A GB1163502 A GB 1163502A GB 98868 A GB98868 A GB 98868A GB 98868 A GB98868 A GB 98868A GB 1163502 A GB1163502 A GB 1163502A
Authority
GB
United Kingdom
Prior art keywords
reaction
phenol
activating
cycloaliphatic polyamines
curing agents
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB98868A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ruetgerswerke & Teerverwertung
Original Assignee
Ruetgerswerke & Teerverwertung
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ruetgerswerke & Teerverwertung filed Critical Ruetgerswerke & Teerverwertung
Publication of GB1163502A publication Critical patent/GB1163502A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/12—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms
    • C07D295/125—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms with the ring nitrogen atoms and the substituent nitrogen atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
    • C07D295/13—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms with the ring nitrogen atoms and the substituent nitrogen atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/44—Nitrogen atoms not forming part of a nitro radical
    • C07D233/46—Nitrogen atoms not forming part of a nitro radical with only hydrogen atoms attached to said nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • C08G59/621—Phenols
    • C08G59/623—Aminophenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Epoxy Resins (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,163,502. Polyamine condensates; curing epoxy resins. RUTGERSWERKE UND TEERVERWERTUNG A.G. 8 Jan., 1968 [12 Jan., 1967], No. 988/68. Headings C3B and C3R. Cycloaliphatic polyamines, e.g. 1 - amino - 3- aminomethyl - 3,5,5 - trimethylcyclohexane, are reacted with a mono- or poly-hydric, mono- or poly-nuclear phenol in the presence of an aldehyde, e.g. formaldehyde, or a substance which yields formaldehyde under the conditions of reaction. The products are useful in curing epoxy resins at room temperature. Suitable phenols are: phenol, cresol, xylenols, resorcinol, hydroquinone or bisphenols. In examples, the condensation reaction is carried out by adding aqueous formaldehyde to a mixture of the polyamine and phenol at temperatures up to 100‹ C.
GB98868A 1967-01-12 1968-01-08 Method for activating cycloaliphatic polyamines as curing agents for reaction with epoxide compounds Expired GB1163502A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DER0045040 1967-01-12

Publications (1)

Publication Number Publication Date
GB1163502A true GB1163502A (en) 1969-09-10

Family

ID=7407484

Family Applications (1)

Application Number Title Priority Date Filing Date
GB98868A Expired GB1163502A (en) 1967-01-12 1968-01-08 Method for activating cycloaliphatic polyamines as curing agents for reaction with epoxide compounds

Country Status (7)

Country Link
AT (1) AT273509B (en)
BE (1) BE708856A (en)
CH (1) CH487957A (en)
DE (1) DE1618801C3 (en)
FR (1) FR1568011A (en)
GB (1) GB1163502A (en)
NL (1) NL6717189A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3950451A (en) * 1971-02-27 1976-04-13 Asahi Denka Kogyo K.K. Hardenable epoxy resin composition
CN111732716A (en) * 2020-06-22 2020-10-02 中国林科院林产化工研究所南京科技开发有限公司 Mannes base curing agent for epoxy floor sealing primer and preparation method thereof

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2612211A1 (en) * 1975-03-28 1976-10-07 American Velodur Metal HARDER FOR EPOXY RESINS
FR2345458A2 (en) * 1976-03-25 1977-10-21 Roussel Uclaf Pesticidal phosphoryloxy-thiadiazole derivs. - esp. useful as nematocides and insecticides by contact and ingestion
EP0066447A1 (en) * 1981-05-25 1982-12-08 Mitsubishi Gas Chemical Company, Inc. Reaction of a phenol, aldehyde and amine to produce hardening agent for epoxy resins

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3950451A (en) * 1971-02-27 1976-04-13 Asahi Denka Kogyo K.K. Hardenable epoxy resin composition
CN111732716A (en) * 2020-06-22 2020-10-02 中国林科院林产化工研究所南京科技开发有限公司 Mannes base curing agent for epoxy floor sealing primer and preparation method thereof
CN111732716B (en) * 2020-06-22 2021-09-07 中国林业科学研究院林产化学工业研究所 Mannes base curing agent for epoxy floor sealing primer and preparation method thereof

Also Published As

Publication number Publication date
AT273509B (en) 1969-08-11
NL6717189A (en) 1968-07-15
DE1618801A1 (en) 1972-04-20
DE1618801B2 (en) 1973-07-05
CH487957A (en) 1970-03-31
BE708856A (en) 1968-05-16
DE1618801C3 (en) 1974-02-28
FR1568011A (en) 1969-05-23

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years