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GB1004665A - Polymerizing 2-alkyl(1,3 butadienes) - Google Patents

Polymerizing 2-alkyl(1,3 butadienes)

Info

Publication number
GB1004665A
GB1004665A GB2975062A GB2975062A GB1004665A GB 1004665 A GB1004665 A GB 1004665A GB 2975062 A GB2975062 A GB 2975062A GB 2975062 A GB2975062 A GB 2975062A GB 1004665 A GB1004665 A GB 1004665A
Authority
GB
United Kingdom
Prior art keywords
alkyl
aluminium
polymerized
etherate
triisobutyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2975062A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goodyear Tire and Rubber Co
Original Assignee
Goodyear Tire and Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Goodyear Tire and Rubber Co filed Critical Goodyear Tire and Rubber Co
Publication of GB1004665A publication Critical patent/GB1004665A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

2-Alkyl-1,3-butadienes, the alkyl group having 1 to 8 carbon atoms, are polymerized using a catalyst system comprising titanium tetrachloride and the phenyl and/or naphthyl etherates or an organo-aluminium compound <FORM:1004665/C3/1> wherein R1 is an alkyl (including cycloalkyl), aryl or aralkyl radical or a halogen or hydrogen atom and R2 and R3 are alkyl, aryl or aralkyl radicals, the aluminium to titanium mol. ratio varying from 0.8 : 1 to 1.2 : 1. In the examples: (1) isoprene is polymerized in pentane using aluminium triisobutyl diphenyl etherate and titanium tetrachloride; (2) isoprene is polymerized using the anisole etherate of triisobutyl aluminium; (3) 2-ethyl-1,3-butadiene is polymerized using aluminium triisobutyl diphenyl etherate and titanium tetrachloride. The poly mers may be vulcanized.
GB2975062A 1961-10-12 1962-08-02 Polymerizing 2-alkyl(1,3 butadienes) Expired GB1004665A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US14455361A 1961-10-12 1961-10-12

Publications (1)

Publication Number Publication Date
GB1004665A true GB1004665A (en) 1965-09-15

Family

ID=22509102

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2975062A Expired GB1004665A (en) 1961-10-12 1962-08-02 Polymerizing 2-alkyl(1,3 butadienes)

Country Status (4)

Country Link
BE (1) BE622492A (en)
GB (1) GB1004665A (en)
LU (1) LU42370A1 (en)
NL (1) NL284293A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3492281A (en) * 1967-06-29 1970-01-27 Goodyear Tire & Rubber Process for the polymerization of diolefins with beta titanium trichloride and organoaluminum compounds

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3492281A (en) * 1967-06-29 1970-01-27 Goodyear Tire & Rubber Process for the polymerization of diolefins with beta titanium trichloride and organoaluminum compounds

Also Published As

Publication number Publication date
NL284293A (en)
LU42370A1 (en) 1962-11-17
BE622492A (en)

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