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ES2169812T3 - Procedimiento catalitico de gases, con contenido elevado en oxigeno, con miras a la reduccion de emisiones de oxidos de nitrogeno. - Google Patents

Procedimiento catalitico de gases, con contenido elevado en oxigeno, con miras a la reduccion de emisiones de oxidos de nitrogeno.

Info

Publication number
ES2169812T3
ES2169812T3 ES96931848T ES96931848T ES2169812T3 ES 2169812 T3 ES2169812 T3 ES 2169812T3 ES 96931848 T ES96931848 T ES 96931848T ES 96931848 T ES96931848 T ES 96931848T ES 2169812 T3 ES2169812 T3 ES 2169812T3
Authority
ES
Spain
Prior art keywords
oxygen
view
nitrogen oxides
oxide
catalytic gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96931848T
Other languages
English (en)
Inventor
Philippe Barthe
Catherine Hedouin
Thierry Seguelong
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhodia Chimie SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Chimie SAS filed Critical Rhodia Chimie SAS
Application granted granted Critical
Publication of ES2169812T3 publication Critical patent/ES2169812T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/208—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/206—Rare earth metals
    • B01D2255/2065—Cerium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20715—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/2073—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/40—Mixed oxides
    • B01D2255/407—Zr-Ce mixed oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/01—Engine exhaust gases
    • B01D2258/012—Diesel engines and lean burn gasoline engines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

LA INVENCION SE REFIERE A UN METODO PARA EL TRATAMIENTO CATALITICO DE GASES CON ELEVADO CONTENIDO EN OXIGENO QUE REDUCE LAS EMISIONES DE OXIDOS DE NITROGENO Y QUE SE CARACTERIZA PORQUE UTILIZA UNA COMPOSICION CATALITICA QUE COMPRENDE OXIDO DE MANGANESO Y AL MENOS UN OXIDO ELEGIDO ENTRE EL OXIDO DE CERIO Y EL OXIDO DE CIRCONIO. ESTA COMPOSICION PUEDE INCLUIR, ADEMAS, AL MENOS OTRO ELEMENTO ELEGIDO ENTRE LOS GRUPOS VIII, IB, IVB Y VB. EL METODO DE LA INVENCION SE APLICA ESPECIALMENTE AL TRATAMIENTO DE GASES DE ESCAPE DE MOTORES DE COMBUSTION INTERNA, ESPECIALMENTE DE MOTORES DIESEL O DE MOTORES QUE FUNCIONAN CON MEZCLAS POBRES.
ES96931848T 1995-09-20 1996-09-16 Procedimiento catalitico de gases, con contenido elevado en oxigeno, con miras a la reduccion de emisiones de oxidos de nitrogeno. Expired - Lifetime ES2169812T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9511020A FR2738756B1 (fr) 1995-09-20 1995-09-20 Procede de traitement de gaz, a teneur elevee en oxygene en vue de la reduction des emissions des oxydes d'azote, utilisant une composition catalytique comprenant de l'oxyde de manganese et de l'oxyde de cerium et/ou de zirconium

Publications (1)

Publication Number Publication Date
ES2169812T3 true ES2169812T3 (es) 2002-07-16

Family

ID=9482741

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96931848T Expired - Lifetime ES2169812T3 (es) 1995-09-20 1996-09-16 Procedimiento catalitico de gases, con contenido elevado en oxigeno, con miras a la reduccion de emisiones de oxidos de nitrogeno.

Country Status (14)

Country Link
EP (1) EP0861116B1 (es)
JP (1) JP3345426B2 (es)
KR (1) KR19990063627A (es)
CN (1) CN1200053A (es)
AT (1) ATE210490T1 (es)
AU (1) AU7088196A (es)
BR (1) BR9610631A (es)
CA (1) CA2230714C (es)
DE (1) DE69617993T2 (es)
ES (1) ES2169812T3 (es)
FR (1) FR2738756B1 (es)
MX (1) MX9802171A (es)
MY (1) MY132526A (es)
WO (1) WO1997010892A1 (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2770790B1 (fr) * 1997-11-10 1999-12-10 Rhodia Chimie Sa Composition a support a base d'un oxyde de cerium, d'un oxyde de zirconium et d'un oxyde de scandium ou de terre rare et utilisation pour le traitement des gaz d'echappement
FR2771306B1 (fr) * 1997-11-25 2000-02-04 Rhodia Chimie Sa Composition a base de manganese et utilisation comme piege a nox pour le traitement de gaz d'echappement
FR2791907B1 (fr) * 1999-04-12 2002-06-21 Rhodia Chimie Sa COMPOSITIONS UTILISABLES COMME PIEGE A NOx, A BASE DE MANGANESE ET D'UN ALCALIN OU D'UN ALCALINO-TERREUX ET UTILISATION DANS LE TRAITEMENT DES GAZ D'ECHAPPEMENT
FR2792547B1 (fr) * 1999-04-23 2001-07-06 Rhodia Chimie Sa COMPOSITION UTILISABLE COMME PIEGE A NOx, A BASE DE MANGANESE ET D'UN ALCALINO-TERREUX OU D'UNE TERRE RARE ET UTILISATION DANS LE TRAITEMENT DES GAZ D'ECHAPPEMENT
US6103207A (en) * 1999-04-26 2000-08-15 Ford Global Technologies, Inc. Treating diesel exhaust with a catalytic particulate mixture
FR2793161B1 (fr) * 1999-05-07 2001-10-12 Renault Dispositif d'epuration des gaz d'echappement pour moteur a combustion interne
FR2793162B1 (fr) * 1999-05-07 2001-07-27 Ecia Equip Composants Ind Auto COMPOSE A ACTIVITE CATALYTIQUE OU A ACTIVITE DE PIEGEAGE, UTILISABLE COMME PIEGE A NOx ASSOCIANT DEUX COMPOSITIONS A BASE DE MANGANESE ET D'UN AUTRE ELEMENT CHOISI PARMI LES ALCALINS, LES ALCALINO-TERREUX ET LES TERRES RARES.
WO2000067904A1 (fr) * 1999-05-07 2000-11-16 Rhodia Chimie COMPOSE UTILISABLE COMME PIEGE A NOx, ASSOCIANT DEUX COMPOSITIONS A BASE DE MANGANESE ET D'UN AUTRE ELEMENT CHOISI PARMI LES ALCALINS, LES ALCALINO-TERREUX ET LES TERRES RARES ET SON UTILISATION DANS LE TRAITEMENT DES GAZ D'ECHAPPEMENT
FR2793163B1 (fr) 1999-05-07 2001-08-10 Ecia Equip Composants Ind Auto Composition d'epuration avec traitement des nox des gaz d'echappement d'un moteur a combustion interne
FR2793164B1 (fr) * 1999-05-07 2001-08-10 Ecia Equip Composants Ind Auto Composition d'epuration des gaz d'echappement d'un moteur a combustion interne
US6727202B2 (en) 2001-08-21 2004-04-27 Engelhard Corporation Enhanced NOx trap having increased durability
JP5164665B2 (ja) * 2008-04-09 2013-03-21 第一稀元素化学工業株式会社 セリウム−ジルコニウム系複合酸化物及びその製造方法
US8057767B1 (en) * 2010-08-10 2011-11-15 GM Global Technology Operations LLC Base metal oxides oxidation catalyst
US8466083B2 (en) * 2010-08-27 2013-06-18 GM Global Technology Operations LLC Bi-functional catalyst materials for lean exhaust NOx reduction
US8545779B2 (en) * 2011-01-13 2013-10-01 GM Global Technology Operations LLC Sulfur-tolerant perovskite NOx oxidation catalysts
US8959894B2 (en) 2011-03-24 2015-02-24 GM Global Technology Operations LLC Manganese-based oxides promoted lean NOx trap (LNT) catalyst
JP5816648B2 (ja) * 2013-04-18 2015-11-18 三井金属鉱業株式会社 排気ガス浄化用触媒組成物及び排気ガス浄化用触媒
EP3096873A1 (en) 2014-01-21 2016-11-30 Council of Scientific and Industrial Research Non noble metal based diesel oxidation catalyst
RU2736939C2 (ru) * 2015-07-01 2020-11-23 Басф Корпорейшн Катализаторы для удаления закиси азота для выхлопных систем
CN105664924A (zh) * 2016-01-13 2016-06-15 南京大学 形貌效应强化低温活性的脱硝催化剂及其制备方法和应用
TWI766429B (zh) * 2020-11-09 2022-06-01 財團法人工業技術研究院 的方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH064126B2 (ja) * 1985-06-10 1994-01-19 株式会社日本触媒 排ガス浄化方法
US5294419A (en) * 1990-11-30 1994-03-15 Masakatsu Hiraoka Method for removing nitrogen oxides and organic chlorine compounds from combustion waste gas
DE69427932T2 (de) * 1993-05-10 2002-04-04 Cosmo Oil Co. Ltd., Tokio/Tokyo Katalysator zur katalytischen Reduktion von Stickstoffoxiden
DE69408957T2 (de) * 1993-12-28 1998-09-17 Riken Kk Vorrichtung und Verfahren zur Reinigung von Abgas
EP0667182A3 (en) * 1994-02-10 1995-10-18 Riken Kk Exhaust gas purifier and method for cleaning exhaust gas.

Also Published As

Publication number Publication date
DE69617993D1 (de) 2002-01-24
MX9802171A (es) 1998-11-29
CA2230714A1 (fr) 1997-03-27
EP0861116B1 (fr) 2001-12-12
WO1997010892A1 (fr) 1997-03-27
CA2230714C (fr) 2002-04-09
CN1200053A (zh) 1998-11-25
DE69617993T2 (de) 2002-07-18
FR2738756A1 (fr) 1997-03-21
FR2738756B1 (fr) 1998-12-11
AU7088196A (en) 1997-04-09
ATE210490T1 (de) 2001-12-15
BR9610631A (pt) 1999-03-16
JP3345426B2 (ja) 2002-11-18
JPH11500354A (ja) 1999-01-12
KR19990063627A (ko) 1999-07-26
EP0861116A1 (fr) 1998-09-02
MY132526A (en) 2007-10-31

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