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FI108044B - Elektriskt ledande beläggningsmassa, förfarande för dess framställning och dess användning - Google Patents

Elektriskt ledande beläggningsmassa, förfarande för dess framställning och dess användning Download PDF

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Publication number
FI108044B
FI108044B FI890621A FI890621A FI108044B FI 108044 B FI108044 B FI 108044B FI 890621 A FI890621 A FI 890621A FI 890621 A FI890621 A FI 890621A FI 108044 B FI108044 B FI 108044B
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FI
Finland
Prior art keywords
group
conductive polymer
electrically conductive
solvent
cal
Prior art date
Application number
FI890621A
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English (en)
Finnish (fi)
Other versions
FI890621A0 (fi
FI890621L (fi
Inventor
Michael Feldhues
Guenther Kaempf
Original Assignee
Hoechst Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst Ag filed Critical Hoechst Ag
Publication of FI890621A0 publication Critical patent/FI890621A0/fi
Publication of FI890621L publication Critical patent/FI890621L/fi
Application granted granted Critical
Publication of FI108044B publication Critical patent/FI108044B/sv

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/127—Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/044—Forming conductive coatings; Forming coatings having anti-static properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D165/00—Coating compositions based on macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24—Electrically-conducting paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2465/00—Characterised by the use of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Derivatives of such polymers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Physics & Mathematics (AREA)
  • Paints Or Removers (AREA)
  • Conductive Materials (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Non-Insulated Conductors (AREA)
  • Measurement And Recording Of Electrical Phenomena And Electrical Characteristics Of The Living Body (AREA)
  • Ultra Sonic Daignosis Equipment (AREA)
  • Measuring Pulse, Heart Rate, Blood Pressure Or Blood Flow (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Claims (6)

1. Elektriskt ledande beläggningsmassa, kännetecknad av att den innehäller 10-90 vikt-% av en elektriskt ledande polymer med 8-100 5 strukturenheter, vilka är förbundna med varandra via 2-ställning och/eller 5-ställning, och vilka statistiskt sett bestär av i medeltal 60-100 mol-% strukturenheter, vilka härstammar frän ätminstone en monomer enligt formel (I), r1 R2 10 (I). väri R1 avser en rakkedjad eller förgrenad C^-alkoxigrupp och 15 R2 avser en väteatom eller en C^-alkoxigrupp; 0-40 vikt-% är strukturenheter, vilka härstammar frän ätminstone en monomer enligt formel (II), r4 r5 » Ä r3 r6 väri R4 och R5 vardera avser självständigt en väteatom, en halogenatom, en C,.12-:: 25 alkylgrupp, alkoxialkyl, arylmetyl, aryl, en Cn^-alkoxigrupp eller en grupp -0(CH2CH20)nCH3, där n är 1-4, eller tillsammans med de C-atomer vid vilka de är bundna bildar en aromatisk ring, R3 och R6 avser vardera självständigt en väteatom eller R3 bildar tillsammans med R4 och de C-atomer vid vilka de är bundna eller R5 30 bildar tillsammans med R6 och de C-atomer vid vilka de är bundna en aroma-,·] tisk ring och X avser en syreatom, en svavelatom, en NH-grupp, en N-alkylgrupp eller en N-arylgrupp; 0-40 vikt-% är strukturenheter, vilka härstammar frän ätminstone en monomer 35 enligt formel (III), 22 1 08044 r7 Κβ R-!xR10 Xl—.—X&. ...... H H 5 vari R7, R8, R9 och R10 vardera avser självständigt en väteatom, en C^-alkylgrupp, en arylgrupp eller en C^o-alkoxigrupp, Y och Z avser vardera självständigt en syreatom, en svavelatom, en NH-10 grupp, en N-alkylgrupp eller en N-arylgrupp och R11 avser en arylengrupp, en heteroarylengrupp eller ett konjugerat system med formeln (-CH=CH-)P·, där p är 0,1,2 eller 3; och • 0-40 vikt-% är strukturenheter, vilka härstammar fran atminstone en monomer enligt formel (IV), 15 R 1 2 R 1 3 H R1 4 20 väri R12 och R13 vardera avser självständigt en väteatom, en halogenatom, en C^-alkylgrupp, en C-^o-alkoxigrupp, en C^-acylaminogrupp eller en C^-acyloxigrupp, R14 avser en halogenatom, en C^-alkylgrupp, en C^-alkoxigrupp, en C^-I! 25 acylaminogrupp, en C^^-acylgrupp eller en C^^-acyloxigrupp och X har ovan angivna betydelse; varvid den elektriskt ledande polymeren föreligger i oxiderad form och upplö-ses fullständigt vid 25 °C i aprotiska lösningsmedel, varvid lösningar erhälls, vilka innehäller minst 0,5 g polymer i 100 cm3 lösningsmedelblandning, och 30 1 0-90 vikt-% av en icke-ledande polymer, som löses upp eller fäs att svälla i ett sädant lösningsmedel vars 5P-värde är under 8,5 (cal/cm3)15 och 5H-värde är under 6,5 (cal/cm3)41.
2. Beläggningsmassa enligt patentkrav 1, kännetecknad av att den elektriskt ledande polymeren och den icke-ledande polymeren löses 35 upp eller fas att svälla i ett sädant lösningsmedel eller en sadan lösningsme- 108044 delblandning vars 5P-värde är under 5,5 (cal/cm3)1* och 5H-värde är under 5,0 (cal/cm3)*4.
3. Beläggningsmassa enligt patentkrav 1, kännetecknad av , att den icke-ledande polymeren är polyvinylformal, polyvinylacetal, polyvinyl- 5 butyral, polyvinylacetat, polyvinylklorid, polyvinylmetyleter, polyvinylmetylke-ton, polymaleinsyraanhydrid, polystyren, poly-N-vinylkarbazol, poly-N-vinylpyrrolidon, polyvinylpyridin, polymetylakrylat, polyakrylnitril, polyacetalde-hyd, polyakrolein, polyetylenoxid, polytetrahydrofuran, alifatisk polyester, poly-karbonat, polybutylisocyanat, naturligt gummi, cyklokautschukharts, polyure- 10 tan, metylcellulosa, etylcellulosa, cellulosatriacetat eller polymetylsiloxan.
4. Förfarande för att framställa en beläggningsmassa enligt patentkrav 1, kännetecknat av att den elektriskt ledande polymeren och en eventuell icke-ledande polymer upplöses tillsammans i ett lösningsmedel, vars δρ-värde är under 8,5 (cal/cm3)1* och 5h-värde är under 6,5 (cal/cm3)4*, eller de 15 tilläts svälla i ett sädant lösningsmedel och blandningen ätervinns frän lös-ningsmedlet.
5. Användning av en beläggningsmassa enligt patentkrav 1, kännetecknad av att den används för framställning av elektriskt ledande skikt pa ytan av icke-ledande och halvledande material.
6. Plastfolie, kännetecknad av att den är belagd med en beläggningsmassa enligt patentkrav 1. »« • < ’ > < • ·
FI890621A 1988-02-13 1989-02-09 Elektriskt ledande beläggningsmassa, förfarande för dess framställning och dess användning FI108044B (sv)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3804521 1988-02-13
DE3804521A DE3804521A1 (de) 1988-02-13 1988-02-13 Elektrisch leitende beschichtungsmasse, verfahren zu ihrer herstellung und ihre verwendung

Publications (3)

Publication Number Publication Date
FI890621A0 FI890621A0 (fi) 1989-02-09
FI890621L FI890621L (fi) 1989-08-14
FI108044B true FI108044B (sv) 2001-11-15

Family

ID=6347352

Family Applications (1)

Application Number Title Priority Date Filing Date
FI890621A FI108044B (sv) 1988-02-13 1989-02-09 Elektriskt ledande beläggningsmassa, förfarande för dess framställning och dess användning

Country Status (14)

Country Link
US (1) US5213714A (sv)
EP (1) EP0328981B1 (sv)
JP (1) JPH02147671A (sv)
CN (1) CN1035315A (sv)
AT (1) ATE95829T1 (sv)
AU (1) AU617149B2 (sv)
CA (1) CA1340364C (sv)
DE (2) DE3804521A1 (sv)
DK (1) DK173759B1 (sv)
ES (1) ES2059583T3 (sv)
FI (1) FI108044B (sv)
IL (1) IL89247A0 (sv)
NO (1) NO305913B1 (sv)
PT (1) PT89687B (sv)

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Also Published As

Publication number Publication date
DE3804521A1 (de) 1989-08-24
AU2978589A (en) 1989-08-17
DK63589D0 (da) 1989-02-10
NO890584L (no) 1989-08-14
CA1340364C (en) 1999-02-02
DE58905864D1 (de) 1993-11-18
ATE95829T1 (de) 1993-10-15
FI890621A0 (fi) 1989-02-09
DK173759B1 (da) 2001-09-10
FI890621L (fi) 1989-08-14
PT89687B (pt) 1995-05-31
DK63589A (da) 1989-08-14
EP0328981A3 (de) 1991-03-20
JPH02147671A (ja) 1990-06-06
NO890584D0 (no) 1989-02-10
US5213714A (en) 1993-05-25
EP0328981A2 (de) 1989-08-23
AU617149B2 (en) 1991-11-21
CN1035315A (zh) 1989-09-06
ES2059583T3 (es) 1994-11-16
NO305913B1 (no) 1999-08-16
PT89687A (pt) 1989-10-04
EP0328981B1 (de) 1993-10-13
IL89247A0 (en) 1989-09-10

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