FR2964318A1 - Use of a cosmetic composition comprising bio-heteropolysaccharide, mineral particles comprising particles containing silicate, and surfactant for the cosmetic treatment of hair and for styling the hair - Google Patents

Abstract

Use of a cosmetic composition comprising: one or more bio-heteropolysaccharide, mineral particles comprising particles containing at least 10 wt.% of one or more silicates, and surfactant (less than 4 wt.%), for the treatment of hair, is claimed. An independent claim is included for a cosmetic composition comprising one or more bioheteropolysaccharides and mineral particles having particles containing at least 10 wt.% of one or more silicates, one or more sugar derivatives different from the bioheteropolysaccharides, where the composition contains an amount of surfactants of less than 4 wt.% of the composition.

Description

The present invention relates to the use for hair treatment of a composition comprising, in a cosmetically acceptable medium, at least one bioheteropolysaccharide and particles. particular minerals, as well as to a process for the cosmetic treatment of the hair and to particular compositions. In the field of styling, in particular among hair products intended for shaping and / or maintaining the hairstyle, the hair compositions generally consist of an alcoholic or aqueous solution and one or more fixing polymers mixed with various cosmetic adjuvants. These compositions may in particular be in the form of gels or hair mousse which are generally applied to wet hair before blow drying or drying. It is known to use polysaccharides in styling gels or in aerosols. However, the styling effects provided are often insufficient even by greatly increasing the concentrations of these polymers. Moreover, if these concentrations are increased, the cosmetic properties are not good, particularly at the level of the touch which becomes sticky.

There is therefore a real need to have a cosmetic composition that has good styling and cosmetic properties, and that overcomes the disadvantages mentioned above. The Applicant has discovered that by combining a biohétéropolysaccharide with particular mineral particles for the treatment of hair it was possible to obtain good styling and cosmetic properties. The present invention therefore relates to the use for the treatment of hair of a cosmetic composition comprising: - one or more biohétéropolysaccharides, and - mineral particles selected from particles containing at least 10% by weight of one or more silicates said composition containing an amount of surfactants of less than 4% by weight relative to the total weight of the composition,

The invention also relates to a cosmetic treatment method using the preceding composition. Other objects, features, aspects and advantages of the invention will emerge even more clearly on reading the description and examples which follow. By "styling" is meant fixing and / or maintaining the shape of the hairstyle.

XANTHAN GUM-TYPE POLYSACCHARIDE The composition according to the invention comprises one or more bioheteropolysaccharides.

For the purposes of the present invention, the term "bioheteropolysaccharides" means substances synthesized by fermentation of sugars by microorganisms. In particular, bioheteropolysaccharides often have units selected from the mannose, glucose and glucuronic acid or galacturonic acid units in their chain, these units optionally being acylated. There may be mentioned xanthan gums produced by the bacterium xanthomonas campestri and mutants and variants thereof. Mention may also be made of scleroglucan gums produced by Sclerotium rolfsii, gellan gums produced by Pseudomonas elodea or Sphingomonias, pullulan gums produced by Aureobacidium pullulens, Curdlar gums produced by faecalis-like alkaligenic Faecalis, dextran gums produced by many organisms including Leuconostoc mesenteroides and Leuconostoc dextrantum, grifolane gums produced by Grifola frondara, lentinan gums produced by Lentinus e dodes, Schizophyllane gums produced by Schizophyllum commine, spirulinane gums produced by Spirulina sybsyla and krestine gums produced by Coriates versicolor.

Preferably, xanthan and scleroglucan gums are used. Even more preferably, the xanthan gums are used. Lebiohétéropolysaccharide can be chemically modified or not. Preferably, the bioheteropolysaccharide is not chemically modified. Preferably, the molecular weight (MW) of the polysaccharide is between 100,000 and 50,000,000. Even more preferably, the molecular weight is between 250,000 and 800,000.

As bioheteropolysaccharide e present in the composition according to the invention, mention may be made of the products Amaze XT, Rhodicare XC and Keltrol CG. The xanthan gum polysaccharide or polysaccharides generally represent from 0.01 to 30%, preferably from 0.1 to 20%, better still from 0.1 to 10% by weight of the total weight of the composition used according to the invention. .

MINERAL PARTICLES The composition used according to the invention also comprises mineral particles chosen from particles containing at least 10% by weight of one or more silicates. The mineral particles generally have a number-average primary size of between 2 nm and 2 μm, preferably between 5 nm and 500 nm, better still between 10 nm and 250 nm.

The particles according to the invention may have any shape, for example the form of spheres, flakes, needles, platelets or totally random forms. They are preferably substantially spherical. The silicate particles are insoluble in the compositions. Within the meaning of the present invention, the term "primary particle size" means the maximum dimension that can be measured between two diametrically opposite points of an individual particle. The size can be determined, for example, by transmission electron microscopy or from the measurement of the specific surface area by the BET method or by means of a laser granulometer.

As explained above, the mineral particles are particles containing at least 10% by weight of at least one silicate. Particles containing at least 10% by weight of at least one silicate may further comprise a metal or metalloid oxide, for example silicon, boron or aluminum oxide. Preferably, the mineral particles are particles of one or more silicates, that is to say particles that comprise substantially only one or more silicates. The silicates suitable in the compositions of the present invention may be of natural or synthetic origin. The silicates that may be used according to the invention may be chosen from magnesium silicates, and / or lithium and / or sodium silicates. Mention may in particular be made of the compounds marketed by LAPORTE under the name LAPONITE XLG and LAPONITE XLS.

The mineral particles containing at least 10% by weight of one or more silicates generally represent from 0.01 to 20%, preferably from 0.1 to 10%, better still from 0.1 to 5% by weight relative to the weight. total of the composition. The weight ratio biohétéropolysaccharide (s) / mineral particles containing at least 10% by weight of one or more silicates preferably ranges from 0.01 to 100, more preferably from 0.1 to 10.

Surfactant As explained above, the composition according to the invention may comprise one or more surfactants provided that their total content is less than 4% by weight relative to the total weight of the composition. The surfactant (s) optionally present in the composition according to the invention may be anionic, amphoteric, nonionic, zwitterionic or cationic surfactants. Surfactants suitable for the implementation of the present invention are in particular the following:

(i) Anionic surfactant (s): The term "anionic surfactant" is understood to mean a surfactant comprising as ionic or ionizable groups only anionic groups. These anionic groups are preferably chosen from the groups CO2H, CO2-, SO3H, SO3-, OSO3H, OSO3-, H2PO3, HPO3-, PO3 2-, H2PO2 HPO2, HPO2-, PO2-, POH, PO-. Examples of anionic surfactants that can be used in the composition according to the invention include alkyl sulphates, alkyl ether sulphates, alkyl amido ether sulphates, alkylaryl polyether sulphates, monoglyceride sulphates, alkyl sulphonates, alkyl amide sulphonates, alkyl aryl sulphonates and alpha sulphonates. olefin-sulfonates, paraffin-sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamidesulfosuccinates, alkylsulfoacetates, acylsarcosinates, acylglutamates, alkylsulfosuccinamates, acylisethionates and N-acyltaurates, salts of alkyl monoesters and polyglycoside-polycarboxylic acids, acyllactylates, D-galactoside-uronic acid salts, alkyl ether-carboxylic acid salts, alkyl acid salts aryl ether carboxylic acids, alkyl amidoether carboxylic acid salts; and the corresponding non-salified forms of all these compounds; the alkyl and acyl groups of all these compounds having from 6 to 24 carbon atoms and the aryl group denoting a phenyl group. These compounds may be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units.

The salts of C6-24 alkyl monoesters and of polyglycoside-polycarboxylic acids may be chosen from C6-24 alkyl polyglycoside citrates, C6-24 alkyl polyglycoside tartrates and polyglycoside sulphosuccinates. of C6-24 alkyl.

When the anionic surfactant (ii) is in salt form, it can be selected from alkali metal salts such as sodium or potassium salt and preferably sodium salts, ammonium salts, amine salts and in particular aminoalcohols or alkaline earth metal salts such as magnesium salt.

By way of example of aminoalcohol salts, mention may be made in particular of the salts of mono-, di- and triethanolamine, the salts of mono-, di- or tri-isopropanolamine, the salts of 2-amino-2-methyl 1-propanol, 2-amino-2-methyl-1,3-propanediol and tris (hydroxymethyl) amino methane.

The alkali metal or alkaline earth metal salts and in particular the sodium or magnesium salts are preferably used.

(ii) Nonionic surfactant (s): Nonionic surfactants are also well-known compounds per se (see in particular in this connection "Handbook of Surfactants" by MR PORTER, Blackie & Son editions ( Glasgow and London), 1991, pp 116-178). Thus, they may be chosen in particular from (non-limiting list) alcohols, alpha-diols, alkylphenols, these compounds being polyethoxylated, polypropoxylated and having at least one fatty chain comprising, for example, 8 to 18 carbon atoms, the number of groups ethylene oxide or propylene oxide ranging in particular from 2 to 50. Mention may also be made of copolymers of ethylene oxide and propylene oxide, condensates of ethylene oxide and propylene oxide on fatty alcohols; polyethoxylated fatty amides preferably having from 2 to 30 moles of ethylene oxide, polyglycerolated fatty amides comprising on average 1 to 5 glycerol groups and in particular 1.5 to 4; oxyethylenated sorbitan fatty acid esters having from 2 to 30 moles of ethylene oxide; sucrose fatty acid esters, polyethylene glycol fatty acid esters, N-alkyl glucamine derivatives, amine oxides such as C10-C14 alkyl oxides or N-oxides; acylaminopropylmorpholine. Polyalkylpolyglucosides may also be mentioned.

Among the polyalkylglucosides, mention may be made, for example, of the products sold by HENKEL under the name APG, such as the products APG 300, APG 350, APG 500, APG 550, APG 625 and APG base 10-12; the products sold by the company SEPPIC under the trade names TRITON CG 110 (or ORAMIX CG 110) and TRITON CG 312 (or ORAMIX NS 10); those sold by B.A.F. under the name LUTENSOL GD 70; sold by HENKEL under the names PLANTAREN 1200, PLANTAREN 1300, PLANTAREN 2000, and PLANTACARE 2000, PLANTACARE 818, PLANTACARE 1200. (iii) Amphoteric (s) or zwitterionic surfactant (s):

The amphoteric or zwitterionic surfactant (s) that may be used in the present invention may be in particular derivatives of secondary or tertiary aliphatic amines, optionally quaternized, in which the aliphatic group is a linear or branched chain containing from 8 to 22 carbon atoms. said amine derivatives containing at least one anionic group such as, for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group. Mention may in particular be made of (C 8 -C 20) alkyl betaines, sulphobetaines, (C 8 -C 20) alkylamido (C 3-8 alkyl) betaines or (C 8 -C 20) alkylamido (C 6 -C 8 alkyl) sulphobetainesThe optionally used quaternized secondary or tertiary aliphatic amine derivatives, as defined above, may also be mentioned compounds of respective structures (Al) and (A2): Ra-CONHCH2CH2-N + (Rb) (Rc) ) (CH20OO-) (Al)

in which: Ra represents a C10-C30 alkyl or alkenyl group derived from an acid Ra-COOH, preferably present in hydrolyzed coconut oil, a heptyl, nonyl or undecyl group, Rb represents a beta-hydroxyethyl group, and Rc represents a carboxymethyl group; and Ra'-CONHCH2CH2-N (B) (B ') (A2)

wherein: B represents -CH2CH2OX ', B' represents - (CH2) z-Y ', with z = 1 or 2, X' represents the group -CH2-COOH, CH2-COOZ ', -CH2CH2-COOH, -CH2CH2 -COOZ ', or a hydrogen atom, Y' represents -COOH, -COOZ ', the group -CH2-CHOH-SO3H or -CH2-CHOH-SO3Z', Z 'represents an ion derived from an alkali metal or alkaline earth such as sodium, an ammonium ion or an ion derived from an organic amine. Ra 'represents a C10-C30 alkyl or alkenyl group of a Ra'-COOH acid preferably present in coconut oil or in hydrolysed linseed oil, an alkyl group, in particular a C17 group and its iso form, unsaturated C17 group. These compounds are classified in the CTFA dictionary, 5th edition, 1993, under the names cocoamphodiacétate disodium, lauroamphodiacétate disodium, caprylamphodiacétate disodium, capryloamphodiacétate disodium, cocoamphodipropionate disodium, lauroamphodipropionate disodium, caprylamphodipropionate disodium, capryloamphodipropionate disodium, acid lauroamphodipropionic, cocoamphodipropionic acid. By way of example, mention may be made of cocoamphodiacetate marketed by Rhodia under the trade name MIRANOL® C2M concentrate. (iv) Cationic surfactants:

Among the cationic surfactants, mention may be made in particular (non-limiting list) of the salts of primary, secondary or tertiary fatty amines, optionally polyoxyalkylenated; quaternary ammonium salts such as tetraalkylammonium, alkylamidoalkyltrialkylammonium, trialkylbenzylammonium, trialkylhydroxyalkylammonium or alkylpyridinium chlorides or bromides; imidazoline derivatives; or oxides of amines with a cationic character.

As quaternary ammonium salts, mention may be made, for example: - those corresponding to the following general formula (I): R8 \ NR (R11) in which the radicals R8 to R11, which may be identical or different, represent an aliphatic radical, linear or branched, containing from 1 to 30 carbon atoms, or an aromatic radical such as aryl or alkylaryl The aliphatic radicals may comprise heteroatoms such as in particular oxygen, nitrogen, sulfur and halogens The aliphatic radicals are, for example, chosen from C1-C30 alkyl radicals, C1-30 alkoxy radicals, polyoxyalkylene (C2-C6) alkyl radicals, C1-30 alkylamide radicals, alkyl (C12-C22) amidoalkyl (C2-C6) alkyl radicals, and the like. (C 12 -C 22) acetate and hydroxyC 1-30 alkyl; X is an anion selected from the group of halides, phosphates, acetates, lactates, (C 2 -C 6) alkyl sulfates, alkyl- or alkylarylsulfonates. quaternary ammonium of formula (I), it is preferred on the one hand, the chlorides of t traalkylammonium such as, for example, dialkyldimethylammonium or alkyltrimethylammonium chlorides in which the alkyl radical comprises about 12 to 22 carbon atoms, in particular behenyltrimethylammonium chloride, distearyldimethylammonium chloride, cetyltrimethylammonium chloride, benzyldimethylstearylammonium or d on the other hand, palmitylamidopropyltrimethylammonium chloride or stearamidopropyldimethyl (myristyl acetate) ammonium chloride sold under the name CERAPHYL® 70 by VAN DYK. (I) X- - the quaternary ammonium salts of imidazoline, such as those of formula (II) below: + in which R12 represents an alkenyl or alkyl radical containing from 8 to 30 carbon atoms, for example derivatives of tallow fatty acids, R13 represents a hydrogen atom, a C1-C4 alkyl radical or an alkenyl or alkyl radical containing from 8 to 30 carbon atoms, R14 represents a C1-C4 alkyl radical, R15 represents an atom, hydrogen, a C1-C4 alkyl radical, X- is an anion selected from the group of halides, phosphates, acetates, lactates, alkylsulfates, alkyl- or alkylaryl-sulfonates. Preferably, R12 and R13 denote a mixture of alkenyl or alkyl radicals containing from 12 to 21 carbon atoms, for example fatty acid derivatives of tallow, R14 denotes a methyl radical, R15 denotes a hydrogen atom. Such a product is for example marketed under the name REWOQUAT® W 75 by the company REWO; - Quaternary di or triammonium salts in particular of formula (III): ++ R17 R19 R16-N- (CH2) 3 -N-R21 2X-R18 R2o

in which R 16 denotes an alkyl radical containing about 16 to 30 carbon atoms, optionally hydroxylated and / or interrupted by one or more oxygen atoms, R 17 is chosen from hydrogen or an alkyl radical containing from 1 to 4 carbon atoms or a group (R16a) (R17a) (R18a) N- (CH2) 3-, NB (+ to be deleted in other projects because not mandatory) R16a, R17a, R18a, R18, R19, R20 and R21, same or different are chosen from hydrogen or an alkyl radical containing from 1 to 4 carbon atoms, and X- is an anion chosen from the group of halides, acetates, phosphates, nitrates and methylsulphates. Such compounds are, for example, the Finquat CT-P proposed by the company Finetex (Quaternium 89), the Finquat CT proposed by Finetex (Quaternium 75). It is also possible to use, as cationic surfactants, the quaternary ammonium salts containing at least one ester function, such as those of the following formula IV: ## STR5 ## wherein R22 is ## STR2 ## in which R22 is chosen from among the C1-C6 alkyl radicals and the C1-C6 hydroxyalkyl or dihydroxyalkyl radicals R23 is chosen from: OII - the radical -C- - the radicals R27 hydrocarbon radicals C1-C22, branched, saturated or unsaturated, - hydrogen atom, R25 is chosen from: OII - the radical R28 -C - - R29 hydrocarbon radicals C1-C6, branched, saturated or unsaturated, - the hydrogen atom, linear or linear or R24, R26 and R28, which may be identical or different, are chosen from linear or branched, saturated C7-C21 hydrocarbon radicals; or unsaturated; r, s and t, identical or different, are integers ranging from 2 to 6; y is an integer from 1 to 10; x and z, which are identical or different, are integers ranging from 0 to 10; X- is a simple or complex anion, organic or inorganic; with the proviso that the sum x + y + z is from 1 to 15, that when x is 0 then R23 is R27 and that when z is 0 then R25 is R29. The alkyl radicals R22 may be linear or branched and more particularly linear.

Preferably, R 22 denotes a methyl, ethyl, hydroxyethyl or dihydroxypropyl radical, and more particularly a methyl or ethyl radical. Advantageously, the sum x + y + z is from 1 to 10. When R 23 is a hydrocarbon radical R 27, it can be long and have from 12 to 22 carbon atoms, or short and have from 1 to 3 carbon atoms. When R 25 is a hydrocarbon R 29 radical, it preferably has 1 to 3 carbon atoms. Advantageously, R24, R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated C11-C21 hydrocarbon radicals, and more particularly from linear or branched, saturated or saturated C11-C21 alkyl and alkenyl radicals. or unsaturated. Preferably, x and z, identical or different, are 0 or 1.

Advantageously, y is equal to 1. Preferably, r, s and t, identical or different, are 2 or 3, and even more particularly are equal to 2. The anion is preferably a halide (chloride, bromide or iodide) or an alkyl sulphate more particularly methyl sulphate. However, it is possible to use methanesulphonate, phosphate, nitrate, tosylate, an anion derived from an organic acid such as acetate or lactate or any other anion compatible with ammonium with an ester function.

The X- anion is even more particularly chloride or methylsulfate.

In the composition according to the invention, the ammonium salts of formula (IV) are used more particularly in which: R 22 denotes a methyl or ethyl radical,

- x and y are equal to 1;

z is 0 or 1; r, s and t are equal to 2;

R23 is chosen from the radical R26-C-, methyl, ethyl or C14-C22 hydrocarbon radicals;

the hydrogen atom - R 25 is chosen from O I I - the radical R 28 -C - the hydrogen atom

- R24, R26 and R28, identical or different, are chosen from

the linear or branched, saturated or unsaturated C13-C17 hydrocarbon radicals, and preferably among the alkyl and alkenyl radicals;

C13-C17, linear or branched, saturated or unsaturated.

Advantageously, the hydrocarbon radicals are linear.

There may be mentioned, for example, the compounds of formula (IV) such as the salts (in particular chloride or methylsulfate) of diacyloxyethyl-dimethylammonium, of diacyloxyethyl-hydroxyethyl-

methylammonium, monoacyloxyethyl dihydroxyethyl

methylammonium, triacyloxyethylmethylammonium,

monoacyloxyethyl-hydroxyethyl-dimethylammonium and mixtures thereof. The acyl radicals preferably have from 14 to 18 carbon atoms and come more particularly from a vegetable oil such as palm oil or sunflower oil. When the compound contains more than one acyl radical, the latter may be identical or different.

These products are obtained, for example, by direct esterification of triethanolamine, triisopropanolamine, alkyldiethanolamine or alkyldiisopropanolamine optionally oxyalkylenated on fatty acids or mixtures of fatty acids of plant or animal origin, or by transesterification. of their methyl esters. This esterification is followed by quaternization using an alkylating agent such as an alkyl halide (preferably methyl or ethyl), a dialkyl sulphate (preferably methyl or ethyl) or methane sulphonate. methyl, methyl paratoluenesulfonate, glycol or glycerol chlorohydrin. Such compounds are, for example, sold under the names DEHYQUART® by the company HENKEL, STEPANQUAT® by the company STEPAN, NOXAMIUM® by the company CECA, REWOQUAT® WE 18 by the company REWO-WITCO.

The composition according to the invention preferably contains a mixture of quaternary ammonium mono-, di- and triester salts with a majority by weight of diester salts. As a mixture of ammonium salts, it is possible to use, for example, the mixture containing 15 to 30% by weight of acyloxyethyl-dihydroxyethyl-methylammonium methylsulfate, 45 to 60% of diacyloxyethyl-hydroxyethyl-methylammonium methyl sulfate and 15 to 30% triacyloxyethyl-methylammonium methylsulfate, acyl radicals having from 14 to 18 carbon atoms and from partially partially hydrogenated palm oil.

It is also possible to use the ammonium salts containing at least one ester function described in US-A-4874554 and US-A-4137180.

Among the preferred cationic surfactants, mention may in particular be made of methyl alkyl alkylamidoethyl imidazolinium methosulphate (Quaternium-87) marketed by the company Degussa under the reference VARISOFT W 575 PG, or behenyltrimethylammonium chloride marketed by Clariant under the name GENAMIN KDMP reference. There may also be mentioned cetyl trimethyl ammonium chloride.

Preferably, the surfactant (s) optionally present in the compositions used according to the invention are chosen from nonionic and / or cationic surfactants.

The surfactant or surfactants represent when they are present generally from 0.01 to 3.5%, preferably from 0.05 to 3%, better still from 0.1 to 2.5% by weight, of the total weight of the composition.

COSMETIC MEDIA The cosmetic composition according to the invention preferably further comprises one or more additives chosen from silicones, fatty substances, non-silicone polymers other than bioheteropolysaccharides. The silicones optionally present in the composition according to the invention are in particular polyorganosiloxanes which may be in the form of aqueous solutions, that is to say solubilized, or optionally in the form of dispersions or microdispersions, or of emulsions aqueous. The polyorganosiloxanes may also be in the form of oils, waxes, resins or gums.

Organopolysiloxanes are further defined in Walter Noll's "Chemistry and Technology of Silicones" (1968) Academie Press. Silicones can be volatile or non-volatile. When they are volatile, the silicones are more particularly chosen from those having a boiling point of between 60 ° C. and 260 ° C., and even more particularly from: (i) cyclic silicones containing from 3 to 7 silicon atoms and preferably 4 to 5. It is, for example, octamethylcyclotetrasiloxane sold in particular under the name "VOLATILE SILICONE 7207" by UNION CARBIDE or "SILBIONE 70045 V 2" by RHONE POULENC, decamethylcyclopentasiloxane marketed under the name of "VOLATILE SILICONE 7158" by UNION CARBIDE, "SILBIONE 70045 V 5" by RHONE POULENC, as well as their mixtures.

Mention may also be made of cyclocopolymers of the dimethylsiloxane / methylalkylsiloxane type, such as the "VOLATILE SILICONE FZ 3109" marketed by the company UNION CARBIDE, of chemical structure 1-D "-D 'D" -D'-1 H3 I H3 with D Si-O- with D ': Si-0 1 CH3 C8H17 Cyclic silicone mixtures with organic compounds derived from silicon, such as the mixture of octamethylcyclotetrasiloxane and tetramethylsilylpentaerythritol (50/50), and the mixture of octamethylcyclotetrasiloxane and oxy-1,1 '(hexa-2,2,2', 2 ', 3,3'-trimethylsilyloxy) bis-neopentane; (ii) linear volatile silicones having 2 to 9 silicon atoms and having a viscosity of less than or equal to 5.10.6 m 2 / s at 25 ° C. It is, for example, decamethyltetrasiloxane marketed in particular under the name "SH 200 "by the company TORAY SILICONE. Silicones included in this class are also described in the article published in Cosmetics and toiletries, Vol. 91, Jan. 76, p. 27-32 - TODD & BYERS "Volatile Silicone fluids for cosmetics". Non-volatile silicones and more particularly polyalkylsiloxanes, polyarylsiloxanes, polyalkylarylsiloxanes, silicone gums and resins, polyorganosiloxanes modified with organofunctional groups and their mixtures are preferably used. These silicones are more particularly chosen from polyalkylsiloxanes, among which, for example, polydimethylsiloxanes containing trimethylsilyl end groups (dimethicone according to the CTFA name) having a viscosity of 5 × 10 -6 to 2.5 m 2 / s at 25 ° C. and preferably 1 × 10 -5 to 1 m2 / s. The viscosity of the silicones is, for example, measured at 25 ° C. according to the ASTM 445 Appendix C standard. Among these polyalkylsiloxanes, mention may be made, without limitation, of the following commercial products: SILBIONE oils of the 47 and 70 047 series or MIRASIL oils marketed by RHONE POULENC such as, for example, 70 047 V 500 000; oils of the MIRASIL series marketed by RHONE POULENC; the oils of the 200 series of Dow Corning, such as, more particularly, the DC200 with a viscosity of 60,000 Cst; - VISCASIL oils from GENERAL ELECTRIC and some oils from SF series (SF 96, SF 18) from GENERAL ELECTRIC.

Mention may also be made of polydimethylsiloxanes with dimethylsilanol end groups (Dimethiconol according to the CTFA name), such as the oils of the 48 series of the company Rhone-Poulenc. Mention may also be made of polydimethylsiloxanes containing aminoethyl aminopropyl and alpha-omega silanol groups.

In this class of polyalkylsiloxanes, mention may also be made of the products sold under the names "ABIL WAX 9800 and 9801" by GOLDSCHMIDT, which are poly (C1-C20) alkylsiloxanes. The polyalkylarylsiloxanes are particularly chosen from polydimethyl methylphenylsiloxanes and linear and / or branched polydimethyl diphenylsiloxanes with a viscosity of from 1 × 10 -5 to 5 × 10 -2 m 2 / s at 25 ° C. Among these polyalkylarylsiloxanes include by way of example the products sold under the following names: - SILBIONE oils of the 70 641 series RHONE POULENC; - RHODORSIL 70 633 and 763 series oils from RHONE POULENC; - DOW CORNING 556 COSMETIC GRAD FLUID oil from Dow Corning; the silicones of the PK series of BAYER, such as the product PK20; the silicones of the PN, PH series of BAYER, such as the PN1000 and PH1000 products; - some oils of the SF series of GENERAL ELECTRIC such as SF 1023, SF 1154, SF 1250, SF 1265.

The silicone gums that may be present in the composition according to the invention are in particular polydiorganosiloxanes having high average molecular weights of between 200,000 and 1,000,000 used alone or in a mixture in a solvent. This solvent may be chosen from volatile silicones, polydimethylsiloxane (PDMS) oils, polyphenylmethylsiloxane (PPMS) oils, isoparaffins, polyisobutylenes, methylene chloride, pentane, dodecane, tridecanes or their mixtures.

Mention may be made more particularly of the following products: polydimethylsiloxane gums, polydimethylsiloxane / methylvinylsiloxane gums, polydimethylsiloxane / diphenylsiloxane gums, polydimethylsiloxane / phenylmethylsiloxane gums, polydimethylsiloxane / diphenylsiloxane / methylvinylsiloxane gums. More particularly useful products are the following mixtures: - mixtures formed from a hydroxylated polydimethylsiloxane at the end of the chain (called dimethiconol according to the CTFA dictionary nomenclature) and a cyclic poly-dimethylsiloxane (called cyclomethicone according to the nomenclature of the CTFA dictionary) such as the product Q2 1401 sold by the company Dow Corning; mixtures formed from a polydimethylsiloxane gum with a cyclic silicone such as the product SF 1214 Silicone Fluid from the company General Electric, this product is an SF 30 gum corresponding to a dimethicone, having a number average molecular weight of 500 000 solubilized in oil SF 1202 Silicone Fluid corresponding to decamethylcyclopentasiloxane; mixtures of two PDMSs of different viscosities, and more particularly of a PDMS gum and a PDMS oil, such as the product SF 1236 from the company General Electric. The product SF 1236 is the mixture of an SE 30 gum defined above having a viscosity of 20 m 2 / s and an SF 96 oil with a viscosity of 5 × 10 -6 m 2 / s.

This product preferably comprises 15% of SE gum and 85% of an SF 96 oil. The organopolysiloxane resins optionally present in the composition according to the invention are crosslinked siloxane systems containing the units: R2SiOz12, R3SiO112, RSiO312 and SiO412 in which R represents a hydrocarbon group having 1 to 16 carbon atoms or a phenyl group. Among these products, those particularly preferred are those in which R denotes a lower alkyl radical C1-C4, more particularly methyl, or a phenyl radical. Among these resins may be mentioned the product sold under the name "Dow Corning 593" or those sold under the names "Silicone Fluid SS 4230 and SS 4267" by the company General Electric and which are silicones of dimethyl / trimethyl siloxane structure. Mention may also be made of the trimethylsiloxysilicate type resins sold in particular under the names X22-4914, X21-5034 and X21-5037 by the company Shinetsu.

The organomodified silicones optionally present in the composition according to the invention are silicones as defined above and comprising in their structure one or more organofunctional groups attached via a hydrocarbon radical.

Among the organomodified silicones, mention may be made of polyorganosiloxanes comprising: polyethyleneoxy and / or polypropyleneoxy groups optionally comprising C 6 -C 24 alkyl groups such as the products called dimethicone copolyol marketed by the company Dow Corning under the name DC 1248 or the oils SILWET L 722, L 7500, L 77, L 711 of the company UNION CARBIDE and the alkyl (C12) methicone copolyol marketed by the company Dow Corning under the name Q2 5200; thiol groups such as the products sold under the names "GP 72 A" and "GP 71" from GENESEE; alkoxylated groups, such as the product marketed under the name "Silicone Copolymer F-755" by SWS Silicones and Abil Wax 2428, 2434 and 2440 by the company GOLDSCHMIDT; hydroxyl groups such as the hydroxyalkyl-functional polyorganosiloxanes described in the French patent application FRA-85 16334; acyloxyalkyl groups such as, for example, the polyorganosiloxanes described in US Pat. No. 4,957,732; anionic groups of the carboxylic type, for example in the products described in the patent EP 186 507 of the company Chisso Corporation, or of the alkylcarboxylic type, such as those present in the product X-22-3701E from the company Shin-Etsu; 2-hydroxyalkylsulfonate; 2-hydroxyalkylthiosulphate such as the products marketed by GOLDSCHMIDT under the names "ABIL 5201" and "ABIL S255"; hydroxyacylamino groups, such as the polyorganosiloxanes described in patent application EP 342 834. Mention may be made, for example, of the product Q2-8413 from Dow Corning.

Among the organomodified silicones, mention may also be made of amino silicones. Amino silicone means any silicone comprising at least one primary, secondary, tertiary amine or a quaternary ammonium group.

The amino silicones used in the cosmetic composition according to the present invention are chosen from: (a) the compounds corresponding to the following formula (V):

(R1) a (T) 3-a-Si [OSi (T) 2] n- [OSi (T) b (R1) 2-b] m-OSi (T) 3-a- (R1) a (V) ) in which, T is a hydrogen atom, or a phenyl, hydroxyl (-OH), or C 1 -C 8 alkyl, and preferably methyl or C 1 -C 8 alkoxy, preferably methoxy, a is the number 0 or an integer of 1 to 3, and preferably 0, b is 0 or 1, and in particular 1,

m and n are numbers such that the sum (n + m) may vary in particular from 1 to 2,000 and in particular from 50 to 150, n being able to designate a number from 0 to 1,999 and in particular from 49 to 149 and m being able to designate a number from 1 to 2,000, and in particular from 1 to 10; R1 is a monovalent radical of formula -CqH2qL wherein q is a number from 2 to 8 and L is an optionally quaternized amino group selected from the groupings: - N (R2) -CH2-CH2-N (R2) 2; -N (R 2) 2 N + (R 2) 3 Q-

- N + (R2) (H) 2 Q- - N + (R2) 2HQ-

N (R 2) -CH 2 -CH 2 -N + (R 2) (H) 2 Q-,

in which R 2 may designate a hydrogen atom, a phenyl, a benzyl, or a monovalent saturated hydrocarbon radical, for example a C 1 -C 20 alkyl radical, and Q - represents a halide ion such as, for example, fluoride, chloride, bromide or iodide.

In particular, the amino silicones corresponding to the definition of the formula (V) are chosen from the compounds corresponding to the following formula (VI): ## STR2 ## CH3 CH3 n CH3 NH 1 (CH2) 2 m

NH2 (VI)

in which R, R ', R ", identical or different, denote a C 1 -C 4 alkyl radical, preferably CH 3, a C 1 -C 4 alkoxy radical, preferably methoxy, or OH; A represents a linear or branched, C3-C8, preferably C3-C6; m and n are integers dependent on the molecular weight and whose sum is between 1 and 2000. According to a first possibility, R, R ', R ", identical or different, represent a C1-C4 alkyl or hydroxyl radical, A represents a C3 alkylene radical and m and n are such that the weight average molecular weight of the compound is between about 5,000 and 500,000. Compounds of this type are referred to in the CTFA dictionary as "amodimethicone". According to a second possibility, R, R ', R ", which may be identical or different, represent a C1-C4 alkoxy or hydroxyl radical, at least one of the radicals R or R" is an alkoxy radical and A represents a radical alkylene radical. C3. The hydroxyl / alkoxy molar ratio is preferably between 0.2 / 1 and 0.4 / 1 and advantageously equal to 0.3 / 1. Moreover, m and n are such that the weight average molecular weight of the compound is between 2000 and 106. More particularly, n is between 0 and 999 and m is between 1 and 1000, the sum of n and m being between 1 and 1000. In this category of compounds, mention may be made inter alia of the Belsil®ADM 652 product marketed by Wacker.

According to a third possibility, R, R ", different, represent a C1-C4 alkoxy or hydroxyl radical, at least one of the radicals R, R" is an alkoxy radical, R 'represents a methyl radical and A represents a radical. C3 alkylene. The molar ratio of hydroxy / alkoxy is preferably between 1 / 0.8 and 1 / 1.1, and advantageously is equal to 1 / 0.95. Furthermore, m and n are such that the weight average molecular weight of the compound is between 2000 and 200000. More particularly, n is between 0 and 999 and m is between 1 and 1000, the sum of n and m being between 1 and 1000. More particularly, there may be mentioned F1uidWR® 1300 product, marketed by Wacker. According to a fourth possibility, R, R "represent a hydroxyl radical, R 'represents a methyl radical and A is a C4-C8 alkylene radical, preferably a C4 radical, and m and n are such that the average molecular weight by weight of the compound is between 2000 and 106. More particularly, n is between 0 and 1999 and m is between 1 and 2000, the sum of n and m being between 1 and 2000.

A product of this type is especially marketed under the name DC28299 by Dow Corning.

It should be noted that the molecular mass of these silicones is determined by gel permeation chromatography (ambient temperature, polystyrene standard, μ styragem columns, THF eluent, flow rate of 1 mm / m, 200 μl of a 0.5% solution are injected by weight of silicone in THF and the detection is carried out by refractometry and UV-metry).

A product corresponding to the definition of the formula (V) is in particular the polymer referred to in the CTFA dictionary "trimethylsilylamodimethicone", corresponding to the following formula (VII): CH 3 CH 3 (CH 3) 3 SiO SiO SiO Si (CH 3) 3 1 CH3 CH2 n CHCH3 CH2 NH m (i H2) 2

NH 2 (VII) wherein n and m have the meanings given above according to formula (I).

Such compounds are described for example in EP 95238; a compound of formula (VII) is for example sold under the name Q2-8220 by the company OSI.

(b) the compounds corresponding to the following formula (VIII): ## STR2 ##

in which,

R3 represents a monovalent hydrocarbon radical C1-C18, and in particular a C1-C18 alkyl radical, or C2-C18 alkenyl, for example methyl;

R4 represents a divalent hydrocarbon radical, especially a C1-C18 alkylene radical or a divalent C 1 -C 18 alkyleneoxy radical for example C 1 -C 8;

Q- is a halide ion, especially chloride;

r represents an average statistical value of 2 to 20 and in particular 2 to 8;

s represents an average statistical value of 20 to 200 and in particular of 20 to 50.

Such compounds are described more particularly in US Patent 4185087.

A compound in this class is that sold by Union Carbide under the name "Ucar Silicone ALE 56". c) the quaternary ammonium silicones of formula (IX): 2X-R 7 R 7 Si-R 6 -CH 2 -CHOH-CH 2 -N-R 7 R 7 R 7 (IX) R 3 R 3 Si

Wherein R7, which are the same or different, represent a monovalent or monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in which R 7 R 7 R 7 R 7 R 7 especially a C1-C18 alkyl radical, a C2-C18 alkenyl radical or a ring comprising 5 or 6 carbon atoms, for example methyl; R 6 represents a divalent hydrocarbon radical, in particular a C 1 -C 18 alkylene radical or a divalent C 1 -C 18, for example C 1 -C 8, alkyleneoxy radical connected to Si by an SiC bond; R8, which may be identical or different, represent a hydrogen atom, a monovalent hydrocarbon radical containing from 1 to 18 carbon atoms, and in particular a Ci-C18 alkyl radical, a C 2 -C 18 alkenyl radical or a radical -R6- NHCOR7; X - is an anion such as a halide ion, especially chloride or an organic acid salt (acetate, etc.); r represents an average statistical value of 2 to 200 and in particular 5 to 100; These silicones are for example described in application EP-A-0530974. d) the amino silicones of formula (X): R 1 R 3 Si-O 1 R 2 Si R 5 1 x R 4 3 Si O NH 1 (ÇmH 2 m) (X) NH 2 in which: R 1, R 2, R 3 and R 4, identical or different, , denote a C1-C4 alkyl radical or a phenyl group, - R5 denotes a C1-C4 alkyl radical or a hydroxyl group, - n is an integer ranging from 1 to 5, - m is an integer ranging from 1 to 5; and wherein x is selected such that the amine value is between 0.01 and 1 meq / g. Particularly preferred silicones are polysiloxanes containing amine groups such as amodimethicones or trimethylsilylamodimethicones (CTFA 4th edition 1997), and even more particularly silicones with quaternary ammonium groups. When these compounds are used, a particularly interesting embodiment is their use together with cationic and / or nonionic surfactants. As an example, it is possible to use the product sold under the name "Cationic Emulsion DC 939" by Dow Corning, which comprises, in addition to amodimethicone, a cationic surfactant which is trimethylketylammonium chloride and a non-surface-active agent. ionic compound of formula: C13H27- (OC2H4) 12-OH, known under the name CTFA "trideceth-12". Another commercial product that can be used according to the invention is the product sold under the name "Dow Corning Q2 7224" by the company Dow Corning, comprising in combination the trimethylsilylamodimethicone of formula (VII) described above, a nonionic surfactant of formula: C8H17-C6H4- (OCH2CH2) 40-OH, known under the name CTFA "octoxynol-40", a second nonionic surfactant of the formula: C12H25- (OCH2-CH2) 6-OH, known under the name CTFA "isolaureth-6", and propylene glycol.

The silicone or silicones generally represent from 0 to 30%, preferably from 0.2 to 20% by weight, of the total weight of the composition. As explained above, the cosmetic composition according to the invention may also comprise one or more non-silicone polymers different from the bioheteropolysaccharides described above.

The polymer or polymers other than the bioheteropolysaccharides described above may be of natural, plant, and / or synthetic origin. The additional polymers may be chosen from cationic, anionic, amphoteric and nonionic polymers.

For the purposes of the present invention, the term "cationic polymer" means any polymer comprising cationic groups and / or groups that can be ionized into cationic groups. The cationic polymers that can be used in the cosmetic composition according to the invention are preferably chosen from polymers comprising primary, secondary, tertiary and / or quaternary amine groups forming part of the polymer chain or directly connected thereto, and having a mass number average molecular weight of from 500 to about 5,000,000, and preferably from 1,000 to 3,000,000. Among these polymers, there may be mentioned more particularly the following cationic polymers: (1) homopolymers or copolymers of esters or acrylic amide or methacrylic amide containing amine functions, comprising at least the following formulas:

Wherein R 1 and R 2, which may be identical or different, each represent a hydrogen atom or an alkyl group having from 1 to 6 atoms; embedded image in which R 1 and R 2, which may be identical or different, each represent a hydrogen atom or an alkyl group having from 1 to 6 atoms of carbon ; R3 denotes a hydrogen atom or a CH3 group; A is a linear or branched alkyl group having 1 to 6 carbon atoms or a hydroxyalkyl group having 1 to 4 carbon atoms; R4, R5, R6, which may be identical or different, represent an alkyl group having from 1 to 18 carbon atoms or a benzyl group; X denotes a methosulphate anion or a halide such as chloride or bromide. The copolymers of family (1) also contain one or more comonomer-derived units which may be selected from the family of acrylamides, methacrylamides, diacetone-acrylamides, acrylamides and methacrylamides substituted on the nitrogen by lower alkyl groups (C 1.4 ), groups derived from acrylic or methacrylic acids or their esters, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, vinyl esters. Thus, among these copolymers of the family (1), there may be mentioned: one of the units of I 3 -CH-C 2 1 C = O or -CH-C RZ R 5 + R 4 N -R 6 [X] R 5 - the copolymers of dimethylaminoethyl acrylamide and methacrylate quaternized with dimethyl sulphate or with a dimethyl halide, such as the product sold under the name HERCOFLOC® by the company Hercules, - the copolymers of acrylamide and methacryloyloxyethyltrimethylammonium chloride described, for example, in the patent application EP-A-080976 and sold under the name BINA QUAT P 100 by Ciba GEIGY, - copolymers of acrylamide and methacryloyloxyethyltrimethylammonium methosulphate, such as that sold under the name RETEN by Hercules, vinylpyrrolidone / dialkylaminoalkyl acrylate or methacrylate copolymers, whether or not quaternized, such as the products sold under the name "GAFQUAT®" by ISP, such as, for example, "GAFQUAT® 734" or "GAFQUAT® 734"; AFQUAT® 755 ", or the products called" COPOLYMER® 845, 958 and 937 ". These polymers are described in detail in French Pat. Nos. 2,077,143 and 2,393,573, the dimethylaminoethyl methacrylate / vinylcaprolactam / vinylpyrrolidone terpolymers, such as the product sold under the name GAFFIX® VC 713 by the company ISP, and the copolymers quaternized vinylpyrrolidone / dimethylaminopropyl methacrylamide such as in particular the product sold under the name "GAFQUAT® HS 100" by the company ISP; crosslinked polymers of methacryloyloxyalkyl (C1-C4) trialkyl (C1-C4) ammonium salts, such as the polymers obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized with methyl chloride, or by copolymerization of acrylamide with dimethylaminoethyl methacrylate quaternized with chloride; of methyl, the homo or copolymerization being followed by crosslinking with an olefinically unsaturated compound, in particular methylenebisacrylamide. It is more particularly possible to use a crosslinked acrylamide / methacryloyloxyethyltrimethylammonium chloride copolymer (20/80 by weight) in the form of a dispersion containing 50% by weight of said copolymer in mineral oil. This dispersion is marketed under the name "SALCARE® SC 92" by the company CIBA. It is also possible to use a crosslinked homopolymer of methacryloyloxyethyltrimethylammonium chloride containing about 50% by weight of the homopolymer in mineral oil or in a liquid ester. These dispersions are sold under the names "SALCARE® SC 95" and "SALCARE® SC 96" by the company CIBA. (2) cationic polysaccharides, and in particular those chosen from a) derivatives of cellulose ethers containing quaternary ammonium groups described in patent FR 1492597. These polymers are also defined in the CTFA dictionary as quaternary ammoniums of hydroxyethyl cellulose reacted with an epoxide substituted with a trimethylammonium group; b) cellulose derivatives grafted with a water-soluble monomer comprising a quaternary ammonium, and described in particular in US Pat. No. 4 131 576, such as hydroxyalkylcelluloses, such as hydroxymethyl-, hydroxyethyl- or hydroxypropyl-cellulose grafted in particular with a methacryloyloxyethyl salt; trimethylammonium, methacrylamidopropyl trimethylammonium, dimethyl diallylammonium. The marketed products corresponding to this definition are more particularly the products sold under the name "CELQUAT L 200" and "CELQUAT H 100" by the company National Starch. c) cationic polygalactomannans such as those described in US Pat. Nos. 3,589,578 and 4,031,307, such as guar gums containing cationic trialkylammonium groups. Such products are marketed in particular under the trade names JAGUAR C13 S, JAGUAR C 15, JAGUAR C 17 by the company MEYHALL; (3) quaternary copolymers of vinylpyrrolidone and vinylimidazole; (4) chitosans or their salts; the salts that can be used are, in particular, chitosan acetate, lactate, glutamate, gluconate or pyrrolidonecarboxylate.

Among these compounds, mention may be made of chitosan having a degree of deacetylation of 90.5% by weight sold under the name KYTAN BRUT STANDARD by ABER TECHNOLOGIES, the pyrrolidone carboxylate of chitosan sold under the name KYTAMER® PC by the company Amerchol. The anionic polymers generally used are polymers having groups derived from carboxylic, sulfonic or phosphoric acid and have a number-average molecular weight of between about 500 and 5,000,000.

The carboxylic groups are provided by unsaturated mono- or di-carboxylic acid monomers, such as those corresponding to the formula: ## STR2 ## wherein n is an integer from 0 to 10, Al represents a methylene group, optionally connected to the carbon atom of the unsaturated group or to the neighboring methylene group when n is greater than 1, by means of a heteroatom such as oxygen or sulfur, R7 denotes a hydrogen atom, a phenyl or benzyl group, R8 denotes a hydrogen atom, a lower alkyl or carboxyl group, R9 denotes a hydrogen atom, a lower alkyl group, a -CH2-COOH group, phenyl or benzyl. In the abovementioned formula, a lower alkyl group preferably denotes a group having 1 to 4 carbon atoms and in particular the methyl and ethyl groups. The anionic polymers with carboxylic groups that are preferred according to the invention are: A) copolymers of acrylic acid and of acrylamide sold in the form of their sodium salts under the names RETEN 421, 423 or 425 by the company HERCULES, the salts of sodium polyhydroxycarboxylic acids.

B) copolymers of acrylic or methacrylic acid with a monoethylenic monomer such as ethylene, styrene, vinyl esters, esters of acrylic or methacrylic acid, optionally grafted onto a polyalkylene glycol such as polyethylene glycol, and optionally crosslinked. Such polymers are described in particular in French Patent No. 1,222,944 and German Application No. 2,330,956, copolymers of this type comprising in their chain an acrylamide unit optionally N-alkylated and / or hydroxyalkylated such as described in particular in the Luxembourg patent applications Nos. 75370 and 75371 or proposed under the name QUADRAMER by AMERICAN CYANAMID. Mention may also be made of methacrylic acid / ethyl acrylate / tertiobutyl acrylate terpolymers, such as the product marketed under the name LUVIMER® 100 P by the company BASF.

Mention may also be made of methacrylic acid / acrylic acid / ethyl acrylate / methyl methacrylate copolymers in aqueous dispersion, sold under the name AMERHOLD® DR 25 by the company Amerchol. C) Crotonic acid copolymers, such as those comprising in their chain vinyl acetate or propionate units, and optionally other monomers such as allyl or methallyl esters, vinyl ethers or vinyl esters of a saturated carboxylic acid, linear or branched, long hydrocarbon chain, such as those comprising at least 5 carbon atoms, these polymers may optionally be grafted or crosslinked, or another vinyl ester, allylic or methallyl monomer of a carboxylic acid a- or (3- Such polymers are described, inter alia, in French Patents 1,222,944, 1,580,545, 2,265,782, 2,265,781, 1,564,110 and 2,439,798. 28-29-30, 26-13-14 and 28-13-10 marketed by the company National Starch D) copolymers of C4-C8 monounsaturated carboxylic acids or anhydrides chosen from: (i) one or more maleic, fumaric and itaconic acids or anhydrides and (ii) at least one monomer selected from vinyl esters, vinyl ethers, vinyl halides, phenylvinyl derivatives, acrylic acid and its esters, anhydride functions of these copolymers being optionally monoesterified or monoamidified. Such polymers are described in particular in US Pat. Nos. 2,047,398, 2,723,248, 2,102,113 and GB Patent No. 839,805. Commercial products are especially those sold under the names GANTREZ® AN or ES by the ISP company. copolymers comprising (i) one or more maleic, citraconic and itaconic anhydride units and (ii) one or more monomers chosen from allyl or methallyl esters optionally containing one or more acrylamide, methacrylamide, α-olefin or acrylic or methacrylic ester groups; acrylic or methacrylic acids or vinylpyrrolidone in their chain, the anhydride functions of these copolymers being optionally monoesterified or monoamidified. These polymers are, for example, described in French patents Nos. 2,350,384 and 2,357,241 of the applicant. E) Polyacrylamides having carboxylate groups.

Homopolymers and copolymers comprising sulphonic groups are polymers comprising vinylsulphonic, styrene-sulphonic, naphthalenesulphonic or acrylamidoalkylsulphonic units. These polymers may be chosen in particular from: - the salts of polyvinylsulphonic acid having a molecular mass of between about 1,000 and 100,000, as well as copolymers with an unsaturated comonomer such as acrylic or methacrylic acids and their esters, as well as acrylamide or its derivatives, vinyl ethers and vinylpyrrolidone. salts of polystyrene-sulphonic acid, such as the sodium salts sold, for example, under the names Flexan® 500 and Flexan® 130 by National Starch. These compounds are described in patent FR 2 198 719. - polyacrylamidesulfonic acid salts such as those mentioned in US Pat. No. 4,128,631, and more particularly the polyacrylamidoethylpropanesulphonic acid sold under the name COSMEDIA POLYMER HSP 1180 by Henkel. Preferably, the anionic polymers are chosen from acrylic acid copolymers such as acrylic acid / ethyl acrylate / N-tert-butylacrylamide terpolymers sold in particular under the name ULTRAHOLD® STRONG by BASF, copolymers derived from crotonic acid. such as vinyl acetate / vinyl tert-butylbenzoate / crotonic acid terpolymers and crotonic acid / vinyl acetate / vinyl neododecanoate terpolymers sold in particular under the name Resin 28-29-30 by the company National Starch, polymers derived from maleic, fumaric, itaconic acids or anhydrides with vinyl esters, vinyl ethers, vinyl halides, phenylvinyl derivatives, acrylic acid and its esters such as monoesterified methyl vinyl ether / maleic anhydride copolymers sold, for example, under the name GANTREZ® by the company ISP, the copolymers of methacrylate acid methyl methacrylate sold under the name EUDRAGIT® L by the company ROHM PHARMA, the copolymers of methacrylic acid and of ethyl acrylate sold under the name Luvimer® MAEX or MAE by the company BASF and the copolymers acetate of vinyl / crotonic acid sold in particular under the name Luviset CA 66 by the company BASF and polyvinylglycol grafted vinyl acetate / crotonic acid copolymers sold under the name ARISTOFLEX® A by the company BASF. Among the anionic polymers mentioned above, it is more particularly preferred to use in the context of the present invention the monoesterified methyl vinyl ether / maleic anhydride copolymers sold under the name Gantrez® ES 425 by the company ISP, the acrylic acid / ethyl acrylate terpolymers. / N-tert-butylacrylamide sold under the name ULTRAHOLD® STRONG by BASF, the copolymers of methacrylic acid and methyl methacrylate sold under the name EUDRAGIT® L by the company ROHM PHARMA, vinyl acetate terpolymers / tert-butylbenzoate vinyl / crotonic acid and the crotonic acid / vinyl acetate / vinyl neododecanoate terpolymers sold under the name Resin 28-29-30 by the company National Starch, the copolymers of methacrylic acid and ethyl acrylate sold under the name LUVIMER® MAEX or MAE by BASF. The amphoteric polymers that can be used in accordance with the invention can be chosen from polymers comprising units B and C statistically distributed in the polymer chain where B denotes a unit derived from a monomer comprising at least one basic nitrogen atom and C denotes a pattern derived from an acidic monomer having one or more carboxylic or sulfonic groups, or B and C may denote groups derived from zwitterionic monomers of carboxybetaines or sulfobetaines; B and C may also designate a cationic polymer chain comprising primary, secondary, tertiary or quaternary amine groups, in which at least one of the amine groups carries a carboxylic or sulphonic group connected via a hydrocarbon group, or B and C are part of a chain of an ethylene-α, β-dicarboxylic polymer having one of the carboxylic groups reacted with a polyamine having one or more primary or secondary amine groups. Amphoteric polymers corresponding to the definition given above, which are more particularly preferred, are chosen from the following polymers: (1) copolymers with acidic vinyl units and with basic vinyl units, such as those resulting from the copolymerization of a monomer derived from a vinyl compound bearing a carboxylic group such as, more particularly, acrylic acid, methacrylic acid, acyl maleic acid, alpha-chloroacrylic acid, and a basic monomer derived from a substituted vinyl compound containing at least one basic atom, such as more particularly methacrylate and dialkylaminoalkyl acrylate, dialkylaminoalkylmethacrylamide and acrylamide. Such compounds are described in US Pat. No. 3,836,537. (2) polymers comprising units derived from: at least one monomer chosen from acrylamides or methacrylamides substituted on the nitrogen atom by an alkyl group (b) at least one acidic comonomer containing one or more reactive carboxylic groups, and (c) at least one basic comonomer such as primary, secondary, tertiary and quaternary amine substituted esters of acrylic and methacrylic acids, and quaternization product of dimethylaminoethyl methacrylate with dimethyl or diethyl sulfate. The N-substituted acrylamides or methacrylamides which are more particularly preferred according to the invention are those compounds whose alkyl groups contain from 2 to 12 carbon atoms, and more particularly N-ethylacrylamide, N-tert-butylacrylamide, N-tert-octylacrylamide, N octylacrylamide, N-decylacrylamide, N-dodecylacrylamide and the corresponding methacrylamides. The acidic comonomers are chosen more particularly from acrylic, methacrylic, crotonic, itaconic, maleic and fumaric acids as well as alkyl monoesters having 1 to 4 carbon atoms of maleic or fumaric acids or anhydrides. Preferred basic comonomers are aminoethyl, butylaminoethyl, N, N'-dimethylaminoethyl, N-tert-butylaminoethyl methacrylates. The copolymers whose CTFA (4th Ed., 1991) name is octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer, such as the products sold under the name AMPHOMER® or LOVOCRYL® 47 by the company National Starch, are particularly used. (3) polyamino amides crosslinked and partially or completely acylated deriving from poyaminoamides of general formula: CO-RI CO-Z (XII) in which R10 represents a divalent group derived from a saturated dicarboxylic acid, a mono or dicarboxylic aliphatic acid with an ethylenic double bond, an ester of a lower alkanol having 1 to 6 carbon atoms of these acids or a group deriving from the addition of any of said acids with a bis-primary amine or bis- secondary, and Z denotes a group derived from a bis-primary, mono- or bis-secondary polyalkylenepolyamine and preferably represents a) in the proportions of 60 to 100 mol%, the group

NH (CH2). NH where x = 2 and p = 2 or 3, or x = 3 and p = 2 this group derived from diethylene triamine, triethylenetetraamine or dipropylene triamine; b) in the proportions of 0 to 40 mol%, the group (IX) above, wherein x = 2 and p = 1 and which is derived from ethylenediamine, or the group derived from piperazine: c) in the proportions of 0 to 20 mol%, the -NH-20 (CH 2) 6 -NH- group derived from hexamethylenediamine, these polyaminoamides being crosslinked by the addition reaction of a bifunctional crosslinking agent chosen from epihalohydrins, diepoxides, dianhydrides, bis-unsaturated derivatives, by means of 0.025 to 0.35 mole of crosslinking agent per amine group of the polyaminoamide, and acylated by the action of acrylic acid, chloroacetic acid or an alkane-sultone or their salts. The saturated carboxylic acids are preferably chosen from acids having 6 to 10 carbon atoms, such as adipic, trimethyl-2,2,4-adipic and trimethyl-2,4,4-adipic acids, terephthalic acids, ethylenic double bond such as, for example, acrylic, methacrylic, itaconic acids.

The alkane sultones used in the acylation are preferably propane or butane sultone, the salts of the acylating agents are preferably the sodium or potassium salts.

(4) polymers comprising zwitterionic units of formula: in which R 11 denotes a polymerizable unsaturated group such as an acrylate, methacrylate, acrylamide or methacrylamide group, y and z; represent an integer from 1 to 3, R12 and R13 represent a hydrogen atom, a methyl, ethyl or propyl group, R14 and R15 represent a hydrogen atom or an alkyl group such that the sum of the carbon atoms in R14 and R15 does not exceed 10.

The polymers comprising such units may also comprise units derived from non-zwitterionic monomers such as dimethyl- or diethylaminoethyl acrylate or methacrylate or alkyl acrylates or methacrylates, acrylamides or methacrylamides, or vinyl acetate.

By way of example, mention may be made of methyl methacrylate / methyl dimethylcarboxymethylammonioethylmethacrylate copolymers, such as the product sold under the name DIAFORMER Z301 by Sandoz. (5) polymers derived from chitosan having monomeric units corresponding to the following formulas: ## STR2 ## the unit (D) being present in proportions between 0 and 30%, the unit (E) in proportions of between 5 and 50% and the unit (F) in proportions of between 30 and 90%, it being understood that in this unit (F), R16 represents a group of formula :

18 i 19 R17 C (0) q

in which if q = 0, R 17, R 18 and R 19, which may be identical or different, each represent a hydrogen atom, a methyl, hydroxyl, acetoxy or amino residue, a monoalkylamine residue or a dialkylamine residue optionally interrupted by one or more carbon atoms. nitrogen and / or optionally substituted by one or more amine, hydroxyl, carboxyl, alkylthio, sulphonic groups, an alkylthio radical whose alkyl group carries an amino residue, at least one of the groups R17, R18 and R19 being in this case a hydrogen atom; or if q = 1, R 17, R 18 and R 19 each represent a hydrogen atom, as well as the salts formed by these compounds with bases or acids. (6) Polymers containing units corresponding to the general formula (XIII), for example, described in French Patent 1,400,366 (XIII) R20 (CH 2 CH 2) CH 2 COOH CO N -R 21 R 24 in which R 20 represents a hydrogen atom, a CH3O group, CH3CH2O, phenyl, R21 denotes a hydrogen atom or a lower alkyl group such as methyl, ethyl, R22 denotes a hydrogen atom or a C1-C6 lower alkyl group such as methyl , ethyl, R23 denotes a C1-C6 lower alkyl group such as methyl, ethyl or a group corresponding to the formula: -R24-N (R22) 2, R24 representing a group -CH2-CH2-, -CH2-CH2- CH2-, -CH2-CH (CH3) -, R22 having the meanings mentioned above. (7) The polymers derived from the N-carboxyalkylation of chitosan, such as N-carboxymethylchitosan or N-carboxybutylchitosan, sold under the name "Evalsan" by Jan Dekker. (8) Amphoteric polymers of the -D-X-D-X type chosen from: a) the polymers obtained by the action of chloroacetic acid or sodium chloroacetate on compounds comprising at least one unit of formula:

Where D denotes a group and X denotes the symbol E or E ', E or E', which may be identical or different, denotes a divalent group which is a straight or branched chain alkylene group comprising up to 7 atoms; carbon in the main chain unsubstituted or substituted by hydroxyl groups and which may further comprise oxygen, nitrogen, sulfur, 1 to 3 aromatic and / or heterocyclic rings; the oxygen, nitrogen and sulfur atoms being present in the form of ether, thioether, sulphoxide, sulphone, sulphonium, alkylamine, alkenylamine, hydroxyl groups, benzylamine, amine oxide, quaternary ammonium, amide, imide groups, alcohol, ester and / or urethane.

b) polymers of formula: -D-X-D-X- (XV) where D denotes a group / -N N / and X denotes the symbol E or E 'and at least once E'; E having the meaning indicated above and E 'is a divalent group which is a straight or branched chain alkylene group having up to 7 carbon atoms in the main chain, substituted or unsubstituted by one or more hydroxyl groups and comprising one or more nitrogen atoms, the nitrogen atom being substituted by an alkyl chain optionally interrupted by an oxygen atom and necessarily comprising one or more carboxyl functions or one or more hydroxyl functions and betaineized by reaction with the acid; chloroacetic acid or sodium chloroacetate. (9) (C1-C5) alkyl vinyl ether / maleic anhydride copolymers partially modified by semiamidation with an N, N-dialkylaminoalkylamine such as N, N-dimethylaminopropylamine or by semi-esterification with an N, N-dialkylaminoalkanol. These copolymers may also comprise other vinylic comonomers such as vinylcaprolactam. Among the amphoteric polymers described above, the most particularly preferred according to the invention are those of the family (3) such as the copolymers whose CTFA name is Octylacrylamide / acrylates / butylamino-ethylmethacrylate copolymer, such as the products sold under them. denominations AMPHOMER®, AMPHOMER® LV 71 or LOVOCRYL® 47 by the company National Starch and those of the family (4) such as methyl methacrylate / dimethylcarboxymethylammonioethylmethacrylate copolymers sold for example under the name DIAFORMER® Z301 by SANDOZ. The nonionic polymers that can be used according to the present invention are chosen, for example, from: homopolymers of vinylpyrrolidone; polyalkyloxazolines; homopolymers of vinyl acetate; vinyl acetate copolymers such as, for example, copolymers of vinyl acetate and acrylic ester, copolymers of vinyl acetate and ethylene, or copolymers of vinyl acetate and of maleic ester, for example, dibutyl maleate; homopolymers and copolymers of acrylic esters, such as, for example, copolymers of alkyl acrylates and of alkyl methacrylates such as the products offered by the company Rohm & Haas under the names PRIMAL® AC-261 K and EUDRAGIT® NE 30D, by the company BASF under the name 8845, by the company HOECHST under the name APPRETAN® N9212; copolymers of acrylonitrile and of a nonionic monomer chosen, for example, from butadiene and alkyl (meth) acrylates; mention may be made of the products sold under the name CJ 0601 B by the company Rohm &Haas; homopolymers of styrene; styrene copolymers such as, for example, styrene and alkyl (meth) acrylate copolymers such as Mowilith® LDM 6911, Mowilith® DM 611 and Mowilith® LDM 6070 products supplied by the company Hoechst, the RHODOPAS products ® SD 215 and RHODOPAS® DS 910 offered by RHODIA CHIMIE; copolymers of styrene, alkyl methacrylate and alkyl acrylate; copolymers of styrene and butadiene; or copolymers of styrene, butadiene and vinylpyridine; polyamides; homopolymers of vinyllactam such as polyvinylcaprolactam sold under the name Luviskol® PLUS by the company BASF; and homopolymers of vinylpyrrolidone. copolymers of vinyllactam such as a poly (vinylpyrrolidone / vinyllactam) copolymer sold under the trade name Luvitec® VPC 55K65W by BASF, poly (vinylpyrrolidone / vinyl acetate) copolymers, such as those sold under the name PVPVA® S630L by ISP, Luviskol® VA 73, VA 64, VA 55, VA 37 and VA 28 by BASF; and poly (vinylpyrrolidone / vinyl acetate / vinyl propionate) terpolymers such as, for example, that marketed under the name Luviskol® VAP 343 by the company BASF. The alkyl groups of the nonionic polymers mentioned above preferably have from 1 to 6 carbon atoms. It is also possible to use, as polymers, functionalized or non-silicone or non-silicone, cationic, nonionic, anionic or amphoteric polyurethanes, or mixtures thereof. The polyurethanes particularly targeted by the present invention are those described in the applications EP 0 751 162, EP 0 637 600, EP 0 648 485 and FR 2 743 297 of which the applicant is the holder, as well as in the applications EP 0 656 021 and WO 94/03510 of the company BASF, and EP 0 619 111 of the company National Starch. As polyurethanes particularly suitable in the present invention, mention may be made of the products sold under the names LUVISET PUR® and LUVISET® Si PUR by the company BASF. The non-silicone polymers other than the bioheteropolysaccharides may also be synthetic associative or non-associative thickening polymers. There may be mentioned crosslinked acrylic acid homopolymers (INCI name: CARBOMER) and nonionic or anionic associative polyurethanes, such as compounds ACULYN 44 and 46, and VISCOPHOBE DB 1000.

The non-silicone polymer or polymers other than the bioheteropolysaccharides described above represent when they are present generally from 0.01 to 20%, preferably from 0.1 to 10% by weight, of the total weight of the composition. As explained above, the composition according to the invention may contain one or more preferably non-silicone fatty substances such as vegetable, animal, mineral and synthetic oils, fatty alcohols, non-salified fatty acids and waxes. By fatty alcohol is meant in the sense of the present invention, any pure saturated or unsaturated fatty alcohol, linear or branched having at least 8 carbon atoms.

The fatty alcohol may have the structure R-OH, in which R denotes a linear or branched, saturated or unsaturated radical containing from 8 to 40 carbon atoms and preferably from 8 to 30; R preferably denotes a C12-C24 alkyl or C12-C24 alkenyl group. R may be substituted with one or more hydroxy groups.

As examples of fatty alcohols, mention may be made of lauryl, cetyl, dodecyl, decyl, stearyl, oleic, behenic, linoleic, undecylenic, palmitoleic, arachidonic, erucic alcohols and mixtures thereof. The fatty alcohol can be a mixture of fatty alcohols, which means that in a commercial product can coexist several species of fatty alcohols in the form of a mixture. As a mixture of fatty alcohols, there may be mentioned cetylstearyl alcohol or cetearyl alcohol. Advantageously, the fatty alcohol is solid or pasty at a temperature of 25 ° C. For the purposes of the present invention, the term "solid or pasty fatty alcohol at 25 ° C." means a fatty alcohol having a viscosity measured with a rheometer with a shear rate of 1 s -1 greater than or equal to 1 Pa.s. Preferably, the fatty alcohols used in the cosmetic composition according to the invention are cetyl alcohol and cetearyl alcohol. By fatty acids is meant in the sense of the present invention, any pure carboxylic acid saturated or unsaturated, linear or branched having at least 8 carbon atoms. As examples of fatty acid, mention may be made of lauric acid and oleic acid.

The cosmetic composition according to the invention may further contain one or more cosmetic adjuvants chosen from fibers, perfumes, floral waters, essential oils, plasticizers, non-polymeric polyols, sunscreens, basifying agents, agents and the like. acidifying agents, preservatives, permanent or temporary dyes, mineral fillers other than the particles of the invention, flakes, conditioning agents, antifoaming agents, moisturizing agents, humectants, emollients, non-thickening agents polymers, peptizers, ceramides, pseudo-ceramides, vitamins and provitamins, proteins, sequestering agents, solubilizing agents, oxidizing agents, anti-corrosion agents and reducing agents or antioxidants. Those skilled in the art will take care to choose any adjuvants and their amount so that they do not affect the properties of the composition according to the invention. The compositions of the invention preferably comprise a cosmetically acceptable medium. By a cosmetically acceptable medium is meant a medium which is compatible with keratin materials and in particular the hair. The cosmetically acceptable medium comprises water or a mixture of water and one or more cosmetically acceptable organic solvents. The cosmetically acceptable organic solvents are preferably chosen from C1-C4 lower alcohols, polyols, polyol ethers, C3-C4 ketones, C1-C4 alkyl acetates, dimethoxyethane, diethoxyethane, and the like. their mixtures. The composition according to the invention may be in the form of cream, paste or preferably in the form of foam (aerosol or not), or gel. When the cosmetic composition according to the invention is in the form of a foam, it can be packaged in an aerosol. In this case, it comprises one or more propellants. The propellant (s) is (are) chosen from non-liquefied compressed gases, such as air, nitrogen, nitrous oxide, carbon dioxide or dimethyl ether, or from liquefied gases such as volatile hydrocarbons such as n-butane, isobutane, propane, pentane and halogenated hydrocarbons. For example, a mixture of one or more volatile hydrocarbons can be used with dimethyl ether. The foam can still be obtained without thruster by means of a pump bottle. The present invention relates preferably to the use of a cosmetic composition described above for styling the hair.

The present invention also relates to a cosmetic treatment method comprising the application to the hair of a cosmetic composition as defined above. The present invention also relates to a cosmetic specific composition comprising: - one or more biohétéropolysaccharides, and - mineral particles chosen from particles containing at least 10% by weight of one or more silicates, - one or more sugar derivatives other than biohétéropolysaccharides . said composition containing an amount of surfactants of less than 4% by weight relative to the total weight of the composition,

The bioheteropolysaccharides, the mineral particles and the surfactants that may be present are the same as those described above.

The different sugar derivatives of bioheteropolysaccharides include mono- or disaccharides and polysaccharides different from bioheteropolysaccharides. Mono- or disaccharides are preferably selected from glucose, fructose, xylose and sucrose. The polysaccharides different from the bioheteropolysaccharides are preferably chosen from pectins, celluloses, alginates, guar gums, starches, gum tragacanth, gum arabic.These polysaccharides may or may not be modified chemically. ionic or ionic.

Synthetically modified polymers may be chosen for example from starch derivatives such as carboxymethyl starch and diamidon phosphate, cellulose derivatives such as hydroxyethylcellulose and carboxymethylcellulose and guar derivatives such as 1 (hydroxypropylguar. The sugar derivative or derivatives different from the bioheteropolysaccharides preferably represent from 0.01 to 20% and even more preferentially from 0.1 to 10% of the total weight of the composition.

The invention is illustrated by the following nonlimiting examples.

EXAMPLES

Styling gels Take a small amount of product, and apply it to wet, damp or dry hair, and carve the desired hairstyle with your finger. Obtaining a good hairstyle with good cosmetic properties. Quantities are expressed in% of Active Matter Hair Styling Gel 1 2 3 Xanthan Gum AMAZE XT NATIONAL STARCH 1,2 Xanthan Gum KELTROL CG KELCO 3 Xanthan Gum RHODICARE CGT RHODIA 5 Laponite Mg Li Na Laponite XLG DEGUSSA 0.8 0, 7 0.3 Honey 0.2 Sucrose 0.6 Sorbitol 10 Glycerol 2 2 2 Xylitol 5 Sodium Lauroyl Sarcosinate ORAMIX L30 SEPPIC 2 Decyl Glucoside ORAMIX NS 10 SEPPIC 2 Denatured alcohol 0 3 Preservatives, Neutralizer, Fragrance QS QS QS Water QS 100 QS 100 QS100 20 Styling mousse (aerosol, or foam pump) Take a small amount of product, and apply it on wet, damp or dry hair, and sculpt with your finger or brushing the desired hairstyle. Obtaining a good styling with good cosmetic properties. Quantities are expressed in% of Active Matte Styling Foam 1 2 3 Xanthan Gum AMAZE XT NATIONAL STARCH 1.2 Xanthan Gum KELTROL CG KELCO 0.4 Xanthan Gum RHODICARE CGT RHODIA 4 Mg Li Laponite Na Laponite XLG DEGUSSA 0 , 3 0.7 0.5 Honey 1 0.2 Sucrose 0.6 Sorbitol 3 2 Glycerol 1 2 Xylito l 5 Sodium Lauroyl Sarcosinate ORAMIX L30 SEPPIC 2 Decyl Glucoside ORAMIX NS 10 SEPPIC 3.5 2 Denatured alcohol 5 3 Hydrocarbon propellant 10 Preservatives, Neutralizer, Fragrance QS QS QS Water QS100 QS100 QS100

Claims (13)

REVENDICATIONS1. Use for the treatment of the hair of a cosmetic composition comprising: - one or more biohétéropolysaccharides, and - mineral particles chosen from particles containing at least 10% by weight of one or more silicates, said composition containing a quantity of surfactants less than 4% by weight relative to the total weight of the composition. 2. Use according to claim 1, characterized in that the biohétéropolysaccharides are chosen from xanthan gums, scleroglucan gums, gellan gums, pullulan gums, Curdlar gums, dextran gums produced by many organisms. including Leuconostoc mesenteroides and Leuconostoc dextrantum, grifolane gums, lentinan gums, schizophyllane gums, spirulinane gums and krestine gums. 3. Use according to claims 1 or 2, characterized in that the biohétéropolysaccharides are chosen from xanthan gums. 4. Use according to any one of the preceding claims, characterized in that the bioheteropolysaccharide (s) represent from 0.01 to 30%, preferably from 0.1 to 20%, better still from 0.1 to 10% by weight relative to to the total weight of the composition. 5. Use according to any one of the preceding claims characterized in that the mineral particles are selected from the particles of one or more silicates. 6. Use according to any one of the preceding claims characterized in that the or silicates are selected from magnesium silicates, and / or lithium and / or sodium. 7. Use according to any one of the preceding claims characterized in that the mineral particles containing at least 10% by weight of one or more silicates represent from 0.01 to 20%, preferably from 0.1 to 10%, better from 0.1 to 5% by weight relative to the total weight of the composition. 8. Use according to any one of the preceding claims characterized in that the bioheteropolysaccharide (s) / mineral particles weight ratio containing at least 10% by weight of one or more silicates ranges from 0.01 to 100, more preferably 0, 1 to 10. 9. Use according to any one of the preceding claims characterized in that it contains one or more surfactant is selected from anionic surfactants, cationic, nonionic or amphoteric and preferably nonionic and / or cationic. 10. Use according to any one of the preceding claims characterized in that the surfactant content is from 0.01 to 3.5%, preferably from 0.05 to 3%, better from 0.1 to 2.5%. by weight of the total weight of the composition. 11. Use according to any one of the preceding claims characterized in that the composition comprises water or a mixture of water and one or more cosmetically acceptable organic solvents preferably selected from C1-C4 lower alcohols, polyols, polyol ethers, C3-C4 ketones, C1-C4 alkyl acetates, dimethoxyethane, diethoxyethane, and mixtures thereof. 12. Use according to any one of the preceding claims characterized in that the composition is in the form of foam, aerosol or not, or gel. 13. Cosmetic composition comprising: - one or more biohétéropolysaccharides as described according to any one of claims 1 to 3, and - mineral particles selected from particles containing at least 10% by weight of one or more silicates as described according to any one of claims 1 and 5 or 6, - one or more sugar derivatives other than biohétéropolysaccharides. said composition containing an amount of surfactants of less than 4% by weight relative to the total weight of the composition. Composition according to claim 13, characterized in that the sugar derivatives other than the bioheteropolysaccharides are chosen from glucose and fructose. xylose and sucrose, pectins, modified or unmodified celluloses, alginates, modified or unmodified guar gums, modified or unmodified starches, gum tragacanth, gum arabic. 15. Composition according to claims 13 to 14, characterized in that the sugar derivative or derivatives different from the biohétéropolysaccharides preferably represent from 0.01 to 20% and even more preferentially from 0.1 to 10% of the total weight of the composition. .