ES2150158T3 - Proceso para producir microesferas inorganicas y microbalones de vidrio. - Google Patents
Proceso para producir microesferas inorganicas y microbalones de vidrio.Info
- Publication number
- ES2150158T3 ES2150158T3 ES97103986T ES97103986T ES2150158T3 ES 2150158 T3 ES2150158 T3 ES 2150158T3 ES 97103986 T ES97103986 T ES 97103986T ES 97103986 T ES97103986 T ES 97103986T ES 2150158 T3 ES2150158 T3 ES 2150158T3
- Authority
- ES
- Spain
- Prior art keywords
- inorganic microspheres
- size
- produce inorganic
- spraying
- glass microballs
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/14—Methods for preparing oxides or hydroxides in general
- C01B13/32—Methods for preparing oxides or hydroxides in general by oxidation or hydrolysis of elements or compounds in the liquid or solid state or in non-aqueous solution, e.g. sol-gel process
- C01B13/328—Methods for preparing oxides or hydroxides in general by oxidation or hydrolysis of elements or compounds in the liquid or solid state or in non-aqueous solution, e.g. sol-gel process by processes making use of emulsions, e.g. the kerosine process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/02—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops
- B01J2/04—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops in a gaseous medium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/30—Preparation of aluminium oxide or hydroxide by thermal decomposition or by hydrolysis or oxidation of aluminium compounds
- C01F7/308—Thermal decomposition of nitrates
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/10—Forming beads
- C03B19/1005—Forming solid beads
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/10—Forming beads
- C03B19/1005—Forming solid beads
- C03B19/102—Forming solid beads by blowing a gas onto a stream of molten glass or onto particulate materials, e.g. pulverising
- C03B19/1025—Bead furnaces or burners
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/10—Forming beads
- C03B19/107—Forming hollow beads
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/10—Forming beads
- C03B19/108—Forming porous, sintered or foamed beads
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C11/00—Multi-cellular glass ; Porous or hollow glass or glass particles
- C03C11/002—Hollow glass particles
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C12/00—Powdered glass; Bead compositions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/32—Spheres
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/32—Spheres
- C01P2004/34—Spheres hollow
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Glass Compositions (AREA)
- Glanulating (AREA)
- Catalysts (AREA)
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Compounds (AREA)
- Manufacturing Of Micro-Capsules (AREA)
Abstract
UN PROCEDIMIENTO DE PRODUCCION DE MICROESFERAS INORGANICAS (ESFERAS SOLIDAS O ESFERAS HUECAS) QUE COMPRENDE LAS FASES DE PULVERIZACION DE UN MATERIAL MEDIANTE PULVERIZACION HUMEDA CON UN TAMAÑO DE PARTICULA MEDIO DE COMO MAXIMO 5 {MI}M, OBTENIENDOSE UNA SUSPENSION DE UN MATERIAL EN POLVO PULVERIZADO; PULVERIZACION DE DICHA SUSPENSION PARA FORMAR GOTITAS LIQUIDAS, Y CALENTAMIENTO DE DICHAS GOTITAS PARA FUNDIR O SINTERIZAR EL MATERIAL PULVERULENTO Y OBTENER MICROESFERAS INORGANICAS. ASIMISMO, SE DESCRIBEN MICROGLOBOS DE VIDRIO DE DENSIDAD APARENTE DE ENTRE 0,1 Y 1,5 G/CM{SUP,3} Y UN TAMAÑO MEDIO DE PARTICULA ENTRE 1 Y 20 {MI}M, DONDE 80 % DE LAS PARTICULAS TIENEN UN TAMAÑO COMPRENDIDO ENTRE 1 Y 50 {MI}M.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP08685796A JP3633091B2 (ja) | 1996-04-09 | 1996-04-09 | 微小無機質球状中実体の製造方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2150158T3 true ES2150158T3 (es) | 2000-11-16 |
Family
ID=13898494
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES97103986T Expired - Lifetime ES2150158T3 (es) | 1996-04-09 | 1997-03-10 | Proceso para producir microesferas inorganicas y microbalones de vidrio. |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5849055A (es) |
| EP (1) | EP0801037B1 (es) |
| JP (1) | JP3633091B2 (es) |
| DE (1) | DE69702801T2 (es) |
| ES (1) | ES2150158T3 (es) |
Families Citing this family (65)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK0958495T3 (da) | 1997-02-06 | 2003-03-10 | Therasense Inc | In vitro analysand sensor med lille volumen |
| US6360562B1 (en) * | 1998-02-24 | 2002-03-26 | Superior Micropowders Llc | Methods for producing glass powders |
| US6338790B1 (en) | 1998-10-08 | 2002-01-15 | Therasense, Inc. | Small volume in vitro analyte sensor with diffusible or non-leachable redox mediator |
| JP3960700B2 (ja) * | 1999-02-23 | 2007-08-15 | 電気化学工業株式会社 | 超微粉シリカの製造方法 |
| US6245733B1 (en) | 1999-04-30 | 2001-06-12 | James Mosbaugh | Porous agglomerations of fused microspheres |
| WO2001002314A1 (fr) * | 1999-06-30 | 2001-01-11 | Asahi Glass Company, Limited | Fines spheres creuses de verre et procede de preparation associe |
| WO2001062311A1 (en) * | 2000-02-25 | 2001-08-30 | James Mosbaugh | Method of shaping porous agglomerations of fused microspheres |
| CA2402886C (en) | 2000-03-14 | 2012-02-14 | James Hardie Research Pty Limited | Fiber cement building materials with low density additives |
| EP1156021A1 (en) * | 2000-05-19 | 2001-11-21 | Asahi Glass Co., Ltd. | Hollow aluminosilicate glass microspheres and process for their production |
| EP1160212A1 (en) * | 2000-05-31 | 2001-12-05 | Asahi Glass Co., Ltd. | Hollow glass microspheres and method for producing the same |
| JP3690245B2 (ja) * | 2000-06-05 | 2005-08-31 | 株式会社村田製作所 | ガラス粉末の製造方法 |
| US6461415B1 (en) * | 2000-08-23 | 2002-10-08 | Applied Thin Films, Inc. | High temperature amorphous composition based on aluminum phosphate |
| US6573209B1 (en) * | 2000-10-13 | 2003-06-03 | Applied Thin Films, Inc. | Zirconium nitride and yttrium nitride solid solution composition |
| US6645639B1 (en) * | 2000-10-13 | 2003-11-11 | Applied Thin Films, Inc. | Epitaxial oxide films via nitride conversion |
| US20040096515A1 (en) * | 2001-12-07 | 2004-05-20 | Bausch Andreas R. | Methods and compositions for encapsulating active agents |
| US6631030B2 (en) * | 2001-03-30 | 2003-10-07 | 3M Innovative Properties Company | Projection screens and methods for making such projection screens |
| JP4318872B2 (ja) * | 2001-07-18 | 2009-08-26 | 電気化学工業株式会社 | 微細球状シリカ粉末の製造方法 |
| EP1908512A1 (en) * | 2002-07-15 | 2008-04-09 | Asahi Glass Company, Limited | Process for producing inorganic spheres |
| JP2005535554A (ja) * | 2002-08-14 | 2005-11-24 | アプライド シン フィルムズ,インコーポレイティッド | リン酸アルミニウム化合物、組成物、材料及び関連複合体 |
| NZ538497A (en) | 2002-08-23 | 2007-03-30 | James Hardie Int Finance Bv | Synthetic hollow microspheres |
| US7455798B2 (en) * | 2002-08-23 | 2008-11-25 | James Hardie International Finance B.V. | Methods for producing low density products |
| US7993570B2 (en) | 2002-10-07 | 2011-08-09 | James Hardie Technology Limited | Durable medium-density fibre cement composite |
| US8021758B2 (en) * | 2002-12-23 | 2011-09-20 | Applied Thin Films, Inc. | Aluminum phosphate compounds, coatings, related composites and applications |
| JP4271045B2 (ja) * | 2003-04-17 | 2009-06-03 | 矢崎総業株式会社 | アルミナ中空粒子の製造方法 |
| WO2004101137A1 (en) * | 2003-05-16 | 2004-11-25 | James Hardie International Finance B.V. | Methods for producing low density products |
| ATE485886T1 (de) * | 2003-06-18 | 2010-11-15 | Asahi Glass Co Ltd | Verfahren und vorrichtung zur herstellung von anorganischen sphären |
| US7563756B2 (en) * | 2003-08-27 | 2009-07-21 | Brandi Brady | Scented tablet for toilet and method for scenting restroom effluent |
| US20050065240A1 (en) * | 2003-09-24 | 2005-03-24 | Kyte William J, | Grout composition, dispenser therefor, and method of use |
| US20090156385A1 (en) | 2003-10-29 | 2009-06-18 | Giang Biscan | Manufacture and use of engineered carbide and nitride composites |
| US7998571B2 (en) | 2004-07-09 | 2011-08-16 | James Hardie Technology Limited | Composite cement article incorporating a powder coating and methods of making same |
| FR2875494B1 (fr) * | 2004-09-17 | 2007-01-19 | Sylvain Rakotoarison | Microspheres de silice, procede de fabrication, assemblages et utilisations possibles de ces microspheres de silice |
| WO2006091929A2 (en) | 2005-02-24 | 2006-08-31 | James Hardie International Finance B.V. | Alkali resistant glass compositions |
| JP2008535644A (ja) | 2005-03-04 | 2008-09-04 | プレジデント・アンド・フエローズ・オブ・ハーバード・カレツジ | 多重エマルジョンの形成のための方法および装置 |
| CN100360442C (zh) * | 2005-07-11 | 2008-01-09 | 张伟 | 一种空心微珠的制备方法 |
| GB0515088D0 (en) * | 2005-07-22 | 2005-08-31 | Imerys Minerals Ltd | Particulate glass compositions and methods of production |
| CA2632760C (en) | 2005-12-08 | 2017-11-28 | James Hardie International Finance B.V. | Engineered low-density heterogeneous microparticles and methods and formulations for producing the microparticles |
| TWI432381B (zh) * | 2005-12-12 | 2014-04-01 | Grace W R & Co | 氧化鋁粒子 |
| AU2007236561B2 (en) | 2006-04-12 | 2012-12-20 | James Hardie Technology Limited | A surface sealed reinforced building element |
| DE102007004242B4 (de) * | 2007-01-23 | 2018-01-04 | Schott Ag | Verfahren zum Herstellen eines Formkörpers aus Quarzglas durch Sintern, Formkörper und Verwendung des Formkörpers |
| JP2008247626A (ja) * | 2007-03-29 | 2008-10-16 | Isuzu Seiko Glass Kk | 紫外線吸収能を有する屈折率分布型光学素子の製造方法 |
| JP5062593B2 (ja) | 2007-12-03 | 2012-10-31 | 独立行政法人産業技術総合研究所 | リグニンを原料とする炭素微粒子及びその製造方法 |
| US8209927B2 (en) | 2007-12-20 | 2012-07-03 | James Hardie Technology Limited | Structural fiber cement building materials |
| US20090191276A1 (en) * | 2008-01-24 | 2009-07-30 | Fellows And President Of Harvard University | Colloidosomes having tunable properties and methods for making colloidosomes having tunable properties |
| WO2010033200A2 (en) | 2008-09-19 | 2010-03-25 | President And Fellows Of Harvard College | Creation of libraries of droplets and related species |
| JP5288408B2 (ja) * | 2009-01-22 | 2013-09-11 | 独立行政法人産業技術総合研究所 | 中空炭素微粒子およびその製造方法 |
| US20120211084A1 (en) | 2009-09-02 | 2012-08-23 | President And Fellows Of Harvard College | Multiple emulsions created using jetting and other techniques |
| US20110152057A1 (en) * | 2009-12-21 | 2011-06-23 | Gang Qi | Hollow microspheres |
| US8261577B2 (en) * | 2009-12-21 | 2012-09-11 | 3M Innovative Properties Company | Method for making hollow microspheres |
| EP2397448A1 (de) * | 2010-06-17 | 2011-12-21 | Bene_fit Systems GmbH & Co. KG | Zubereitung, Herstellung und Anwendung von feinteiligem Pulvermaterial auf Glasbasis |
| EP2655273A2 (en) * | 2010-12-20 | 2013-10-30 | 3M Innovative Properties Company | Hollow microspheres and method of making hollow microspheres |
| BR112013029729A2 (pt) | 2011-05-23 | 2017-01-24 | Basf Se | controle de emulsões, incluindo emulsões múltiplas |
| US20140220350A1 (en) | 2011-07-06 | 2014-08-07 | President And Fellows Of Harvard College | Multiple emulsions and techniques for the formation of multiple emulsions |
| CN102701573B (zh) * | 2012-01-01 | 2016-02-03 | 洛阳北苑特种陶瓷有限公司 | 一种熔融石英空心球的制备方法 |
| US9102560B2 (en) * | 2013-01-17 | 2015-08-11 | Sibelco Asia Pte. Ltd. | Charging load for making TFT glass and method of making same |
| JP6027935B2 (ja) * | 2013-03-29 | 2016-11-16 | 出光ライオンコンポジット株式会社 | ポリアリーレンスルフィド樹脂組成物及びその用途 |
| US9016090B2 (en) | 2013-06-12 | 2015-04-28 | Hamid Hojaji | Glass microspheres comprising sulfide, and methods of producing glass microspheres |
| CN105392742B (zh) | 2013-07-18 | 2018-05-11 | 3M创新有限公司 | 玻璃微泡、粗制产品及其制备方法 |
| WO2015069634A1 (en) | 2013-11-08 | 2015-05-14 | President And Fellows Of Harvard College | Microparticles, methods for their preparation and use |
| CN103755146A (zh) * | 2013-12-14 | 2014-04-30 | 蚌埠玻璃工业设计研究院 | 一种固体浮体材料空心玻璃微珠及其制备方法 |
| US10196296B2 (en) | 2015-01-17 | 2019-02-05 | Hamid Hojaji | Fluid permeable and vacuumed insulating microspheres and methods of producing the same |
| US9643876B2 (en) | 2015-10-04 | 2017-05-09 | Hamid Hojaji | Microspheres and methods of making the same |
| AU2016338907B2 (en) | 2015-10-13 | 2022-07-07 | President And Fellows Of Harvard College | Systems and methods for making and using gel microspheres |
| CN106830982B (zh) * | 2017-03-21 | 2020-04-17 | 兰州理工大学 | 一种制备空心陶瓷微球的方法 |
| MY202033A (en) * | 2018-07-26 | 2024-03-29 | Omya Int Ag | Hollow spherical glass particles |
| CN113830999A (zh) * | 2021-09-29 | 2021-12-24 | 苏州大学 | 一种合成球形石英粉的装置和方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL6512347A (es) * | 1965-09-23 | 1967-03-28 | ||
| US3838998A (en) * | 1971-01-07 | 1974-10-01 | R Carson | Process for forming hollow glass micro-spheres from admixed high and low temperature glass formers |
| JPS5224200A (en) * | 1975-08-12 | 1977-02-23 | Dowa Mining Co Ltd | Method for production of spherical ferrite powder |
| US4333857A (en) * | 1979-01-15 | 1982-06-08 | Filtrol Corporation | Attrition resistant zeolite containing catalyst |
| EP0160267B1 (en) * | 1984-04-24 | 1991-02-27 | Kanto Kagaku Kabushiki Kaisha | Porous cordierite ceramics, a process for producing same and use of the porous cordierite ceramics |
| US5256180A (en) * | 1984-06-21 | 1993-10-26 | Saint Gobain Vitrage | Apparatus for production of hollow glass microspheres |
| FR2566384B1 (fr) * | 1984-06-21 | 1986-09-05 | Saint Gobain Vitrage | Perfectionnements aux techniques de production de microspheres en verre |
| US4649037A (en) * | 1985-03-29 | 1987-03-10 | Allied Corporation | Spray-dried inorganic oxides from non-aqueous gels or solutions |
| JPS61263628A (ja) * | 1985-05-17 | 1986-11-21 | Mitsubishi Mining & Cement Co Ltd | セラミツクスマイクロ球の製造方法 |
| US4715878A (en) * | 1987-03-12 | 1987-12-29 | Gte Products Corporation | Process for producing finely divided spherical glass powders |
| BE1002001A4 (fr) * | 1988-02-18 | 1990-05-15 | Mitsubishi Mining & Cement Co | Procede de preparation de microspheres ceramiques. |
| US4983550A (en) * | 1988-08-24 | 1991-01-08 | Potters Industries, Inc. | Hollow glass spheres |
| DE3930098A1 (de) * | 1989-09-09 | 1991-03-14 | Basf Lacke & Farben | Verfahren zur herstellung von anorganischen oxidischen pigmenten bzw. oxidischen keramischen farbkoerpern |
| FR2671072B1 (fr) * | 1990-11-14 | 1993-12-03 | Saint Gobain Vitrage Internal | Verre silico-sodo-calcique, microspheres obtenues a partir de ce verre et procede pour leur fabrication. |
| US5069702A (en) * | 1990-12-20 | 1991-12-03 | W. R. Grace & Co.-Conn. | Method of making small hollow glass spheres |
| DE4237145A1 (de) * | 1992-11-04 | 1994-05-11 | Grace Gmbh | Aluminiumphosphatzusammensetzung mit hohem Porenvolumen und großem Porendurchmesser, Verfahren zu deren Herstellung und deren Verwendung |
| JPH06263464A (ja) * | 1992-12-11 | 1994-09-20 | Asahi Glass Co Ltd | ガラス微小中空体の製造方法およびガラス微小中空体 |
| JP2996354B2 (ja) * | 1993-09-08 | 1999-12-27 | ピー キュー コーポレーション | 中空ボロシリケート微小球及び製造方法 |
-
1996
- 1996-04-09 JP JP08685796A patent/JP3633091B2/ja not_active Expired - Fee Related
-
1997
- 1997-03-07 US US08/813,067 patent/US5849055A/en not_active Expired - Fee Related
- 1997-03-10 ES ES97103986T patent/ES2150158T3/es not_active Expired - Lifetime
- 1997-03-10 DE DE69702801T patent/DE69702801T2/de not_active Expired - Fee Related
- 1997-03-10 EP EP97103986A patent/EP0801037B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH09278463A (ja) | 1997-10-28 |
| DE69702801D1 (de) | 2000-09-21 |
| EP0801037A1 (en) | 1997-10-15 |
| US5849055A (en) | 1998-12-15 |
| EP0801037B1 (en) | 2000-08-16 |
| DE69702801T2 (de) | 2001-03-29 |
| JP3633091B2 (ja) | 2005-03-30 |
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