ES2085261T3 - Elaboracion mejorada de polimeros de isoolefina. - Google Patents
Elaboracion mejorada de polimeros de isoolefina.Info
- Publication number
- ES2085261T3 ES2085261T3 ES88311634T ES88311634T ES2085261T3 ES 2085261 T3 ES2085261 T3 ES 2085261T3 ES 88311634 T ES88311634 T ES 88311634T ES 88311634 T ES88311634 T ES 88311634T ES 2085261 T3 ES2085261 T3 ES 2085261T3
- Authority
- ES
- Spain
- Prior art keywords
- molecular weight
- isoolefine
- elaboration
- polymers
- improved
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000642 polymer Polymers 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 3
- 229920001577 copolymer Polymers 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0008—Compositions of the inner liner
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
- C08F10/10—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
- C08F210/10—Isobutene
- C08F210/12—Isobutene with conjugated diolefins, e.g. butyl rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
- C08L23/283—Iso-olefin halogenated homopolymers or copolymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/918—Polymer prepared by cationic polymerization
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Una composición material que comprende un caucho de homopolímero de isoolefina C4-C7, caucho de copolímero butílico, o mezclas de los mismos, en la cual la distribución de pesos moleculares de dicho caucho o de dicha mezcla es tal que la razón de los momentos de dicha distribución de pesos moleculares, Mz/Mw, es igual a o supera 2,0 y la porción de dicha distribución de pesos moleculares que es igual a y mayor que 4 veces el peso molecular pico, Mp, comprende al menos 10 por ciento en peso de las especies polímeras totales, Mp es mayor que 250.000, y en la cual dichas especies polímeras de peso molecular inferior a Mp están sustancialmente exentas de ramificación.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/131,938 US5071913A (en) | 1987-12-11 | 1987-12-11 | Rubbery isoolefin polymers exhibiting improved processability |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2085261T3 true ES2085261T3 (es) | 1996-06-01 |
Family
ID=22451686
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES95110803T Expired - Lifetime ES2134976T3 (es) | 1987-12-11 | 1988-12-08 | Tratamiento mejorado de polimeros de isoolefina. |
ES88311634T Expired - Lifetime ES2085261T3 (es) | 1987-12-11 | 1988-12-08 | Elaboracion mejorada de polimeros de isoolefina. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES95110803T Expired - Lifetime ES2134976T3 (es) | 1987-12-11 | 1988-12-08 | Tratamiento mejorado de polimeros de isoolefina. |
Country Status (10)
Country | Link |
---|---|
US (1) | US5071913A (es) |
EP (2) | EP0320263B1 (es) |
JP (1) | JP2865299B2 (es) |
KR (1) | KR0135766B1 (es) |
CN (1) | CN1036022A (es) |
AU (1) | AU2674788A (es) |
BR (1) | BR8806522A (es) |
CA (1) | CA1330144C (es) |
DE (2) | DE3855069T2 (es) |
ES (2) | ES2134976T3 (es) |
Families Citing this family (69)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5264494A (en) * | 1991-05-15 | 1993-11-23 | Polysar Rubber Corporation | Halogenated butyl rubber graft copolymers |
US5286804A (en) * | 1991-09-17 | 1994-02-15 | Exxon Chemical Patents Inc. | Halogenation of star-branched butyl rubber with improved neutralization |
US5194538A (en) * | 1992-07-15 | 1993-03-16 | Polysar Corporation | Preparation of butyl rubber with bimodal molecular weight distribution |
US5578682A (en) * | 1995-05-25 | 1996-11-26 | Exxon Chemical Patents Inc. | Bimodalization of polymer molecular weight distribution |
US6835778B2 (en) * | 1995-08-29 | 2004-12-28 | Chevron Phillips Chemical Company Lp | Conjugated diene/monovinylarene block copolymers blends |
DE19628450A1 (de) * | 1996-07-15 | 1998-01-22 | Bayer Ag | Verfahren zur Herstellung von hochverzweigten Polyisoolefinen |
US6255389B1 (en) | 1998-08-27 | 2001-07-03 | Advanced Elastomer Systems, L.P. | Star-branched rubber thermoplastic elastomer vulcanizates |
CA2372278A1 (en) | 1999-05-19 | 2000-11-23 | Exxon Chemical Patents, Inc. | Isobutylene based elastomer blends having improved strength, elasticity, and reduced permeability |
US6939933B2 (en) * | 2000-12-20 | 2005-09-06 | Exxonmobil Chemical Patents Inc. | Process for polymerizing cationically polymerizable monomers |
US6710116B1 (en) | 2000-10-18 | 2004-03-23 | Exxonmobil Chemical Patents Inc. | Abrasion resistant transparent and colorable elastomeric compositions |
CA2316741A1 (en) * | 2000-08-24 | 2002-02-24 | Bayer Inc. | Improved processability butyl rubber and process for production thereof |
US6632680B1 (en) * | 2000-09-22 | 2003-10-14 | Deslauriers Paul J. | Measurement of short chain branching in olefin copolymers using chemometric analysis |
US7425591B2 (en) * | 2001-10-16 | 2008-09-16 | Exxonmobil Chemical Patents Inc | Elastomeric composition |
HUP0303578A3 (en) * | 2000-10-18 | 2007-05-29 | Exxonmobil Chem Patents Inc | Elastomeric composition |
US20060167184A1 (en) * | 2000-10-18 | 2006-07-27 | Waddell Walter H | Innerliners for use in tires |
TWI285658B (en) * | 2000-12-12 | 2007-08-21 | Lanxess Deutschland Gmbh | Rubber composition for inner liner |
TWI283257B (en) * | 2000-12-12 | 2007-07-01 | Lanxess Deutschland Gmbh | A process for the preparation of an isobutene/isoprene-copolymer |
EP1379563A2 (fr) * | 2001-01-10 | 2004-01-14 | Solvay (Societe Anonyme) | Procede de preparation de polymeres halogenes en deux etapes et polymeres halogenes plurimodales |
DE10132337A1 (de) * | 2001-07-04 | 2003-01-16 | Basf Ag | Polyisobuten-Zusammensetzung |
US20040030036A1 (en) * | 2001-10-16 | 2004-02-12 | Waddell Walter H. | Elastomeric composition |
US6939921B2 (en) * | 2001-10-16 | 2005-09-06 | Exxonmobil Chemical Patents Inc. | Colorable elastomeric composition |
CA2386646C (en) * | 2002-05-16 | 2010-07-20 | Bayer Inc. | Rubber compound for a vibration dampening device |
US6837287B2 (en) * | 2002-06-13 | 2005-01-04 | The Goodyear Tire & Rubber Company | Self-sealing pneumatic tire and preparation thereof |
JP4690195B2 (ja) | 2002-12-20 | 2011-06-01 | エクソンモービル・ケミカル・パテンツ・インク | 新しい配列分布を有するポリマー |
EP1905581A1 (en) | 2003-10-27 | 2008-04-02 | ExxonMobil Chemical Patents Inc. | Microlayered composites and processes for making the same |
US20050166551A1 (en) * | 2004-02-02 | 2005-08-04 | Keane J. A. | Multilayer high clarity shrink film comprising monovinylarene-conjugated diene copolymer |
CA2581050C (en) * | 2004-06-15 | 2012-01-10 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions, air barriers, and processes for making the same |
CA2592498C (en) * | 2004-12-29 | 2011-09-13 | Exxonmobil Chemical Patents Inc. | Select elastomeric blends and their use in articles |
US7906600B2 (en) * | 2004-12-29 | 2011-03-15 | Exxonmobil Chemical Patents Inc. | Processable filled, curable halogenated isoolefin elastomers |
WO2007003209A1 (en) * | 2005-07-01 | 2007-01-11 | Pirelli Tyre S.P.A. | Process for manufacturing tires |
EP2502742B1 (en) | 2005-10-27 | 2017-06-21 | ExxonMobil Chemical Patents Inc. | Construction comprising tie layer for pneumatic tire |
US7803629B2 (en) * | 2006-06-27 | 2010-09-28 | Chevron Phillips Chemical Company, Lp | Method for employing SEC-FTIR data to predict mechanical properties of polyethylene |
US7498381B1 (en) | 2006-08-02 | 2009-03-03 | Exxonmobil Chemical Patents Inc. | Low permeability elastomeric-metal phosphate nanocomposites |
WO2008140875A1 (en) * | 2007-05-16 | 2008-11-20 | Exxonmobil Chemical Patents Inc. | Catalyst system for olefin polymerization and polymers produced therefrom |
CN101353403B (zh) * | 2007-07-27 | 2012-02-08 | 中国石油化工股份有限公司 | 星形支化聚异丁烯或丁基橡胶的制备方法 |
CA2696102C (en) * | 2007-08-31 | 2012-09-11 | Exxonmobil Chemical Patents Inc. | Method for reducing depositions in polymerization vessels |
FR2925388A1 (fr) * | 2007-12-21 | 2009-06-26 | Michelin Soc Tech | Dispositif et procede de preparation d'un profile d'un gel thermoplastique elastomere |
CN101613427B (zh) * | 2008-06-27 | 2011-04-20 | 北京化工大学 | 高反应活性聚异丁烯的制备方法 |
WO2010006983A1 (en) * | 2008-07-15 | 2010-01-21 | Lanxess International Sa | Common solvent process for producing high molecular weight halobutyl rubber |
WO2011031437A1 (en) * | 2009-09-10 | 2011-03-17 | Exxonmobil Chemical Patents Inc. | Elastomeric copolymers, copolymer compositions, and their use in articles |
MY162735A (en) * | 2010-01-20 | 2017-07-14 | Arlanxeo Deutschland Gmbh | Common solvent process for producing high molecular weight halogenated rubber |
CN103140515B (zh) | 2010-07-30 | 2015-07-01 | 株式会社普利司通 | 共聚物、橡胶组合物、交联橡胶组合物和轮胎 |
CN102464736B (zh) * | 2010-11-19 | 2013-07-24 | 北京化工大学 | 制备聚异丁烯的工艺方法及聚合装置 |
EP2739488A2 (en) * | 2011-08-03 | 2014-06-11 | Milliken & Company | Reinforced rubber article with tape elements |
US9469753B2 (en) | 2013-07-22 | 2016-10-18 | Exxonmobil Chemical Patents Inc. | Propylene copolymers in elastomeric compositions |
JP6328773B2 (ja) * | 2013-12-23 | 2018-05-23 | アランセオ・シンガポール・プライヴェート・リミテッド | 高純度ハロゲン化ゴム |
EP3087138B1 (en) * | 2013-12-23 | 2021-06-09 | Arlanxeo Singapore Pte. Ltd. | Rubbers with tunable levels of metal containing anti-agglomerants |
SG11201608806XA (en) * | 2014-04-30 | 2016-11-29 | Arlanxeo Singapore Pte Ltd | Highly unsaturated multi-modal polyisoolefin composition and process for preparation thereof |
EP3231820A1 (en) * | 2016-04-15 | 2017-10-18 | ARLANXEO Canada Inc. | Polymer compositions having a halo-containing polymer with a multi-functional phosphine linkage |
US10899718B2 (en) | 2016-09-02 | 2021-01-26 | Bridgestone Corporation | Polymers functionalized with N-protected hydantoin compounds |
JP6820128B2 (ja) * | 2016-09-07 | 2021-01-27 | 中国石油化工股▲ふん▼有限公司 | ブチルゴム、その製造方法、ゴム製品、組成物及び応用、並びに、車両用タイヤインナーライナー、インナーチューブ及び加硫ブラダー |
JP6984610B2 (ja) * | 2016-11-15 | 2021-12-22 | 日本ゼオン株式会社 | 合成ポリイソプレンラテックス |
WO2019036085A1 (en) | 2017-08-18 | 2019-02-21 | Exxonmobil Chemical Patents Inc | HYDROCARBON RESINS FOR BUTYL BASED COMPOSITIONS AND PROCESSES FOR PREPARING THE SAME |
DE102018202610A1 (de) | 2018-02-21 | 2019-08-22 | Continental Reifen Deutschland Gmbh | Extrudervorrichtung zum Extrudieren von Kautschukmischungen mit einer Füttereinheit, Verwendung der Füttereinheit zum Füttern von Kautschukmischungen in eine Zuführeinheit einer Extrudervorrichtung sowie Verfahren zum Herstellen einer extrudierten Kautschukmischung |
CN110240762B (zh) * | 2018-03-08 | 2022-03-29 | 中国石油化工股份有限公司 | 一种橡胶组合物及其应用和一种轮胎内胎及其制备方法 |
CN110240761B (zh) * | 2018-03-08 | 2022-07-12 | 中国石油化工股份有限公司 | 一种橡胶组合物及其应用和一种硫化胶囊及其制备方法 |
JP7077421B2 (ja) | 2018-04-03 | 2022-05-30 | エクソンモービル ケミカル パテンツ インコーポレイテッド | イソブチレン系ポリマーを官能化するための無溶媒プロセス |
CN112135848B (zh) | 2018-04-03 | 2023-08-29 | 埃克森美孚化学专利公司 | 具有烯属侧链取代基的基于异丁烯的聚合物及含有它的可固化组合物 |
US12006393B2 (en) | 2018-04-03 | 2024-06-11 | ExxonMobil Engineering & Technology Company | Thioacetate functionalized isobutylene-based polymers and curable compositions containing the same |
CN110763528B (zh) * | 2018-07-25 | 2022-06-03 | 中国石油天然气股份有限公司 | 一种确定橡胶支化度的方法 |
CN109917029A (zh) * | 2018-11-22 | 2019-06-21 | 内蒙合成化工研究所 | 一种脂肪族聚醚多元醇官能度及分布的测定方法 |
CN112011019B (zh) * | 2019-05-31 | 2022-11-04 | 中国石油天然气股份有限公司 | 一种卤化双峰分布星型支化丁基橡胶的制备方法 |
CN112011003B (zh) * | 2019-05-31 | 2022-11-04 | 中国石油天然气股份有限公司 | 一种用于丁基橡胶支化的官能化四臂星型支化剂的制备方法 |
CN112011018B (zh) * | 2019-05-31 | 2022-11-04 | 中国石油天然气股份有限公司 | 一种淤浆法制备双峰分布星型支化丁基橡胶的方法 |
CN112011017B (zh) * | 2019-05-31 | 2022-11-04 | 中国石油天然气股份有限公司 | 一种溶液法制备双峰分布星型支化丁基橡胶的方法 |
WO2021011883A1 (en) | 2019-07-17 | 2021-01-21 | Exxonmobil Chemical Patents Inc. | Ethylene-based copolymer and propylene-alpha-olefin-diene compositions for use in layered articles |
CN112646098B (zh) * | 2019-10-12 | 2022-09-20 | 中国石油化工股份有限公司 | 嵌段共聚物及其制备方法 |
WO2021262842A1 (en) | 2020-06-26 | 2021-12-30 | Exxonmobil Chemical Patents Inc. | COPOLYMERS OF ETHYLENE, α-OLEFIN, NON-CONJUGATED DIENE, AND ARYL-SUBSTITUTED CYCLOALKENE, METHODS TO PRODUCE, BLENDS, AND ARTICLES THEREFROM |
WO2021262838A1 (en) | 2020-06-26 | 2021-12-30 | Exxonmobil Chemical Patents Inc. | Copolymers composed of ethylene, a-olefin, non-conjugated diene, and substituted styrene and articles therefrom |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1443149A (en) * | 1922-02-02 | 1923-01-23 | Schidrowitz Philip | Rubber composition and method of making the same |
FR555448A (fr) * | 1922-09-14 | 1923-06-29 | Vultex Ltd | Perfectionnements à la fabrication de caoutchouc |
US2356128A (en) | 1939-10-20 | 1944-08-22 | Jasco Inc | Mixed olefinic polymerization process and product |
US2781334A (en) | 1952-05-01 | 1957-02-12 | Exxon Research Engineering Co | Divinyl aromatic modified isoolefinmultiolefin copolymers |
US2729626A (en) | 1952-05-01 | 1956-01-03 | Exxon Research Engineering Co | Isoolefin-multiolefin copolymers |
US2671774A (en) | 1952-07-28 | 1954-03-09 | Standard Oil Dev Co | High extrusion modified isoolefinmultiolefin copolymers |
GB799043A (en) * | 1953-09-08 | 1958-07-30 | Oliver Wallis Burke Jr | Improvement in vinylic fillers and the reinforcement of elastic and plastic materials therewith |
US3135721A (en) | 1959-10-20 | 1964-06-02 | Exxon Research Engineering Co | Method of preventing reactor fouling |
US3219641A (en) | 1961-05-10 | 1965-11-23 | Exxon Research Engineering Co | Process for modifying butyl rubber |
BE627652A (es) * | 1962-01-29 | |||
DE1258091B (de) * | 1965-05-08 | 1968-01-04 | Basf Ag | Verfahren zur Herstellung von ungesaettigten Isobutylen-Pfropfcopolymerisaten |
DE1276687B (de) | 1965-09-15 | 1968-09-05 | Siemens Ag | Schaltungsanordnung fuer Fernschreibvermittlungslanlagen zum Umsetzen von Einfachstrom- in Doppelstromzeichen |
US3904708A (en) * | 1966-07-26 | 1975-09-09 | Joseph P Kennedy | Process for graft polymerization |
US3933942A (en) * | 1968-01-08 | 1976-01-20 | Exxon Research And Engineering Company | Process for graft polymerization |
US4139695A (en) * | 1975-11-13 | 1979-02-13 | Exxon Research & Engineering Co. | High molecular weight high unsaturation C4-C10 isoolefin conjugated diolefin copolymers and multipolymers containing methylcyclopentadiene |
GB1604393A (en) * | 1977-09-09 | 1981-12-09 | Dunlop Ltd | Tyres |
US4245060A (en) | 1978-08-07 | 1981-01-13 | Exxon Research & Engineering Co. | Functional group containing cyclic diolefin butyl rubbers |
US4358560A (en) * | 1979-08-02 | 1982-11-09 | Exxon Research & Engineering Co. | Stabilized slurries of isoolefin polymers |
US4252710A (en) * | 1979-08-02 | 1981-02-24 | Exxon Research & Engineering Co. | Stabilized slurries of isoolefin polymers |
JPS5813090B2 (ja) * | 1979-08-24 | 1983-03-11 | 横浜ゴム株式会社 | タイヤトレッド用ゴム組成物の製造方法 |
US4474924A (en) * | 1983-01-27 | 1984-10-02 | Exxon Research & Engineering Co. | Stabilized slurries of isoolefin polymers |
CA1247773A (en) * | 1983-12-12 | 1988-12-28 | Bridgestone Corporation | Pneumatic tire suitable for running on snow and ice roads |
EP0234114A3 (en) * | 1985-12-16 | 1990-01-17 | Exxon Research And Engineering Company | End-capped polymer chains, graft and star copolymers, and process of making same |
-
1987
- 1987-12-11 US US07/131,938 patent/US5071913A/en not_active Expired - Lifetime
-
1988
- 1988-12-08 EP EP88311634A patent/EP0320263B1/en not_active Expired - Lifetime
- 1988-12-08 DE DE3855069T patent/DE3855069T2/de not_active Expired - Lifetime
- 1988-12-08 ES ES95110803T patent/ES2134976T3/es not_active Expired - Lifetime
- 1988-12-08 DE DE3856349T patent/DE3856349T2/de not_active Expired - Lifetime
- 1988-12-08 ES ES88311634T patent/ES2085261T3/es not_active Expired - Lifetime
- 1988-12-08 EP EP95110803A patent/EP0678529B1/en not_active Expired - Lifetime
- 1988-12-09 CA CA000585501A patent/CA1330144C/en not_active Expired - Fee Related
- 1988-12-09 JP JP63311805A patent/JP2865299B2/ja not_active Expired - Lifetime
- 1988-12-09 AU AU26747/88A patent/AU2674788A/en not_active Abandoned
- 1988-12-09 BR BR888806522A patent/BR8806522A/pt not_active IP Right Cessation
- 1988-12-10 KR KR1019880016450A patent/KR0135766B1/ko not_active IP Right Cessation
- 1988-12-12 CN CN88108392A patent/CN1036022A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
EP0678529A3 (en) | 1995-11-15 |
EP0320263B1 (en) | 1996-03-06 |
KR890010074A (ko) | 1989-08-05 |
CA1330144C (en) | 1994-06-07 |
DE3856349D1 (de) | 1999-08-19 |
EP0678529B1 (en) | 1999-07-14 |
DE3855069D1 (de) | 1996-04-11 |
AU2674788A (en) | 1989-06-15 |
CN1036022A (zh) | 1989-10-04 |
US5071913A (en) | 1991-12-10 |
ES2134976T3 (es) | 1999-10-16 |
DE3855069T2 (de) | 1996-10-10 |
EP0678529A2 (en) | 1995-10-25 |
EP0320263A2 (en) | 1989-06-14 |
DE3856349T2 (de) | 2000-02-24 |
JPH01207342A (ja) | 1989-08-21 |
EP0320263A3 (en) | 1991-11-27 |
JP2865299B2 (ja) | 1999-03-08 |
KR0135766B1 (ko) | 1998-04-23 |
BR8806522A (pt) | 1989-08-22 |
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