[go: up one dir, main page]

ES2103763T3 - Un proceso continuo para la sintesis del trans-1,4-polibutadieno. - Google Patents

Un proceso continuo para la sintesis del trans-1,4-polibutadieno.

Info

Publication number
ES2103763T3
ES2103763T3 ES91117431T ES91117431T ES2103763T3 ES 2103763 T3 ES2103763 T3 ES 2103763T3 ES 91117431 T ES91117431 T ES 91117431T ES 91117431 T ES91117431 T ES 91117431T ES 2103763 T3 ES2103763 T3 ES 2103763T3
Authority
ES
Spain
Prior art keywords
trans
polybutadiene
reaction area
continuously
cures
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91117431T
Other languages
English (en)
Inventor
Kenneth Floyd Castner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goodyear Tire and Rubber Co
Original Assignee
Goodyear Tire and Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Goodyear Tire and Rubber Co filed Critical Goodyear Tire and Rubber Co
Application granted granted Critical
Publication of ES2103763T3 publication Critical patent/ES2103763T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

EL TRANS-1,4-POLIBUTADIENO ES UNA RESINA TERMOPLASTICA GRACIAS A SU ALTO NIVEL DE CRISTALINIDAD. A CAUSA DE QUE EL TRANS-1,4-POLIBUTADIENO CONTIENE MUCHOS ENLACES DOBLES EN SU SOPORTE, PUEDE MEZCLARSE Y CO-CURARSE CON GOMAS . AUNQUE EL TRANS-1,4-POLIBUTADIENO ES UNA RESINA TERMOPLASTICA, SE VUELVE ELASTOMERICA CUANDO SE CURA SOLA O CUANDO SE CO-CURA CON UNA O MAS GOMAS. AL UTILIZAR EL SISTEMA DE CATALIZACION Y LAS TECNICAS DE ESTA INVENCION , EL TRANS-1,4-POLIBUTADIENO PUEDE SINTETIZARSE CONTINUAMENTE EN UN GRAN NIVEL DE CONVERSION CON SOLAMENTE UNAS MINIMAS CANTIDADES DE FORMACION DE GEL. ESTA INVENCION DESCRIBE ESPECIFICAMENTE UN PROCESO PARA SINTETIZAR TRANS-1,4-POLIBUTADIENO EN UN PROCESO CONTINUO QUE COMPRENDE EL CARGAR CONTINUAMENTE MONOMERO 1,3-BUTADIENO, UN COMPUESTO DE ORGANOCOBALTO , UN COMPUESTO DE ORGANOALUMINIO, UN FENOL PARA-SUSTITUIDO, DISULFURO DE CARBONO, Y UN DISOLVENTE ORGANICO EN UNA ZONA DE REACCION; PERMITIENDO AL MONOMERO DE 1,3-BUTADIENO EL POLIMERIZAR EN DICHA ZONADE REACCION PARA FORMAR EL TRANS-1,4-POLIBUTADIENO; Y SACANDO CONTINUAMENTE EL TRANS-1,4-POLIBUTADIENO DE DICHA ZONA DE REACCION. ES MUCHO MEJOR PARA EL FENOL SUSTITUIDO DE PARA-ALQUILO UTILIZADO EN ESTE PROCESO EL CONTENER DE 12 A 26 ATOMOS DE CARBONO APROXIMADAMENTE.
ES91117431T 1990-10-22 1991-10-12 Un proceso continuo para la sintesis del trans-1,4-polibutadieno. Expired - Lifetime ES2103763T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/601,100 US5089574A (en) 1990-10-22 1990-10-22 Trans-1,4-polybutadiene synthesis

Publications (1)

Publication Number Publication Date
ES2103763T3 true ES2103763T3 (es) 1997-10-01

Family

ID=24406228

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91117431T Expired - Lifetime ES2103763T3 (es) 1990-10-22 1991-10-12 Un proceso continuo para la sintesis del trans-1,4-polibutadieno.

Country Status (9)

Country Link
US (1) US5089574A (es)
EP (1) EP0482457B1 (es)
JP (1) JP3232113B2 (es)
KR (1) KR0182315B1 (es)
BR (1) BR9104449A (es)
CA (1) CA2035828C (es)
DE (1) DE69126089T2 (es)
ES (1) ES2103763T3 (es)
MX (1) MX9101539A (es)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5733988A (en) * 1994-06-29 1998-03-31 Union Carbide Chemicals & Plastics Technology Corporation Process for reducing polymer build-up in recycle lines and heat exchangers during polymerizations employing butadiene, isoprene, and/or styrene
US5448002A (en) * 1994-08-12 1995-09-05 The Goodyear Tire & Rubber Company Synthesis of trans-1,4-polybutadiene having controlled molecular weight
US5834573A (en) * 1997-05-21 1998-11-10 The Goodyear Tire & Rubber Company Synthesis of trans-1,4-polybutadiene
US5854351A (en) * 1997-06-20 1998-12-29 The Goodyear Tire & Rubber Company Radio frequency heating of trans-1, 4-polybutadiene
US6013736A (en) * 1998-02-16 2000-01-11 The Goodyear Tire & Rubber Company Metal deactivator for cobalt catalyzed polymers
US6310152B1 (en) * 2000-10-24 2001-10-30 The Goodyear Tire & Rubber Company Synthesis of elastomeric high trans-1,4-polybutadiene
US6617406B2 (en) 2001-08-30 2003-09-09 The Goodyear Tire & Rubber Company Synthesis of elastomeric high trans-1,4-polybutadiene
US7087660B2 (en) * 2003-07-29 2006-08-08 The Goodyear Tire & Rubber Company Preparation of components and articles with directed high frequency energy heated silica-rich rubber components containing high softening point polymer and sulfur curative
US7189792B2 (en) * 2004-12-31 2007-03-13 The Goodyear Tire & Rubber Company Catalyst for synthesizing high trans polymers
MX2009006746A (es) * 2006-12-19 2009-08-28 Dow Global Technologies Inc Polimeros elastomericos modificados con sulfuro.
US20080216934A1 (en) * 2007-03-08 2008-09-11 Paul Harry Sandstrom Tire with sidewall comprised of low viscosity trans 1,4-polybutadiene, cis 1,4-polyisoprene rubber and cis 1,4-polybutadiene rubber
US8729167B2 (en) * 2008-06-06 2014-05-20 Styron Europe Gmbh Modified elastomeric polymers
KR101111249B1 (ko) * 2008-09-29 2012-03-14 금호석유화학 주식회사 방향족 유기황화합물로 분지화 및 기능화된 고 1,4-트랜스 폴리부타디엔
MX2011004961A (es) * 2008-11-11 2011-05-31 Styron Europe Gmbh Proceso para remover el silanol de la preparacion de un polimero modificado.
KR101174454B1 (ko) * 2009-04-09 2012-08-17 금호석유화학 주식회사 분자량 조절이 가능한 고 1,4-트랜스 폴리부타디엔 제조용 촉매
CN102933613B (zh) 2009-12-21 2015-03-11 斯泰隆欧洲有限责任公司 改性聚合物组合物
MX2012007324A (es) 2009-12-21 2012-11-21 Styron Europe Gmbh Composiciones de polimeros modificados.
WO2012041804A2 (en) 2010-09-30 2012-04-05 Styron Europe Gmbh Polymer compositions
BR112015005491A2 (pt) 2012-09-14 2017-07-04 Trinseo Europe Gmbh composto macromolecular modificado, método para fazer o composto macromolecular modificado, composição de polímero, composição de polímero vulcanizado, método para fazer uma composição de polímero vulcanizado, artigo, composto iniciador de polimerização de amino silano e método para fazer o iniciador de polimerização de amino silano
SG11201600063SA (en) 2013-07-22 2016-02-26 Trinseo Europe Gmbh Polymerisation initiators
US9487604B2 (en) 2013-11-25 2016-11-08 Korea Kumho Petrochemical Co., Ltd. Bimetallic cobalt-aluminum adduct catalyst system for preparing high trans-1,4-polybutadiene
WO2016008507A1 (en) 2014-07-14 2016-01-21 Trinseo Europe Gmbh Aminosilyl-substituted diarylethene compounds for anionic polymerisation
ES2636745T3 (es) 2015-01-14 2017-10-09 Trinseo Europe Gmbh Composiciones de polímero elastomérico funcionalizado, sus procedimientos de preparación, y composiciones de caucho reticuladas de las mismas
EP3133093A1 (en) 2015-08-20 2017-02-22 Trinseo Europe GmbH Elastomeric polymer
EP3363804A1 (en) 2017-02-20 2018-08-22 Trinseo Europe GmbH Metallated benzylsilanes and their use as polymerization initiators

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS42187Y1 (es) * 1964-06-24 1967-01-09
US3928297A (en) * 1971-06-08 1975-12-23 Exxon Research Engineering Co High molecular weight, high unsaturation isobutylene-conjugated diene copolymers
US3993856A (en) * 1974-07-25 1976-11-23 The Firestone Tire & Rubber Company Process for polymerizing butadiene
US4153767A (en) * 1977-11-22 1979-05-08 Ube Industries Limited Method of producing 1,2-polybutadiene
JPS56109204A (en) * 1980-01-31 1981-08-29 Japan Synthetic Rubber Co Ltd Preparation of polybutadiene
JPS5964609A (ja) * 1982-10-05 1984-04-12 Ube Ind Ltd 補強ポリブタジエンの製造法
JPS5968316A (ja) * 1982-10-14 1984-04-18 Ube Ind Ltd １．３−ブタジエンの重合法
US4645809A (en) * 1986-01-23 1987-02-24 The Goodyear Tire & Rubber Company Direct method for preparing syndiotactic 1,2-polybutadiene

Also Published As

Publication number Publication date
MX9101539A (es) 1994-06-30
KR920008086A (ko) 1992-05-27
US5089574A (en) 1992-02-18
EP0482457B1 (en) 1997-05-14
CA2035828C (en) 2001-06-05
KR0182315B1 (ko) 1999-05-15
CA2035828A1 (en) 1992-04-23
DE69126089D1 (de) 1997-06-19
JPH04285603A (ja) 1992-10-09
EP0482457A1 (en) 1992-04-29
BR9104449A (pt) 1992-06-09
JP3232113B2 (ja) 2001-11-26
DE69126089T2 (de) 1997-10-16

Similar Documents

Publication Publication Date Title
ES2103763T3 (es) Un proceso continuo para la sintesis del trans-1,4-polibutadieno.
US4048034A (en) Photopolymerization using an alpha-aminoacetophenone
ES519120A0 (es) Procedimiento para preparar un catalizador apropiado para la polimerizacion o la copolimerizacion de mono-1-olefinas que tienen de 2 a 8 atomos de carbono.
AR007713A1 (es) Un metodo para polimerizar en fase de vapor al 1.3 butadieno en cis-1,4- polibutadieno
ES519119A0 (es) Procedimiento para preparar un catalizador apropiado para la polimerizacion o la copolimerizacion de mono-1-olefinas que tienen de 2 a 8 atomos de carbono.
EP0364854A3 (de) Verfahren zur Herstellung von Formkörpern mit einer verdichteten Randzone und einem zelligen Kern, vorzugsweise Schuhsohlen
AR005010A1 (es) Metodo para convertir metanol a olefinas
ES2070075B1 (es) "un procedimiento de sintesis de un polimero poliisoprenico con propiedades como el caucho"
ES2084800T3 (es) Sistema catalitico para la polimerizacion de 1,3-butadieno a trans-1,4-polibutadieno.
MX9202788A (es) Proceso para preparar fluorenilo que contiene metalocenos y producto obtenido mediante el mismo.
ATE530951T1 (de) Lichtempfindliche harzzusammensetzung
ES2151011T3 (es) Composicion de caucho desprovista de precursor de nitrosamina cancerigena y que sirve de goma de union.
CO4560577A1 (es) Proceso para oligomerizar olefinas
BR9907230A (pt) Processos para a preparação de um macrÈmero e de um polìmero, macrÈmero, poliol polìmero, espuma de poliuretano flexìvel, e, artigo moldado
ES2101322T3 (es) Procedimiento de produccion de piezas industriales por accion de la luz sobre un material polimerizable o reticulable liquido sin necesidad de soportes.
ES2156012T3 (es) Agentes desmoldeantes internos para la obtencion de cuerpos moldeados autodesmoldeables constituidos por productos de poliadicion de poliisocianato.
NO953739L (no) Polymerisasjonsprosess for olefiner
NO306472B1 (no) Fremgangsmåte ved fremstilling av en bitumen/polymerblanding som er vulkaniserbar under 100_C, og anvendelse av denne
ATE335770T1 (de) Photohärtbare organische polymerzusammensetzung
ES2109582T3 (es) Procedimiento para la obtencion de omega-difluorcarboxilcompuestos alifaticos.
DE69428094D1 (de) Verfahren zur Herstellung eines Verbundwerkstoffes und damit erhaltener Werkstoff
AU591249B2 (en) N,N'-substituted bis-(2,4-diamino-S-triazin-6-YL)- tetrasulphides and disproportionation products thereof, processes for their production and their use in vulcanizable rubber mixtures
FR2594125B1 (fr) Nouveau procede de composition coulable de grande durete a base d'un complexe resines-charges greffees par voie chimique
ES2133814T3 (es) Procedimiento para la obtencion de compuestos organicos que contienen grupos epoxido.
ES2138352T3 (es) Copolimero de etileno-penteno-hexeno, procedimiento para su preparacion y utilizacion para la produccion de peliculas.

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 482457

Country of ref document: ES