FR2453187A1 - Procede de preparation de polyesters de masse moleculaire elevee et produits obtenus - Google Patents
Procede de preparation de polyesters de masse moleculaire elevee et produits obtenusInfo
- Publication number
- FR2453187A1 FR2453187A1 FR8006311A FR8006311A FR2453187A1 FR 2453187 A1 FR2453187 A1 FR 2453187A1 FR 8006311 A FR8006311 A FR 8006311A FR 8006311 A FR8006311 A FR 8006311A FR 2453187 A1 FR2453187 A1 FR 2453187A1
- Authority
- FR
- France
- Prior art keywords
- high molecular
- polyesters
- preparation
- molecular mass
- products obtained
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/80—Solid-state polycondensation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
L'invention a pour objet un polyester de masse moléculaire élevée, à faible teneur en carboxyle et utilisant une faible quantité de catalyseur. Il se prépare par un procédé en deux stades : une opération en phase fondue jusqu'à ce que la viscosité intrinsèque du prépolymère soit de 0,15 à 0,45 dl/g et une polymérisation à l'état solide en lit fluidisé jusqu'à une viscosité intrinsèque d'au moins 0,60 dl/G. Le produit polycondensé est stable et de couleur claire.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/025,697 US4205157A (en) | 1979-04-02 | 1979-04-02 | Method for production of high molecular weight polyester with low catalyst level and low carboxyl content |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2453187A1 true FR2453187A1 (fr) | 1980-10-31 |
Family
ID=21827573
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR8006311A Pending FR2453187A1 (fr) | 1979-04-02 | 1980-03-21 | Procede de preparation de polyesters de masse moleculaire elevee et produits obtenus |
Country Status (11)
Country | Link |
---|---|
US (1) | US4205157A (fr) |
JP (1) | JPS55133421A (fr) |
KR (1) | KR830002013B1 (fr) |
AU (1) | AU534752B2 (fr) |
BE (1) | BE882560A (fr) |
BR (1) | BR8001835A (fr) |
CA (1) | CA1141079A (fr) |
DE (1) | DE3012692A1 (fr) |
FR (1) | FR2453187A1 (fr) |
GB (1) | GB2045786B (fr) |
IT (1) | IT1128104B (fr) |
Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4310658A (en) * | 1980-06-18 | 1982-01-12 | Allied Corporation | Production of polyester thermally stabilized with an oxirane |
DE3213025C2 (de) * | 1982-04-02 | 1997-06-12 | Fischer Karl Ind Gmbh | Verfahren zur Nachkondensation von Polykondensaten |
JPS6155115A (ja) * | 1984-08-27 | 1986-03-19 | Nippon Ester Co Ltd | ポリアリレ−トの製造方法 |
JPH0641513B2 (ja) * | 1984-11-20 | 1994-06-01 | 三菱レイヨン株式会社 | ポリエステルの製造法 |
JPS61123624A (ja) * | 1984-11-20 | 1986-06-11 | Mitsubishi Rayon Co Ltd | ポリエステルの製法 |
US4818808A (en) * | 1987-04-22 | 1989-04-04 | Kanebo, Ltd. | Process for producing polyesters using a niobium compound as a catalyst |
AU623406B2 (en) * | 1988-06-24 | 1992-05-14 | De Beers Industrial Diamond Division (Proprietary) Limited | Particle sorting apparatus and method |
IT1226148B (it) * | 1988-07-04 | 1990-12-19 | Ausimont Spa | Copoliesteri termoplastici segmentati aventi proprieta' elastomeriche. |
DE4309227A1 (de) * | 1993-03-23 | 1994-09-29 | Zimmer Ag | Kontinuierliches Verfahren zur Herstellung von Polyester für Lebensmittelverpackungen |
DE4432839A1 (de) * | 1994-09-15 | 1996-03-21 | Zimmer Ag | Verfahren zur Einstellung des Trübungsgrades von Ethylenterephthalat-Polymeren |
IT1283083B1 (it) * | 1996-05-30 | 1998-04-07 | Sinco Eng Spa | Procedimento perfezionato per la produzione di resine poliestere |
US5663281A (en) * | 1996-07-30 | 1997-09-02 | E. I. Du Pont De Nemours And Company | Process for preparing high molecular weight polyesters |
US5760161A (en) * | 1997-02-10 | 1998-06-02 | Albemarle Corporation | Process for making unsaturated, thermosetting, brominated phthalic anhydride/polyol polyester resins |
ATE434637T1 (de) * | 2002-02-14 | 2009-07-15 | Mitsui Chemicals Inc | Polyesterharz und katalysator für die polyesterherstellung, verfahren zur herstellung von polyesterharz mit dem katalysator. |
DE10259694A1 (de) * | 2002-12-18 | 2004-07-01 | Bühler AG | Herstellung eines Polyester-Performs mit reduziertem Acetaldehydgehalt |
US7098300B1 (en) | 2002-12-19 | 2006-08-29 | Uop Llc | Apparatus and process for continuous solid-state poly-condensation in a fluidized reactor with multiple stages |
BRPI0410573B1 (pt) * | 2003-05-21 | 2015-12-01 | Dak Americas Mississippi Inc | resinas de poliéster de cristalização lenta e o método para a produção das mesmas |
US20050261462A1 (en) * | 2004-05-20 | 2005-11-24 | Nichols Carl S | Methods of making titanium-catalyzed polyester resins |
US7094863B2 (en) * | 2003-05-21 | 2006-08-22 | Wellman, Inc. | Polyester preforms useful for enhanced heat-set bottles |
US20070059465A1 (en) * | 2004-05-20 | 2007-03-15 | Thompson David E | Polyester Resins for High-Strength Articles |
DE102004010680A1 (de) | 2004-03-04 | 2005-10-06 | Zimmer Ag | Verfahren zur Herstellung von hochkondensierten Polyestern in der festen Phase |
DE102004012579A1 (de) * | 2004-03-12 | 2005-09-29 | Bühler AG | Verfahren zur Herstellung eines teilkristallinen Polykondensates |
US20080006961A1 (en) * | 2004-10-18 | 2008-01-10 | Hayward Donald W | Method For Accelerating The Solid-Stating Of Polyethylene Terephthalate |
EP1939237A4 (fr) | 2005-09-01 | 2009-09-02 | Mitsubishi Chem Corp | Procédé de production de polyester |
US8586701B2 (en) * | 2005-10-28 | 2013-11-19 | Eastman Chemical Company | Process for the preparation of copolyesters based on 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
MY166613A (en) | 2005-11-22 | 2018-07-17 | Gfbiochemicals Ltd | Glycerol levulinate ketals and their use |
DE102006012587B4 (de) * | 2006-03-16 | 2015-10-29 | Lurgi Zimmer Gmbh | Verfahren und Vorrichtung zur Kristallisation von Polyestermaterial |
TWI402293B (zh) * | 2006-04-06 | 2013-07-21 | Teijin Fibers Ltd | Production method of polyethylene terephthalate |
US7211634B1 (en) | 2006-04-28 | 2007-05-01 | Eastman Chemical Company | Process for the preparation of polyesters containing 1,4-cyclohexanedimethanol |
KR101895184B1 (ko) | 2007-11-21 | 2018-09-04 | 이스트만 케미칼 컴파니 | 플라스틱 젖병, 다른 취입 성형된 제품, 및 이들의 제조 방법 |
US8791225B2 (en) * | 2008-06-06 | 2014-07-29 | Dak Americas Mississippi Inc. | Titanium-nitride catalyzed polyester |
WO2010036884A1 (fr) * | 2008-09-25 | 2010-04-01 | Segetis, Inc. | Dérivés céto-esters |
GB201310837D0 (en) | 2013-06-18 | 2013-07-31 | Dupont Teijin Films Us Ltd | Polyester film -IV |
GB201411044D0 (en) | 2014-06-20 | 2014-08-06 | Dupont Teijin Films Us Ltd | Copolyestermides and films made therefrom |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3405098A (en) * | 1965-10-29 | 1968-10-08 | Du Pont | Process for preparing high viscosity linear condensation polyesters from partially polymerized glycol terephthalates |
FR2091807A5 (en) * | 1970-05-21 | 1972-01-14 | Sandoz Sa | Coatings of poly(ethylene glycol terephthalate) with good mechanical - thermal and electrical props |
FR2111783A1 (fr) * | 1970-10-23 | 1972-06-09 | Sandoz Sa | |
JPS5173592A (en) * | 1974-12-23 | 1976-06-25 | Asahi Chemical Ind | Senjohoriesuteruno kosojugohoho |
EP0003961A1 (fr) * | 1978-02-13 | 1979-09-19 | The Goodyear Tire & Rubber Company | Procédé pour la préparation de polytéréphtalate d'éthylèneglycol de poids moléculaire élevé exempt de catalyseur |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3644291A (en) * | 1968-11-20 | 1972-02-22 | Fmc Corp | Titanium compounds as polycondensation catalysts in preparation of linear polyesters |
US3732182A (en) * | 1970-05-01 | 1973-05-08 | Mitsubishi Rayon Co | Process for preparing linear polyesters |
DE2045914B2 (de) * | 1970-09-17 | 1975-11-27 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur Herstellung von linearen, hochmolekularen Polyestern |
US4080317A (en) * | 1970-10-23 | 1978-03-21 | Ciba-Geigy Ag | High molecular weight polycondensates from solid phase condensation |
US3842041A (en) * | 1972-07-21 | 1974-10-15 | Ici Ltd | Solid state manufacture of polyesters |
US4133800A (en) * | 1974-01-28 | 1979-01-09 | Imperial Chemical Industries Limited | Polyester production |
-
1979
- 1979-04-02 US US06/025,697 patent/US4205157A/en not_active Expired - Lifetime
-
1980
- 1980-02-11 CA CA000345377A patent/CA1141079A/fr not_active Expired
- 1980-03-04 AU AU56107/80A patent/AU534752B2/en not_active Ceased
- 1980-03-18 KR KR1019800001127A patent/KR830002013B1/ko active
- 1980-03-20 IT IT48213/80A patent/IT1128104B/it active
- 1980-03-21 GB GB8009634A patent/GB2045786B/en not_active Expired
- 1980-03-21 FR FR8006311A patent/FR2453187A1/fr active Pending
- 1980-03-27 BR BR8001835A patent/BR8001835A/pt unknown
- 1980-03-31 BE BE0/200060A patent/BE882560A/fr not_active IP Right Cessation
- 1980-04-01 DE DE19803012692 patent/DE3012692A1/de not_active Withdrawn
- 1980-04-02 JP JP4343680A patent/JPS55133421A/ja active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3405098A (en) * | 1965-10-29 | 1968-10-08 | Du Pont | Process for preparing high viscosity linear condensation polyesters from partially polymerized glycol terephthalates |
FR2091807A5 (en) * | 1970-05-21 | 1972-01-14 | Sandoz Sa | Coatings of poly(ethylene glycol terephthalate) with good mechanical - thermal and electrical props |
FR2111783A1 (fr) * | 1970-10-23 | 1972-06-09 | Sandoz Sa | |
JPS5173592A (en) * | 1974-12-23 | 1976-06-25 | Asahi Chemical Ind | Senjohoriesuteruno kosojugohoho |
EP0003961A1 (fr) * | 1978-02-13 | 1979-09-19 | The Goodyear Tire & Rubber Company | Procédé pour la préparation de polytéréphtalate d'éthylèneglycol de poids moléculaire élevé exempt de catalyseur |
Non-Patent Citations (1)
Title |
---|
CA1976 * |
Also Published As
Publication number | Publication date |
---|---|
GB2045786B (en) | 1983-05-25 |
AU534752B2 (en) | 1984-02-16 |
KR830001989A (ko) | 1983-05-21 |
KR830002013B1 (ko) | 1983-10-06 |
BR8001835A (pt) | 1980-11-18 |
GB2045786A (en) | 1980-11-05 |
AU5610780A (en) | 1980-10-09 |
IT8048213A0 (it) | 1980-03-20 |
JPS55133421A (en) | 1980-10-17 |
US4205157A (en) | 1980-05-27 |
DE3012692A1 (de) | 1980-10-16 |
IT1128104B (it) | 1986-05-28 |
BE882560A (fr) | 1980-07-16 |
CA1141079A (fr) | 1983-02-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
FR2453187A1 (fr) | Procede de preparation de polyesters de masse moleculaire elevee et produits obtenus | |
EP0250351A3 (fr) | Procédé pour la préparation de dispersions de polymères dans les polyesters hydroxylés | |
DE3772221D1 (de) | Suessware und verfahren zur herstellung derselben. | |
CA2039776A1 (fr) | Procede pour l'obtention de polyterephtalate d'ethylene modifie; fibres exemptes de boulochage issues du polymere ainsi modifie | |
FR2377420A1 (fr) | Procede de polymerisation en masse continue | |
EP0383540A3 (fr) | Composition de pâte huileuse | |
GB9514090D0 (en) | Non-catalysed oxidation of maltodextrin with an oxygen containing oxidant | |
FR2418237A1 (fr) | Procede pour l'obtention de compositions a base de derives de glycoproteines, produits resultant de ce procede et leurs applications | |
JPH021712A (ja) | アクリル酸又はメタアクリル酸のエステル‐ウレタン誘導体 | |
EP0654058B1 (fr) | Peroxycarbonates polymeres et leur procede de production | |
DK0618245T3 (da) | Polyol/epoxid-additionsprodukter til anvendelse som emulgator til flydende epoxidharpikser | |
EP0240301A2 (fr) | Désorption d'oxygène pour des polyesters ayant une couleur améliorée | |
GB991786A (en) | Organosilicon compounds | |
JPH02243668A (ja) | メチル−2−tert−ブチル−5−チオフェノールの製造法 | |
AU6480490A (en) | Polyester mixture, it's preparation and use | |
KR900006390A (ko) | 신규한 디 알릴 테레프탈레이트계 프레폴리머 및 그 제조방법 | |
KR970706229A (ko) | 나일론 6 및/또는 6.6의 아디프산으로의 전환방법(conversion of nylon 6 and/or nylon 6.6 to adipic acid) | |
EP0041629B1 (fr) | Compositions contenant des composés liquides viscoélastiques | |
KR940011578A (ko) | 중합체 수지 및 운데실렌산 또는 그의 유도체를 함유하는 조성물 | |
US3492275A (en) | Ionogenic polymerization of lactams | |
Oswald et al. | Organic sulfur compounds. XIX. Addition of dithiols to diallyl maleate: A new concept of polyester synthesis1 | |
ES422143A1 (es) | Un metodo para producir tereftalato de polietileno. | |
US2993030A (en) | Process for polymerizing vinylene carbonate | |
FR2419282A1 (fr) | Nouveau derive de benzonitrile, son procede de preparation et son application | |
Bailey et al. | A Regiospecific Free Radical Ring-Opening Polymerization |