FR2746405A1 - Combinaisons de stabilisants a base de derives de 2,2,6,6-tetramethylpiperidine et de composes organiques du zinc pour des polymeres chlores - Google Patents

Combinaisons de stabilisants a base de derives de 2,2,6,6-tetramethylpiperidine et de composes organiques du zinc pour des polymeres chlores Download PDF

Info

Publication number: FR2746405A1
Authority: FR; France
Prior art keywords: alkyl; acid; tert; butyl; compounds
Prior art date: 1996-03-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

FR9703402A

Other languages

English (en)

French (fr)

Inventor

Horst Zinke

Wolfgang Wehner

Karl Josef Kuhn

Valerio Borzatta

Gerhard Rytz

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Novartis AG

BASF Schweiz AG

Original Assignee

Ciba Geigy AG

Ciba Spezialitaetenchemie Holding AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-03-22

Filing date

1997-03-20

Publication date

1997-09-26

1997-03-20 Application filed by Ciba Geigy AG, Ciba Spezialitaetenchemie Holding AG filed Critical Ciba Geigy AG

1997-09-26 Publication of FR2746405A1 publication Critical patent/FR2746405A1/fr

Status Withdrawn legal-status Critical Current

Links

229920000642 polymer Polymers 0.000 title claims abstract description 56
239000003381 stabilizer Substances 0.000 title claims abstract description 34
150000003752 zinc compounds Chemical class 0.000 title claims abstract description 9
RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical class CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 title description 2
150000001875 compounds Chemical class 0.000 claims abstract description 38
229910052717 sulfur Inorganic materials 0.000 claims abstract description 18
229910052760 oxygen Inorganic materials 0.000 claims abstract description 7
229910007541 Zn O Inorganic materials 0.000 claims abstract description 4
-1 R2-CX-NG (CH2) b Chemical group 0.000 claims description 131
239000000203 mixture Substances 0.000 claims description 53
239000010457 zeolite Substances 0.000 claims description 51
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 21
239000011575 calcium Substances 0.000 claims description 16
229910052791 calcium Inorganic materials 0.000 claims description 12
125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 11
125000000217 alkyl group Chemical group 0.000 claims description 11
229910052783 alkali metal Inorganic materials 0.000 claims description 10
229910052782 aluminium Inorganic materials 0.000 claims description 10
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 10
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 10
150000001340 alkali metals Chemical class 0.000 claims description 8
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 8
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 7
125000003342 alkenyl group Chemical group 0.000 claims description 7
235000014113 dietary fatty acids Nutrition 0.000 claims description 7
239000000194 fatty acid Substances 0.000 claims description 7
229930195729 fatty acid Natural products 0.000 claims description 7
230000000087 stabilizing effect Effects 0.000 claims description 7
150000001342 alkaline earth metals Chemical class 0.000 claims description 6
239000003963 antioxidant agent Substances 0.000 claims description 6
125000004925 dihydropyridyl group Chemical group N1(CC=CC=C1)* 0.000 claims description 6
238000000034 method Methods 0.000 claims description 6
229920005862 polyol Polymers 0.000 claims description 6
150000003077 polyols Chemical class 0.000 claims description 6
RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical class OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 claims description 5
125000000753 cycloalkyl group Chemical group 0.000 claims description 5
229910052751 metal Inorganic materials 0.000 claims description 5
239000002184 metal Substances 0.000 claims description 5
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 4
HDFRDWFLWVCOGP-UHFFFAOYSA-N carbonothioic O,S-acid Chemical class OC(S)=O HDFRDWFLWVCOGP-UHFFFAOYSA-N 0.000 claims description 4
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 4
150000002118 epoxides Chemical class 0.000 claims description 4
239000004611 light stabiliser Substances 0.000 claims description 4
239000000126 substance Substances 0.000 claims description 4
239000006096 absorbing agent Substances 0.000 claims description 3
150000001341 alkaline earth metal compounds Chemical class 0.000 claims description 3
150000002739 metals Chemical class 0.000 claims description 3
125000004178 (C1-C4) alkyl group Chemical class 0.000 claims 4
125000000229 (C1-C4)alkoxy group Chemical class 0.000 claims 1
125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 1
CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical class [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims 1
150000001339 alkali metal compounds Chemical class 0.000 claims 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 38
229910021536 Zeolite Inorganic materials 0.000 description 35
239000011701 zinc Substances 0.000 description 24
229920000915 polyvinyl chloride Polymers 0.000 description 20
239000004800 polyvinyl chloride Substances 0.000 description 20
229910052725 zinc Inorganic materials 0.000 description 20
150000002148 esters Chemical class 0.000 description 19
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 18
239000011734 sodium Substances 0.000 description 17
229910052757 nitrogen Inorganic materials 0.000 description 16
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 15
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 15
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 14
229910052700 potassium Inorganic materials 0.000 description 14
239000000047 product Substances 0.000 description 14
239000007983 Tris buffer Substances 0.000 description 13
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
229910001868 water Inorganic materials 0.000 description 12
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 11
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 11
239000012964 benzotriazole Substances 0.000 description 11
239000011777 magnesium Substances 0.000 description 11
239000004014 plasticizer Substances 0.000 description 11
229910052708 sodium Inorganic materials 0.000 description 11
239000004305 biphenyl Substances 0.000 description 10
235000010290 biphenyl Nutrition 0.000 description 10
125000006267 biphenyl group Chemical group 0.000 description 10
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 9
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 9
239000002253 acid Substances 0.000 description 9
239000000654 additive Substances 0.000 description 9
229920001577 copolymer Polymers 0.000 description 9
239000000049 pigment Substances 0.000 description 9
229910052749 magnesium Inorganic materials 0.000 description 8
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 7
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 7
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 7
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 6
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 6
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
229910052744 lithium Inorganic materials 0.000 description 6
238000002844 melting Methods 0.000 description 6
230000008018 melting Effects 0.000 description 6
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 6
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 6
ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 6
BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 5
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 5
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
235000006708 antioxidants Nutrition 0.000 description 5
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
150000007942 carboxylates Chemical group 0.000 description 5
229910052681 coesite Inorganic materials 0.000 description 5
229910052906 cristobalite Inorganic materials 0.000 description 5
XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 5
239000000314 lubricant Substances 0.000 description 5
SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 5
BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 5
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
238000007493 shaping process Methods 0.000 description 5
229910052682 stishovite Inorganic materials 0.000 description 5
229910052905 tridymite Inorganic materials 0.000 description 5
SQHKJSPPFSVNDF-UHFFFAOYSA-N 1,2,2,3-tetrakis(hydroxymethyl)cyclohexan-1-ol Chemical compound OCC1CCCC(O)(CO)C1(CO)CO SQHKJSPPFSVNDF-UHFFFAOYSA-N 0.000 description 4
JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 description 4
ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 4
ZPIRWAHWDCHWLM-UHFFFAOYSA-N 2-dodecylsulfanylethanol Chemical compound CCCCCCCCCCCCSCCO ZPIRWAHWDCHWLM-UHFFFAOYSA-N 0.000 description 4
QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 4
CKPKHTKLLYPGFM-UHFFFAOYSA-N 6,6-dimethylheptane-1,1-diol Chemical compound CC(CCCCC(O)O)(C)C CKPKHTKLLYPGFM-UHFFFAOYSA-N 0.000 description 4
229910018072 Al 2 O 3 Inorganic materials 0.000 description 4
NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 4
YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 4
229910000272 alkali metal oxide Inorganic materials 0.000 description 4
229910052788 barium Inorganic materials 0.000 description 4
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 4
FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 4
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
238000000576 coating method Methods 0.000 description 4
239000007859 condensation product Substances 0.000 description 4
PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Chemical compound CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 description 4
ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 4
238000009472 formulation Methods 0.000 description 4
229910052739 hydrogen Inorganic materials 0.000 description 4
239000000395 magnesium oxide Substances 0.000 description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
125000005498 phthalate group Chemical class 0.000 description 4
ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 4
YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 4
150000003839 salts Chemical class 0.000 description 4
239000000377 silicon dioxide Substances 0.000 description 4
235000012239 silicon dioxide Nutrition 0.000 description 4
229910052712 strontium Inorganic materials 0.000 description 4
KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 4
150000005846 sugar alcohols Polymers 0.000 description 4
YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 4
125000003944 tolyl group Chemical group 0.000 description 4
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 4
125000005591 trimellitate group Chemical group 0.000 description 4
FJFYFBRNDHRTHL-UHFFFAOYSA-N tris(8-methylnonyl) benzene-1,2,4-tricarboxylate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC(C)C)C(C(=O)OCCCCCCCC(C)C)=C1 FJFYFBRNDHRTHL-UHFFFAOYSA-N 0.000 description 4
FPEXZUSKGJEHCF-UHFFFAOYSA-N 2,3,5-trioxabicyclo[2.2.2]octane Chemical compound O1CC2CCC1OO2 FPEXZUSKGJEHCF-UHFFFAOYSA-N 0.000 description 3
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
KXPXKNBDCUOENF-UHFFFAOYSA-N 2-(Octylthio)ethanol Chemical compound CCCCCCCCSCCO KXPXKNBDCUOENF-UHFFFAOYSA-N 0.000 description 3
YEXOWHQZWLCHHD-UHFFFAOYSA-N 3,5-ditert-butyl-4-hydroxybenzoic acid Chemical compound CC(C)(C)C1=CC(C(O)=O)=CC(C(C)(C)C)=C1O YEXOWHQZWLCHHD-UHFFFAOYSA-N 0.000 description 3
KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
239000001361 adipic acid Substances 0.000 description 3
235000011037 adipic acid Nutrition 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
150000001412 amines Chemical class 0.000 description 3
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 3
GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 3
150000001991 dicarboxylic acids Chemical class 0.000 description 3
238000001125 extrusion Methods 0.000 description 3
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229910052500 inorganic mineral Inorganic materials 0.000 description 3
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
235000010755 mineral Nutrition 0.000 description 3
239000011707 mineral Substances 0.000 description 3
238000000465 moulding Methods 0.000 description 3
AJUOPYIBDGGQOL-UHFFFAOYSA-N n',n'-bis(2-hydroxyethyl)oxamide Chemical compound NC(=O)C(=O)N(CCO)CCO AJUOPYIBDGGQOL-UHFFFAOYSA-N 0.000 description 3
150000002815 nickel Chemical class 0.000 description 3
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
229940049964 oleate Drugs 0.000 description 3
239000011591 potassium Substances 0.000 description 3
239000003549 soybean oil Substances 0.000 description 3
235000012424 soybean oil Nutrition 0.000 description 3
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
239000001993 wax Substances 0.000 description 3
239000008096 xylene Substances 0.000 description 3
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229920002451 polyvinyl alcohol Polymers 0.000 description 1
KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Substances [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
235000019260 propionic acid Nutrition 0.000 description 1
125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
235000013772 propylene glycol Nutrition 0.000 description 1
RQGPLDBZHMVWCH-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole Chemical compound C1=NC2=CC=NC2=C1 RQGPLDBZHMVWCH-UHFFFAOYSA-N 0.000 description 1
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000004064 recycling Methods 0.000 description 1
239000012744 reinforcing agent Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
229960003656 ricinoleic acid Drugs 0.000 description 1
FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
229910052711 selenium Inorganic materials 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
229910052814 silicon oxide Inorganic materials 0.000 description 1
229910052665 sodalite Inorganic materials 0.000 description 1
APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
239000004334 sorbic acid Substances 0.000 description 1
235000010199 sorbic acid Nutrition 0.000 description 1
229940075582 sorbic acid Drugs 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
229910052566 spinel group Inorganic materials 0.000 description 1
238000009987 spinning Methods 0.000 description 1
238000010186 staining Methods 0.000 description 1
229940114926 stearate Drugs 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1
TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
239000000758 substrate Substances 0.000 description 1
239000011593 sulfur Chemical group 0.000 description 1
239000002600 sunflower oil Substances 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
239000003760 tallow Substances 0.000 description 1
239000011975 tartaric acid Substances 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
150000000000 tetracarboxylic acids Chemical class 0.000 description 1
239000004753 textile Substances 0.000 description 1
230000008646 thermal stress Effects 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
NJRXVEJTAYWCQJ-UHFFFAOYSA-N thiomalic acid Chemical compound OC(=O)CC(S)C(O)=O NJRXVEJTAYWCQJ-UHFFFAOYSA-N 0.000 description 1
NBOMNTLFRHMDEZ-UHFFFAOYSA-N thiosalicylic acid Chemical class OC(=O)C1=CC=CC=C1S NBOMNTLFRHMDEZ-UHFFFAOYSA-N 0.000 description 1
DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
229960000984 tocofersolan Drugs 0.000 description 1
235000010384 tocopherol Nutrition 0.000 description 1
229960001295 tocopherol Drugs 0.000 description 1
235000019149 tocopherols Nutrition 0.000 description 1
238000005809 transesterification reaction Methods 0.000 description 1
150000003918 triazines Chemical class 0.000 description 1
150000003852 triazoles Chemical class 0.000 description 1
STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
150000003628 tricarboxylic acids Chemical class 0.000 description 1
229960001147 triclofos Drugs 0.000 description 1
150000005691 triesters Chemical class 0.000 description 1
QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 description 1
XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
IGQFKXMQIMEIJV-UHFFFAOYSA-N tris(11-methyldodecyl) benzene-1,2,4-tricarboxylate Chemical compound CC(C)CCCCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCCCCC(C)C)C(C(=O)OCCCCCCCCCCC(C)C)=C1 IGQFKXMQIMEIJV-UHFFFAOYSA-N 0.000 description 1
KOWVWXQNQNCRRS-UHFFFAOYSA-N tris(2,4-dimethylphenyl) phosphate Chemical compound CC1=CC(C)=CC=C1OP(=O)(OC=1C(=CC(C)=CC=1)C)OC1=CC=C(C)C=C1C KOWVWXQNQNCRRS-UHFFFAOYSA-N 0.000 description 1
GPMOBJJCAQQUHJ-UHFFFAOYSA-N tris(2-ethylbutyl) phosphate Chemical compound CCC(CC)COP(=O)(OCC(CC)CC)OCC(CC)CC GPMOBJJCAQQUHJ-UHFFFAOYSA-N 0.000 description 1
WDRCVXGINNJWPH-UHFFFAOYSA-N tris(6-methylheptyl) benzene-1,2,4-tricarboxylate Chemical compound CC(C)CCCCCOC(=O)C1=CC=C(C(=O)OCCCCCC(C)C)C(C(=O)OCCCCCC(C)C)=C1 WDRCVXGINNJWPH-UHFFFAOYSA-N 0.000 description 1
HHYYESPSICZLHA-UHFFFAOYSA-N tris(hexylsulfanyl)phosphane Chemical compound CCCCCCSP(SCCCCCC)SCCCCCC HHYYESPSICZLHA-UHFFFAOYSA-N 0.000 description 1
ZFVSFOABZDBFRD-UHFFFAOYSA-N tris(octylsulfanyl)phosphane Chemical compound CCCCCCCCSP(SCCCCCCCC)SCCCCCCCC ZFVSFOABZDBFRD-UHFFFAOYSA-N 0.000 description 1
235000013799 ultramarine blue Nutrition 0.000 description 1
125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
150000004670 unsaturated fatty acids Chemical class 0.000 description 1
235000021122 unsaturated fatty acids Nutrition 0.000 description 1
229940005605 valeric acid Drugs 0.000 description 1
239000003981 vehicle Substances 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
FUSUHKVFWTUUBE-UHFFFAOYSA-N vinyl methyl ketone Natural products CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
UIYCHXAGWOYNNA-UHFFFAOYSA-N vinyl sulfide Chemical group C=CSC=C UIYCHXAGWOYNNA-UHFFFAOYSA-N 0.000 description 1
239000011709 vitamin E Substances 0.000 description 1
235000019165 vitamin E Nutrition 0.000 description 1
229940046009 vitamin E Drugs 0.000 description 1
239000010456 wollastonite Substances 0.000 description 1
229910052882 wollastonite Inorganic materials 0.000 description 1
238000004383 yellowing Methods 0.000 description 1
239000011667 zinc carbonate Substances 0.000 description 1
235000004416 zinc carbonate Nutrition 0.000 description 1
229910000010 zinc carbonate Inorganic materials 0.000 description 1
UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
229910021511 zinc hydroxide Inorganic materials 0.000 description 1
229940007718 zinc hydroxide Drugs 0.000 description 1
IQBAOEIFIGDDCB-UHFFFAOYSA-L zinc;2,2-bis(octylsulfanyl)propanoate Chemical compound [Zn+2].CCCCCCCCSC(C)(C([O-])=O)SCCCCCCCC.CCCCCCCCSC(C)(C([O-])=O)SCCCCCCCC IQBAOEIFIGDDCB-UHFFFAOYSA-L 0.000 description 1
RBEYUVZBFYVXEX-UHFFFAOYSA-L zinc;2-sulfanylacetate Chemical compound [Zn+2].[O-]C(=O)CS.[O-]C(=O)CS RBEYUVZBFYVXEX-UHFFFAOYSA-L 0.000 description 1
JIXJDKNPPOUBJH-UHFFFAOYSA-L zinc;2-sulfanylbenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1S.[O-]C(=O)C1=CC=CC=C1S JIXJDKNPPOUBJH-UHFFFAOYSA-L 0.000 description 1
YCFZZALTCSESPA-UHFFFAOYSA-L zinc;2-sulfanylbutanedioate Chemical compound [Zn+2].[O-]C(=O)CC(S)C([O-])=O YCFZZALTCSESPA-UHFFFAOYSA-L 0.000 description 1
QRHGLIRJVQVCJZ-UHFFFAOYSA-L zinc;2-sulfanyldecanoate Chemical compound [Zn+2].CCCCCCCCC(S)C([O-])=O.CCCCCCCCC(S)C([O-])=O QRHGLIRJVQVCJZ-UHFFFAOYSA-L 0.000 description 1
WLVAUUBKRRARBW-UHFFFAOYSA-L zinc;2-sulfanylpropanoate Chemical compound [Zn+2].CC(S)C([O-])=O.CC(S)C([O-])=O WLVAUUBKRRARBW-UHFFFAOYSA-L 0.000 description 1
YMTQMTSQMKJKPX-UHFFFAOYSA-L zinc;diphenoxide Chemical class [Zn+2].[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 YMTQMTSQMKJKPX-UHFFFAOYSA-L 0.000 description 1
PCHQDTOLHOFHHK-UHFFFAOYSA-L zinc;hydrogen carbonate Chemical compound [Zn+2].OC([O-])=O.OC([O-])=O PCHQDTOLHOFHHK-UHFFFAOYSA-L 0.000 description 1
DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
239000002076 α-tocopherol Substances 0.000 description 1
235000004835 α-tocopherol Nutrition 0.000 description 1
235000007680 β-tocopherol Nutrition 0.000 description 1
239000011590 β-tocopherol Substances 0.000 description 1
QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/138—Phenolates
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)

FR9703402A 1996-03-22 1997-03-20 Combinaisons de stabilisants a base de derives de 2,2,6,6-tetramethylpiperidine et de composes organiques du zinc pour des polymeres chlores Withdrawn FR2746405A1 (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CH75196		1996-03-22

Publications (1)

Publication Number	Publication Date
FR2746405A1 true FR2746405A1 (fr)	1997-09-26

Family

ID=4194353

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FR9703402A Withdrawn FR2746405A1 (fr)	1996-03-22	1997-03-20	Combinaisons de stabilisants a base de derives de 2,2,6,6-tetramethylpiperidine et de composes organiques du zinc pour des polymeres chlores

Country Status (16)

Country	Link
JP (1)	JPH1045983A (sv)
AT (1)	AT413210B (sv)
BE (1)	BE1012198A5 (sv)
BR (1)	BR9701422A (sv)
CA (1)	CA2200536A1 (sv)
DE (1)	DE19711690A1 (sv)
DK (1)	DK29697A (sv)
ES (1)	ES2147078B1 (sv)
FR (1)	FR2746405A1 (sv)
GB (1)	GB2311292B (sv)
IT (1)	IT1290431B1 (sv)
NL (1)	NL1005608C2 (sv)
NO (1)	NO971335L (sv)
SE (1)	SE9701011L (sv)
TW (1)	TW354800B (sv)
ZA (1)	ZA972426B (sv)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19752481A1 (de) *	1997-11-27	1999-06-02	Cit Alcatel	Isoliermaterial auf der Basis von Polyvinylchlorid
JP2000273248A (ja) *	1999-03-19	2000-10-03	Mitsubishi Chem Mkv Co	熱可塑性エラストマー及びその製造方法
JP2000273254A (ja) *	1999-03-19	2000-10-03	Mitsubishi Chem Mkv Co	熱可塑性エラストマー及びその製造方法
GB0219260D0 (en)	2002-08-19	2002-09-25	Clariant Gmbh	Improvements in or relating to organic compounds
US8822575B2 (en)	2007-08-28	2014-09-02	Basf Se	Stabilizer mixture
CN103554009B (zh) *	2013-10-22	2016-05-04	山西省化工研究所（有限公司）	一种尼龙多功能稳定剂的制备方法

Citations (7)

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Publication number	Priority date	Publication date	Assignee	Title
FR2074871A5 (sv) *	1970-01-08	1971-10-08	Sankyo Co
EP0421933A1 (de) *	1989-10-06	1991-04-10	Ciba-Geigy Ag	Stabilisierte chlorhaltige Polymerzusammensetzungen
EP0432096A1 (de) *	1989-12-06	1991-06-12	Ciba-Geigy Ag	Stabilisierte chlorhaltige Zusammensetzung
EP0446171A2 (de) *	1990-03-08	1991-09-11	Ciba-Geigy Ag	Stabilisierte chlorhaltige Polymerzusammensetzungen
EP0488950A1 (de) *	1990-11-30	1992-06-03	Ciba-Geigy Ag	Stabilisierte chlorhaltige Polymere
EP0488951A1 (de) *	1990-11-30	1992-06-03	Ciba-Geigy Ag	Stabilisierte chlorhaltige Polymere
EP0570337A2 (de) *	1992-05-13	1993-11-18	Ciba-Geigy Ag	Stabilisierte chlorhaltige Polymerzusammensetzungen

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Publication number	Priority date	Publication date	Assignee	Title
US5283273A (en) *	1990-11-30	1994-02-01	Ciba-Geigy Corporation	Stabilized chlorine-containing polymers
EP0796888B1 (de) *	1996-03-22	2005-12-14	Wolfgang Wehner	Stabilisatorkombination für chlorhaltige Polymere

1997
- 1997-03-17 DK DK029697A patent/DK29697A/da not_active Application Discontinuation
- 1997-03-19 SE SE9701011A patent/SE9701011L/sv not_active Application Discontinuation
- 1997-03-20 CA CA002200536A patent/CA2200536A1/en not_active Abandoned
- 1997-03-20 DE DE19711690A patent/DE19711690A1/de not_active Withdrawn
- 1997-03-20 ZA ZA9702426A patent/ZA972426B/xx unknown
- 1997-03-20 FR FR9703402A patent/FR2746405A1/fr not_active Withdrawn
- 1997-03-21 IT IT97MI000662A patent/IT1290431B1/it active IP Right Grant
- 1997-03-21 AT AT0050297A patent/AT413210B/de not_active IP Right Cessation
- 1997-03-21 NO NO971335A patent/NO971335L/no not_active Application Discontinuation
- 1997-03-21 ES ES009700618A patent/ES2147078B1/es not_active Expired - Fee Related
- 1997-03-21 TW TW086103573A patent/TW354800B/zh active
- 1997-03-21 BR BR9701422A patent/BR9701422A/pt not_active Application Discontinuation
- 1997-03-21 GB GB9705846A patent/GB2311292B/en not_active Expired - Fee Related
- 1997-03-21 JP JP9108012A patent/JPH1045983A/ja active Pending
- 1997-03-21 BE BE9700251A patent/BE1012198A5/fr not_active IP Right Cessation
- 1997-03-21 NL NL1005608A patent/NL1005608C2/nl not_active IP Right Cessation

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2074871A5 (sv) *	1970-01-08	1971-10-08	Sankyo Co
EP0421933A1 (de) *	1989-10-06	1991-04-10	Ciba-Geigy Ag	Stabilisierte chlorhaltige Polymerzusammensetzungen
EP0432096A1 (de) *	1989-12-06	1991-06-12	Ciba-Geigy Ag	Stabilisierte chlorhaltige Zusammensetzung
EP0446171A2 (de) *	1990-03-08	1991-09-11	Ciba-Geigy Ag	Stabilisierte chlorhaltige Polymerzusammensetzungen
EP0488950A1 (de) *	1990-11-30	1992-06-03	Ciba-Geigy Ag	Stabilisierte chlorhaltige Polymere
EP0488951A1 (de) *	1990-11-30	1992-06-03	Ciba-Geigy Ag	Stabilisierte chlorhaltige Polymere
EP0570337A2 (de) *	1992-05-13	1993-11-18	Ciba-Geigy Ag	Stabilisierte chlorhaltige Polymerzusammensetzungen

Also Published As

Publication number	Publication date
JPH1045983A (ja)	1998-02-17
SE9701011D0 (sv)	1997-03-19
NO971335D0 (no)	1997-03-21
IT1290431B1 (it)	1998-12-03
ATA50297A (de)	2005-05-15
TW354800B (en)	1999-03-21
GB2311292A (en)	1997-09-24
DE19711690A1 (de)	1997-11-06
BE1012198A5 (fr)	2000-07-04
AT413210B (de)	2005-12-15
SE9701011L (sv)	1997-09-23
NL1005608A1 (nl)	1997-09-23
GB2311292B (en)	2000-10-04
ITMI970662A1 (it)	1998-09-21
DK29697A (da)	1997-09-23
ZA972426B (en)	1997-09-22
GB9705846D0 (en)	1997-05-07
ES2147078B1 (es)	2001-04-01
ES2147078A1 (es)	2000-08-16
CA2200536A1 (en)	1997-09-22
NO971335L (no)	1997-09-23
NL1005608C2 (nl)	2000-05-22
BR9701422A (pt)	1998-11-10

Publication	Publication Date	Title
DE19741777B4 (de)	2010-07-01	Monomere Bisphosphite als Stabilisatoren für halogenhaltige Polymere und für Schmierstoffe
ES2246023T3 (es)	2006-02-01	Combinaciones de estabilizantes para polimeros clorados.
US6013703A (en)	2000-01-11	Stabilizer combination for chlorine-containing polymers
KR19980024864A (ko)	1998-07-06	Ｎ,ｎ-디메틸-6-아미노우라실로써 안정화된 경질 ｐｖｃ
JPH0711084A (ja)	1995-01-13	ポリ塩化ビニルの安定化
EP1569994B1 (de)	2008-01-09	Monosubstituierte 6-aminouracile zum stabilisieren von halogenhaltigen polymeren
NO309941B1 (no)	2001-04-23	Stabilisert myk-PVC-blanding, dens fremstilling og anvendelse
EP1510545A2 (de)	2005-03-02	Oxaalkyl-6-Aminouracile zum Stabilisieren von halogenhaltigen Polymeren
CN100467517C (zh)	2009-03-11	用于含卤聚合物的稳定剂组合物
AU3230099A (en)	1999-12-09	Cyanoacetylureas for stabilizing halogenated polymers
FR2746405A1 (fr)	1997-09-26	Combinaisons de stabilisants a base de derives de 2,2,6,6-tetramethylpiperidine et de composes organiques du zinc pour des polymeres chlores
BE1012427A3 (fr)	2000-11-07	Combinaisons de stabilisants a base de n-piperidinylmelamines monomeres et de composes organiques du zinc pour des polymeres chlores.
JPH1053571A (ja)	1998-02-24	塩素含有ポリマーのための安定剤
BE1012645A5 (fr)	2001-02-06	Bisphosphites monomeres et oligomeres comme stabilisants pour polymeres.
JPH07300544A (ja)	1995-11-14	安定化ハロゲン含有ポリマー
GB2345695A (en)	2000-07-19	Stabilizer combinations for halogen-containing polymers
DE29924285U1 (de)	2002-09-12	Cyanacetylharnstoffe zum Stabilisieren von halogenhaltigen Polymeren
MXPA97007315A (es)	1998-11-12	Bisfosfitos monomeros y oligomeros como estabilizadores del poli(cloruro de vinilo)

Legal Events

Date	Code	Title
1999-01-08	TP	Transmission of property
2001-09-28	CD	Change of name or company name
2001-09-28	TP	Transmission of property
2003-01-10	ST	Notification of lapse