ES2183544T3 - Tratamiento superficial con plasma de lentes de contacto de hidrogel de silicona. - Google Patents
Tratamiento superficial con plasma de lentes de contacto de hidrogel de silicona.Info
- Publication number
- ES2183544T3 ES2183544T3 ES99918751T ES99918751T ES2183544T3 ES 2183544 T3 ES2183544 T3 ES 2183544T3 ES 99918751 T ES99918751 T ES 99918751T ES 99918751 T ES99918751 T ES 99918751T ES 2183544 T3 ES2183544 T3 ES 2183544T3
- Authority
- ES
- Spain
- Prior art keywords
- lens
- silicone hydrogel
- hydrogel contact
- contact lens
- fissures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000017 hydrogel Substances 0.000 title abstract 2
- 229920001296 polysiloxane Polymers 0.000 title abstract 2
- 238000004381 surface treatment Methods 0.000 title 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 2
- 238000004630 atomic force microscopy Methods 0.000 abstract 2
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 230000001954 sterilising effect Effects 0.000 abstract 1
- 238000004659 sterilization and disinfection Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/123—Treatment by wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00009—Production of simple or compound lenses
- B29D11/00038—Production of contact lenses
- B29D11/00125—Auxiliary operations, e.g. removing oxygen from the mould, conveying moulds from a storage to the production line in an inert atmosphere
- B29D11/00192—Demoulding, e.g. separating lenses from mould halves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y15/00—Nanotechnology for interacting, sensing or actuating, e.g. quantum dots as markers in protein assays or molecular motors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/056—Forming hydrophilic coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/08—Heat treatment
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
- G02B1/043—Contact lenses
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/12—Optical coatings produced by application to, or surface treatment of, optical elements by surface treatment, e.g. by irradiation
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/02—Lenses; Lens systems ; Methods of designing lenses
- G02C7/04—Contact lenses for the eyes
- G02C7/049—Contact lenses having special fitting or structural features achieved by special materials or material structures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2343/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Derivatives of such polymers
- C08J2343/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2443/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Derivatives of such polymers
- C08J2443/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2483/04—Polysiloxanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
- Nanotechnology (AREA)
- Ophthalmology & Optometry (AREA)
- General Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Thermal Sciences (AREA)
- Eyeglasses (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
Abstract
Un método para tratar la superficie de una lente de contacto de hidrogel de silicona mediante una fabricación controlada incluyendo los pasos siguientes: (a) tratar con plasma la lente con una atmósfera conteniendo oxígeno durante más de 4 minutos por lado, a un vatiaje de 100 a 1000 vatios y una presión de 0,1 a 1,0 Torr (13,3 a 133 N/m2), para producir un recubrimiento conteniendo silicato, (b) hidratar la lente sumergiendo la lente en una solución acuosa, por lo que la cantidad de agua absorbida por la lente es al menos cinco por ciento en peso del material de lente, (c) someter la lente hidratada a esterilización por calor, por lo que la lente esterilizada por calor tiene un recubrimiento conteniendo silicato caracterizado por una configuración de mosaico de placas sobresalientes rodeadas por fisuras en retroceso al ver una imagen de Atomic Force Microscopy (AFM) de 50x50 micras (m) cuadradas, donde la profundidad de las fisuras es como media entre aproximadamente 100 y 500 angströms (10 y 50 nm) y la cobertura de placa es como media entre 40 y 99 por ciento.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US8433298P | 1998-05-05 | 1998-05-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2183544T3 true ES2183544T3 (es) | 2003-03-16 |
Family
ID=22184287
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES99918751T Expired - Lifetime ES2183544T3 (es) | 1998-05-05 | 1999-04-21 | Tratamiento superficial con plasma de lentes de contacto de hidrogel de silicona. |
Country Status (13)
Country | Link |
---|---|
US (2) | US6193369B1 (es) |
EP (1) | EP1080138B1 (es) |
JP (1) | JP2002513947A (es) |
KR (1) | KR20010043297A (es) |
CN (1) | CN1299387A (es) |
AU (1) | AU740278B2 (es) |
BR (1) | BR9910345A (es) |
CA (1) | CA2328897A1 (es) |
DE (1) | DE69902654T2 (es) |
ES (1) | ES2183544T3 (es) |
ID (1) | ID26512A (es) |
TW (1) | TW506982B (es) |
WO (1) | WO1999057177A1 (es) |
Families Citing this family (124)
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EP1927882B1 (en) | 1999-12-10 | 2015-09-23 | Novartis AG | Contact lens |
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US6599559B1 (en) | 2000-04-03 | 2003-07-29 | Bausch & Lomb Incorporated | Renewable surface treatment of silicone medical devices with reactive hydrophilic polymers |
JP2003517503A (ja) * | 2000-05-12 | 2003-05-27 | ボシュ・アンド・ロム・インコーポレイテッド | 可撓性カーボンコーティングを有するシリコーンヒドロゲルコンタクトレンズのプラズマ表面処理 |
JP2004512866A (ja) * | 2000-09-19 | 2004-04-30 | ボシュ・アンド・ロム・インコーポレイテッド | ポリマーレンズコーティングを適用するための方法 |
US20040151755A1 (en) * | 2000-12-21 | 2004-08-05 | Osman Rathore | Antimicrobial lenses displaying extended efficacy, processes to prepare them and methods of their use |
US6774178B2 (en) * | 2001-01-05 | 2004-08-10 | Novartis Ag | Tinted, high Dk ophthalmic molding and a method for making same |
US6815074B2 (en) | 2001-05-30 | 2004-11-09 | Novartis Ag | Polymeric materials for making contact lenses |
US6609794B2 (en) * | 2001-06-05 | 2003-08-26 | Adaptive Optics Associates, Inc. | Method of treating the human eye with a wavefront sensor-based ophthalmic instrument |
US6648860B2 (en) | 2001-07-13 | 2003-11-18 | Liebel-Flarsheim Company | Contrast delivery syringe with internal hydrophilic surface treatment for the prevention of bubble adhesion |
US20030095230A1 (en) * | 2001-08-02 | 2003-05-22 | Neely Frank L. | Antimicrobial lenses and methods of their use related patent applications |
US6669341B2 (en) | 2001-08-31 | 2003-12-30 | Metrologic Instruments, Inc. | Ophthalmic instrument having wavefront sensor with multiple imaging devices that simultaneously capture multiple images of an array of spots produced by a lenslet array |
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US20040150788A1 (en) * | 2002-11-22 | 2004-08-05 | Ann-Margret Andersson | Antimicrobial lenses, processes to prepare them and methods of their use |
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AU2003902102A0 (en) * | 2003-05-02 | 2003-05-22 | The Institute For Eye Research | Contact lens |
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- 1999-04-21 BR BR9910345-1A patent/BR9910345A/pt not_active IP Right Cessation
- 1999-04-21 JP JP2000547142A patent/JP2002513947A/ja active Pending
- 1999-04-21 CA CA002328897A patent/CA2328897A1/en not_active Abandoned
- 1999-04-21 WO PCT/US1999/008749 patent/WO1999057177A1/en not_active Application Discontinuation
- 1999-04-21 DE DE69902654T patent/DE69902654T2/de not_active Expired - Fee Related
- 1999-04-21 US US09/295,675 patent/US6193369B1/en not_active Expired - Fee Related
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DE69902654T2 (de) | 2003-04-10 |
KR20010043297A (ko) | 2001-05-25 |
EP1080138B1 (en) | 2002-08-28 |
BR9910345A (pt) | 2001-01-09 |
EP1080138A1 (en) | 2001-03-07 |
DE69902654D1 (de) | 2002-10-02 |
AU740278B2 (en) | 2001-11-01 |
CA2328897A1 (en) | 1999-11-11 |
CN1299387A (zh) | 2001-06-13 |
WO1999057177A1 (en) | 1999-11-11 |
TW506982B (en) | 2002-10-21 |
JP2002513947A (ja) | 2002-05-14 |
ID26512A (id) | 2001-01-11 |
US20030039748A1 (en) | 2003-02-27 |
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