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FR3096053B1 - Poudre de copolymère à blocs polyamides et à blocs polyéthers - Google Patents

Poudre de copolymère à blocs polyamides et à blocs polyéthers Download PDF

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Publication number
FR3096053B1
FR3096053B1 FR1905131A FR1905131A FR3096053B1 FR 3096053 B1 FR3096053 B1 FR 3096053B1 FR 1905131 A FR1905131 A FR 1905131A FR 1905131 A FR1905131 A FR 1905131A FR 3096053 B1 FR3096053 B1 FR 3096053B1
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France
Prior art keywords
composition
polyamide
block
polyether
mass
Prior art date
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Active
Application number
FR1905131A
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English (en)
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FR3096053A1 (fr
Inventor
Alexis Morfin
Benoît Brule
Apolline Palais
Nadine Decraemer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
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Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1905131A priority Critical patent/FR3096053B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to PCT/FR2020/050808 priority patent/WO2020229782A1/fr
Priority to JP2021568100A priority patent/JP7564827B2/ja
Priority to KR1020217041265A priority patent/KR20220010607A/ko
Priority to US17/610,830 priority patent/US20220213274A1/en
Priority to CN202080042190.7A priority patent/CN113950510B/zh
Priority to EP20737239.2A priority patent/EP3969501A1/fr
Publication of FR3096053A1 publication Critical patent/FR3096053A1/fr
Application granted granted Critical
Publication of FR3096053B1 publication Critical patent/FR3096053B1/fr
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10Processes of additive manufacturing
    • B29C64/141Processes of additive manufacturing using only solid materials
    • B29C64/153Processes of additive manufacturing using only solid materials using layers of powder being selectively joined, e.g. by selective laser sintering or melting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/30Auxiliary operations or equipment
    • B29C64/307Handling of material to be used in additive manufacturing
    • B29C64/314Preparation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y40/00Auxiliary operations or equipment, e.g. for material handling
    • B33Y40/10Pre-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • B33Y70/10Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y80/00Products made by additive manufacturing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/40Polyamides containing oxygen in the form of ether groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/12Powdering or granulating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K3/32Phosphorus-containing compounds
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K3/346Clay
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • C08K7/24Expanded, porous or hollow particles inorganic
    • C08K7/26Silicon- containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • C08K9/06Ingredients treated with organic substances with silicon-containing compounds
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06Polyamides derived from polyamines and polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D177/00Coating compositions based on polyamides obtained by reactions forming a carboxylic amide link in the main chain; Coating compositions based on derivatives of such polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2096/00Use of specified macromolecular materials not provided for in a single one of main groups B29K2001/00 - B29K2095/00, as moulding material
    • B29K2096/04Block polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0085Copolymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
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    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/387Borates

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Optics & Photonics (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Civil Engineering (AREA)
  • Composite Materials (AREA)
  • Structural Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

L’invention concerne une composition comprenant une poudre de copolymère à blocs polyamides et à blocs polyéthers, le copolymère étant sous forme de particules ayant une teneur en charges pulvérulentes de 0 à 10 % en masse et le copolymère ayant un rapport massique des blocs polyamides sur les blocs polyéthers inférieur ou égal à 0,7, les blocs polyamides ayant une masse molaire en nombre inférieure ou égale à 1000 g/mol ; et la composition comprenant un agent d’écoulement à une teneur supérieure ou égale à 0,3 % en masse. L’invention concerne également le procédé de préparation de cette composition, l’utilisation de la composition pour la construction des articles tridimensionnels, ainsi que les articles tridimensionnels fabriqués à partir de ladite composition.
FR1905131A 2019-05-16 2019-05-16 Poudre de copolymère à blocs polyamides et à blocs polyéthers Active FR3096053B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1905131A FR3096053B1 (fr) 2019-05-16 2019-05-16 Poudre de copolymère à blocs polyamides et à blocs polyéthers
JP2021568100A JP7564827B2 (ja) 2019-05-16 2020-05-15 ポリアミドブロック及びポリエーテルブロックを有するコポリマー粉末
KR1020217041265A KR20220010607A (ko) 2019-05-16 2020-05-15 폴리아미드 블록 및 폴리에테르 블록을 포함하는 공중합체 분말
US17/610,830 US20220213274A1 (en) 2019-05-16 2020-05-15 Copolymer powder with polyamide blocks and polyether blocks
PCT/FR2020/050808 WO2020229782A1 (fr) 2019-05-16 2020-05-15 Poudre de copolymère à blocs polyamides et à blocs polyéthers
CN202080042190.7A CN113950510B (zh) 2019-05-16 2020-05-15 具有聚酰胺嵌段和聚醚嵌段的共聚物粉末
EP20737239.2A EP3969501A1 (fr) 2019-05-16 2020-05-15 Poudre de copolymère à blocs polyamides et à blocs polyéthers

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1905131 2019-05-16
FR1905131A FR3096053B1 (fr) 2019-05-16 2019-05-16 Poudre de copolymère à blocs polyamides et à blocs polyéthers

Publications (2)

Publication Number Publication Date
FR3096053A1 FR3096053A1 (fr) 2020-11-20
FR3096053B1 true FR3096053B1 (fr) 2021-11-19

Family

ID=67660326

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1905131A Active FR3096053B1 (fr) 2019-05-16 2019-05-16 Poudre de copolymère à blocs polyamides et à blocs polyéthers

Country Status (7)

Country Link
US (1) US20220213274A1 (fr)
EP (1) EP3969501A1 (fr)
JP (1) JP7564827B2 (fr)
KR (1) KR20220010607A (fr)
CN (1) CN113950510B (fr)
FR (1) FR3096053B1 (fr)
WO (1) WO2020229782A1 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20220356305A1 (en) * 2019-06-26 2022-11-10 Evolve Additive Solutions, Inc. Thermoplastic elastomer material for selective deposition-based additive manufacturing and method of making same
WO2022173641A1 (fr) * 2021-02-10 2022-08-18 Cabot Corporation Procédé de production d'élastomères thermoplastiques et composite polymère obtenu par ce procédé
FR3124112A1 (fr) * 2021-06-17 2022-12-23 Fabulous Procédé de fabrication additive, composition de poudre polymere comportant un additif de détéction, et objet obtenu par ledit procédé
FR3125050B1 (fr) * 2021-07-08 2024-10-11 Arkema France Poudre de polymère thermoplastique pour construction d’articles 3D
FR3125051B1 (fr) * 2021-07-08 2024-10-11 Arkema France Poudre de polymère thermoplastique pour construction d’articles 3D
FR3144138A1 (fr) * 2022-12-26 2024-06-28 Arkema France Poudre de polymère thermoplastique à large distribution granulométrique
FR3144817A1 (fr) * 2023-01-11 2024-07-12 Arkema France Composition comprenant au moins un polyamide aliphatique recycle
FR3144818A1 (fr) * 2023-01-11 2024-07-12 Arkema France Composition comprenant au moins un elastomere polyamide recycle
FR3144819A1 (fr) * 2023-01-11 2024-07-12 Arkema France COMPOSITION COMPRENANT AU MOINS UN POLYAMIDE DE FORMULE XY ou A/XY RECYCLE
WO2024202802A1 (fr) * 2023-03-29 2024-10-03 株式会社巴川コーポレーション Composition, procédé de mise en forme et article mis en forme
EP4512846A1 (fr) 2023-08-21 2025-02-26 Ems-Chemie Ag Matériaux ignifuges pour technologies de fusion à lit de poudre et utilisation de ces matériaux dans un procédé couche par couche

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5652326A (en) 1993-03-03 1997-07-29 Sanyo Chemical Industries, Ltd. Polyetheresteramide and antistatic resin composition
US6110411A (en) 1997-03-18 2000-08-29 Clausen; Christian Henning Laser sinterable thermoplastic powder
FR2846332B1 (fr) 2002-10-23 2004-12-03 Atofina Copolymeres transparents a blocs polyamides et blocs polyethers
JP4193588B2 (ja) 2003-05-26 2008-12-10 宇部興産株式会社 ポリアミド系エラストマー
US7056975B2 (en) 2003-05-27 2006-06-06 Ube Industries, Ltd. Thermoplastic resin composition having improved resistance to hydrolysis
JP4161802B2 (ja) 2003-05-27 2008-10-08 宇部興産株式会社 ポリアミド組成物
DE102005008044A1 (de) 2005-02-19 2006-08-31 Degussa Ag Polymerpulver mit Blockpolyetheramid, Verwendung in einem formgebenden Verfahren und Formkörper, hergestellt aus diesem Polymerpulver
FR2955330B1 (fr) 2010-01-19 2012-01-20 Arkema France Composition de poudre thermoplastique et objets tridimensionnels fabriques par frittage d'une telle composition
FR2960773B1 (fr) * 2010-06-03 2015-12-11 Oreal Procedes de traitement cosmetique utilisant un revetement a base d'un polymere polyamide-polyether
FR3047245B1 (fr) * 2016-01-29 2018-02-23 Arkema France Mousse de copolymere a blocs polyamides et a blocs polyethers
CN115260749A (zh) 2016-10-17 2022-11-01 捷普有限公司 沉淀聚醚嵌段酰胺和热塑性聚乙烯以增强用于三维打印的操作窗口
FR3058918B1 (fr) 2016-11-18 2021-01-01 Arkema France Composition de poudre frittable magnetique et objets tridimensionnels fabriques par frittage d'une telle composition
FR3071840B1 (fr) 2017-10-04 2019-10-11 Arkema France Composition de poudre thermoplastique et objet tridimensionnel renforce fabrique par impression 3d d'une telle composition

Also Published As

Publication number Publication date
CN113950510A (zh) 2022-01-18
JP2022532376A (ja) 2022-07-14
FR3096053A1 (fr) 2020-11-20
US20220213274A1 (en) 2022-07-07
EP3969501A1 (fr) 2022-03-23
KR20220010607A (ko) 2022-01-25
CN113950510B (zh) 2024-03-26
WO2020229782A1 (fr) 2020-11-19
JP7564827B2 (ja) 2024-10-09

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