FR2880267A1 - Cosmetic composition, useful e.g. as a product of skin make-up and/or lips, comprises a fatty liquid phase, dispersion particles of homopolymer or cross linked acrylic or vinyl copolymers, a stabilizing polymer and a pasty compound - Google Patents

Abstract

Cosmetic composition (A), comprises: a fatty liquid phase; dispersion particles of homopolymer or cross-linked acrylic or vinyl copolymers; a stabilizing polymer (stabilizing dispersion of polymer sequences, grafted polymers or statistical polymers); and a pasty compound, where the average brightness at 60[deg] of a deposit of (A), after spread out over a support, is >=35%.

Description

The present invention relates to a cosmetic composition containing

  polymer particles dispersed in a liquid fatty phase and at least one particular pasty compound.

  The cosmetic composition is intended in particular for the make-up or care of the skin, including the scalp, the face or the human body, the lips or integuments of human beings, such as hair, eyelashes, eyebrows or nails.

  The composition of the invention may in particular constitute a make-up product of the body, lips or integuments of human beings having, in addition, non-therapeutic care properties. It is especially a lipstick or a lip gloss, a blush or eyeshadow, a tattoo product, a mascara, an eyeliner, a nail polish, an artificial tanning product, a product coloring or hair care.

  It has been described in EP 925 780, makeup compositions containing a dispersion of uncrosslinked copolymer of methyl acrylate and acrylic acid in an 85/15 ratio in isododecane. These compositions, however, have the disadvantage of leading to a dull and uncomfortable film.

  The applicant has found, surprisingly, that the combination of a particular pasty compound with a fatty phase containing a dispersion of polymer particles makes it possible in particular to obtain a makeup that is glossy on application, having good color fastness. over time, while also having good application properties, especially sliding application, without presenting problems of comfort and stickiness.

  In particular, the product of the invention makes it possible to obtain continuous deposits that are non-sticky, have good coverage, and do not migrate. It also has good application properties, and the color is deposited correctly in a single pass.

  The holding and gloss properties of the composition according to the invention combined with good application properties make it a product that is particularly suitable for producing skin makeup products, in particular lipsticks such as lipsticks, which are glossy when lips, eyes such as mascara, eyeliners, eyeshadows, or skin such as foundations.

  The invention applies to care and / or treatment products, such as balms and creams of daily care and sun protection of the skin of the face of the skin, including the scalp. The invention applies to make-up products of the skin, both of the face and of the human body, such as foundations especially cast in stick or cup, anti-ring products and ephemeral tattoo products. The invention also applies to personal hygiene products such as deodorants, especially in stick form, and to eye makeup products such as eyeliners, in particular in the form of pencils, and mascaras, in particular in the form of bread.

  The present invention thus has for its first object a cosmetic composition comprising at least one liquid fatty phase, a dispersion of particles of homopolymer or radical copolymer, acrylic or vinyl dispersed in said fatty phase, a stabilizing polymer of said dispersion chosen from polymers sequenced, graft polymers and random polymers and at least one pasty compound. The composition advantageously has a mean gloss measured at 60, once spread on a support, greater than or equal to 35 in 100.

  The subject of the present invention is a cosmetic composition comprising at least one liquid fatty phase, a dispersion of homopolymer or radical copolymer particles, acrylic or vinyl dispersed in said fatty phase, a stabilizing polymer of said dispersion chosen from block polymers. graft polymers and random polymers and at least two pasty compounds.

  By "liquid fatty phase", in the sense of the application, is meant any nonaqueous liquid medium at ambient temperature (25 ° C.) and atmospheric pressure (760 mmHg), composed of one or more fatty substances that are liquid at room temperature. also called oils, as well as gelling agents and stabilizers of the pigments possibly present in the composition, when they are liquid at ambient temperature and atmospheric pressure. This fatty phase may contain a volatile liquid fatty phase and / or a non-volatile fatty phase.

  The term "non-volatile fatty phase" means any medium that may remain on the skin or the lips without evaporating. A non-volatile fatty phase has in particular a vapor pressure at room temperature and atmospheric pressure, non-zero less than 0.02 mmHg and better still less than 10-3 mmHg.

  By "volatile fatty phase" is meant any non-aqueous medium capable of evaporating from the skin or lips, at room temperature and atmospheric pressure. This volatile phase notably comprises oils having a vapor pressure at ambient temperature (25 ° C.) and atmospheric pressure (760 mmHg) ranging from 10 -3 to 300 mmHg (0.13 Pa to 40,000 Pa), in particular ranging from 0.02 to 300 mmHg (2.66 Pa to 40,000 Pa).

  Advantageously, the composition is capable of forming a deposit having a mean gloss measured at 60 greater than or equal to 45. The apolar oil is advantageously such that, when it is in sufficient quantity, the composition is capable of forming a deposit having a medium gloss. measured at 60 greater than or equal to 50.

  By medium gloss, is meant the brightness as it can be measured using a gloss meter, conventionally by the following method.

  On a brand contrast card BYK Gardner and reference Prüfkarten, Art. 2853, preliminarily attached to a 1 mm glass plate, a 25 μm thick layer of the composition was spread with an automatic spreader (Bar Coater, Sheen). The layer covers at least the black background of the card. When the composition is solid, it is melted if necessary on the map after spreading so that it covers the black background. As soon as the composition is spread out, the gloss is measured at 60 on the black background using a BYK GARDNER brand glossmeter and microTR1-GLOSS reference. Four contrast maps are thus prepared for measuring the average gloss of the composition, and the average of the four measurements is taken. For the measurement to be correct, the standard deviation must be less than or equal to 3%.

  The subject of the invention is also a cosmetic process for the care or makeup of keratin materials and in particular the lips, superficial body growths or the skin, consisting in applying to the lips, the integuments or the skin a cosmetic composition as defined above.

  The composition according to the invention comprises at least one pasty compound.

  For the purposes of the present invention, the term "pasty" means a lipophilic fatty compound having a reversible solid / liquid state change and comprising at a temperature of 23 ° C. a liquid fraction and a solid fraction.

  The pasty compound preferably has a hardness at 20 ° C ranging from 0.001 to 0.5 MPa, preferably from 0.002 to 0.4 MPa.

  The hardness is measured according to a method of penetration of a probe into a sample of compound and in particular using a texture analyzer (for example TA-XT2i from Rhéo) equipped with a stainless steel cylinder. 2 mm in diameter. The hardness measurement is carried out at 20 C in the center of 5 samples. The cylinder is introduced into each sample at a pre-rate of 1 mm / sec and then at a measuring speed of 0.1 mm / s, the penetration depth being 0.3 mm. The measured value of the hardness is that of the maximum peak.

  This pasty compound is furthermore, at a temperature of 23 ° C., in the form of a liquid fraction and a solid fraction. In other words, the starting melting temperature of the pasty compound is less than 23 ° C. The liquid fraction of the pasty compound measured at 23 ° C. represents from 23 to 97% by weight of the compound. This liquid fraction at 23 ° C. preferably represents between 40 and 85% by weight of the compound.

  The liquid fraction by weight of the pasty compound at 23 ° C. is equal to the ratio of the enthalpy of fusion consumed at 23 ° C. on the heat of fusion of the pasty compound.

  The heat of fusion of the pasty compound is the enthalpy consumed by the compound to pass from the solid state to the liquid state. The pasty compound is said to be in the solid state when the entirety of its mass is in solid form. The pasty compound is said to be in a liquid state when all of its mass is in liquid form.

  The enthalpy of fusion of the pasty compound is equal to the area under the curve of the thermogram obtained using a differential scanning calorimeter (DS C), such as the calorimeter sold under the name MDSC 2920 by the company TA instrument, with a rise in temperature of 5 or 10 C per minute, according to the standard ISO 11357-3: 1999. The enthalpy of fusion of the pasty compound is the amount of energy required to pass the compound from the solid state to the liquid state. It is expressed in J / g.

  The heat of fusion consumed at 23 ° C. is the quantity of energy absorbed by the sample to pass from the solid state to the state that it has at 23 ° C. consisting of a liquid fraction and a liquid fraction. solid fraction.

  The liquid fraction of the pasty compound measured at 32 ° C is preferably 40 to 100% by weight of the compound, preferably 50 to 100%, preferably 80 to 100%, more preferably 90 to 100% by weight of the compound. . When the liquid fraction of the pasty compound measured at 32 C is 100%, the temperature of the end of the melting range of the pasty compound is less than or equal to 32 C.

  The liquid fraction of the pasty compound measured at 32 ° C. is equal to the ratio of the enthalpy of fusion consumed at 32 ° C. on the heat of fusion of the pasty compound. The enthalpy of fusion consumed at 32 ° C. is calculated in the same way as the heat of fusion consumed at 23 ° C.

  The pasty compound is preferably selected from synthetic compounds and constituents of vegetable origin. A pasty compound can be obtained synthetically from starting materials of plant origin.

  The pasty compound is advantageously chosen from lanolin and its derivatives - polymeric silicone compounds or non-polymeric fluorinated compounds or non-vinyl polymers, in particular: olefin homopolymers olefin copolymers homopolymers and copolymers of olefins hydrogenated dienes; linear or branched oligomers, homo or copolymers of alkyl (meth) acrylates preferably having a C 8 -C 30 alkyl group; homo and copolymeric oligomers of vinyl esters having C 8 -C 30 alkyl groups; homo- oligomers and copolymers of vinyl ethers having C 8 -C 30 alkyl groups, the liposoluble polyethers resulting from the polyetherification between one or more C2-C100, preferably C2-C50 diols, the esters and the polyesters, and mixtures thereof.

  The pasty compound is preferably polymer, in particular hydrocarbon-based.

  A preferred silicone and fluoro pasty compound is polymethyl trifluoropropyl methylalkyl dimethylsiloxane, manufactured under the name X22-1088 by SHIN ETSU.

  When the pasty compound is a silicone and / or fluorinated polymer, the composition corn-25 advantageously takes a compatibilizing agent such as short chain esters such as isodecyl neopentanoate.

  Among the liposoluble polyethers, copolymers of ethylene oxide and / or propylene oxide with C6-C30 long-chain alkylene oxides are particularly preferred, more preferably such as the weight ratio of the ethylene oxide and / or or propylene oxide with alkylene oxides in the copolymer is from 5:95 to 70:30. In this family, mention will in particular be made of copolymers such as long-chain alkylene oxides are arranged in blocks having an average molecular weight of 1,000 to 10,000, for example a polyoxyethylene / polydodecyl glycol block copolymer such as dodecanediol ethers (22). mol) and polyethylene glycol (45 EO) marketed under the tradename ELFACOS ST9 by Akzo Nobel.

  Among the esters, the esters of an oligomeric glycerol, in particular the esters of diglycerol, in particular the condensates of adipic acid and of glycerol, for which part of the hydroxyl groups of the glycerols have reacted with a mixture of fatty acids such as stearic acid, capric acid, stearic acid and isostearic acid and 12-hydroxystearic acid, such as those marketed under the trademark Softisan 649 by the company Sasol - the phytosterol esters; peritaerythritol esters; esters formed from at least one alcohol, at least one of the alcohols being a Guerbet alcohol and a diacid dimer formed from at least one unsaturated fatty acid, such as the ester of tall oil fatty acids comprising 36 carbon atoms and a mixture of i) Guerbet alcohols comprising 32 carbon atoms and ii) behenyl alcohol; the dimer ester of linoleic acid and a mixture of two Guerbet alcohols, 2-tetradecyloctadecanol (32 carbon atoms) and 2-hexadecylicosanol (36 carbon atoms).

  the non-crosslinked polyesters resulting from the polycondensation between a linear or branched C 4 -C 50 dicarboxylic acid or polycarboxylic acid and a C2-050 diol or polyol, the polyesters which result from the esterification, with a polycarboxylic acid; an aliphatic hydroxy carboxylic acid ester such as Risocast DA-L and Risocast DA-H marketed by the Japanese company KOKYU ALCOHOL KOGYO, which are esters resulting from the esterification reaction of hydrogenated castor oil with dilinoleic acid or isostearic acid aliphatic ester esters resulting from the esterification of an aliphatic hydroxycarboxylic acid ester with an aliphatic carboxylic acid; (Salacos HCIS (V) -L sold by the company Nishing Oit) The aliphatic carboxylic acid comprises from 4 to 30 and preferably from 8 to 30 carbon atoms. It is preferably selected from hexanoic acid, heptanoic acid, octanoic acid, 2-ethyl hexanoic acid, nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, acid tridecanoic acid, tetradecanoic acid, pentadecanoic acid, hexadecanoic acid, hexydecanoic acid, heptadecanoic acid, octadecanoic acid, isostearic acid, nonadecanoic acid, eicosanoic acid, acid isoarachidic acid, octyldodecanoic acid, henicosanoic acid, docosanoic acid, and mixtures thereof.

  The aliphatic carboxylic acid is preferably branched.

  The aliphatic hydroxy carboxylic acid ester is advantageously derived from a hydroxylated aliphatic carboxylic acid having from 2 to 40 carbon atoms, preferably from 10 to 34 carbon atoms and better still from 12 to 28 carbon atoms, and from 1 to to 20 hydroxyl groups, preferably 1 to 10 hydroxyl groups and more preferably 1 to 6 hydroxyl groups. The aliphatic hydroxy carboxylic acid ester is chosen from: a) partial or total esters of saturated linear monohydroxylated aliphatic monocarboxylic acids; b) partial or total esters of unsaturated monohydroxylated aliphatic monocyclic arboxylic acids; c) partial or total esters of saturated monohydroxylated aliphatic polycarboxylic acids; d) partial or total esters of saturated polyhydroxylated aliphatic polycarboxylic acids; e) the partial or total esters of C2 to C16 aliphatic polyols reacted with a mono or polyhydroxylated aliphatic mono or poly carboxylic acid, and mixtures thereof.

  The aliphatic ester esters are advantageously chosen from: the ester resulting from the esterification reaction of hydrogenated castor oil with isostearic acid in proportions of 1 to 1 (1: 1) or monoisostearate of hydrogenated castor, - the ester resulting from the esterification reaction of hydrogenated castor oil with isostearic acid in proportions 1 to 2 (1/2) or hydrogenated castor oil diisostearate, the ester resulting from the esterification reaction of hydrogenated castor oil with isostearic acid in proportions 1 to 3 (1/3) or hydrogenated castor oil triisostearate, and mixtures thereof.

  The pasty compound is preferably 0.5 to 99%, more preferably 1 to 60%, more preferably 2 to 30% and more preferably 5 to 15% by weight of the composition.

  The mass ratio between the polymer particles and the pasty compound is advantageously between 1 to 100, preferably between 0.2 and 5, preferably between 0.5 and 3, more preferably of the order of 1.

  According to the invention, the polymer in the form of particles dispersed in the liquid fatty phase is an insoluble solid in the liquid fatty phase of the composition even at its softening temperature, unlike a wax of polymeric origin which is it soluble in the liquid organic phase (or fat phase) at its melting point. The polymer also allows the formation of a continuous and homogeneous film-forming deposit and / or is characterized by the entanglement of the polymer chains. With a wax, even obtained by polymerization, a recrystallization is obtained after melting in the liquid organic phase. This recrystallization is particularly responsible for the loss of the gloss of the composition.

  The composition according to the invention thus advantageously comprises at least one stable dispersion of generally spherical polymer particles of one or more polymers, in a physiologically acceptable liquid fatty phase. These dispersions may in particular be in the form of polymer nanoparticles in stable dispersion in said liquid organic phase. The nanoparticles are preferably of average size between 5 and 800 nm, and better between 50 and 500 nm. It is however possible to obtain polymer iparticle sizes up to 1 m.

  Preferably, the dispersed polymer particles are insoluble in water-soluble alcohols such as, for example, ethanol.

  The dispersion polymers that can be used in the first composition of the invention preferably have a molecular weight of the order of 2,000 to 10,000,000 g / mol, and a Tg of -100 ° C. to 300 ° C. and better still -50 to 100. C, preferably from -10 C to 50 C.

  It is possible to use film-forming polymers, preferably having a low Tg, less than or equal to the temperature of the skin and in particular less than or equal to 40 C.

  Preferably the polymer used is film-forming, that is to say able to form alone or in combination with a plasticizer, an isolatable film. However, it is possible to use a non-film-forming polymer.

  The term "non-film-forming polymer" means a polymer that is not capable of forming an isolable film alone. This polymer makes it possible, in combination with a nonvolatile compound of the oil type, to form a continuous and homogeneous deposit on the skin and / or the lips.

  Among the film-forming polymers, mention may be made of homopolymers or radical copolymers, acrylic or vinyl, preferably having a Tg of less than or equal to 40 C and especially ranging from 10 to 30 C, used alone or in mixture.

  Among the non-film-forming polymers, there may be mentioned homopolymers or radical copolymers, vinyl or acrylic, optionally crosslinked, preferably having a Tg greater than 40 C and in particular ranging from 45 to 150 C, used alone or in mixture.

  Radical polymer is understood to mean a polymer obtained by polymerization of unsaturated monomers, in particular ethylenic monomers, each monomer being capable of homopolymerizing (unlike polycondensates). The radical polymers may in particular be vinyl polymers or copolymers, especially acrylic polymers.

  The acrylic polymers may result from the polymerization of ethylenically unsaturated monomers having at least one acid group and / or esters of these acidic monomers or amides of these acids.

  As monomer carrying an acid group, α, β-ethylenic unsaturated carboxylic acids such as acrylic acid, methacrylic acid, crotonic acid, maleic acid, itaconic acid can be used. It is preferable to use (meth) acrylic acid and crotonic acid, and more preferably (meth) acrylic acid.

  The acidic monomer esters are advantageously chosen from esters of (meth) acrylic acid (also called (meth) acrylates), such as alkyl (meth) acrylates, in particular C 1 -C 20 alkyl, preferably C1-C8, the (meth) acrylates of aryl, in particular of C6-C10 aryl, hydroxyalkyl (meth) acrylates, in particular of hydroxy-C2-C6 alkyl. As alkyl (meth) acrylates, there may be mentioned methyl (meth) acrylate, ethyl, butyl, isobutyl, 2-ethylhexyl and lauryl. Hydroxyalkyl (meth) acrylates that may be mentioned include hydroxyethyl (meth) acrylate and 2-hydroxypropyl (meth) acrylate. Aryl (meth) acrylates include benzyl or phenyl acrylate.

  Particularly preferred (meth) acrylic acid esters are alkyl (meth) acrylates.

  The radical polymer used is preferably copolymers of (meth) acrylic acid and (meth) acrylate, especially of C1-C4 alkyl. More preferentially, it is possible to use methyl acrylates optionally copolymerized with acrylic acid.

  As amides of the acidic monomers, mention may be made of (meth) acrylamides, and in particular N-alkyl (meth) acrylamides, in particular C 2 -C 12 alkyl such as N-ethyl acrylamide, Nt-butyl acrylamide, N-octyl acrylamide; N-dialkyl (C1-C4) (meth) acrylamides.

  The acrylic polymers can also result from the polymerization of ethylenically unsaturated monomers having at least one amine group, in free form or partially or totally neutralized, or even partially or totally quaternized. Such monomers may be, for example, dimethylaminoethyl (meth) acrylate, dimethylaminoethyl methacrylamide, vinylamine, vinylpyridine or diallyldimethylammonium chloride.

  The vinyl polymers may also result from the homopolymerization or copolymerization of at least one monomer chosen from vinyl esters and styrene monomers. In particular, these monomers can be polymerized with acidic monomers and / or their esters and / or their amides, such as those mentioned above. Examples of vinyl esters include vinyl acetate, vinyl propionate, vinyl neodecanoate, vinyl pivalate, vinyl benzoate, and vinyl t-butyl benzoate. Styrene monomers include styrene and alpha-methyl styrene.

  The list of monomers given is not limiting and it is possible to use any monomer known to those skilled in the art falling into the categories of acrylic and vinyl monomers (including monomers modified with a silicone chain).

  Other vinyl monomers which may be used include: N-vinylpyrrolidone, vinylcaprolactam, vinyl N-alkyl (C 1 -C 6) pyrroles, vinyl oxazoles, vinyl thiazoles, vinylpyrimidines, vinylimidazoles, olefins such as ethylene, propylene, butylene, isoprene, butadiene.

  The vinyl polymer may be crosslinked with one or more difunctional monomers, especially comprising at least two ethylenic unsaturations, such as ethylene glycol dimethacrylate or diallyl phthalate.

  The dispersion polymer (s) in the organic liquid phase may represent from 5 to 40% by weight of the solids content of the composition, preferably from 5 to 35% and better still from 8 to 30% by weight.

  It is preferable to use a dispersion of particles of film-forming polymer, the particles being dispersed in a volatile oil.

  According to one embodiment, the composition contains a solid stabilizer at room temperature. The polymer particles are preferably surface stabilized with a stabilizer which may be a block polymer, a graft polymer, and / or a random polymer, alone or in admixture. The stabilization can be carried out by any known means, and in particular by direct addition of the block polymer, graft polymer and / or random polymer, during the polymerization.

  The stabilizer is preferably also present in the mixture before polymerization of the polymer. However, it is also possible to add it continuously, in particular when the monomers are also added continuously.

  2-30% by weight of stabilizer can be used in relation to the initial mixture of monomers, and preferably 5-20% by weight.

  When a grafted and / or sequenced polymer is used as a stabilizer, the synthesis solvent is chosen such that at least a part of the grafts or sequences of said polymer-stabilizer is soluble in said solvent, the other part of the grafts or sequences not soluble in them. The polymer-stabilizer used during the polymerization must be soluble or dispersible in the synthesis solvent. In addition, a stabilizer whose insoluble sequences or grafts have a certain affinity for the polymer formed during the polymerization is preferably chosen.

  Among the graft polymers, mention may be made of silicone polymers grafted with a hydrocarbon chain; hydrocarbon polymers grafted with a silicone chain.

  Thus grafted or sequenced block copolymers comprising at least one block of polyorganosiloxane type and at least one block of a radical polymer, such as graft copolymers of the acrylic / silicone type that can be used in particular when the non-aqueous medium is silicone are used. .

  It is also possible to use block or graft block copolymers comprising at least one polyorganosiloxane type block and at least one polyether block. The polyorganopolysiloxane block may in particular be a polydimethylsiloxane or else a poly (C2-C18) alkylsiloxane; the polyether block may be a C 2 -C 18 polyalkylene, in particular polyoxyethylene and / or polyoxypropylene. In particular, it is possible to use dimethicones copolyol or alkyl (C2-O18) dimethicones copolyol such as those sold under the name "Dow Corning 3225C" by the company Dow Corning, lauryl meticones such as those sold under the name "Dow Corning" Q2-5200 by the company "Dow Corning".

  As block or grafted block copolymers, mention may also be made of those comprising at least one block resulting from the polymerization of at least one ethylenic monomer, with one or more optionally conjugated ethylenic bonds, such as ethylene or dienes such as butadiene and isoprene, and at least one block of a vinyl polymer and better styrenic. When the ethylenic monomer comprises several optionally conjugated ethylenic bonds, the residual ethylenic irisaturations after the polymerization are generally hydrogenated. Thus, in known manner, the polymerization of isoprene leads, after hydrogenation, to the formation of ethylene-propylene block, and the polymerization of butadiene leads, after hydrogenation, to the formation of ethylene-butylene block. Among these polymers, mention may be made of block copolymers, especially of the "diblock" or "triblock" type of the polystyrene / polyisoprene (SI), polystyrene / polybutadiene (SB) type, such as those sold under the name 'LUVITOL HSB' by BASF , of the polystyrene / copoly (ethylene-propylene) (SEP) type, such as those sold under the name 'Kraton' by Shell Chemical Co or else from the polystyrene / copoly (ethylenebutylene) (SEB) type. In particular, Kraton G1650 (SEBS), Kraton G1651 (SEBS), Kraton G1652 (SEBS), Kraton G1657X (SEBS), Kraton G1701X (SEP), Kraton G1702X (SEP), Kraton can be used. G1726X (SEB), Kraton D-1101 (SBS), Kraton D-1102 (SBS), Kraton D-1107 (SIS). The polymers are generally called copolymers of hydrogenated dienes or not.

  It is also possible to use Gelled Permethyl 99A-750, 99A-753-59 and 99A-753-58 (mixture of triblock and star polymer), Versagel 5960 from Penreco (triblock + star polymer); OS129880, OS129881 and OS84383 from Lubrizol (styrene / methacrylate copolymer).

  As grafted or sequenced block copolymers comprising at least one block resulting from the polymerization of at least one ethylenic monomer with one or more ethylenic bonds and at least one block of an acrylic polymer, mention may be made of two or three-block copolymers poly (methyl methyl acrylate) / polyisobutylene or graft copolymers with poly (methyl methyl acrylate) backbone and polyisobutylene grafts.

  As grafted or sequenced block copolymers comprising at least one block resulting from the polymerization of at least one ethylenic monomer with one or more ethylenic bonds and at least one block of a polyether such as a C2-C18 polylkylene (polyethylene and / or polyoxypropylene, in particular), mention may be made of polyoxyethylene / polybutadiene or polyoxyethylene / polyisobutylene bi- or triblock copolymers.

  When a random polymer is used as a stabilizer, it is chosen so that it has a sufficient quantity of groups making it soluble in the envisaged synthetic solvent.

  It is thus possible to use copolymers based on alkyl acrylates or methacrylates derived from C 1 -C 4 alcohols, and alkyl acrylates or methacrylates derived from C 8 -C 30 alcohols. In particular, mention may be made of stearyl methacrylate / methyl methacrylate copolymer.

  When the synthesis solvent of the polymer is apolar, it is preferable to choose as a stabilizer, a polymer providing the most complete coverage of the particles possible, several polymer-stabilizer chains then being adsorbed on a polymer particle obtained by polymerization.

  In this case, it is preferred to use as stabilizer, either a graft polymer or a block polymer, so as to have a better interfacial activity. Indeed, the sequences or grafts insoluble in the synthetic solvent provide a larger coverage to Na surface of the particles.

  When the liquid synthetic solvent comprises at least one silicone oil, the stabilizing agent is preferably selected from the group consisting of grafted or sequenced block copolymers comprising at least one block of polyorganosiloxane type and at least one block of a polymer radical or a polyether or a polyester such as polyoxypropylene and / or oxyethylenated blocks.

  When the liquid fatty phase does not comprise silicone oil, the stabilizing agent is preferably chosen from the group consisting of: (a) grafted or sequenced block copolymers comprising at least one block of polyorganosiloxane type and at least one block of a radical polymer or a polyether or a polyester, - (b) copolymers of alkyl acrylates or methacrylates derived from C1-C4 alcohols, and acrylates or methacrylates of alkyl derived from C 8 -C 30 alcohols; (c) grafted or sequenced block copolymers comprising at least one block resulting from the polymerization of at least one ethylenic monomer, with conjugated ethylenic bonds, and at least one block of a vinyl or acrylic polymer or a polyether or polyester, or mixtures thereof.

  Diblock polymers are preferably used as the stabilizing agent.

  When the polymer has a glass transition temperature too high for the desired application, it can be associated with a plasticizer so as to lower this temperature of the mixture used. The plasticizer may be chosen from plasticizers usually used in the field of application and in particular from compounds that may be solvents of the polymer. Coalescing agents can also be used to help the polymer form a continuous and homogeneous deposit.

  The coalescing agents or plasticizers that can be used in the invention are especially those mentioned in document FR-A-2782 917.

  The composition may contain a plasticizer of the polymer, so as to lower the Tg of the polymer film and improve the adhesion of the polymer film to its support, particularly the keratin materials. In particular, the plasticizing compound lowers the glass transition temperature of the polymer by at least 2, 3 or 4 C, preferably from 5 ° C to 20 ° C. In a preferred embodiment, the plasticizing compound lowers, in particular, the glass transition temperature of the polymer of at least 2, 3 or 4 C, preferably 5 C to 20 C, when the plasticizer compound represents at most 10% by weight of the polymer.

  According to one embodiment, the compound may be chosen from esters of at least one carboxylic acid comprising 1 to 7 carbon atoms and a polyol comprising at least 4 hydroxyl groups.

  The polyol according to the invention may be an ose or a polyol derived from an ose, such as erythritol, xylitol or sorbitol. The polyol may be a mono- or polysaccharide comprising one to 10 monosaccharides, preferably one to four, more preferably one or two monosaccharides. The polyol may be selected from erythritol, xylitol, sorbitol, glucose, and sucrose.

  The polyol according to the invention is preferably a disaccharide. Among the disaccharides, mention may be made of sucrose (alpha-Dglucopyranosyl- (1-2) -beta-D-fructofuranose), lactose (beta-Dgalactopyranosyl- (1-4) -beta-D-glucopyranose) and maltose ( alpha-Dglucopyranosyl- (1-4) -beta-D-glucopyranose).

  The plasticizer may consist of a polyol substituted with at least two different monocarboxylic acids, or with at least three different monocarboxylic acids. The acid is preferably a monocarboxylic acid chosen in particular from acids comprising 1 to 7 carbon atoms, preferably 1 to 5 carbon atoms, for example acetic, n-propanoic, isopropanoic, n-butanoic or isobutanoic acids, tertiobutanoic, n-pentanoic and benzoic.

  According to a preferred embodiment, the ester is sucrose di-acetatehexa- (2-methylpropanoate).

  The liquid fatty phase of the composition may consist of any cosmetically or dermatologically acceptable oil, and generally physiologically acceptable, especially selected from oils of mineral, vegetable or synthetic origin, carbonaceous, hydrocarbon, fluorinated and / or silicone, alone. or mixed as long as they form a homogeneous and macroscopically stable mixture and where they are compatible with the intended use.

  The total liquid fatty phase of the composition can represent from 5% to 90% of the total weight of the composition and preferably from 20 to 85%. Advantageously, it represents at least 30% of the total weight of the composition. Preferably, this fatty phase contains at least one volatile oil.

  Volatile Oils of the Fatty Phase According to the invention, one or more volatile oils are advantageously used. These oils may be hydrocarbon oils or silicone oils optionally comprising pendant alkyl or alkoxy groups or at the end of the silicone chain.

  As the volatile silicone oil that can be used in the invention, mention may be made of linear or cyclic silicones having a viscosity at room temperature of less than 8 cSt and in particular having from 2 to 7 silicon atoms, these silicones optionally comprising alkyl or alkoxy groups having from 1 to 10 carbon atoms. As volatile silicone oil that can be used in the invention, there may be mentioned in particular octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane and their mixtures.

  As the volatile oil that may be used in the invention, isobutylene oils (also called isoparaffins) C8-C16 are particularly preferred, such as isododecane, isodecane and isohexadecane, for example the oils sold under the trade names ISOPAR. of PERMETHYL and in particular isododecane (PERMETHYL 99 A).

  The volatile oils represent in particular from 5 to 85% of the total weight of the composition, and better still from 20 to 75%.

  Synthetic Solvent of Polymer Particles The polymer dispersion can be manufactured as described in EP-A-749747.

  A mixture comprising the initial monomers and a radical initiator is prepared. This mixture is dissolved in a solvent called, in the remainder of the present description, "synthetic solvent". When the fatty phase is a non-volatile oil, the polymerization can be carried out in an apolar organic solvent (synthetic solvent), then the non-volatile oil (which must be miscible with the said synthesis solvent) is added and the synthesis solvent is selectively distilled off. .

  A synthesis solvent is chosen such that the initial monomers and the radical initiator are soluble therein, and the polymer particles obtained are insoluble therein so that they precipitate during their formation. In particular, the synthesis solvent can be chosen from alkanes such as heptane, isododecane or cyclohexane.

  When the fatty phase chosen is a volatile oil, the polymerization can be carried out directly in the said oil, which thus also acts as a synthesis solvent. The monomers must also be soluble there, as well as the radical initiator, and the polymer obtained must be insoluble.

  The monomers are preferably present in the synthesis solvent, before polymerization, in a proportion of 5-20% by weight of the reaction mixture. All of the monomers may be present in the solvent before the start of the reaction, or a portion of the monomers may be added as the polymerization reaction progresses.

  The radical initiator may be in particular azobisisobutyronitrile or tert-butylperoxy-2-ethylhexanoate.

  The volatile phase of the composition can be constituted by or comprise the synthesis solvent of the dispersed polymer particles.

  Non-volatile oil of the fatty phase The fatty phase preferably contains at least one nonpolar nonpolar oil or slightly polar.

  As a non-volatile low polar oil that can be used in the invention, mention may be made of apolines or, in particular, oils comprising an alkyl chain, in particular a C 3 -C 40 alkyl chain. As an example of apolar or low polar oils, mention may be made of: linear or branched hydrocarbons such as liquid paraffin, petroleum jelly and naphthalene oils, and hydrogenated polyisobutene; hydrocarbon oils of animal origin, such as squalene; vegetable hydrocarbon oils such as liquid triglycerides of fatty acids of at least 10 carbon atoms; esters and synthetic ethers, in particular of fatty acids, silicone oils, such as polydimethylsiloxanes (PDMS), optionally comprising a C 3 -C 40 alkyl or alkoxy chain or a phenyl chain such as phenyltrimethicones or polyalkylmethylsiloxanes, optionally fluorinated; as polymethyltrifluoropropyldimethylsiloxanes, or by functional groups such as hydroxyl, thiol and / or amine groups; polysiloxanes modified with fatty acids, fatty alcohols or polyoxyalkylenes, - fluorinated oils; - their mixtures.

  These nonpolar or nonpolar volatile oils may represent from 0.1 to 30% of the total weight of the composition, more preferably from 0.5 to 25%.

  Preferably, the nonvolatile oil is selected from esters having 10 to 40 carbon atoms, preferably monoesters of aliphatic alcohol and aliphatic carboxylic acid.

  The fatty phase may also contain a polar oil chosen from fatty acid esters of 7 to 29 carbon atoms, such as diisostearyl malate, isopropyl palmitate, diisopropyl adipate, and caprylic / capric acid triglycerides. such as those sold by Stearineries Dubois or those sold under the names Miglyol 810, 812 and 818 by Dynamit Nobel, shea butter oil, isopropyl myristate, butyl stearate, hexyl laurate , diisopropyl adipate, isononyl isononate, 2-hexyl-decyl laurate, 2-octyldecyl palmitate, myristate or 2-octyl-dodecyl lactate, 2-diethylhexyl succinate 2-ethylhexyl palmitate, octyl-2-dodecyl stearate, castor oil; the esters of lanolic acid, lauric acid and stearic acid; higher fatty alcohols (7 to 29 carbon atoms) such as stearyl alcohol, linoleic or linolenic alcohol, isostearyl alcohol, octyl 2-dodecanol, decanol, dodecanol, octadecanol or oleic alcohol; higher fatty acids (7 to 29 carbon atoms) such as myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid or isostearic acid; their mixtures.

  These non-volatile polar oils may represent from 0.1 to 10% of the total weight of the composition and better still from 1 to 5%.

  According to one particular embodiment of the invention, the liquid fatty phase contains at least one apolar volatile oil and at least one apolar non-volatile oil.

  The composition according to the invention may furthermore comprise, according to the type of application envisaged, at least one wax.

  A wax, within the meaning of the present invention, is a lipophilic fat compound, solid at room temperature (25 ° C.), with reversible solid / liquid state change, having a melting point of greater than 40 ° C. and up to 200 ° C. C, and having in the solid state an anisotropic crystalline organization. The size of the crystals is such that the crystals diffract and / or diffuse the light, conferring on the composition a cloudy, more or less opaque appearance. By bringing the wax to its melting temperature, it is possible to render it miscible with oils and to form a homogeneous mixture microscopically, but by bringing the temperature of the mixture to room temperature, a recrystallization of the wax in the oils of the mixed. It is this recrystallization in the mixture which is responsible for reducing the brightness of said mixture.

  In the context of the present invention, linear hydrocarbon waxes are preferred. Their melting point is advantageously greater than 35 ° C., for example greater than 35 ° C., preferably greater than 80 ° C.

  The linear hydrocarbon waxes are advantageously chosen from substituted linear alkanes, unsubstituted linear alkanes, linear unsubstituted alkenes, substituted linear alkenes, and an unsubstituted compound consisting solely of carbon and hydrogen. The substituents mentioned above do not contain carbon atoms.

  The linear hydrocarbon waxes include polymers and copolymers of ethylene, with a molecular weight of between 400 and 800, for example Polywax 500 or Polywax 45 400 sold by New Phase Technologies.

  Linear hydrocarbon waxes include linear paraffin waxes, such as S & P 206, S & P 173 and S & P 434 paraffins from Strahi & Pitsch.

  Linear hydrocarbon waxes include long chain linear alcohols, such as products comprising a mixture of polyethylene and alcohols containing 20 to 50 carbon atoms, especially Perforrracol 425 or Performacol 550 (mixture in proportions 20/80) sold by New Phase Technologies The waxes may be present in a proportion of 2-30% by weight in the composition and better still from 5 to 20%, preferably between 5 and 15%, in order not to reduce the brightness of the composition too much. and film deposited on the lips and / or the skin.

  The composition of the invention may, in addition, contain one or more cosmetic or dermatological active agents such as those conventionally used.

  As cosmetic, dermatological, hygienic or pharmaceutical active agents that can be used in the composition of the invention, mention may be made of moisturizers, vitamins, essential fatty acids, sphingolipids and sunscreens. These active agents are used in amounts customary to those skilled in the art and especially at concentrations of 0 to 20% and especially 0.001 to 15% of the total weight of the composition.

  The composition may furthermore comprise any other additive usually used in such compositions, such as water, antioxidants, gelling agents, perfumes, preservatives and essential oils.

  Of course, those skilled in the art will take care to choose this or these optional additional compounds, and / or their quantity, in such a way that the advantageous properties of the composition according to the invention are not, or not substantially, impaired by the addition considered.

  The composition of the cosmetic makeup product according to the invention may contain a coloring agent which may be chosen from water-soluble or fat-soluble dyes, pigments, pearlescent agents and mixtures thereof.

  By pigments, it is necessary to understand white or colored particles, mineral or organic, insoluble in the liquid organic phase, intended to color and / or opacify the composition. Pigments include mother-of-pearl.

  By nacres, it is necessary to include iridescent particles, in particular produced by certain shellfish in their shell or else synthesized, insoluble in the medium of the composition.

  By dyes, it is necessary to understand generally organic compounds soluble in fatty substances such as oils or in a hydroalcoholic phase.

  The fat-soluble dyes are, for example, Sudan Red, D & C Red No. 17, D & C Green No. 6, 13-Carotene, Soybean Oil, Sudan Brown, D & C Yellow No. 11, D & C Violet No. 2, D & C Orange No. 5, yellow quinoline, annatto, bromoacids. The water-soluble dyes are, for example, beet juice, methylene blue, caramel.

  The pigments may be white or colored, inorganic and / or organic, interferential or not. Among the inorganic pigments, titanium dioxide, optionally surface-treated, zirconium or cerium oxides, as well as oxides of zinc, iron (black, yellow or red or chromium, manganese violet) may be mentioned. , ultramarine blue, chromium hydrate and ferric blue Among the organic pigments, mention may be made of carbon black, organic lacquer-type pigments of barium, strontium, calcium or aluminum, of which those subject to certification by the Food and Drug Administration (FDA) (example D & C or FD & C) and those exempt from FDA certification as cochineal carmine lacquers Pigments can represent from 0.1 to 50% of active ingredient and in particular 0.5 at 35% and better still from 2 to 25% of the total weight of the composition.

  The pearlescent pigments may be chosen from white pearlescent pigments such as mica coated with titanium, or bismuth oxychloride, colored pearlescent pigments such as titanium mica with iron oxides, titanium mica with in particular ferric blue or chromium oxide, titanium mica with an organic pigment of the aforementioned type as well as pearlescent pigments based on bismuth oxychloride. They may represent from 0 to 25% (of active material) of the total weight of the composition and better still from 0.1 to 15% (if present). It is thus possible to use pigments with goniochromatic properties, and / or pigments with a metallic effect as described in the application filed for the number FR 0209246, the contents of which are incorporated by reference into the present application.

  The composition may contain at least one filler which may be present in a proportion of 0.001 to 35% of the total weight of the composition, preferably 0.5 to 15%.

  These include talc, mica, kaolin, starch, nylon powders (especially Orgasol), polyethylene powders, polytetrafluoroethylene (Teflon) powders, and boron nitride.

  microspheres of copolymers such as Expancel (Nobel Industry), Polytrap 603 (Dow Corning), Polypore L 200 (Chemdal Corporation), silicone resin microbeads (Toshiba Tospearl, for example), silica fillers such as Aerosil 200, Aerosil 300; Sunsphare L-31, Sunphare H-31 marketed by Asahi Glass; Chemicelen marketed by Asahi Chemical; silica and titanium dioxide composites such as the TSG series marketed by Nippon Sheet Glass - polyurethane powders, in particular crosslinked polyurethane powders comprising a copolymer, said copolymer comprising trimethylol hexyl lactone. In particular, it may be a hexamethylene diisocyanate / trimethylol hexyllactone polymer. Such particles are in particular commercially available, for example under the name PLASTIC POWDER D-400 or PLASTIC POWDER D-800 from TOSHIKI, the N-acylamino acids may comprise an acyl group having from 8 to 22 atoms. carbons, such as, for example, 2-ethylhexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl and cocoyl; for example lauroyl lysine.

  The filler may be, for example, a filler whose mean particle size is less than 100 μm, in particular between 1 and 50 μm, for example between 4 and 20 μm.

  The filler can be of any shape, essentially spherical or in the form of platelets.

  The coloring agent or filler may further be present as a particulate paste.

  The composition according to the invention, when it contains solid particles at ambient temperature, is prepared by introducing them into the composition in the form of a colloidal dispersion also called "particulate paste", as described in application WO 02/39961 whose contents are incorporated by reference in this application.

  By colloidal dispersion or "particulate paste" is meant in the sense of the invention a concentrated colloidal dispersion of particles coated or not in a continuous medium, stabilized with a dispersing agent or optionally without dispersing agent. These particles may be chosen from pigments, pearlescent agents, solid fillers and mixtures thereof. These particles may be of any shape, in particular of spherical or elongated shape such as fibers. They are insoluble in the environment.

  The dispersing agent serves to protect the dispersed particles against agglomeration or flocculation. The dispersant concentration generally used to stabilize a colloidal dispersion is from 0.3 to 5 mg / m 2, preferably from 0.5 to 4 mg / m 2, of particle surface area. This dispersing agent may be a surfactant, an oligomer, a polymer or a mixture of several of them, bearing one or more functionalities having a strong affinity for the surface of the particles to be dispersed. In particular, they can cling physically or chemically to the surface of the pigments. These dispersants have, in addition, at least one functional group compatible or soluble in the continuous medium. In particular, esters of hydroxystearic acid, in particular C 8 to C 20 fatty acids, and polyols such as glycerol, diglycerol, such as poly (12-hydroxystolic acid) stearate, are used. molecular weight of about 750 g / mol, such as the product sold under the name Solsperse 21 000 by the company Avecia, the 2-polyglyceryl dipolyhydroxystearate (CTFA name) sold under the reference Dehymyls PGPH by Henkel or the polyhydroxystearic acid such as than that sold under the reference Arlacel P100 by Uniqema and their mixtures.

  As another dispersant that may be used in the composition of the invention, mention may be made of the quaternary ammonium derivatives of polycondensed fatty acids, such as the Solsperse 17 000 sold by the company Avecia, the poly dimethylsiloxane / oxypropylene mixtures such as those sold by the Dow company. Corning under the references DC2-5185, DC2-5225 C. The polydihydroxystearic acid and esters of hydroxy-12-stearic acid are preferably intended for a hydrocarbon or fluorinated medium, while mixtures of dimethylsiloxane oxyethylene / oxypropylene are preferably for a silicone medium.

  The colloidal dispersion is a suspension of particles of generally micron size (<10 μm) in a continuous medium. The volume fraction of particles in a concentrated dispersion is 20% to 40%, preferably greater than 30%, which corresponds to a weight content of up to 70% depending on the density of the particles.

  The particles dispersed in the medium may consist of inorganic or organic particles or mixtures thereof such as those described below.

  The continuous medium of the paste may be any and contain any solvent or liquid fatty substance and mixtures thereof. Advantageously, the liquid medium of the particulate paste is one of the liquid fatty substances or oils that it is desired to use in the composition, thus forming part of the liquid fatty phase.

  Advantageously, the "particulate paste" or colloidal dispersion is a "pigment paste" containing a colloidal dispersion of colored particles, coated or not.

  These colored particles are pigments, nacres or a mixture of pigments and / or nacres.

  Advantageously, the colloidal dispersion represents from 0.5 to 60% by weight of the composition and better still from 2 to 40% and more preferably from 2 to 30%.

  The composition of the product according to the invention may be in any galenical form normally used for topical application and especially in the form of an oily or aqueous solution, an oily or aqueous gel, an oil-in-water emulsion or water-in-oil, a multiple emulsion, an oil dispersion in water through vesicles, the vesicles being located at the oil / water interface, or a powder. The composition can be fluid or solid.

  Advantageously, the composition is in continuous fat phase and preferably in anhydrous form and may contain less than 5% water, and even more preferably less than 1% water relative to the total weight of the first or second composition.

  The composition may have the appearance of a lotion, a cream, an ointment, a soft paste, an ointment, a solid cast or molded and especially stick or cup, or compacted solid.

  Preferably, the composition is in the form of a more or less rigid stick.

  The product according to the invention can be advantageously used for the makeup of the skin and / or lips and / or integuments according to the nature of the ingredients used. In particular, the product of the invention may be in the form of a solid foundation, a lipstick stick or paste, a concealer, or an eye contour, an eyeliner or a mascara. eyeshadow, body make-up product or a product for coloring the skin.

  The product is in particular a lipstick.

  The compositions of the invention can be obtained by heating the various constituents to the melting temperature of the highest waxes, then pouring the molten mixture into a mold (cup or thimble). They can also be obtained by extrusion as described in application EP-A-0 667 146.

  The invention is illustrated in more detail in the following examples. Percentages are percentages by weight.

  Example: Lipstick NAME INCI% by weight Comparative example OCTYLDODECYL NEOPENTANOATE 13,14 13,14 VP / HEXADECENE COPOLYMER 6,97 6,97 ARACHIDYL PROPIONATE 6,01 6,01 POLYBUTENE (INDOPOL H 100 from BP) 2 2 BISDIGLYCERYL POLYACYLADIPATE -2 8.01 - POLYVINYL LAURATE - 8.01 Sucrose isobutyrate acid 3 3 (EASTMAN SAIB marketed by EASTMAN CHEMICAL) BHT 0.06 0.06 POLYETHYLENE (PERFORMALENE 500 9.93 9.93 NPT) OZOKERITE (OZOKERITE WAX SP 1020 P 3.63 3.63 STRAHL & PITCH) PIGMENTS 10.25 10.25 HDI / TRIMETHYLOL HEXYLLACTONE 2 2 CROSSPOLYMER (Plastic Powder HDI) Polymer Dispersion 35 In the Comparative Example the pasty compound was replaced by a compound whose liquid fraction at 23 C is equal to 100% The brightness of Example 2 measured according to the method described above is equal to 51, while the gloss of the comparative example is equal to 32.

  Preparation of the Polymer Dispersion A dispersion of non-crosslinked copolymer of methyl acrylate and acrylic acid in a ratio of 95: 5 in isododecane was prepared according to the method of Example 1 of EP-A- 749,746, replacing heptane with isododecane. A dispersion of surface-stabilized poly (methyl acrylate / acrylic acid) particles in isododecane is thus obtained by a polystyrene / copoly (ethylene-propylene) block diblock copolymer sold under the name Kraton G1701, having a content ratio of 25% dry weight.

Claims (33)

  Cosmetic composition comprising at least one liquid fatty phase, a dispersion of particles of homopolymer or radical copolymer, acrylic or vinyl, a stabilizing polymer of said dispersion chosen from block polymers, graft polymers and random polymers and at least a pasty compound, the average gloss measured at 60 of a deposit of said composition, after being spread on a support, is greater than or equal to 35 out of 100.   2. Composition according to claim 1, characterized in that the average gloss measured at 60 is greater than or equal to 40 out of 100.   3. Cosmetic composition according to one of the preceding claims, characterized in that the average gloss measured at 60 of the composition is greater than or equal to 45, more preferably greater than or equal to 50.   4. Composition according to one of the preceding claims, characterized in that the pasty compound is such that when it is in sufficient quantity, the average gloss measured at 60 of a deposit of said composition, after being spread on a support , is greater than or equal to 35 out of 100.   5. Composition according to one of the preceding claims, characterized in that the pasty compound has a hardness at 20 C ranging from 0.001 to 0.5 MPa, in particular from 0.002 to 0.4 MPa.   6. Composition according to any one of the preceding claims, characterized in that the liquid fraction of the pasty compound at 23 C represents from 40 to 85% by weight of the compound.   7. Cosmetic composition comprising at least one liquid fatty phase, a dispersion of radicalic vinyl polymer particles dispersed in said fatty phase, a stabilizing polymer of said dispersion chosen from block polymers, graft polymers and random polymers, and at least two pasty compounds.   8. Composition according to any one of the preceding claims, characterized in that the pasty compound (s) are chosen from: - polymeric or non-polymeric silicone compounds, - polymeric or non-polymeric fluorinated compounds, - vinyl polymers, in particular: homopolymers of olefins copolymers of olefins - homopolymers and copolymers of hydrogenated dienes - linear or branched oligomers, homo or copolymers of alkyl (meth) acrylates preferably having a C 5 -C 30 alkyl group - homo oligomers and copolymers of vinyl esters having C5-C33 alkyl groups; homo- and copolymer oligomers of vinyl ethers having C5-C30 alkyl groups; liposoluble polyethers resulting from polyetherification between one or more C2-C100 diols; preferably C2-050; esters, and mixtures thereof.   9. Composition according to any one of claims 1 to 8, characterized in that the or one of the pasty compounds is polymethyl trifluoropropyl methylalkyl dimethylsiloxane.   10. Composition according to Claim 8, characterized in that the liposoluble polyether is chosen from ethylene oxide and / or propylene oxide copolymers with C6-C30 long-chain alkylene oxides, more preferably such as: the weight ratio of the ethylene oxide and / or propylene oxide with alkylene oxides in the copolymer is from 5:95 to 70:30.   11. Composition according to claim 10, characterized in that the liposoluble polyether is a polyoxyethylene / polydodecyl glycol block copolymer.   12. Composition according to claim 8, characterized in that the esters are chained among: - oligomeric glycerol esters, in particular the diglycerol esters, in particular the adipic acid and glycerol condensates, for which part of the hydroxyl groups of glycerols reacted with a mixture of fatty acids such as stearic acid, capric acid, stearic acid and isostearic acid and 12-hydroxystearic acid, - phytosterol esters, - pentaerythritol esters - esters formed from at least one alcohol, at least one of which is a Guerbet alcohol and a diacid moiety formed from at least one unsaturated fatty acid, non-crosslinked polyesters resulting from the polycondensation between a linear or branched C 4 -C 50 dicarboxylic acid or polycarboxylic acid and a C2-050 diol or polyol, - the polyesters which result from the esterification, by a polycarboxylic acid of an aliphatic hydroxycarboxylic acid ester such as the esters resulting from the esterification reaction of hydrogenated castor oil with dilinoleic acid or isostearic acid - the ester aliphatic esters resulting from the esterification of an aliphatic hydroxycarboxylic acid ester with an aliphatic carboxylic acid; 13. Composition according to any one of the preceding claims, characterized in that the or at least one of the pasty compounds is hydrocarbon.   14. Composition according to any one of the preceding claims, characterized in that it comprises at least two pasty compounds chosen from pasty esters.   15. Composition according to one of the preceding claims, characterized in that the polymer particles have a mean size of between 5 and 800 nm.   16. Composition according to one of the preceding claims, characterized in that the polymer particles are insoluble in water-soluble alcohols.   17. Composition according to one of the preceding claims, characterized in that the polymer particles are chosen from acrylic polymers or copolymers.   18. Composition according to one of the preceding claims, characterized in that the polymer is film-forming.   19. Composition according to one of the preceding claims, characterized in that the polymer represents, in dry matter, from 5 to 40% of the total weight of the composition, preferably from 5 to 35% and better still from 8 to 30% .   20. Composition according to one of the preceding claims, characterized in that the stabilizer is a grafted or sequenced block polymer, comprising at least one block resulting from the polymerization of diene and at least one block of a vinyl polymer.   21. Composition according to the preceding claim, characterized in that the stabilizer is a diblock polymer.   22. Composition according to one of the preceding claims, characterized in that it comprises a plasticizer of the polymer.   23. Composition according to the preceding claim, characterized in that the plasticizer of the polymer is chosen from esters of at least one carboxylic acid comprising 1 to 7 carbon atoms and a polyol comprising at least 4 hydroxyl groups.   24. Composition according to one of the preceding claims, wherein the liquid fatty phase comprises a non-volatile fatty phase and a volatile fatty phase.   25. Composition according to the preceding claim, characterized in that the volatile liquid fatty phase contains isododecane or isohexadecane.   26. The composition of claim 25, wherein the non-volatile liquid fatty phase comprises at least one ester oil.   27. Composition according to claim 26, characterized in that the ester oil is chosen from aliphatic alcohol and aliphatic carboxylic acid monoesters.   28. Composition according to one of the preceding claims, characterized in that it contains at least one wax.   29. Composition according to one of the preceding claims, in the form of a stick or stick, in the form of a flexible paste, or in the form of a liquid.   30. Composition according to one of the preceding claims, being in anhydrous form.   31. Composition according to one of the preceding claims, being in the form of a care product and / or makeup of the skin and / or lips.   32. Composition according to one of the preceding claims, in the form of a foundation, a blush or an eyeshadow, a lipstick, a base or balm care for the lips, a concealer, an eyeliner, a mascara.   33. A method of cosmetic care or makeup of the lips or the skin, comprising applying to the lips or the skin respectively a cosmetic composition as defined in the preceding claims.