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ES2527359B1 - ADSORBENT COMPOSITE MATERIAL THAT INCLUDES NOBLE METALS AND A TENSIOACTIVE POLYMER, SYNTHESIS PROCEDURE AND ITS USE FOR THE DESULFURATION OF FLUIDS - Google Patents

ADSORBENT COMPOSITE MATERIAL THAT INCLUDES NOBLE METALS AND A TENSIOACTIVE POLYMER, SYNTHESIS PROCEDURE AND ITS USE FOR THE DESULFURATION OF FLUIDS Download PDF

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Publication number
ES2527359B1
ES2527359B1 ES201330939A ES201330939A ES2527359B1 ES 2527359 B1 ES2527359 B1 ES 2527359B1 ES 201330939 A ES201330939 A ES 201330939A ES 201330939 A ES201330939 A ES 201330939A ES 2527359 B1 ES2527359 B1 ES 2527359B1
Authority
ES
Spain
Prior art keywords
fluids
composite material
polymer
noble metals
tensioactive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
ES201330939A
Other languages
Spanish (es)
Other versions
ES2527359A1 (en
Inventor
Ramon Pons Pons
Jordi Morros Camps
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RECURSOS ENERGETICOS DE BIOMASA SL
RECURSOS ENERGETICOS DE BIOMASA S L
Consejo Superior de Investigaciones Cientificas CSIC
Original Assignee
RECURSOS ENERGETICOS DE BIOMASA SL
RECURSOS ENERGETICOS DE BIOMASA S L
Consejo Superior de Investigaciones Cientificas CSIC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RECURSOS ENERGETICOS DE BIOMASA SL, RECURSOS ENERGETICOS DE BIOMASA S L, Consejo Superior de Investigaciones Cientificas CSIC filed Critical RECURSOS ENERGETICOS DE BIOMASA SL
Priority to ES201330939A priority Critical patent/ES2527359B1/en
Priority to PCT/ES2014/070504 priority patent/WO2014202815A1/en
Publication of ES2527359A1 publication Critical patent/ES2527359A1/en
Application granted granted Critical
Publication of ES2527359B1 publication Critical patent/ES2527359B1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3425—Regenerating or reactivating of sorbents or filter aids comprising organic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/12—Recovery of used adsorbent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/46—Materials comprising a mixture of inorganic and organic materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Material compuesto adsorbente que comprende metales nobles y un polímero tensioactivo, procedimiento de síntesis y su utilización para la desulfuración de fluidos.#La invención se refiere a un material de elevada superficie específica compuesto por un polímero tensioactivo y nanopartículas metálicas, a su procedimiento de síntesis, y a la utilización de dicho material como agente desulfurador de alto rendimiento, en fluidos que contengan impurezas de compuestos sulfurados, especialmente combustibles fluidos, y más especialmente, en derivados del petróleo u otras fuentes dedicadas al campo de la energía.Adsorbent composite material comprising noble metals and a surfactant polymer, synthesis process and its use for the desulfurization of fluids. # The invention relates to a high surface specific material composed of a surfactant polymer and metal nanoparticles, to its synthesis process , and the use of said material as a high performance desulfurizing agent, in fluids containing impurities of sulfur compounds, especially fluid fuels, and more especially, in petroleum derivatives or other sources dedicated to the field of energy.

Description



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Claims (1)



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ES201330939A 2013-06-21 2013-06-21 ADSORBENT COMPOSITE MATERIAL THAT INCLUDES NOBLE METALS AND A TENSIOACTIVE POLYMER, SYNTHESIS PROCEDURE AND ITS USE FOR THE DESULFURATION OF FLUIDS Expired - Fee Related ES2527359B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
ES201330939A ES2527359B1 (en) 2013-06-21 2013-06-21 ADSORBENT COMPOSITE MATERIAL THAT INCLUDES NOBLE METALS AND A TENSIOACTIVE POLYMER, SYNTHESIS PROCEDURE AND ITS USE FOR THE DESULFURATION OF FLUIDS
PCT/ES2014/070504 WO2014202815A1 (en) 2013-06-21 2014-06-20 Adsorbent composite material comprising noble metals and a surfactant polymer, synthesis method and use thereof for the desulfurisation of fluids

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES201330939A ES2527359B1 (en) 2013-06-21 2013-06-21 ADSORBENT COMPOSITE MATERIAL THAT INCLUDES NOBLE METALS AND A TENSIOACTIVE POLYMER, SYNTHESIS PROCEDURE AND ITS USE FOR THE DESULFURATION OF FLUIDS

Publications (2)

Publication Number Publication Date
ES2527359A1 ES2527359A1 (en) 2015-01-22
ES2527359B1 true ES2527359B1 (en) 2015-11-02

Family

ID=52103995

Family Applications (1)

Application Number Title Priority Date Filing Date
ES201330939A Expired - Fee Related ES2527359B1 (en) 2013-06-21 2013-06-21 ADSORBENT COMPOSITE MATERIAL THAT INCLUDES NOBLE METALS AND A TENSIOACTIVE POLYMER, SYNTHESIS PROCEDURE AND ITS USE FOR THE DESULFURATION OF FLUIDS

Country Status (2)

Country Link
ES (1) ES2527359B1 (en)
WO (1) WO2014202815A1 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10696906B2 (en) 2017-09-29 2020-06-30 Marathon Petroleum Company Lp Tower bottoms coke catching device
US12000720B2 (en) 2018-09-10 2024-06-04 Marathon Petroleum Company Lp Product inventory monitoring
US12031676B2 (en) 2019-03-25 2024-07-09 Marathon Petroleum Company Lp Insulation securement system and associated methods
US11975316B2 (en) 2019-05-09 2024-05-07 Marathon Petroleum Company Lp Methods and reforming systems for re-dispersing platinum on reforming catalyst
US11384301B2 (en) 2020-02-19 2022-07-12 Marathon Petroleum Company Lp Low sulfur fuel oil blends for stability enhancement and associated methods
US11898109B2 (en) 2021-02-25 2024-02-13 Marathon Petroleum Company Lp Assemblies and methods for enhancing control of hydrotreating and fluid catalytic cracking (FCC) processes using spectroscopic analyzers
US11702600B2 (en) 2021-02-25 2023-07-18 Marathon Petroleum Company Lp Assemblies and methods for enhancing fluid catalytic cracking (FCC) processes during the FCC process using spectroscopic analyzers
US11905468B2 (en) 2021-02-25 2024-02-20 Marathon Petroleum Company Lp Assemblies and methods for enhancing control of fluid catalytic cracking (FCC) processes using spectroscopic analyzers
US20220268694A1 (en) 2021-02-25 2022-08-25 Marathon Petroleum Company Lp Methods and assemblies for determining and using standardized spectral responses for calibration of spectroscopic analyzers
US11692141B2 (en) 2021-10-10 2023-07-04 Marathon Petroleum Company Lp Methods and systems for enhancing processing of hydrocarbons in a fluid catalytic cracking unit using a renewable additive
CA3188122A1 (en) 2022-01-31 2023-07-31 Marathon Petroleum Company Lp Systems and methods for reducing rendered fats pour point

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004004209A1 (en) * 2004-01-27 2005-08-18 Merck Patent Gmbh Use of random copolymer with hydrophobic and hydrophilic groups in different structural units as emulsifier is useful for producing polymer-modified nanoparticles, e.g. of silica, silver or metal sulfide or carbonate for use in polymer
CN103041764B (en) * 2012-12-24 2014-12-31 南京工业大学 Adsorbent for fuel oil desulfurization, preparation method and application thereof

Also Published As

Publication number Publication date
ES2527359A1 (en) 2015-01-22
WO2014202815A1 (en) 2014-12-24

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Effective date: 20220728