FR2074731A1 - Oxazoles prepn - by heating nitriles with ketones alpha-substituted with a reactive group - Google Patents
Oxazoles prepn - by heating nitriles with ketones alpha-substituted with a reactive groupInfo
- Publication number
- FR2074731A1 FR2074731A1 FR7002214A FR7002214A FR2074731A1 FR 2074731 A1 FR2074731 A1 FR 2074731A1 FR 7002214 A FR7002214 A FR 7002214A FR 7002214 A FR7002214 A FR 7002214A FR 2074731 A1 FR2074731 A1 FR 2074731A1
- Authority
- FR
- France
- Prior art keywords
- oxazoles
- heating
- prepn
- nitriles
- substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000010438 heat treatment Methods 0.000 title abstract 2
- 150000002825 nitriles Chemical class 0.000 title abstract 2
- 150000002916 oxazoles Chemical class 0.000 title abstract 2
- 150000002576 ketones Chemical class 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 125000004423 acyloxy group Chemical group 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 239000003814 drug Substances 0.000 abstract 1
- 238000007429 general method Methods 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 150000003230 pyrimidines Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
- C07D263/02—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
- C07D263/30—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D263/32—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
General method for preparation of oxazoles of formula (I): by heating a mixture of a nitrile of formula R'CN with a compound of formula: R2CO-CH(X)-R3 at 50-200 degrees C in an acid medium. In (I), R1, R2, R3 = H, aliphatic, cyclic, aromatic or heterocyclic group; X = halogen, OH, acyloxy. (I) are intermediates for dyestuffs, pharmaceuticals, plant-treatment agents, plastics and certain pyrimidines Also useful as solvents, stabilisers and pH control agents.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7002214A FR2074731A1 (en) | 1970-01-22 | 1970-01-22 | Oxazoles prepn - by heating nitriles with ketones alpha-substituted with a reactive group |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7002214A FR2074731A1 (en) | 1970-01-22 | 1970-01-22 | Oxazoles prepn - by heating nitriles with ketones alpha-substituted with a reactive group |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2074731A1 true FR2074731A1 (en) | 1971-10-08 |
Family
ID=9049433
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7002214A Withdrawn FR2074731A1 (en) | 1970-01-22 | 1970-01-22 | Oxazoles prepn - by heating nitriles with ketones alpha-substituted with a reactive group |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2074731A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6063136A (en) * | 1996-08-26 | 2000-05-16 | L'oreal S.A. | Compositions containing pyrrolo-oxazole couplers for dyeing keratin fibers and dyeing methods |
US6139589A (en) * | 1996-08-26 | 2000-10-31 | L'oreal S.A. | Compositions for dyeing keratin fibers containing pyrazolo[3, 4-d]thiazoles as couplers and dyeing methods |
US6340372B1 (en) | 1996-08-26 | 2002-01-22 | L'oreal S.A. | Compositions for dyeing keratin fibers containing S-oxide-thiazolo-azoles and/or S,S-dioxide-thiazolo-azoles; their use for dyeing as couplers, method of dyeing |
-
1970
- 1970-01-22 FR FR7002214A patent/FR2074731A1/en not_active Withdrawn
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6063136A (en) * | 1996-08-26 | 2000-05-16 | L'oreal S.A. | Compositions containing pyrrolo-oxazole couplers for dyeing keratin fibers and dyeing methods |
US6139589A (en) * | 1996-08-26 | 2000-10-31 | L'oreal S.A. | Compositions for dyeing keratin fibers containing pyrazolo[3, 4-d]thiazoles as couplers and dyeing methods |
US6340372B1 (en) | 1996-08-26 | 2002-01-22 | L'oreal S.A. | Compositions for dyeing keratin fibers containing S-oxide-thiazolo-azoles and/or S,S-dioxide-thiazolo-azoles; their use for dyeing as couplers, method of dyeing |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
TP | Transmission of property | ||
ST | Notification of lapse |