ES8705839A1 - Procedimiento mejorado para preparar 2,2,2 trifluoroetanol. - Google Patents
Procedimiento mejorado para preparar 2,2,2 trifluoroetanol.Info
- Publication number
- ES8705839A1 ES8705839A1 ES553353A ES553353A ES8705839A1 ES 8705839 A1 ES8705839 A1 ES 8705839A1 ES 553353 A ES553353 A ES 553353A ES 553353 A ES553353 A ES 553353A ES 8705839 A1 ES8705839 A1 ES 8705839A1
- Authority
- ES
- Spain
- Prior art keywords
- trifluoroethanol
- preparation
- zinc
- copper
- producing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
MODIFICACIONES EN UN METODO PARA PREPARAR 2,2,2-TRIFLUOROETANOL. CONSISTE EN HACER REACCIONAR ESTER 2,2,2-TRIFLUOROETILICO DEL ACIDO TRIFLUOROACETICO CON HIDROGENO ELEMENTAL EN FASE ACUOSA, EN PRESENCIA DE UN CATALIZADOR QUE CONTOIENE DE 0 A 0,1 PARTES EN PESO DE OXIDO DE CROMO POR UNA PARTE EN PESO DE OXIDO DE ZINC U OXIDO DE COBRE, LLEVANDOSE A CABO LA REACCION A UNA TEMPERATURA COMPRENDIDA ENTRE 100 Y 400JC Y A UNA PRESION TOTAL COMPRENDIDA ENTRE 1 Y 5 BARES (ABSOLUTOS), Y UTILIZANDOSE UNA RELACION MOLAR DE HIDROGENO A ESTER COMPRENDIDA ENTRE 1:1 Y 5:1. TIENE APLICACIONES EN REACCIONES FOTOLITICAS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19853510883 DE3510883A1 (de) | 1985-03-26 | 1985-03-26 | Verfahren zur herstellung von 2.2.2.-trifluoraethanol |
Publications (2)
Publication Number | Publication Date |
---|---|
ES553353A0 ES553353A0 (es) | 1987-05-16 |
ES8705839A1 true ES8705839A1 (es) | 1987-05-16 |
Family
ID=6266341
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES553353A Expired ES8705839A1 (es) | 1985-03-26 | 1986-03-25 | Procedimiento mejorado para preparar 2,2,2 trifluoroetanol. |
Country Status (7)
Country | Link |
---|---|
US (1) | US4694112A (es) |
EP (1) | EP0199072B1 (es) |
JP (1) | JPH0649664B2 (es) |
AT (1) | ATE59628T1 (es) |
CA (1) | CA1271200A (es) |
DE (2) | DE3510883A1 (es) |
ES (1) | ES8705839A1 (es) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4017492A1 (de) * | 1989-11-06 | 1991-12-05 | Kali Chemie Ag | Reinigungszusammensetzungen aus wasserstoffhaltigen fluorchlorkohlenwasserstoffen und partiell fluorierten alkanolen |
GB9125678D0 (en) * | 1991-12-03 | 1992-01-29 | Ici Plc | Catalyst treatment process |
US5334779A (en) * | 1993-06-01 | 1994-08-02 | Eastman Kodak Company | Catalyst compositions and the use thereof in the hydrogenation of carboxylic acid esters |
JP2897099B2 (ja) * | 1993-09-20 | 1999-05-31 | 富士通株式会社 | タンデム・コネクション・メインテナンス方式 |
AU2578201A (en) * | 1999-12-14 | 2001-06-25 | Halocarbon Products Corporation | Hydrothermal hydrolysis of halogenated compounds |
JP5300392B2 (ja) * | 2008-09-25 | 2013-09-25 | 三井化学株式会社 | イソプロパノールの製造方法 |
JP5605130B2 (ja) * | 2010-09-28 | 2014-10-15 | セントラル硝子株式会社 | 含フッ素アルコールの製造方法 |
CN110624584B (zh) * | 2019-09-09 | 2022-09-13 | 浙江工业大学 | 一种Fe-Zn基氮掺杂纳米催化剂及其制备氟醇类化合物的应用 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3356746A (en) * | 1964-09-30 | 1967-12-05 | Allied Chem | Preparation of 2, 2, 2-trifluoroethanol by catalytic hydrogenation |
US4072726A (en) * | 1977-01-21 | 1978-02-07 | Allied Chemical Corporation | Hydrogenation of fluorinated esters |
BE864567A (fr) * | 1977-04-25 | 1978-07-03 | Chevron Res | Procede d'hydrogenation d'esters en acools |
US4199479A (en) * | 1978-02-24 | 1980-04-22 | Chevron Research Company | Hydrogenation catalyst |
IT1190783B (it) * | 1981-04-29 | 1988-02-24 | Davy Mckee Oil & Chem | Processo per l'idrogenolisi di esteri di acidi carbossilici |
JPS58159433A (ja) * | 1982-03-18 | 1983-09-21 | Mitsubishi Gas Chem Co Inc | エチレングリコ−ルの製造法 |
US4421939A (en) * | 1982-10-15 | 1983-12-20 | Union Carbide Corporation | Production of ethanol from acetic acid |
EP0175558A1 (en) * | 1984-09-17 | 1986-03-26 | EASTMAN KODAK COMPANY (a New Jersey corporation) | Process for the vapor phase hydrogenation of carboxylic acids to esters and alcohols |
JP3783339B2 (ja) * | 1997-06-13 | 2006-06-07 | 松下電工株式会社 | 超音波美容器 |
-
1985
- 1985-03-26 DE DE19853510883 patent/DE3510883A1/de not_active Withdrawn
-
1986
- 1986-03-10 US US06/837,824 patent/US4694112A/en not_active Expired - Lifetime
- 1986-03-15 EP EP86103507A patent/EP0199072B1/de not_active Expired - Lifetime
- 1986-03-15 DE DE8686103507T patent/DE3676336D1/de not_active Expired - Fee Related
- 1986-03-15 AT AT86103507T patent/ATE59628T1/de not_active IP Right Cessation
- 1986-03-25 ES ES553353A patent/ES8705839A1/es not_active Expired
- 1986-03-25 CA CA000504959A patent/CA1271200A/en not_active Expired - Fee Related
- 1986-03-26 JP JP61066098A patent/JPH0649664B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE3510883A1 (de) | 1986-10-09 |
EP0199072A2 (de) | 1986-10-29 |
ATE59628T1 (de) | 1991-01-15 |
ES553353A0 (es) | 1987-05-16 |
US4694112A (en) | 1987-09-15 |
EP0199072B1 (de) | 1991-01-02 |
DE3676336D1 (de) | 1991-02-07 |
CA1271200A (en) | 1990-07-03 |
JPS61221139A (ja) | 1986-10-01 |
EP0199072A3 (en) | 1987-05-06 |
JPH0649664B2 (ja) | 1994-06-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 20041102 |