FR2794997A1 - Solid oil-in-water emulsion for use in make-up products for skin, mucous membranes and-or keratin fibers, comprises aqueous phase containing gellane, at least one oil, and surfactant system - Google Patents
Solid oil-in-water emulsion for use in make-up products for skin, mucous membranes and-or keratin fibers, comprises aqueous phase containing gellane, at least one oil, and surfactant system Download PDFInfo
- Publication number
- FR2794997A1 FR2794997A1 FR9907767A FR9907767A FR2794997A1 FR 2794997 A1 FR2794997 A1 FR 2794997A1 FR 9907767 A FR9907767 A FR 9907767A FR 9907767 A FR9907767 A FR 9907767A FR 2794997 A1 FR2794997 A1 FR 2794997A1
- Authority
- FR
- France
- Prior art keywords
- sep
- emulsion
- emulsion according
- weight
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000007787 solid Substances 0.000 title claims abstract description 13
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 10
- 239000000835 fiber Substances 0.000 title claims abstract description 9
- 239000008346 aqueous phase Substances 0.000 title claims abstract description 8
- 102000011782 Keratins Human genes 0.000 title claims abstract description 7
- 108010076876 Keratins Proteins 0.000 title claims abstract description 7
- 239000007764 o/w emulsion Substances 0.000 title claims abstract description 4
- 210000004400 mucous membrane Anatomy 0.000 title description 5
- 239000000839 emulsion Substances 0.000 claims abstract description 68
- 238000000034 method Methods 0.000 claims abstract description 7
- 210000004209 hair Anatomy 0.000 claims abstract description 5
- 238000004043 dyeing Methods 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 26
- 239000012071 phase Substances 0.000 claims description 26
- -1 glycol ethers Chemical class 0.000 claims description 25
- 239000000049 pigment Substances 0.000 claims description 18
- 239000003921 oil Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 229920002148 Gellan gum Polymers 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 8
- 239000011777 magnesium Substances 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 229910052791 calcium Inorganic materials 0.000 claims description 7
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 7
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical group [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 239000010445 mica Substances 0.000 claims description 6
- 229910052618 mica group Inorganic materials 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- 239000010936 titanium Substances 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 5
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 239000011575 calcium Substances 0.000 claims description 5
- 229940075529 glyceryl stearate Drugs 0.000 claims description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- 229920000881 Modified starch Polymers 0.000 claims description 4
- 239000004368 Modified starch Substances 0.000 claims description 4
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 4
- 229930006000 Sucrose Natural products 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 150000001298 alcohols Chemical class 0.000 claims description 4
- 229940073609 bismuth oxychloride Drugs 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 235000019426 modified starch Nutrition 0.000 claims description 4
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- 229950011392 sorbitan stearate Drugs 0.000 claims description 4
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000005720 sucrose Substances 0.000 claims description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 4
- 150000003626 triacylglycerols Chemical class 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 3
- 239000001639 calcium acetate Substances 0.000 claims description 3
- 229960005147 calcium acetate Drugs 0.000 claims description 3
- 235000011092 calcium acetate Nutrition 0.000 claims description 3
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical group [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229940100460 peg-100 stearate Drugs 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229920000193 polymethacrylate Polymers 0.000 claims description 3
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims description 3
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims description 3
- 229940113124 polysorbate 60 Drugs 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 2
- GYDYJUYZBRGMCC-INIZCTEOSA-N (2s)-2-amino-6-(dodecanoylamino)hexanoic acid Chemical compound CCCCCCCCCCCC(=O)NCCCC[C@H](N)C(O)=O GYDYJUYZBRGMCC-INIZCTEOSA-N 0.000 claims description 2
- 241001133760 Acoelorraphe Species 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 244000144725 Amygdalus communis Species 0.000 claims description 2
- 235000011437 Amygdalus communis Nutrition 0.000 claims description 2
- 235000017060 Arachis glabrata Nutrition 0.000 claims description 2
- 244000105624 Arachis hypogaea Species 0.000 claims description 2
- 235000010777 Arachis hypogaea Nutrition 0.000 claims description 2
- 235000018262 Arachis monticola Nutrition 0.000 claims description 2
- 240000002791 Brassica napus Species 0.000 claims description 2
- 235000004977 Brassica sinapistrum Nutrition 0.000 claims description 2
- ONAIRGOTKJCYEY-XXDXYRHBSA-N CCCCCCCCCCCCCCCCCC(O)=O.O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 Chemical compound CCCCCCCCCCCCCCCCCC(O)=O.O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 ONAIRGOTKJCYEY-XXDXYRHBSA-N 0.000 claims description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 2
- 241001246270 Calophyllum Species 0.000 claims description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- 244000060011 Cocos nucifera Species 0.000 claims description 2
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 2
- 241000208467 Macadamia Species 0.000 claims description 2
- 239000004677 Nylon Substances 0.000 claims description 2
- 240000007817 Olea europaea Species 0.000 claims description 2
- 239000005662 Paraffin oil Substances 0.000 claims description 2
- 244000025272 Persea americana Species 0.000 claims description 2
- 235000008673 Persea americana Nutrition 0.000 claims description 2
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 claims description 2
- 229920002701 Polyoxyl 40 Stearate Polymers 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 244000000231 Sesamum indicum Species 0.000 claims description 2
- 235000003434 Sesamum indicum Nutrition 0.000 claims description 2
- 244000044822 Simmondsia californica Species 0.000 claims description 2
- 235000004433 Simmondsia californica Nutrition 0.000 claims description 2
- 239000004809 Teflon Substances 0.000 claims description 2
- 229920006362 Teflon® Polymers 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 2
- IJCWFDPJFXGQBN-RYNSOKOISA-N [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-octadecanoyloxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCCCC IJCWFDPJFXGQBN-RYNSOKOISA-N 0.000 claims description 2
- 239000000980 acid dye Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 239000001000 anthraquinone dye Substances 0.000 claims description 2
- 239000010477 apricot oil Substances 0.000 claims description 2
- 239000000987 azo dye Substances 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000001110 calcium chloride Substances 0.000 claims description 2
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 claims description 2
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 2
- DRVWBEJJZZTIGJ-UHFFFAOYSA-N cerium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Ce+3].[Ce+3] DRVWBEJJZZTIGJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
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- 229940071160 cocoate Drugs 0.000 claims description 2
- 125000005534 decanoate group Chemical class 0.000 claims description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 150000002191 fatty alcohols Chemical group 0.000 claims description 2
- 150000002194 fatty esters Chemical class 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 229930182478 glucoside Natural products 0.000 claims description 2
- 150000008131 glucosides Chemical class 0.000 claims description 2
- 125000005456 glyceride group Chemical group 0.000 claims description 2
- 229940100242 glycol stearate Drugs 0.000 claims description 2
- 229940087559 grape seed Drugs 0.000 claims description 2
- IIRDTKBZINWQAW-UHFFFAOYSA-N hexaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCO IIRDTKBZINWQAW-UHFFFAOYSA-N 0.000 claims description 2
- 229910052588 hydroxylapatite Inorganic materials 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 claims description 2
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- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
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- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 229940105112 magnesium myristate Drugs 0.000 claims description 2
- 229940091250 magnesium supplement Drugs 0.000 claims description 2
- DMRBHZWQMKSQGR-UHFFFAOYSA-L magnesium;tetradecanoate Chemical compound [Mg+2].CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O DMRBHZWQMKSQGR-UHFFFAOYSA-L 0.000 claims description 2
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- 125000005474 octanoate group Chemical class 0.000 claims description 2
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- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 claims description 2
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- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 2
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- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
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- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
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- 238000003756 stirring Methods 0.000 description 2
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- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
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- 235000013399 edible fruits Nutrition 0.000 description 1
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- 238000005187 foaming Methods 0.000 description 1
- 239000000216 gellan gum Substances 0.000 description 1
- 235000010492 gellan gum Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 150000002315 glycerophosphates Chemical class 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- RFDAIACWWDREDC-FRVQLJSFSA-N glycocholic acid Chemical compound C([C@H]1C[C@H]2O)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(=O)NCC(O)=O)C)[C@@]2(C)[C@@H](O)C1 RFDAIACWWDREDC-FRVQLJSFSA-N 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 150000003893 lactate salts Chemical class 0.000 description 1
- 229960005375 lutein Drugs 0.000 description 1
- KBPHJBAIARWVSC-RGZFRNHPSA-N lutein Chemical compound C([C@H](O)CC=1C)C(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\[C@H]1C(C)=C[C@H](O)CC1(C)C KBPHJBAIARWVSC-RGZFRNHPSA-N 0.000 description 1
- 235000001055 magnesium Nutrition 0.000 description 1
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Inorganic materials [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 150000004701 malic acid derivatives Chemical class 0.000 description 1
- 239000011565 manganese chloride Substances 0.000 description 1
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- 229940099607 manganese chloride Drugs 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
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- 239000012528 membrane Substances 0.000 description 1
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- 230000001333 moisturizer Effects 0.000 description 1
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- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- ATINCSYRHURBSP-UHFFFAOYSA-K neodymium(iii) chloride Chemical compound Cl[Nd](Cl)Cl ATINCSYRHURBSP-UHFFFAOYSA-K 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 230000010363 phase shift Effects 0.000 description 1
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229950008882 polysorbate Drugs 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
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- 230000035807 sensation Effects 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
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- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 150000003408 sphingolipids Chemical class 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001631 strontium chloride Inorganic materials 0.000 description 1
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 150000003892 tartrate salts Chemical class 0.000 description 1
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 description 1
- 239000004149 tartrazine Substances 0.000 description 1
- 235000012756 tartrazine Nutrition 0.000 description 1
- 229960000943 tartrazine Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- KBPHJBAIARWVSC-XQIHNALSSA-N trans-lutein Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2C(=CC(O)CC2(C)C)C KBPHJBAIARWVSC-XQIHNALSSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- NFMWFGXCDDYTEG-UHFFFAOYSA-N trimagnesium;diborate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]B([O-])[O-].[O-]B([O-])[O-] NFMWFGXCDDYTEG-UHFFFAOYSA-N 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
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- FJHBOVDFOQMZRV-XQIHNALSSA-N xanthophyll Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2C=C(C)C(O)CC2(C)C FJHBOVDFOQMZRV-XQIHNALSSA-N 0.000 description 1
- 235000008210 xanthophylls Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/34—Higher-molecular-weight carboxylic acid esters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/0229—Sticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/062—Oil-in-water emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Description
La présente invention concerne une émulsion H/E solide, ainsi que son utilisation dans le domaine cosmétique, notamment pour le maquillage de la peau et/ou des muqueuses et/ou des fibres kératiniques. The present invention relates to a solid O / W emulsion, as well as its use in the cosmetics field, in particular for making up the skin and / or mucous membranes and / or keratinous fibers.
On connaît dans l'industrie cosmétique des produits se présentant sous forme solide. Comme produits de ce type, on peut citer par exemple dans le domaine du maquillage, les bâtons ou "sticks" de rouge à lèvres, de fond de teint ou d'ombre à paupières ; dans le domaine du soin de la peau ou des lèvres, les crayons réparateurs des lèvres, les bâtons ou "sticks" dépigmentants, démaquillants ou hydratants ; dans le domaine de l'hygiène, les sticks déodorants, les sticks ou les pains moussants pour le rasage ou pour le lavage de la peau. In the cosmetics industry, products are known in solid form. Such products include, for example, in the field of make-up, sticks or "sticks" of lipstick, foundation or eye shadow; in the field of skin or lip care, lip repair pencils, depigmenting, makeup or moisturizing sticks or "sticks"; in the field of hygiene, deodorant sticks, sticks or foaming sticks for shaving or for washing the skin.
II est en effet particulièrement intéressant de disposer de produits sous forme de sticks dans la mesure où de tels produits sont très pratiques à utiliser, ils sont facilement transportables, le produit ne risque pas de couler. It is indeed particularly advantageous to have products in the form of sticks insofar as such products are very practical to use, they are easily transportable, the product is not likely to flow.
Par ailleurs, les produits de maquillage sont assez généralement formulés sur la base d'une part d'une phase grasse pour des raisons de confort et de douceur et d'autre part d'une phase pulvérulente qui apporte la couleur souhaitée. Cette phase pulvérulente peut comprendre des pigments et/ou des charges et/ou des nacres. La phase grasse comprend généralement des cires et/ou des composés pâteux qui structurent les sticks. Moreover, the make-up products are quite generally formulated on the basis of a part of a fatty phase for reasons of comfort and softness and secondly of a pulverulent phase which provides the desired color. This pulverulent phase may comprise pigments and / or fillers and / or nacres. The fatty phase generally comprises waxes and / or pasty compounds which structure the sticks.
Or, les sticks formulés à base de cires présentent certains inconvénients : ils ont un caractère gras qui n'est pas apprécié par les utilisateurs et ils manquent de fraîcheur à l'application. En outre, il est difficile d'y introduire des actifs hydrophiles. However, wax-based sticks have certain disadvantages: they have a greasy character that is not appreciated by users and they lack freshness on application. In addition, it is difficult to introduce hydrophilic active agents.
On cherche donc de plus en plus à faire des sticks de maquillage comprenant une phase aqueuse dans la plus grande concentration possible. Toutefois, les sticks comprenant une phase aqueuse importante sont parfois sujets à des problèmes de stabilité et de manque de cohésion. En particulier, ces gels, qui sont réalisés à partir de l'association d'un gélifiant hydrophile et d'eau ont l'inconvénient d'être fragiles et peuvent se casser facilement lors de l'utilisation. Un moyen d'améliorer la solidité des gels est d'augmenter la concentration en gélifiant hydrophile mais les gels deviennent alors difficilement délitables, c'est-à- dire que le prélèvement de matière lors de la prise de produit est insuffisante. We therefore seek more and more to make makeup sticks comprising an aqueous phase in the largest possible concentration. However, the sticks comprising a large aqueous phase are sometimes subject to problems of stability and lack of cohesion. In particular, these gels, which are made from the combination of a hydrophilic gelling agent and water have the disadvantage of being fragile and can break easily during use. One way of improving the strength of the gels is to increase the concentration of hydrophilic gelling agent, but the gels then become difficult to break down, that is to say that the removal of material during the taking of product is insufficient.
Par ailleurs, les sticks aqueux exempts de phase grasse provoquent à l'application des sensations de déssèchement et de tiraillement de la peau, effets jugés indésirables par les utilisateurs. In addition, aqueous sticks free of fatty phase cause the application of sensations of drying and tugging of the skin, effects deemed undesirable by users.
Aussi, il subsiste le besoin d'une composition solide pouvant être utilisée par application directe sur la peau ou à l'aide d'une éponge, délitant bien, confortable, procurant à l'application un effet fraîcheur sans effet de tiraillement ou de déssèchement. La demanderesse a découvert de façon inattendue qu'en associant à un gélifiant hydrophile particulier, à savoir du gellane, une huile et un système tensioactif spécifique, il était possible de réaliser des émulsions solides pouvant se déliter facilement et apportant de la fraîcheur sans effet de tiraillement ou de déssèchement. Also, there remains the need for a solid composition that can be used by direct application to the skin or with the aid of a sponge, disintegrating well, comfortable, providing the application a freshness without tugging or drying effect . The Applicant has unexpectedly discovered that by associating with a particular hydrophilic gelling agent, namely gellan, an oil and a specific surfactant system, it was possible to produce solid emulsions which can be easily disintegrated and providing freshness without any effect. tugging or drying.
La présente invention porte donc sur une émulsion huile-dans-eau (HIE) solide comprenant i) une phase aqueuse gélifiée par du gellane, ii) une phase grasse comprenant au moins une huile et iii) un système tensioactif de HLB supérieur ou égal à 7. The present invention thus relates to a solid oil-in-water emulsion (HIE) comprising i) an aqueous phase gelled with gellan, ii) a fatty phase comprising at least one oil and iii) a surfactant system of HLB greater than or equal to 7.
Les émulsions selon l'invention sont particulièrement confortables : elles s'appliquent facilement, apportent une sensation de fraîcheur et de douceur. Elles ne provoquent pas de sensation de tiraillement ou de déssèchement de la peau après application. Elles présentent d'excellentes propriétés cosmétiques: The emulsions according to the invention are particularly comfortable: they are easily applied, bring a feeling of freshness and softness. They do not cause a feeling of tightness or dryness of the skin after application. They have excellent cosmetic properties:
Les émulsions de l'invention présentent des qualités d'application et de délitage excellentes. En particulier, grâce à l'association selon l'invention, on obtient, à dureté équivalente, un niveau de délitage supérieur à celui des sticks connus. La prise du produit est facile, elle peut s'effectuer directement sur le corps ou avec le doigt ou encore à l'éponge, en prélevant une quantité suffisante de produit, facile à appliquer ensuite sur la peau de façon homogène, sans nécessiter de mouillage préalable. Le maquillage obtenu est uniforme et homogène. The emulsions of the invention have excellent application and disintegration qualities. In particular, thanks to the combination according to the invention, there is obtained, at equivalent hardness, a disintegration level higher than that of known sticks. Taking the product is easy, it can be done directly on the body or with the finger or sponge, by removing a sufficient amount of product, easy to apply then on the skin homogeneously, without the need for wetting prior. The makeup obtained is uniform and homogeneous.
Ces émulsions présentent par ailleurs une excellente cohésion. Elles sont stables dans le temps et à la température. Ainsi, après avoir été conservés deux mois à température ambiante ou à 45 C, elles ne présentent aucun phénomène de synérèse (exsudation) ou encore de déphasage : leur aspect et leur dureté n'ont pas varié. These emulsions also have excellent cohesion. They are stable over time and temperature. Thus, after having been stored for two months at room temperature or at 45 ° C., they show no syneresis phenomenon (exudation) or phase shift: their appearance and their hardness have not varied.
Les émulsions selon l'invention n'exsudent pas, même à de faibles taux de gélifiant, et ils ne nécessitent pas obligatoirement l'intervention d'une technique de préparation particulière. The emulsions according to the invention do not exude, even at low levels of gelling agent, and they do not necessarily require the intervention of a particular preparation technique.
La présente invention a également pour objet un produit de maquillage de la peau ou des fibres kératiniques comprenant une émulsion telle que définie ci- dessus. The present invention also relates to a product for making up the skin or keratin fibers comprising an emulsion as defined above.
La présente invention a encore pour objet un procédé de maquillage de la peau et/ou des muqueuses et/ou des fibres kératiniques, consistant à appliquer sur ces dernières, une émulsion et/ou un produit de maquillage solides tels que définis ci- dessus. The present invention also relates to a process for making up the skin and / or mucous membranes and / or keratinous fibers, comprising applying thereon, a solid emulsion and / or makeup product as defined above.
Au sens de la présente invention, on entend par composition solide, une composition présentant une dureté définie par une force maximum avant rupture allant de 5 à 130 grammes, à température ambiante (20-25 C), après pénétration par un mobile en inox de 2 mm de diamètre dans la matrice de la composition à une épaisseur de 1 mm à une vitesse de 1 mm/s et retrait dudit mobile de la matrice de la composition à une vitesse de 2 mm/s ; la force maximum avant rupture étant mesurée avec un analyseur de texture du type "TAXT2" commercialisé par la Société RHEO. For the purposes of the present invention, the term "solid composition" is intended to mean a composition having a hardness defined by a maximum force before rupture ranging from 5 to 130 grams, at ambient temperature (20-25 ° C.), after penetration by a stainless steel mobile of 2 mm in diameter in the matrix of the composition at a thickness of 1 mm at a speed of 1 mm / s and removal of said mobile from the matrix of the composition at a speed of 2 mm / s; the maximum force before rupture being measured with a texture analyzer of the "TAXT2" type marketed by the company RHEO.
Les émulsions selon l'invention comprennent une phase aqueuse gélifiée par du gellane. Comme gellane, on peut citer la gomme de gellane vendue sous la dénomination commerciale Kelcogel F par la société Nutrasweet-Kelco. The emulsions according to the invention comprise an aqueous phase gelled with gellan. As gellan, mention may be made of gellan gum sold under the trade name Kelcogel F by Nutrasweet-Kelco.
Le gellane est de préférence présent dans l'émulsion selon l'invention à une concentration allant de 0,05 à 10%, de préférence encore de 0,5 à 3%, en poids, par rapport au poids total de l'émulsion. The gellan is preferably present in the emulsion according to the invention at a concentration ranging from 0.05 to 10%, more preferably from 0.5 to 3%, by weight, relative to the total weight of the emulsion.
La phase aqueuse des émulsions de l'invention peut également comprendre un gélifiant hydrophile autre que le gellane, comme les polysaccharides autres que le gellane ou les dérivés de protéines, les gels de synthèse ou d'hémisynthèse de type polyester, en particulier sulfonique, les polyacrylates ou polyméthacrylates et leurs dérivés. The aqueous phase of the emulsions of the invention may also comprise a hydrophilic gelling agent other than gellan, such as polysaccharides other than gellan or protein derivatives, synthetic or semisynthetic gels of the polyester type, in particular the sulphonic type, the polyacrylates or polymethacrylates and their derivatives.
Les émulsions selon l'invention peuvent également comprendre une eau florale telle que l'eau de bleuet et/ou une eau minérale telle que l'eau de VITTEL, l'eau de LUCAS ou l'eau de LA ROCHE POSAY et/ou une eau thermale. The emulsions according to the invention may also comprise a floral water such as cornflower water and / or mineral water such as VITTEL water, LUCAS water or LA ROCHE POSAY water and / or thermal water.
Les émulsions selon l'invention peuvent également comprendre des colorants hydrosolubles choisis parmi les colorants usuels du domaine considéré tels que le sel disodique de ponceau, le sel disodique du vert d'alizarine, le jaune de quinoléine, le sel trisodique d'amarante, le sel disodique de tartrazine, le sel monosodique de rhodamine, le sel disodique de fuchsine, la xanthophylle. The emulsions according to the invention may also comprise water-soluble dyes chosen from the usual dyes of the field in question, such as the disodium salt of a culvert, the disodium salt of alizarin green, the yellow of quinoline, the trisodium salt of amaranth, the disodium salt of tartrazine, monosodium salt of rhodamine, disodium salt of fuchsin, xanthophyll.
De préférence, les émulsions selon l'invention comprennent jusqu'à 99,95% en poids, de préférence de 30 à 99,5% en poids, par rapport au poids total de l'émulsion, d'eau. Preferably, the emulsions according to the invention comprise up to 99.95% by weight, preferably from 30 to 99.5% by weight, relative to the total weight of the emulsion, of water.
Les émulsions selon l'invention peuvent également comprendre des solvants autres que l'eau comme par exemple les alcools primaires tels que l'éthanol et l1sopropanol, les glycols tels que le propylène glycol, le butylène glycol, le dipropylène glycol, le diéthylène glycol, les éthers de glycol tel que les alkyl(Cl - C4)éther de mono, di- ou tripropylène glycol, mono, di- ou triéthylène" glycol, et leurs mélanges. The emulsions according to the invention may also comprise solvents other than water, for example primary alcohols such as ethanol and isopropanol, glycols such as propylene glycol, butylene glycol, dipropylene glycol and diethylene glycol. glycol ethers such as mono-, di- or tripropylene glycol (C1-C4) alkyl, mono-, di- or triethylene glycol, and mixtures thereof.
Les émulsions selon l'invention comprennent également une phase grasse qui comprend au moins une huile. Par huile, on entend, au sens de la présente invention, un corps gras liquide à température ambiante (25 C). The emulsions according to the invention also comprise a fatty phase which comprises at least one oil. For the purposes of the present invention, the term "oil" means a fat that is liquid at room temperature (25 ° C.).
Parmi les huiles utilisables, on peut citer les huiles d'origine animale, végétale ou minérale, telles que l'huile de paraffine, de vaseline, le perhydrosqualène, l'huile d'abricot, l'huile de germes de blé, d'amande douce, de calophyllum, de sésame, de macadamia, de pépins de raisin, de colza, de coprah, d'arachide, de palme, de ricin, d'avocat, de jojoba, d'olive ou de germes de céréales; des esters d'acides gras et de polyol, en particulier les triglycérides liquides; des alcools; des acétylglycérides; des octanoates, décanoates ou ricinoléates d'alcools ou de polyalcools; des triglycérides d'acides gras; des glycérides, les huiles fluorées et perfluorées; les huiles de synthèse telles que les esters gras; les huiles de silicone telles que les huiles de silicone volatile, les polyméthylsiloxanes, les polyméthylphénylsiloxanes, les polysiloxanes modifiés par des acides gras, des alcools gras ou des polyoxyalkylènes, les silicones fluorées, les huiles perfluorées et leurs mélanges. Among the oils that can be used, mention may be made of oils of animal, vegetable or mineral origin, such as paraffin oil, petroleum jelly, perhydrosqualene, apricot oil, wheat germ oil, sweet almond, calophyllum, sesame, macadamia, grape seed, rapeseed, copra, peanut, palm, castor oil, avocado, jojoba, olive or grain sprouts; esters of fatty acids and polyol, in particular liquid triglycerides; alcohols; acetylglycerides; octanoates, decanoates or ricinoleates of alcohols or polyalcohols; triglycerides of fatty acids; glycerides, fluorinated and perfluorinated oils; synthetic oils such as fatty esters; silicone oils such as volatile silicone oils, polymethylsiloxanes, polymethylphenylsiloxanes, polysiloxanes modified with fatty acids, fatty alcohols or polyoxyalkylenes, fluorinated silicones, perfluorinated oils and mixtures thereof.
De préférence, les émulsions selon l'invention sont exemptes de cires. Par cire, on entend, au sens de la présente invention, un corps gras solide ou pâteux à température ambiante (25 C), c'est-à-dire un composé présentant un point de fusion allant de 25 à 130 C. Preferably, the emulsions according to the invention are free of waxes. For the purposes of the present invention, the term "wax" means a solid or pasty fatty substance at ambient temperature (25 ° C.), that is to say a compound having a melting point ranging from 25 to 130 ° C.
La phase grasse peut être présente dans des proportions allant, par exemple, jusqu'à 70%, de préférence de 5% à 50% en poids, par rapport au poids total de l'émulsion. The fatty phase may be present in proportions ranging, for example, up to 70%, preferably from 5% to 50% by weight, relative to the total weight of the emulsion.
Les compositions selon l'invention comprennent également un système tensioactif H/E de HLB (hydrophile-lipophile balance) supérieur ou égal à 7, habituellement utilisés dans les domaines cosmétique. Comme système tensioactif H/E, on peut citer notamment (CTFA) : le cétéaryl-glucoside, le sucrose stéarate, le PEG-40 stéarate, le sorbitan tristéarate, le sorbitan stéarate, le polysorbate 60, le mélange sorbitan stéarate/sucrose cocoate, le mélange de glycéryl stéarate/PEG-100 stéarate, le PEG-400, le stéarate de glycéryle, le mélange de PEG-6/PEG-32/glycol stéarate, et leurs mélanges. The compositions according to the invention also comprise a surfactant system H / E of HLB (hydrophilic-lipophilic balance) greater than or equal to 7, usually used in the cosmetics fields. As O / W surfactant system, mention may be made in particular (CTFA): cetearyl glucoside, sucrose stearate, PEG-40 stearate, sorbitan tristearate, sorbitan stearate, polysorbate 60, sorbitan stearate / sucrose cocoate mixture, the mixture of glyceryl stearate / PEG-100 stearate, PEG-400, glyceryl stearate, the mixture of PEG-6 / PEG-32 / glycol stearate, and mixtures thereof.
On peut particulièrement citer le mélange de glycéryl stéarate/PEG-100 stéarate vendu sous la dénomination commerciale Arlacel 165 FL par la société Unichema, le monostéarate de sorbitane oxyéthyléné 20 OE (oxyde d'éthylène) vendu sous la dénomination commerciale Polysorbate 60 par la société Unichema, le monostéarate de polyéthylène glycol 8 OE vendu sous la dénomination commerciale Estol 3646 par la société Unichema, le mono-di palmitato stéarate de sucrose vendu sous la dénomination commerciale Tegosoft PSE 141 G par la société Goldschmidt. Mention may be made in particular of the glyceryl stearate / PEG-100 stearate mixture sold under the trade name Arlacel 165 FL by the company Unichema, the oxyethylenated sorbitan monostearate 20 EO (ethylene oxide) sold under the trade name Polysorbate 60 by the company Unichema, polyethylene glycol 8 OE monostearate sold under the trade name Estol 3646 by the company Unichema, the sucrose mono-di palmitato stearate sold under the trade name Tegosoft PSE 141 G by the company Goldschmidt.
Le système tensioactif est de préférence présent dans les émulsions selon l'invention à une teneur allant de 0,1% à 15%, de préférence de 0,5% à 7%, en poids, par rapport au poids total de l'émulsion. The surfactant system is preferably present in the emulsions according to the invention at a content ranging from 0.1% to 15%, preferably from 0.5% to 7%, by weight, relative to the total weight of the emulsion. .
Les émulsions selon l'invention peuvent également comprendre une phase pulvérulente qui peut comprendre un pigment et/ou une nacre et/ou une charge. Par pigments, il faut comprendre des particules blanches ou colorées, minérales ou organiques, insolubles dans le milieu, destinées à colorer et/ou opacifier la composition. The emulsions according to the invention may also comprise a pulverulent phase which may comprise a pigment and / or a nacre and / or a filler. By pigments, one must understand white or colored particles, mineral or organic, insoluble in the medium, intended to color and / or opacify the composition.
Les pigments peuvent être présents à raison de 0-40 % en poids, par rapport au poids total de l'émulsion, de préférence à raison de 0,1 à 30% et de préférence encore à raison de 1-20 %. Ils peuvent être blancs ou colorés, minéraux et/ou organiques, de taille usuelle ou nanométrique. Par taille nanométrique, on entend des pigments dont la taille moyenne des particules va de 5 à 100 nm. On peut citer, parmi les pigments et les nanopigments minéraux, les dioxydes de titane, de zirconium ou de cérium, ainsi que les oxydes de zinc, de fer ou de chrome, les nanotitanes, le bleu ferrique. Parmi les pigments organiques, on peut citer le noir de carbone, et les laques couramment employées pour conférer aux lèvres et à la peau un effet de maquillage, qui sont des sels de calcium, de baryum, d'aluminium ou de zirconium, de colorants acides tels que les colorants halogéno-acides, azoïques ou anthraquinoniques. The pigments may be present in a proportion of 0-40% by weight, relative to the total weight of the emulsion, preferably in the proportion of 0.1 to 30% and more preferably in the proportion of 1-20%. They may be white or colored, inorganic and / or organic, of usual or nanometric size. Nanoscale means pigments whose average particle size ranges from 5 to 100 nm. Among the pigments and mineral nanopigments, mention may be made of titanium, zirconium or cerium dioxides, as well as oxides of zinc, iron or chromium, nanotitans and ferric blue. Among the organic pigments, mention may be made of carbon black, and the lacquers commonly used to give the lips and the skin a make-up effect, which are calcium, barium, aluminum or zirconium salts, dyes acids such as halo-acid, azo or anthraquinone dyes.
Les pigments peuvent notamment être enrobés par des composés siliconés tels que des PDMS et/ou par des polymères, notamment des polyéthylènes ou encore par des composés fluorés. On peut ainsi citer les pigments SA de Maprecos ou les pigments PI de Myoshi. The pigments may in particular be coated with silicone compounds such as PDMSs and / or with polymers, in particular polyethylenes or with fluorinated compounds. The SA pigments from Maprecos or the PI pigments from Myoshi can be mentioned.
Par nacres, il faut comprendre des particules irisées qui réfléchissent la lumière. Les nacres peuvent être présentes dans l'émulsion à raison de 0-40% en poids, de préférence à raison de 0,1 à 30% et de préférence encore à raison de 1-20% en poids. By nacres, we must understand iridescent particles that reflect light. The nacres may be present in the emulsion in a proportion of 0-40% by weight, preferably in the range of 0.1 to 30% and more preferably in a proportion of 1 to 20% by weight.
Parmi les nacres envisageables, on peut citer la nacre naturelle, le mica recouvert d'oxyde de titane, d'oxyde de fer, de pigment naturel ou d'oxychlorure de bismuth ainsi que le mica titane coloré. Among the nacres that can be envisaged, mention may be made of natural mother-of-pearl, mica coated with titanium oxide, with iron oxide, with natural pigment or with bismuth oxychloride, and with colored titanium mica.
Par charges, il faut comprendre des particules incolores ou blanches, minérales ou de synthèse, lamellaires ou non lamellaires, destinées à donner du corps ou de la rigidité à la composition, et/ou de la douceur, de la matité et de l'uniformité au maquillage. By fillers, it is necessary to include colorless or white particles, mineral or synthetic, lamellar or non-lamellar, intended to give the body or rigidity to the composition, and / or softness, dullness and uniformity make-up.
Les charges, qui peuvent être présentes dans l'émulsion à raison de 0-60 % en poids, par rapport au poids total de l'émulsion, de préférence à raison de 0,1 à 40%, de préférence encore 1-20%, peuvent être minérales ou de synthèse, lamellaires ou non lamellaires. The fillers, which may be present in the emulsion in a proportion of 0-60% by weight, relative to the total weight of the emulsion, preferably in a proportion of 0.1 to 40%, more preferably 1-20% may be mineral or synthetic, lamellar or non-lamellar.
On peut citer le talc, le mica, la silice, le kaolin, les poudres de Nylon, de poly-p- alanine et de polyéthylène, le Téflon, la lauroyl-lysine, l'amidon éventuellement modifié et ses dérivés, le nitrure de bore, l'oxychlorure de bismuth, les poudres de polymères de tétrafluoroéthylène, les poudres de polyméthylméthacrylate, les poudres de polyuréthanne, les poudres de polystyrène, les poudres de polyester, les microsphères creuses synthétiques, les microéponges, les microbilles de résine de silicone, les oxydes de zinc et de titane, les oxydes de zirconium ou de cérium, le carbonate de calcium précipité, le carbonate et l'hydrocarbonate de magnésium, l'hydroxyapatite, les microsphères de silice creuses, les microcapsules de verre ou de céramique, les savons métalliques dérivés d'acides organiques carboxyliques ayant de 8 à 22 atomes de carbone, de préférence de 12 à 18 atomes de carbone, comme le stéarate de zinc, de magnésium ou de lithium, le laurate de zinc, le myristate de magnésium, les composés SiO2/TiO2/ Si02, Ti02/Ce02/Si02, ou encore Ti02/ZnOITalc, les polymères de polyéthylène terephtalate/polyméthacrylate en forme de paillettes. De manière générale, la phase pulvérulente comprend suffisamment de pigments et/ou nacres et/ou charges pour assurer l'effet maquillage souhaité. Ainsi, de préférence, l'émulsion selon l'invention n'est pas transparente, c'est-à-dire qu'on ne peut pas voir les caractères d'une page de journal à travers. De préférence encore elle n'est pas translucide, c'est-à-dire qu'elle ne permet pas le passage de la lumière. Mention may be made of talc, mica, silica, kaolin, nylon, poly-p-alanine and polyethylene powders, Teflon, lauroyl-lysine, optionally modified starch and its derivatives, nitrile boron, bismuth oxychloride, tetrafluoroethylene polymer powders, polymethyl methacrylate powders, polyurethane powders, polystyrene powders, polyester powders, synthetic hollow microspheres, micro sponges, silicone resin microbeads, zinc and titanium oxides, zirconium or cerium oxides, precipitated calcium carbonate, magnesium carbonate and hydrocarbonate, hydroxyapatite, hollow silica microspheres, glass or ceramic microcapsules, metal soaps derived from organic carboxylic acids having from 8 to 22 carbon atoms, preferably from 12 to 18 carbon atoms, such as zinc, magnesium or lithium stearate zinc laurate, magnesium myristate, SiO 2 / TiO 2 / SiO 2, TiO 2 / CeO 2 / SiO 2 compounds, or TiO 2 / ZnOITalc, polyethylene terephthalate / polymethacrylate polymers in the form of flakes. In general, the pulverulent phase comprises sufficient pigments and / or nacres and / or fillers to ensure the desired makeup effect. Thus, preferably, the emulsion according to the invention is not transparent, that is to say that one can not see the characters of a newspaper page through. More preferably it is not translucent, that is to say that it does not allow the passage of light.
Dans une forme particulièrement avantageuse de l'invention, la phase pulvérulente comprend au moins une charge choisie parmi l'amidon éventuellement modifié et ses dérivés. In a particularly advantageous form of the invention, the pulverulent phase comprises at least one filler chosen from optionally modified starch and its derivatives.
II est possible de modifier la rigidité des émulsions selon l'invention en y ajoutant un ou plusieurs sels qui vont augmenter cette rigidité. Ces sels peuvent être choisis parmi les sels des métaux mono-, di- ou trivalents, et plus particulièrement les sels de métal alcalin et alcalino-terreux et en particulier les sels de sodium, de calcium ou de magnésium. Les ions constituant ces sels peuvent être choisis par exemple parmi les carbonates, les bicarbonates, les sulfates, les glycérophosphates, les borates, les chlorures, les nitrates, les acétates, les hydroxydes, les persulfates ainsi que les sels d'a-hydroxyacides (citrates, tartrates, lactates, malates) ou d'acides de fruits, ou encore les sels d'acides aminés (aspartate, arginate, glycocholate, fumarate). La quantité de sel peut aller de 0,01à 2 % et de préférence de 0,1 à 1 % du poids total de l'émulsion. It is possible to modify the rigidity of the emulsions according to the invention by adding one or more salts which will increase this rigidity. These salts may be chosen from the salts of mono-, di- or trivalent metals, and more particularly the alkali metal and alkaline earth metal salts and in particular the sodium, calcium or magnesium salts. The ions constituting these salts may be chosen for example from carbonates, bicarbonates, sulphates, glycerophosphates, borates, chlorides, nitrates, acetates, hydroxides, persulfates and salts of α-hydroxy acids ( citrates, tartrates, lactates, malates) or of fruit acids, or the salts of amino acids (aspartate, arginate, glycocholate, fumarate). The amount of salt can range from 0.01 to 2% and preferably from 0.1 to 1% of the total weight of the emulsion.
De préférence, le sel est choisi parmi le nitrate de calcium, de magnésium ou de strontium, le borate de calcium ou de magnésium, le chlorure de calcium, de sodium, de magnésium, de strontium, de néodyme ou de manganèse, le sulfate de magnésium ou de calcium, l'acétate de calcium ou de magnésium, et leurs mélanges. De préférence encore, le sel est choisi parmi le chlorure de magnésium et le chlorure de sodium. Preferably, the salt is chosen from calcium, magnesium or strontium nitrate, calcium or magnesium borate, calcium chloride, sodium chloride, magnesium chloride, strontium chloride, neodymium chloride or manganese chloride, magnesium or calcium, calcium or magnesium acetate, and mixtures thereof. More preferably, the salt is selected from magnesium chloride and sodium chloride.
Les émulsions de l'invention contiennent en outre un milieu cosmétiquement ou physiologiquement acceptable, c'est-à-dire un milieu compatible avec toutes les matières kératiniques telles que la peau, les ongles, les cheveux, les cils et sourcils, les muqueuses et les semi-muqueuses, et toute autre zone cutanée du corps et du visage. The emulsions of the invention also contain a cosmetically or physiologically acceptable medium, that is to say a medium that is compatible with all keratin materials such as the skin, the nails, the hair, the eyelashes and the eyebrows, the mucous membranes and the semi-mucous membranes, and any other cutaneous zone of the body and the face.
La composition peut comprendre en outre tout composé complémentaire usuellement utilisé dans le domaine cosmétique, tel que des antioxydants, des parfums, des huiles essentielles, des conservateurs, des actifs cosmétiques ou pharmaceutiques lipophiles ou hydrophiles, des hydratants, des vitamines, des acides gras essentiels, des sphingolipides, des composés auto-bronzants tels que la DHA, des filtres solaires. The composition may furthermore comprise any complementary compound usually used in the cosmetics field, such as antioxidants, perfumes, essential oils, preservatives, lipophilic or hydrophilic cosmetic or pharmaceutical active ingredients, moisturizers, vitamins, essential fatty acids. , sphingolipids, self-tanning compounds such as DHA, sunscreens.
Bien entendu l'homme du métier veillera à choisir ce ou ces éventuels composés complémentaires, et/ou leur quantité, de manière telle que les propriétés avantageuses de l'émulsion selon l'invention ne soient pas, ou substantiellement pas, altérées par l'adjonction envisagée. Les émulsions selon l'invention peuvent être préparées selon les méthodes de préparation classiques des émulsions, ces méthodes étant bien connues de l'homme du métier. Of course, those skilled in the art will take care to choose this or these optional additional compounds, and / or their quantity, in such a way that the advantageous properties of the emulsion according to the invention are not, or not substantially, impaired by the addition envisaged. The emulsions according to the invention can be prepared according to the conventional methods of preparation of the emulsions, these methods being well known to those skilled in the art.
Les émulsions selon l'invention peuvent constituer des produits de maquillage ou de soin de la peau, en particulier du corps, du visage et/ou du cuir chevelu, ou des fibres kératiniques, en particulier des cheveux, des ongles, des cils et/ou des sourcils, ou encore des muqueuses, en particulier des lèvres. Ils peuvent ainsi constituer des produits de maquillage du corps, des fonds de teints, des ombres à paupières, des fards à joues, des anti-cernes, des rouges à lèvres, des crayons du contour des lèvres, des mascaras, des crayons du contour des yeux, des sticks pour la teinture ou le maquillage de mèches de cheveux. The emulsions according to the invention may constitute make-up or skincare products, in particular the body, the face and / or the scalp, or the keratin fibers, in particular the hair, the nails, the eyelashes and / or or eyebrows, or mucous membranes, especially lips. They can thus constitute body make-up products, foundations, eye shadows, blushes, concealer, lipsticks, lip contour pencils, mascaras, contour pencils. eyes, sticks for dyeing or making hair strands.
L'invention est illustrée plus en détails dans les exemples suivants. The invention is further illustrated in the following examples.
Dans les exemples suivants, les quantités sont données en pourcentage en poids par rapport au poids total de la composition. In the following examples, the amounts are given as a percentage by weight relative to the total weight of the composition.
<B><U>EXEMPLE 1</U></B> <B> <U> EXAMPLE 1 </ U> </ B>
La Demanderesse a réalisé l'émulsion solide H/E sous forme de fond de teint en stick suivant
<I><U>Phase <SEP> A</U></I>
<tb> -Mélange <SEP> de <SEP> mono-stéarate <SEP> de <SEP> glycéryle,
<tb> stéarate <SEP> de <SEP> polyéthylène <SEP> glycol <SEP> (1000E)
<tb> vendu <SEP> sous <SEP> la <SEP> dénomination <SEP> <SEP> Arlacel <SEP> 165 <SEP> FL <SEP>
<tb> par <SEP> UNIQEMA <SEP> 2,1%
<tb> - <SEP> Mono-stéarate <SEP> de <SEP> sorbitane <SEP> oxyéthyléné <SEP> (200E)
<tb> vendu <SEP> sous <SEP> la <SEP> dénomination <SEP> commerciale
<tb> <SEP> Polysorbate <SEP> 60 <SEP> <SEP> par <SEP> UNIQEMA <SEP> 0,9%
<tb> -Alcool <SEP> cétylique <SEP> pur <SEP> 0,5%
<tb> -Acide <SEP> stéarique <SEP> (C16-18 <SEP> 50/50) <SEP> 1,5%
<tb> -Isoparrafine <SEP> (6-8 <SEP> moles <SEP> d'isobutylène) <SEP> hydrogénée <SEP> 22%
<tb> - <SEP> Conservateur <SEP> 0,2%
<tb> - <SEP> Pigments <SEP> (Dioxyde <SEP> titane <SEP> , <SEP> oxydes <SEP> de <SEP> fer <SEP> noir/rouge/jaune) <SEP> 7%
<tb> <I><U>Phase <SEP> 8</U></I>
<tb> - <SEP> Eau <SEP> 60,45%
<tb> -Mix <SEP> of <SEP> mono-stearate <SEP> of <SEP> glyceryl,
<tb> stearate <SEP> of <SEP> polyethylene <SEP> glycol <SEP> (1000E)
<tb> sold <SEP> under <SEP> the <SEP> denomination <SEP><SEP> Arlacel <SEP> 165 <SE> FL <SEP>
<tb> by <SEP> UNIQEMA <SEP> 2.1%
<tb> - <SEP> Mono-stearate <SEP> of <SEP> sorbitan <SEP> oxyethylenated <SEP> (200E)
<tb> sold <SEP> under <SEP> the <SEP> denomination <SEP> commercial
<tb><SEP> Polysorbate <SEP> 60 <SEP><SEP> by <SEP> UNIQEMA <SEP> 0.9%
<tb> -Alcohol <SEP> cetyl <SEP> pure <SEP> 0,5%
<tb> -Acide <SEP> stearic <SEP> (C16-18 <SEP> 50/50) <SEP> 1.5%
<tb> -Isoparrafine <SEP> (6-8 <SEP> moles <SEP> isobutylene) <SEP> hydrogenated <SEP> 22%
<tb> - <SEP> Conservative <SEP> 0.2%
<tb> - <SEP> Pigments <SEP> (Dioxide <SEP> titanium <SEP>, <SEP> oxides <SEP> of <SEP> iron <SEP> black / red / yellow) <SEP> 7%
<tb><I><U> Phase <SEP> 8 </ U></I>
<tb> - <SEP> Water <SEP> 60.45%
- <SEP> Conservateur: <SEP> 0,25%
<tb> -Propylène <SEP> glycol <SEP> 3%
<tb> - <SEP> Triéthanolamine <SEP> à <SEP> 99% <SEP> 0,6%
<tb> <I><U>Phase <SEP> C</U></I>
<tb> Gomme <SEP> de <SEP> gellane <SEP> : <SEP> Polysaccharides
<tb> (D-glucose <SEP> 1,3/ <SEP> D-acide <SEP> glucuronique <SEP> -1,4/
<tb> D-glucose <SEP> -1,4/ <SEP> L-Rhamnose <SEP> 1,4) <SEP> vendu <SEP> sous <SEP> la
<tb> dénomination <SEP> commerciale <SEP> <SEP> Kelcogel <SEP> F <SEP> <SEP> par
<tb> NUTRASWEET-KELCO <SEP> 1,5% Mode opératoire: on homogénéise séparément les phases A et B . On les chauffe à 80 C. On émulsionne en versant la phase A dans la phase B sous agitation Moritz (3000trs/mn) à 80 C. On réduit ensuite l'agitation (500 trs /mn) et on ajoute la phase C. On homogénéise 15 min en maintenant la température à 80 C. On coule dans des articles de conditionnement étanches à l'eau. On laisse refroidir à température ambiante. - <SEP> Conservative: <SEP> 0.25%
<tb> -propylene <SEP> glycol <SEP> 3%
<tb> - <SEP> Triethanolamine <SEP> to <SEP> 99% <SEP> 0.6%
<tb><I><U> Phase <SEP> C </ U></I>
<tb> Gum <SEP> of <SEP> gellan <SEP>: <SEP> Polysaccharides
<tb> (D-glucose <SEP> 1,3 / <SEP> D-acid <SEP> glucuronic <SEP> -1,4 /
<tb> D-glucose <SEP> -1.4 / <SEP> L-Rhamnose <SEP> 1.4) <SEP> sold <SEP> under <SEP>
<tb> denomination <SEP> commercial <SEP><SEP> Kelcogel <SEP> F <SEP><SEP> by
<tb> NUTRASWEET-KELCO <SEP> 1.5% Procedure: The phases A and B are homogenized separately. They are heated to 80 ° C. The mixture is emulsified by pouring phase A into phase B with Moritz stirring (3000 rpm) at 80 ° C. The stirring is then reduced (500 rpm) and C-phase is added. homogenize 15 min while maintaining the temperature at 80 C. Sink in waterproof packaging articles. Allowed to cool to room temperature.
On obtient un fond de teint solide légèrement crémeux, qui s'étale facilement , est agréable sur la peau avec un effet frais. A slightly creamy solid foundation is obtained, which spreads easily, is pleasant on the skin with a fresh effect.
<B><U>EXEMPLE 2</U></B> <B> <U> EXAMPLE 2 </ U> </ B>
La Demanderesse a réalisé l'émulsion solide H/E sous forme de fond de teint en stick suivant
<I><U>Phase <SEP> A</U></I>
<tb> -Monostéarate <SEP> de <SEP> polyéthylène <SEP> glycol <SEP> (80E) <SEP> vendu <SEP> sous
<tb> la <SEP> dénomination <SEP> commerciale <SEP> <SEP> Estol <SEP> 3646 <SEP> <SEP> par <SEP> UNIQEMA <SEP> 1,3%
<tb> -Acide <SEP> stéarique <SEP> 0,3<B>%</B>
<tb> -Alcool <SEP> stéarylique <SEP> 0,5%
<tb> -Huiles <SEP> d'amande <SEP> d'abricot <SEP> 13%
<tb> -Cyclohexadiméthylsiloxane <SEP> (viscosité <SEP> : <SEP> 8cst) <SEP> 10%
<tb> -Conservateur <SEP> 0,1
<tb> -Pigments <SEP> (Oxyde <SEP> de <SEP> titane, <SEP> oxydes <SEP> de <SEP> fer) <SEP> 7%
<tb> -Monostearate <SEP> of <SEP> polyethylene <SEP> glycol <SEP> (80E) <SEP> sold <SEP> under
<tb> the <SEP> name <SEP> commercial <SEP><SEP> Estol <SEP> 3646 <SEP><SEP> by <SEP> UNIQEMA <SEP> 1.3%
<tb> -Acide <SEP> stearic <SEP> 0.3 <B>% </ B>
<tb> -Alcohol <SEP> stearyl alcohol <SEP> 0.5%
<tb> -Oils <SEP> of apricot kernel <SEP><13%
<tb> -Cyclohexadimethylsiloxane <SEP> (viscosity <SEP>: <SEP> 8cst) <SEP> 10%
<tb> -Conservator <SEP> 0.1
<tb> -Pigments <SEP> (Oxide <SEP> of <SEP> titanium, <SEP> oxides <SEP> of <SEP> iron) <SEP> 7%
<I><U>Phase <SEP> B</U></I>
<tb> -Glycérine <SEP> 7%
<tb> -Conservateur <SEP> : <SEP> 0,2%
<tb> -Mono-di <SEP> palmito <SEP> stéarate <SEP> de <SEP> sucrose <SEP> vendu
<tb> sous <SEP> la <SEP> dénomination <SEP> commerciale <SEP> <SEP> Tegosoft <SEP> PSE <SEP> 141 <SEP> G <SEP>
<tb> par <SEP> GOLDSCHMIDT <SEP> 1,3%
<tb> -Eau <SEP> 56%
<tb> <I><U>Phase <SEP> C</U></I>
<tb> -Hydroxyde <SEP> de <SEP> sodium <SEP> pur <SEP> - <SEP> 0,04%
<tb> -Eau <SEP> 2,26%
<tb> <I><U>Phase <SEP> D</U></I>
<tb> Gomme <SEP> de <SEP> gellane <SEP> : <SEP> Polysaccharides
<tb> (D-glucose <SEP> 1,3I <SEP> D-acide <SEP> glucuronique <SEP> -1,4/
<tb> D-glucose <SEP> -1,4/ <SEP> L-Rhamnose <SEP> 1,4) <SEP> vendu <SEP> sous <SEP> la
<tb> dénomination <SEP> commerciale <SEP> <SEP> Kelcogel <SEP> F <SEP> <SEP> par
<tb> NUTRASWEET-KELCO <SEP> 1, Cette émulsion a été préparée selon le même mode opératoire que l'exemple 1 en ajoutant (C + D) à la fin. <I><U> Phase <SEP> B </ U></I>
<tb> -Glycerin <SEP> 7%
<tb> -Conservator <SEP>: <SEP> 0.2%
<tb> -Mono-di <SEP> palmito <SEP> stearate <SEP> of <SEP> sucrose <SEP> sold
<tb> under <SEP> the <SEP> name <SEP> commercial <SEP><SEP> Tegosoft <SEP> PSE <SEP> 141 <SEP> G <SEP>
<tb> by <SEP> GOLDSCHMIDT <SEP> 1.3%
<tb> -Water <SEP> 56%
<tb><I><U> Phase <SEP> C </ U></I>
<tb> -Hydroxide <SEP> of <SEP> sodium <SEP> pure <SEP> - <SEP> 0.04%
<tb> -Water <SEP> 2.26%
<tb><I><U> Phase <SEP> D </ U></I>
<tb> Gum <SEP> of <SEP> gellan <SEP>: <SEP> Polysaccharides
<tb> (D-glucose <SEP> 1,3I <SEP> D-acid <SEP> glucuronic <SEP> -1,4 /
<tb> D-glucose <SEP> -1.4 / <SEP> L-Rhamnose <SEP> 1.4) <SEP> sold <SEP> under <SEP>
<tb> denomination <SEP> commercial <SEP><SEP> Kelcogel <SEP> F <SEP><SEP> by
This emulsion was prepared according to the same procedure as Example 1 by adding (C + D) at the end.
On obtient un fond de teint solide ayant l'aspect d'un gel frais agréable à l'application sans effets de tiraillement.A solid foundation is obtained having the appearance of a fresh gel that is pleasant to the application without any tugging effects.
Claims (23)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9907767A FR2794997B1 (en) | 1999-06-18 | 1999-06-18 | SOLID O / W EMULSION COMPRISING GELLANE AND A PARTICULAR SURFACTANT, USES |
| BR0006827-6A BR0006827A (en) | 1999-06-18 | 2000-06-09 | Solid oil-in-water emulsion comprising gelane and a particular surfactant, skin and / or keratin fibers and a make-up process |
| JP2001504496A JP2003502394A (en) | 1999-06-18 | 2000-06-09 | Solid O / W emulsion containing gellan and specific surfactant and use thereof |
| EP00940490A EP1112119A1 (en) | 1999-06-18 | 2000-06-09 | Oil-in-water emulsion comprising gellan and a particular surfactant and uses |
| AU55418/00A AU5541800A (en) | 1999-06-18 | 2000-06-09 | Oil-in-water emulsion comprising gellan and a particular surfactant and uses |
| CA002340069A CA2340069A1 (en) | 1999-06-18 | 2000-06-09 | Oil-in-water emulsion comprising gellan and a particular surfactant and uses |
| KR1020017002060A KR20010072739A (en) | 1999-06-18 | 2000-06-09 | Oil-in-water emulsion comprising gellan and a particular surfactant and uses |
| MXPA01001684A MXPA01001684A (en) | 1999-06-18 | 2000-06-09 | Oil-in-water emulsion comprising gellan and a particular surfactant and uses. |
| PCT/FR2000/001615 WO2000078442A1 (en) | 1999-06-18 | 2000-06-09 | Oil-in-water emulsion comprising gellan and a particular surfactant and uses |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9907767A FR2794997B1 (en) | 1999-06-18 | 1999-06-18 | SOLID O / W EMULSION COMPRISING GELLANE AND A PARTICULAR SURFACTANT, USES |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2794997A1 true FR2794997A1 (en) | 2000-12-22 |
| FR2794997B1 FR2794997B1 (en) | 2002-05-17 |
Family
ID=9546994
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR9907767A Expired - Fee Related FR2794997B1 (en) | 1999-06-18 | 1999-06-18 | SOLID O / W EMULSION COMPRISING GELLANE AND A PARTICULAR SURFACTANT, USES |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP1112119A1 (en) |
| JP (1) | JP2003502394A (en) |
| KR (1) | KR20010072739A (en) |
| AU (1) | AU5541800A (en) |
| BR (1) | BR0006827A (en) |
| CA (1) | CA2340069A1 (en) |
| FR (1) | FR2794997B1 (en) |
| MX (1) | MXPA01001684A (en) |
| WO (1) | WO2000078442A1 (en) |
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| WO2002017875A1 (en) * | 2000-08-31 | 2002-03-07 | Coty B.V. | Highly viscous cosmetic product |
| FR2880266A1 (en) * | 2004-12-30 | 2006-07-07 | Oreal | COSMETIC COMPOSITION CONTAINING ALKOXYL ALCOHOL ESTER AND A FILMOGENIC POLYMER |
| WO2007029153A2 (en) * | 2005-09-09 | 2007-03-15 | The Procter & Gamble Company | Solid skin care composition comprising multiple layers |
| WO2007029152A2 (en) * | 2005-09-09 | 2007-03-15 | The Procter & Gamble Company | Solid skin care composition comprising multiple layers |
| WO2007029154A3 (en) * | 2005-09-09 | 2007-09-27 | Procter & Gamble | Solid skin care composition comprising multiple layers |
| WO2015028381A1 (en) * | 2013-08-29 | 2015-03-05 | L'oreal | Moisturizing composition which may be applied to wet skin in the form of an oil-in-water emulsion; moisturizing care process |
| CN104546512A (en) * | 2013-10-29 | 2015-04-29 | 信越化学工业株式会社 | Aqueous dispersion of silicone rubber particles, and cosmetic |
| CN111263630A (en) * | 2017-10-31 | 2020-06-09 | 株式会社资生堂 | Oil-in-water type emulsified solid cosmetic |
| CN118652466A (en) * | 2024-08-19 | 2024-09-17 | 四川大学 | A kind of developing biodegradable medical polyurethane foam and preparation method thereof |
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| JP4786809B2 (en) * | 2001-03-14 | 2011-10-05 | 株式会社コーセー | Solid cosmetics |
| FR2823504A1 (en) * | 2001-04-17 | 2002-10-18 | Oreal | Solid composition, especially make-up or other cosmetic product in stick form, containing combination of polysaccharide and soap type gelling agents |
| KR20050023598A (en) * | 2003-08-28 | 2005-03-10 | 주식회사 엘지생활건강 | Composition of Toothpaste |
| FR2862222B1 (en) * | 2003-11-18 | 2008-10-10 | Oreal | COSMETIC COMPOSITION COMPRISING GELLANE GUM OR ONE OF ITS DERIVATIVES, A SOLID COMPOUND AND A MONOVALENT SALT, METHODS USING THE SAME, AND USES THEREOF |
| KR101015384B1 (en) * | 2004-12-20 | 2011-02-17 | (주)아모레퍼시픽 | Oil-in-water makeup cosmetic composition containing no emulsifier and method for preparing same |
| KR100678316B1 (en) * | 2006-01-19 | 2007-02-02 | 엘지전자 주식회사 | Air conditioner |
| KR100787328B1 (en) * | 2006-05-11 | 2007-12-18 | (주)아모레퍼시픽 | Emulsion composition having macro-sized lipid capsule particles and skin cosmetic composition using same |
| JP5328090B2 (en) * | 2006-10-04 | 2013-10-30 | 株式会社 資生堂 | Oil-in-water emulsified cosmetic |
| CN101496777B (en) * | 2008-01-30 | 2014-07-02 | 株式会社资生堂 | Oil in water type emulsification cosmetic |
| JP5543161B2 (en) * | 2009-09-18 | 2014-07-09 | 株式会社コーセー | Cosmetic for salmon |
| KR101831766B1 (en) | 2011-11-18 | 2018-02-27 | (주)아모레퍼시픽 | UV protecting cosmetic composition having water splash appearance and a method of preparing thereof |
| IN2014KN02614A (en) | 2012-05-18 | 2015-05-08 | Oreal | |
| KR101977209B1 (en) | 2012-09-12 | 2019-05-10 | (주)아모레퍼시픽 | Semi-permanent hair dye composition |
| CN102920621A (en) * | 2012-11-21 | 2013-02-13 | 安文娟 | Composition of liquid foundation |
| CN106074316B (en) * | 2016-08-26 | 2019-01-11 | 杭州耕香跨境电子商务有限公司 | A kind of preparation method of essence lotion used for cosmetic |
| WO2020069636A1 (en) * | 2018-10-03 | 2020-04-09 | L'oreal | Composition comprising non-volatile/volatile oils and lipophilic dyes, methods and uses thereof |
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- 2000-06-09 WO PCT/FR2000/001615 patent/WO2000078442A1/en not_active Application Discontinuation
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002017875A1 (en) * | 2000-08-31 | 2002-03-07 | Coty B.V. | Highly viscous cosmetic product |
| FR2880266A1 (en) * | 2004-12-30 | 2006-07-07 | Oreal | COSMETIC COMPOSITION CONTAINING ALKOXYL ALCOHOL ESTER AND A FILMOGENIC POLYMER |
| WO2007029153A2 (en) * | 2005-09-09 | 2007-03-15 | The Procter & Gamble Company | Solid skin care composition comprising multiple layers |
| WO2007029152A2 (en) * | 2005-09-09 | 2007-03-15 | The Procter & Gamble Company | Solid skin care composition comprising multiple layers |
| WO2007029153A3 (en) * | 2005-09-09 | 2007-09-20 | Procter & Gamble | Solid skin care composition comprising multiple layers |
| WO2007029154A3 (en) * | 2005-09-09 | 2007-09-27 | Procter & Gamble | Solid skin care composition comprising multiple layers |
| WO2007029152A3 (en) * | 2005-09-09 | 2007-10-11 | Procter & Gamble | Solid skin care composition comprising multiple layers |
| FR3009956A1 (en) * | 2013-08-29 | 2015-03-06 | Oreal | MOISTURIZING COMPOSITION IN THE FORM OF OIL-IN-WATER EMULSION; MOISTURIZING CARE PROCESS |
| WO2015028381A1 (en) * | 2013-08-29 | 2015-03-05 | L'oreal | Moisturizing composition which may be applied to wet skin in the form of an oil-in-water emulsion; moisturizing care process |
| US9913786B2 (en) | 2013-08-29 | 2018-03-13 | L'oreal | Moisturizing composition which may be applied to wet skin in the form of an oil-in-water emulsion; moisturizing care process |
| CN104546512A (en) * | 2013-10-29 | 2015-04-29 | 信越化学工业株式会社 | Aqueous dispersion of silicone rubber particles, and cosmetic |
| CN104546512B (en) * | 2013-10-29 | 2019-04-23 | 信越化学工业株式会社 | Aqueous dispersion of silicone rubber particles, and cosmetic |
| CN111263630A (en) * | 2017-10-31 | 2020-06-09 | 株式会社资生堂 | Oil-in-water type emulsified solid cosmetic |
| EP3705111A4 (en) * | 2017-10-31 | 2021-07-28 | Shiseido Company, Ltd. | Oil-in-water type emulsion solid cosmetic |
| US11266579B2 (en) | 2017-10-31 | 2022-03-08 | Shiseido Company, Ltd. | Oil-in-water type emulsion solid cosmetic |
| CN111263630B (en) * | 2017-10-31 | 2023-12-08 | 株式会社资生堂 | Oil-in-water type emulsified solid cosmetic |
| CN118652466A (en) * | 2024-08-19 | 2024-09-17 | 四川大学 | A kind of developing biodegradable medical polyurethane foam and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1112119A1 (en) | 2001-07-04 |
| AU5541800A (en) | 2001-01-09 |
| MXPA01001684A (en) | 2002-04-08 |
| KR20010072739A (en) | 2001-07-31 |
| CA2340069A1 (en) | 2000-12-28 |
| BR0006827A (en) | 2001-06-05 |
| JP2003502394A (en) | 2003-01-21 |
| WO2000078442A1 (en) | 2000-12-28 |
| FR2794997B1 (en) | 2002-05-17 |
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