GB1112888A - Copolymer latices and articles bonded therewith - Google Patents
Copolymer latices and articles bonded therewithInfo
- Publication number
- GB1112888A GB1112888A GB28446/65A GB2844665A GB1112888A GB 1112888 A GB1112888 A GB 1112888A GB 28446/65 A GB28446/65 A GB 28446/65A GB 2844665 A GB2844665 A GB 2844665A GB 1112888 A GB1112888 A GB 1112888A
- Authority
- GB
- United Kingdom
- Prior art keywords
- butadiene
- acid
- acrylonitrile
- styrene
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title abstract 6
- 229920000126 latex Polymers 0.000 title abstract 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 19
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 6
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 abstract 4
- OIYTYGOUZOARSH-UHFFFAOYSA-N 4-methoxy-2-methylidene-4-oxobutanoic acid Chemical compound COC(=O)CC(=C)C(O)=O OIYTYGOUZOARSH-UHFFFAOYSA-N 0.000 abstract 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 4
- 150000002148 esters Chemical class 0.000 abstract 4
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 abstract 4
- 239000000178 monomer Substances 0.000 abstract 4
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 150000001993 dienes Chemical class 0.000 abstract 3
- 239000004816 latex Substances 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 125000005907 alkyl ester group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 150000008064 anhydrides Chemical class 0.000 abstract 2
- 239000011260 aqueous acid Substances 0.000 abstract 2
- 230000000873 masking effect Effects 0.000 abstract 2
- -1 monomethyl ester Chemical class 0.000 abstract 2
- 150000007519 polyprotic acids Polymers 0.000 abstract 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 abstract 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 abstract 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 1
- LEKIODFWYFCUER-UHFFFAOYSA-N 2-methylidenebut-3-enenitrile Chemical compound C=CC(=C)C#N LEKIODFWYFCUER-UHFFFAOYSA-N 0.000 abstract 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 abstract 1
- NFTQUNYEKGXCNH-UHFFFAOYSA-N C=C.OS(=O)(=O)C1=CC=CC=C1 Chemical compound C=C.OS(=O)(=O)C1=CC=CC=C1 NFTQUNYEKGXCNH-UHFFFAOYSA-N 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 abstract 1
- 239000004677 Nylon Substances 0.000 abstract 1
- 239000004159 Potassium persulphate Substances 0.000 abstract 1
- 229920000297 Rayon Polymers 0.000 abstract 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000002738 chelating agent Substances 0.000 abstract 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 229960001484 edetic acid Drugs 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 239000002657 fibrous material Substances 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 150000002763 monocarboxylic acids Chemical class 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 229920001778 nylon Polymers 0.000 abstract 1
- 238000012856 packing Methods 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 abstract 1
- 235000019394 potassium persulphate Nutrition 0.000 abstract 1
- 239000002964 rayon Substances 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- 150000003440 styrenes Chemical class 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/942—Polymer derived from nitrile, conjugated diene and aromatic co-monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/911—Emulsifying agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2738—Coating or impregnation intended to function as an adhesive to solid surfaces subsequently associated therewith
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paper (AREA)
Abstract
A copolymer latex comprises a dispersion of a copolymer prepared by emulsion polymerization in an aqueous acid material of a monomeric material containing from 20 to 90% of monomer of at least one aliphatic conjugated diene, from 0.5 to 20% of at least one copolymerizable partial alkyl ester of an unsaturated polybasic acid or anhydride of the acid, the alkyl group containing 1 or 2 carbon atoms and the balance being from 10 to 75% of at least one monoolefinic monomer other than the ester. The preferred conjugated diene may be butadiene, isoprene,2-3-diemethyl butadiene, piperylene,2-neopentyl butadiene, 2-chlorobutadiene, 2-cyanobutadiene and others. Specified partial esters are the methyl or ethyl monoesters of fumaric, maleic, glutaconic, citraconic, itaconic, presaconic and aconitic acids-the monomethyl ester of itaconic acid being preferred. Preferred monolefinic monomers are nitriles, styrenes, and esters of an aliphatic alcohol containing from 1 to 6 carbon atoms and an acrylic or an alpha-substituted acrylic acid also vinyl naphthalene, vinyl pyridine, vinyl ethers and ketones and vinylidene chloride are also listed. The latex may also contain from 0.5 to 5% of a copolymerizable olefinically unsaturated monocarboxylic acid. The usual emulsifying agents e.g. the sodium salt of ethylene benzene sulphonate, chelating agents e.g. ethylene diamine tetraacetic acid, peroxide type indicators e.g. potassium persulphate and modifiers e.g. 17-dodecyl mercaptan may be present.ALSO:Fibrous articles comprise a unified mass of non-woven fibrous material internally bonded with a unifying composition comprising a copolymer prepared by emulsion polymerisation in an aqueous acid medium of a monomeric material containing from 20 to 90% of at least one aliphatic conjugated diene, from 0.5 to 20% of at least one partial alkyl ester of an unsaturated polybasic acid or anhydride thereof, the alkyl group containing 1 or 2 carbon atoms and the balance being from 10 to 75% of at least one monoolefinic monomer other than the partial ester (see Division C3). The fabrics may be made from fibres such as cotton, rayon, nylon, and polyester as well as applied to unified paper packings e.g. creped masking tape base, rope tape stock, and flow-tensile flatback base. In a typical example (II) sheets of creped masking tape base are saturated with a copolymer latex, squeezed, forced and cured - the copolymers being (a) butadiene/acrylonitrile / monomethyl itaconate (b) butadiene / acrylonitrile / itaconic acid (c) butadiene / acrylonitrile / methacrylic acid (d) butadiene / styrene / monomethyl itaconate (e) butadiene / styrene / itaconic acid (g) butadiene / styrene / methacrylic acid (g) butadiene / acrylonitrile / styrene / with monomethyl itaconate or itaconic acid or methacrylic acid.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US38453664A | 1964-07-22 | 1964-07-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1112888A true GB1112888A (en) | 1968-05-08 |
Family
ID=23517710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB28446/65A Expired GB1112888A (en) | 1964-07-22 | 1965-07-05 | Copolymer latices and articles bonded therewith |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3422050A (en) |
| JP (1) | JPS5136293B1 (en) |
| BE (1) | BE667259A (en) |
| DE (1) | DE1570118A1 (en) |
| FR (1) | FR1511560A (en) |
| GB (1) | GB1112888A (en) |
| LU (1) | LU49130A1 (en) |
| NL (1) | NL6509511A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998035085A1 (en) * | 1995-09-28 | 1998-08-13 | Gencorp Inc. | Nonwoven fabric of non-cellulose fibers having improved wet tensile strength |
| WO2022193837A1 (en) * | 2021-03-15 | 2022-09-22 | 北京化工大学 | Fumarate/conjugated diene copolymer type bio-based rubber, preparation method therefor, and vulcanized rubber product thereof |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6110525A (en) * | 1997-09-12 | 2000-08-29 | Pro-Sol, Inc. | Coating composition for protecting surfaces and method of using same |
| JPWO2005095508A1 (en) * | 2004-03-31 | 2008-02-21 | 日本ゼオン株式会社 | DIP MOLDING COMPOSITION AND DIP MOLDED ARTICLE |
| CN112521553B (en) * | 2019-09-19 | 2022-02-01 | 北京化工大学 | Itaconate/styrene/butadiene copolymer, preparation method thereof and rubber composition |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2891039A (en) * | 1954-06-05 | 1959-06-16 | Bayer Ag | Terpolymers of diolefins with halfesters of maleic acid and a monoolefinic monomer |
| US2959821A (en) * | 1955-02-11 | 1960-11-15 | Bayer Ag | Dipping process wherein cross-linking agent is applied in coagulating bath |
| FR1147579A (en) * | 1955-03-24 | 1957-11-27 | Bayer Ag | Process for the production of polymerization products |
| US2947733A (en) * | 1957-04-19 | 1960-08-02 | Firestone Tire & Rubber Co | Process of curing a rubbery copolymer of a conjugated diene and a carboxylic acid oranhydride with dicyandiamide, and cured product obtained thereby |
| BE636527A (en) * | 1958-08-01 | |||
| BE634919A (en) * | 1962-07-12 | 1964-01-13 | ||
| US3300431A (en) * | 1963-04-20 | 1967-01-24 | Takeda Chemical Industries Ltd | Non-woven fabric and adhesive composition therefor |
| US3345204A (en) * | 1963-06-06 | 1967-10-03 | Johnson & Johnson | Process of impregnating an instantaneously wettable paper with a rubber latex |
| US3259601A (en) * | 1963-07-31 | 1966-07-05 | Koppers Co Inc | Baked metal primers of ternary butadiene polymer and phosphoric acid |
| US3321432A (en) * | 1963-10-04 | 1967-05-23 | Dow Chemical Co | Textile backing agent comprising an aqueous dispersion of a carboxylcontaining copolymer and the reaction product of epichlorohydrin with an alkylene polyamine |
-
1964
- 1964-07-22 US US384536A patent/US3422050A/en not_active Expired - Lifetime
-
1965
- 1965-07-05 GB GB28446/65A patent/GB1112888A/en not_active Expired
- 1965-07-20 FR FR25344A patent/FR1511560A/en not_active Expired
- 1965-07-21 LU LU49130A patent/LU49130A1/xx unknown
- 1965-07-21 JP JP40043690A patent/JPS5136293B1/ja active Pending
- 1965-07-22 BE BE667259D patent/BE667259A/xx unknown
- 1965-07-22 DE DE19651570118 patent/DE1570118A1/en active Pending
- 1965-07-22 NL NL6509511A patent/NL6509511A/xx unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998035085A1 (en) * | 1995-09-28 | 1998-08-13 | Gencorp Inc. | Nonwoven fabric of non-cellulose fibers having improved wet tensile strength |
| WO2022193837A1 (en) * | 2021-03-15 | 2022-09-22 | 北京化工大学 | Fumarate/conjugated diene copolymer type bio-based rubber, preparation method therefor, and vulcanized rubber product thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1570118A1 (en) | 1970-08-13 |
| LU49130A1 (en) | 1965-09-21 |
| NL6509511A (en) | 1966-01-24 |
| FR1511560A (en) | 1968-02-02 |
| BE667259A (en) | 1966-01-24 |
| JPS5136293B1 (en) | 1976-10-07 |
| US3422050A (en) | 1969-01-14 |
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