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FR2453187A1 - Procede de preparation de polyesters de masse moleculaire elevee et produits obtenus - Google Patents

Procede de preparation de polyesters de masse moleculaire elevee et produits obtenus

Info

Publication number
FR2453187A1
FR2453187A1 FR8006311A FR8006311A FR2453187A1 FR 2453187 A1 FR2453187 A1 FR 2453187A1 FR 8006311 A FR8006311 A FR 8006311A FR 8006311 A FR8006311 A FR 8006311A FR 2453187 A1 FR2453187 A1 FR 2453187A1
Authority
FR
France
Prior art keywords
high molecular
polyesters
preparation
molecular mass
products obtained
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
FR8006311A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goodyear Tire and Rubber Co
Original Assignee
Goodyear Tire and Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Goodyear Tire and Rubber Co filed Critical Goodyear Tire and Rubber Co
Publication of FR2453187A1 publication Critical patent/FR2453187A1/fr
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • C08G63/18Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/80Solid-state polycondensation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

L'invention a pour objet un polyester de masse moléculaire élevée, à faible teneur en carboxyle et utilisant une faible quantité de catalyseur. Il se prépare par un procédé en deux stades : une opération en phase fondue jusqu'à ce que la viscosité intrinsèque du prépolymère soit de 0,15 à 0,45 dl/g et une polymérisation à l'état solide en lit fluidisé jusqu'à une viscosité intrinsèque d'au moins 0,60 dl/G. Le produit polycondensé est stable et de couleur claire.
FR8006311A 1979-04-02 1980-03-21 Procede de preparation de polyesters de masse moleculaire elevee et produits obtenus Pending FR2453187A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/025,697 US4205157A (en) 1979-04-02 1979-04-02 Method for production of high molecular weight polyester with low catalyst level and low carboxyl content

Publications (1)

Publication Number Publication Date
FR2453187A1 true FR2453187A1 (fr) 1980-10-31

Family

ID=21827573

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8006311A Pending FR2453187A1 (fr) 1979-04-02 1980-03-21 Procede de preparation de polyesters de masse moleculaire elevee et produits obtenus

Country Status (11)

Country Link
US (1) US4205157A (fr)
JP (1) JPS55133421A (fr)
KR (1) KR830002013B1 (fr)
AU (1) AU534752B2 (fr)
BE (1) BE882560A (fr)
BR (1) BR8001835A (fr)
CA (1) CA1141079A (fr)
DE (1) DE3012692A1 (fr)
FR (1) FR2453187A1 (fr)
GB (1) GB2045786B (fr)
IT (1) IT1128104B (fr)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4310658A (en) * 1980-06-18 1982-01-12 Allied Corporation Production of polyester thermally stabilized with an oxirane
DE3213025C2 (de) * 1982-04-02 1997-06-12 Fischer Karl Ind Gmbh Verfahren zur Nachkondensation von Polykondensaten
JPS6155115A (ja) * 1984-08-27 1986-03-19 Nippon Ester Co Ltd ポリアリレ−トの製造方法
JPH0641513B2 (ja) * 1984-11-20 1994-06-01 三菱レイヨン株式会社 ポリエステルの製造法
JPS61123624A (ja) * 1984-11-20 1986-06-11 Mitsubishi Rayon Co Ltd ポリエステルの製法
US4818808A (en) * 1987-04-22 1989-04-04 Kanebo, Ltd. Process for producing polyesters using a niobium compound as a catalyst
AU623406B2 (en) * 1988-06-24 1992-05-14 De Beers Industrial Diamond Division (Proprietary) Limited Particle sorting apparatus and method
IT1226148B (it) * 1988-07-04 1990-12-19 Ausimont Spa Copoliesteri termoplastici segmentati aventi proprieta' elastomeriche.
DE4309227A1 (de) * 1993-03-23 1994-09-29 Zimmer Ag Kontinuierliches Verfahren zur Herstellung von Polyester für Lebensmittelverpackungen
DE4432839A1 (de) * 1994-09-15 1996-03-21 Zimmer Ag Verfahren zur Einstellung des Trübungsgrades von Ethylenterephthalat-Polymeren
IT1283083B1 (it) * 1996-05-30 1998-04-07 Sinco Eng Spa Procedimento perfezionato per la produzione di resine poliestere
US5663281A (en) * 1996-07-30 1997-09-02 E. I. Du Pont De Nemours And Company Process for preparing high molecular weight polyesters
US5760161A (en) * 1997-02-10 1998-06-02 Albemarle Corporation Process for making unsaturated, thermosetting, brominated phthalic anhydride/polyol polyester resins
ATE434637T1 (de) * 2002-02-14 2009-07-15 Mitsui Chemicals Inc Polyesterharz und katalysator für die polyesterherstellung, verfahren zur herstellung von polyesterharz mit dem katalysator.
DE10259694A1 (de) * 2002-12-18 2004-07-01 Bühler AG Herstellung eines Polyester-Performs mit reduziertem Acetaldehydgehalt
US7098300B1 (en) 2002-12-19 2006-08-29 Uop Llc Apparatus and process for continuous solid-state poly-condensation in a fluidized reactor with multiple stages
BRPI0410573B1 (pt) * 2003-05-21 2015-12-01 Dak Americas Mississippi Inc resinas de poliéster de cristalização lenta e o método para a produção das mesmas
US20050261462A1 (en) * 2004-05-20 2005-11-24 Nichols Carl S Methods of making titanium-catalyzed polyester resins
US7094863B2 (en) * 2003-05-21 2006-08-22 Wellman, Inc. Polyester preforms useful for enhanced heat-set bottles
US20070059465A1 (en) * 2004-05-20 2007-03-15 Thompson David E Polyester Resins for High-Strength Articles
DE102004010680A1 (de) 2004-03-04 2005-10-06 Zimmer Ag Verfahren zur Herstellung von hochkondensierten Polyestern in der festen Phase
DE102004012579A1 (de) * 2004-03-12 2005-09-29 Bühler AG Verfahren zur Herstellung eines teilkristallinen Polykondensates
US20080006961A1 (en) * 2004-10-18 2008-01-10 Hayward Donald W Method For Accelerating The Solid-Stating Of Polyethylene Terephthalate
EP1939237A4 (fr) 2005-09-01 2009-09-02 Mitsubishi Chem Corp Procédé de production de polyester
US8586701B2 (en) * 2005-10-28 2013-11-19 Eastman Chemical Company Process for the preparation of copolyesters based on 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
MY166613A (en) 2005-11-22 2018-07-17 Gfbiochemicals Ltd Glycerol levulinate ketals and their use
DE102006012587B4 (de) * 2006-03-16 2015-10-29 Lurgi Zimmer Gmbh Verfahren und Vorrichtung zur Kristallisation von Polyestermaterial
TWI402293B (zh) * 2006-04-06 2013-07-21 Teijin Fibers Ltd Production method of polyethylene terephthalate
US7211634B1 (en) 2006-04-28 2007-05-01 Eastman Chemical Company Process for the preparation of polyesters containing 1,4-cyclohexanedimethanol
KR101895184B1 (ko) 2007-11-21 2018-09-04 이스트만 케미칼 컴파니 플라스틱 젖병, 다른 취입 성형된 제품, 및 이들의 제조 방법
US8791225B2 (en) * 2008-06-06 2014-07-29 Dak Americas Mississippi Inc. Titanium-nitride catalyzed polyester
WO2010036884A1 (fr) * 2008-09-25 2010-04-01 Segetis, Inc. Dérivés céto-esters
GB201310837D0 (en) 2013-06-18 2013-07-31 Dupont Teijin Films Us Ltd Polyester film -IV
GB201411044D0 (en) 2014-06-20 2014-08-06 Dupont Teijin Films Us Ltd Copolyestermides and films made therefrom

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3405098A (en) * 1965-10-29 1968-10-08 Du Pont Process for preparing high viscosity linear condensation polyesters from partially polymerized glycol terephthalates
FR2091807A5 (en) * 1970-05-21 1972-01-14 Sandoz Sa Coatings of poly(ethylene glycol terephthalate) with good mechanical - thermal and electrical props
FR2111783A1 (fr) * 1970-10-23 1972-06-09 Sandoz Sa
JPS5173592A (en) * 1974-12-23 1976-06-25 Asahi Chemical Ind Senjohoriesuteruno kosojugohoho
EP0003961A1 (fr) * 1978-02-13 1979-09-19 The Goodyear Tire & Rubber Company Procédé pour la préparation de polytéréphtalate d'éthylèneglycol de poids moléculaire élevé exempt de catalyseur

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3644291A (en) * 1968-11-20 1972-02-22 Fmc Corp Titanium compounds as polycondensation catalysts in preparation of linear polyesters
US3732182A (en) * 1970-05-01 1973-05-08 Mitsubishi Rayon Co Process for preparing linear polyesters
DE2045914B2 (de) * 1970-09-17 1975-11-27 Dynamit Nobel Ag, 5210 Troisdorf Verfahren zur Herstellung von linearen, hochmolekularen Polyestern
US4080317A (en) * 1970-10-23 1978-03-21 Ciba-Geigy Ag High molecular weight polycondensates from solid phase condensation
US3842041A (en) * 1972-07-21 1974-10-15 Ici Ltd Solid state manufacture of polyesters
US4133800A (en) * 1974-01-28 1979-01-09 Imperial Chemical Industries Limited Polyester production

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3405098A (en) * 1965-10-29 1968-10-08 Du Pont Process for preparing high viscosity linear condensation polyesters from partially polymerized glycol terephthalates
FR2091807A5 (en) * 1970-05-21 1972-01-14 Sandoz Sa Coatings of poly(ethylene glycol terephthalate) with good mechanical - thermal and electrical props
FR2111783A1 (fr) * 1970-10-23 1972-06-09 Sandoz Sa
JPS5173592A (en) * 1974-12-23 1976-06-25 Asahi Chemical Ind Senjohoriesuteruno kosojugohoho
EP0003961A1 (fr) * 1978-02-13 1979-09-19 The Goodyear Tire & Rubber Company Procédé pour la préparation de polytéréphtalate d'éthylèneglycol de poids moléculaire élevé exempt de catalyseur

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CA1976 *

Also Published As

Publication number Publication date
GB2045786B (en) 1983-05-25
AU534752B2 (en) 1984-02-16
KR830001989A (ko) 1983-05-21
KR830002013B1 (ko) 1983-10-06
BR8001835A (pt) 1980-11-18
GB2045786A (en) 1980-11-05
AU5610780A (en) 1980-10-09
IT8048213A0 (it) 1980-03-20
JPS55133421A (en) 1980-10-17
US4205157A (en) 1980-05-27
DE3012692A1 (de) 1980-10-16
IT1128104B (it) 1986-05-28
BE882560A (fr) 1980-07-16
CA1141079A (fr) 1983-02-08

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