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ES2530665T3 - Composición de agentes de recubrimiento catalizada por complejo de imidazol-carboxilato de zinc - Google Patents

Composición de agentes de recubrimiento catalizada por complejo de imidazol-carboxilato de zinc Download PDF

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Publication number
ES2530665T3
ES2530665T3 ES12708548T ES12708548T ES2530665T3 ES 2530665 T3 ES2530665 T3 ES 2530665T3 ES 12708548 T ES12708548 T ES 12708548T ES 12708548 T ES12708548 T ES 12708548T ES 2530665 T3 ES2530665 T3 ES 2530665T3
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Spain
Prior art keywords
radical
zinc
aromatic
aryl
composition
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Active
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ES12708548T
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English (en)
Inventor
Elke Westhoff
Peter Hoffmann
Bernadette Möller
Benedikt Schnier
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BASF Coatings GmbH
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BASF Coatings GmbH
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/53—Base coat plus clear coat type
    • B05D7/534—Base coat plus clear coat type the first layer being let to dry at least partially before applying the second layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/54—No clear coat specified
    • B05D7/544—No clear coat specified the first layer is let to dry at least partially before applying the second layer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
    • C08G18/163—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
    • C08G18/165—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22 covered by C08G18/18 and C08G18/24
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/166—Catalysts not provided for in the groups C08G18/18 - C08G18/26
    • C08G18/168—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/20—Heterocyclic amines; Salts thereof
    • C08G18/2009—Heterocyclic amines; Salts thereof containing one heterocyclic ring
    • C08G18/2027—Heterocyclic amines; Salts thereof containing one heterocyclic ring having two nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
    • C08G18/6225—Polymers of esters of acrylic or methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

Composición de agente de recubrimiento que contiene - por lo menos un componente (A) que tiene grupos polihidroxilo, - por lo menos un componente (B) que tiene grupos poliisocianato, - por lo menos un complejo de imidazol-carboxilato de zinc (D) que puede ser producido mediante reacción de por lo menos un biscarboxilato de Zn (II) con uno o varios imidazoles de la fórmula general (I)**Fórmula** donde R1 representa un radical hidrocarburo acíclico o cíclico, saturado o insaturado, un radical hidrocarburo aromático o un radical Rv-arilo, donde Rv representa un radical alquileno y arilo representa un radical aromático, y donde todos los radicales antes mencionados pueden contener heteroátomos, R2, R3 y R4 representan independientemente uno de otro hidrógeno, un radical hidrocarburo acíclico o cíclico, saturado o insaturado, un radical hidrocarburo aromático o un radical Rv-arilo, donde Rv representa un radical alquileno y arilo representa un radical aromático y donde todos los radicales antes mencionados pueden contener heteroátomos, con la condición de que se excluyen complejos de (1-metilimidazol)-bis(2-etilhexanoato) de zinc (D), los cuales son obtenibles por reacción de bis(2-etilhexanoato de zinc (II)) con 1-metilimidazol en una relación molar de 1 a <= 2,2, y - por lo menos un ácido carboxílico aromático (S) monomérico, en el cual el grupo carboxilo está en conjugación con un sistema de electrones pi.
ES12708548T 2011-03-18 2012-03-15 Composición de agentes de recubrimiento catalizada por complejo de imidazol-carboxilato de zinc Active ES2530665T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161453986P 2011-03-18 2011-03-18
EP11158846 2011-03-18
PCT/EP2012/054546 WO2012126796A1 (de) 2011-03-18 2012-03-15 Zink-imidazol-carboxylat-komplex katalysierte beschichtungsmittelzusammensetzung

Publications (1)

Publication Number Publication Date
ES2530665T3 true ES2530665T3 (es) 2015-03-04

Family

ID=45819217

Family Applications (1)

Application Number Title Priority Date Filing Date
ES12708548T Active ES2530665T3 (es) 2011-03-18 2012-03-15 Composición de agentes de recubrimiento catalizada por complejo de imidazol-carboxilato de zinc

Country Status (8)

Country Link
US (1) US9206330B2 (es)
EP (1) EP2686362B1 (es)
JP (1) JP6071993B2 (es)
AU (1) AU2012230533B2 (es)
BR (1) BR112013023578A2 (es)
ES (1) ES2530665T3 (es)
MX (1) MX2013010492A (es)
WO (1) WO2012126796A1 (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014514380A (ja) * 2011-03-14 2014-06-19 ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング ポリウレタン被覆剤組成物、該被覆剤組成物を使用する多工程被覆法ならびにクリヤーラッカーおよび顔料が配合された塗料としての該被覆剤組成物の使用、または自動車補修用塗装のための、および／またはプラスチック基体および／または輸送用車両の被覆のための前記被覆法の使用
EP2686361B1 (de) * 2011-03-14 2014-11-26 BASF Coatings GmbH Polyurethan-beschichtungsmittelzusammensetzung, mehrstufige beschichtungsverfahren unter verwendung dieser beschichtungsmittelzusammensetzungen sowie die verwendung der beschichtungsmittelzusammensetzung als klarlack und pigmentierter lack bzw. anwendung des beschichtungsverfahrens für die automobilreparaturlackierung und/oder für die beschichtung von kunststoffsubstraten und/oder nutzfahrzeugen
BR112013020084B8 (pt) * 2011-03-14 2020-06-30 Basf Coatings Gmbh composição de material de revestimento, método de revestimento multiestágio, uso de uma composição de material de revestimento e uso de pelo menos um complexo zinco-amidina (d) e pelo menos um ácido carboxílico aromático monomérico (s) opcionalmente substituído
CN104039857B (zh) * 2012-01-25 2019-05-31 巴斯夫涂料有限公司 (1-甲基咪唑)双(2-乙基己酸)锌配合物催化的涂料组合物
US9631112B2 (en) 2012-07-25 2017-04-25 Basf Coatings Gmbh Polyurethane coating material composition, multi-stage coating methods, and also the use of the coating material composition
ES2691933T3 (es) 2012-07-25 2018-11-29 Basf Coatings Gmbh Composiciones de agente de recubrimiento de poliuretano, métodos de recubrimiento multietapas
EP2851379A1 (de) 2013-09-23 2015-03-25 BASF Coatings GmbH Beschichtungsmittelzusammensetzungen und daraus hergestelllte, bei niedrigen Temperaturen härtbare Beschichtungen und sowie deren Verwendung
EP2851403A1 (de) 2013-09-23 2015-03-25 BASF Coatings GmbH Beschichtungsmittelzusammensetzungen und daraus hergestellte, bei niedrigen temperaturen härtbare beschichtungen und sowie deren verwendung
JPWO2015087920A1 (ja) * 2013-12-12 2017-03-16 関西ペイント株式会社 塗料組成物
EP2910612A1 (de) 2014-02-20 2015-08-26 BASF Coatings GmbH Beschichtungsmittelzusammensetzungen und daraus hergestellte Beschichtungen und sowie deren Verwendung
US10982037B2 (en) 2016-05-26 2021-04-20 Sekisui Chemical Co., Ltd. Polyurethane composition
WO2020136016A1 (en) 2018-12-24 2020-07-02 Basf Coatings Gmbh Low temperature curing of waterborne coatings
EP3956377A4 (en) * 2019-04-18 2022-11-02 Dow Global Technologies LLC ADHESIVE COMPOSITION
EP4015547A1 (de) 2020-12-15 2022-06-22 Covestro Deutschland AG Nichtionisch hydrophilierte polyisocyanate, katalyse mit zink-komplexen
WO2023157942A1 (ja) * 2022-02-18 2023-08-24 関西ペイント株式会社 塗料組成物及び塗膜形成方法

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Also Published As

Publication number Publication date
JP6071993B2 (ja) 2017-02-01
WO2012126796A1 (de) 2012-09-27
BR112013023578A2 (pt) 2016-12-06
EP2686362B1 (de) 2015-01-14
US9206330B2 (en) 2015-12-08
MX2013010492A (es) 2013-10-17
US20140162074A1 (en) 2014-06-12
AU2012230533B2 (en) 2014-08-28
JP2014510174A (ja) 2014-04-24
AU2012230533A1 (en) 2013-09-19
EP2686362A1 (de) 2014-01-22

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