[go: up one dir, main page]

GB1014361A - Improvements in and relating to the production of aliphatic per-acids - Google Patents

Improvements in and relating to the production of aliphatic per-acids

Info

Publication number
GB1014361A
GB1014361A GB1165863A GB1165863A GB1014361A GB 1014361 A GB1014361 A GB 1014361A GB 1165863 A GB1165863 A GB 1165863A GB 1165863 A GB1165863 A GB 1165863A GB 1014361 A GB1014361 A GB 1014361A
Authority
GB
United Kingdom
Prior art keywords
acid
water
hydrogen peroxide
entraining
aliphatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1165863A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FMC Corp
Original Assignee
FMC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FMC Corp filed Critical FMC Corp
Publication of GB1014361A publication Critical patent/GB1014361A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C07C407/003—Separation; Purification; Stabilisation; Use of additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Fertilizers (AREA)

Abstract

Peracids of lower, saturated aliphatic carboxylic acids having from 1-3 C atoms are made by reacting hydrogen peroxide with the corresponding aliphatic acid in the ratio 0.3 to 5.0 moles hydrogen peroxide/mole of acid at 20-80 DEG C. in a reaction mixture containing 5-20% by weight of a strong, water-entraining acid, and 20-75% by weight of water and vaporizing together from the reaction mixture, at a pressure of 15-350 mm. of mercury, and a temperature of 20 to 80 DEG C. a product containing peracid, aliphatic acid and water. The process may be operated batchwise or continuously. In the continuous process the hydrogen peroxide, aliphatic acid and water, are continuously added to the reaction mixture, the hydrogen peroxide and lower aliphatic acid being added in the proportions of 0.30 to 1.1 mole hydrogen peroxide/mole acid, the concentrations of water and water-entraining acid being maintained at 20-75% and 5-20% respectively. The reaction is carried out at a pressure of 15-350 mm. of mercury, and the product is continuously distilled off. The reaction will normally take place in 10 minutes to 1 hour, preferably 10 to 30 minutes. Suitable water-entraining acid substances are sulphuric acid and other strong acids which boil above 150 DEG C. at atmospheric acid, and alkyl and aryl sulphonic acids, trifluoroacetic acid, and cation-exchange resins, e.g. sulphonated styrene-divinylbenzene copolymers. Sodium sulphate, molybdenum sulphate or calcium sulphate together with a strong acid which boils above 150 DEG C. may also be used. The hydrogen peroxide is normally introduced as an aqueous solution and may be used in a concentration of 20-100%. Comparative examples are given in which 1% sulphuric acid is used as water-entraining acid.
GB1165863A 1962-04-04 1963-03-25 Improvements in and relating to the production of aliphatic per-acids Expired GB1014361A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US18506362A 1962-04-04 1962-04-04

Publications (1)

Publication Number Publication Date
GB1014361A true GB1014361A (en) 1965-12-22

Family

ID=22679414

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1165863A Expired GB1014361A (en) 1962-04-04 1963-03-25 Improvements in and relating to the production of aliphatic per-acids

Country Status (6)

Country Link
AT (1) AT238151B (en)
BE (1) BE630363A (en)
CH (1) CH457385A (en)
DE (1) DE1443853A1 (en)
ES (1) ES285966A1 (en)
GB (1) GB1014361A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4115411A (en) * 1976-05-03 1978-09-19 Henkel Kommanditgesellschaft Auf Aktien Continuous process for epoxidizing organic compounds containing olefinic double bonds
EP1004576A1 (en) * 1998-11-23 2000-05-31 SOLVAY (Société Anonyme) Process for producing peracetic acid
EP0789016B2 (en) † 1996-01-31 2001-06-13 Eka Chemicals AB Method for producing peracetic acid
EP1247801A1 (en) * 2001-04-04 2002-10-09 Kemira Chemicals Oy Process for the production of percarboxylic acid
US6677477B2 (en) 2001-04-04 2004-01-13 Kemira Chemicals Oy Process for the production of peracetic acid
EP1451152B1 (en) * 2001-10-30 2009-06-10 Kemira Oyj Method and arrangement for the preparation of percarboxylic acid
WO2019102742A1 (en) * 2017-11-27 2019-05-31 三菱瓦斯化学株式会社 Method for producing peracetic acid composition to be used as food additive

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3418450A1 (en) * 1984-05-18 1985-11-28 Degussa Ag, 6000 Frankfurt METHOD FOR PRODUCING WATER-INSOLUBLE PEROXYCARBONIC ACIDS
DE4330465A1 (en) * 1993-09-08 1995-03-09 Laporte Gmbh Process and device for the continuous production of peroxycarboxylic acids

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4115411A (en) * 1976-05-03 1978-09-19 Henkel Kommanditgesellschaft Auf Aktien Continuous process for epoxidizing organic compounds containing olefinic double bonds
EP0789016B2 (en) † 1996-01-31 2001-06-13 Eka Chemicals AB Method for producing peracetic acid
EP1004576A1 (en) * 1998-11-23 2000-05-31 SOLVAY (Société Anonyme) Process for producing peracetic acid
EP1247801A1 (en) * 2001-04-04 2002-10-09 Kemira Chemicals Oy Process for the production of percarboxylic acid
US6677477B2 (en) 2001-04-04 2004-01-13 Kemira Chemicals Oy Process for the production of peracetic acid
US6677478B2 (en) 2001-04-04 2004-01-13 Kemira Chemicals Oy Process for the production of percarboxylic acid
EP1451152B1 (en) * 2001-10-30 2009-06-10 Kemira Oyj Method and arrangement for the preparation of percarboxylic acid
US7915445B2 (en) 2001-10-30 2011-03-29 Kemira Oyj Method and arrangement for the preparation of percarboxylic acid
WO2019102742A1 (en) * 2017-11-27 2019-05-31 三菱瓦斯化学株式会社 Method for producing peracetic acid composition to be used as food additive
CN111372469A (en) * 2017-11-27 2020-07-03 三菱瓦斯化学株式会社 Manufacturing method of peracetic acid composition used as food additive
KR20200089664A (en) * 2017-11-27 2020-07-27 미츠비시 가스 가가쿠 가부시키가이샤 Method for preparing peracetic acid composition used as food additive
JPWO2019102742A1 (en) * 2017-11-27 2020-12-10 三菱瓦斯化学株式会社 Method for Producing Peracetic Acid Composition Used as Food Additive
TWI823869B (en) * 2017-11-27 2023-12-01 日商三菱瓦斯化學股份有限公司 Method for manufacturing a peracetic acid composition used as a food additive, a manufacturing device for manufacturing a peracetic acid composition used as a food additive, a peracetic acid composition used as a food additive, and a method for sterilizing food
KR102740111B1 (en) * 2017-11-27 2024-12-06 미츠비시 가스 가가쿠 가부시키가이샤 Method for producing a peracetic acid composition used as a food additive

Also Published As

Publication number Publication date
CH457385A (en) 1968-06-15
BE630363A (en)
ES285966A1 (en) 1963-08-16
AT238151B (en) 1965-01-25
DE1443853A1 (en) 1968-10-24

Similar Documents

Publication Publication Date Title
GB949094A (en) Process for the production of solutions of pure peracetic acid
GB1014361A (en) Improvements in and relating to the production of aliphatic per-acids
DE3264656D1 (en) Process for the production of a peroxy compound
GB791875A (en) Process for the preparation of per-fatty acids
US2802025A (en) Process for the production of lower carboxylic peracids
NO902621L (en) PROCEDURE FOR THE PREPARATION OF PARAFFIN SULPHONIC ACIDS.
GB992742A (en) Preparation of permonosulphates
KR890012930A (en) Method for preparing high purity tetrachloro-1,4-benzoquinone
GB670433A (en) Improvements in or relating to methods of purifying crude phthalic anhydride
GB1000881A (en) Process for making cyclohexanone-oxime
DE3360548D1 (en) Process for the preparation of pinacolone
Kooijman Preparation of hydrogen peroxide from the peroxides formed on oxidizing propane
GB925290A (en) Improvements in or relating to a process for the production of peroxymonophosphoric acid
GB774563A (en) Process for the production of hydroxyalkane-sulphonic acids from their salts
GB768893A (en) Process for the production of methyl bromide
GB824518A (en) A process of preparing colourless maleic acid anhydride of high purity
GB401351A (en) Improvements in or relating to the manufacture of hydrocyanic acid
GB729625A (en) Improvements in or relating to the preparation of non-odorous 2-methyl-4-chlorophenoxyacetic acid and its application as a selective weed-killer
GB817111A (en) A process relating to the recovery of unsymmetrical dimethylhydrazine from aqueous solutions by distillation
GB887908A (en) A process for the purification of isoprene
GB745594A (en) Recovery and preparation of lower percarboxylic acids
GB682354A (en) Improvements in or relating to the preparation of haloacetic acids
GB705470A (en) Improvements in the production of sulphonic acids
GB998834A (en) Improved process for the preparation of 2-halothiobenzamides
GB682724A (en) Process for the manufacture of ferro-calcium-citrate