GB1145999A - Process for the preparation of polymeric polysulphides - Google Patents
Process for the preparation of polymeric polysulphidesInfo
- Publication number
- GB1145999A GB1145999A GB3781265A GB3781265A GB1145999A GB 1145999 A GB1145999 A GB 1145999A GB 3781265 A GB3781265 A GB 3781265A GB 3781265 A GB3781265 A GB 3781265A GB 1145999 A GB1145999 A GB 1145999A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methylene dichloride
- polysulphide
- metal
- polysulphides
- organic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/14—Polysulfides
- C08G75/16—Polysulfides by polycondensation of organic compounds with inorganic polysulfides
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Abstract
1,145,999. Polymeric polysulphides. DUNLOP CO. Ltd. (E. A. Dudley). 26 Aug., 1966 [3 Sept., 1965], No. 37812/65. Heading C3R. Polymeric polysulphides of molecular weight less than 10,000 are obtained by reacting a polysulphide of a metal of Group IA of the Periodic Table with methylene dichloride the reaction mixture also containing as a chain-terminating agent an organic monohalide, whose organic radical is an alkyl, alkenyl, cycloalkyl, aralkyl or aryl radical which also may contain another substituent which does not react with the metal polysulphide. The molar ratio of the methylene dichloride to the metal polysulphide is from 0À5:1 to 1À5:1, and the amount of the organic monohalide is from 1 to 25% by weight of the methylene dichloride and the metal polysulphide. There may also be present a polyhalide containing 3 or more halogen atoms in the molecule, to provide a cross-linked product, and the polyhalide may be present in an amount of from 2 to 25% by weight of the metal polysulphide. The reaction may be carried out in water or in an organic liquid and an anionic surface-active agent may be present. In examples polysulphides are prepared by reacting sodium tetrasulphide with mixtures containing methylene dichloride, benzyl chloride, allyl chloride, n-butyl chloride, ethyl α-bromoacetate and 1,2,3-trichloropropane.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3781265A GB1145999A (en) | 1965-09-03 | 1965-09-03 | Process for the preparation of polymeric polysulphides |
FR74968A FR1515896A (en) | 1965-09-03 | 1966-09-01 | Process for the preparation of polymeric polysulfides |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3781265A GB1145999A (en) | 1965-09-03 | 1965-09-03 | Process for the preparation of polymeric polysulphides |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1145999A true GB1145999A (en) | 1969-03-19 |
Family
ID=10399180
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3781265A Expired GB1145999A (en) | 1965-09-03 | 1965-09-03 | Process for the preparation of polymeric polysulphides |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR1515896A (en) |
GB (1) | GB1145999A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11167263B2 (en) * | 2016-04-20 | 2021-11-09 | Clean Earth Technology Pty Ltd | Metal adsorbent material and uses thereof |
CN115477601A (en) * | 2022-09-22 | 2022-12-16 | 江苏麒祥高新材料有限公司 | Organic polysulfide and preparation method and application thereof |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4438259A (en) * | 1982-01-18 | 1984-03-20 | The Dow Chemical Company | (Vinylaryl)alkyl polysulfide polymers |
-
1965
- 1965-09-03 GB GB3781265A patent/GB1145999A/en not_active Expired
-
1966
- 1966-09-01 FR FR74968A patent/FR1515896A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11167263B2 (en) * | 2016-04-20 | 2021-11-09 | Clean Earth Technology Pty Ltd | Metal adsorbent material and uses thereof |
CN115477601A (en) * | 2022-09-22 | 2022-12-16 | 江苏麒祥高新材料有限公司 | Organic polysulfide and preparation method and application thereof |
Also Published As
Publication number | Publication date |
---|---|
FR1515896A (en) | 1968-03-08 |
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