ES2052688T3 - Material compuesto ceramico-metalico. - Google Patents
Material compuesto ceramico-metalico.Info
- Publication number
- ES2052688T3 ES2052688T3 ES88201851T ES88201851T ES2052688T3 ES 2052688 T3 ES2052688 T3 ES 2052688T3 ES 88201851 T ES88201851 T ES 88201851T ES 88201851 T ES88201851 T ES 88201851T ES 2052688 T3 ES2052688 T3 ES 2052688T3
- Authority
- ES
- Spain
- Prior art keywords
- copper
- alloy
- ceramic
- composite material
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/06—Operating or servicing
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
- C25C3/12—Anodes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/02—Electrodes; Connections thereof
- C25C7/025—Electrodes; Connections thereof used in cells for the electrolysis of melts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Mechanical Engineering (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Electrolytic Production Of Metals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Chemically Coating (AREA)
Abstract
ESTE MATERIAL COMPUESTO METALICO/CERAMICO SE COMPONE DE UNA CUBIERTA SUPERFICIAL CERAMICA FORMADA POR UNA ALEACION OXIDADA DE COBRE ESTABILIZADA A TRAVES DE LA FORMACION DE UNA SOLUCION SOLIDA CON OXIDO DE NIQUEL O MANGANESO EN UN SUSTRATO QUE ES UNA ALEACION RESISTENTE A LA OXIDACION, COMPUESTA ESENCIALMENTE POR COBRE O CUALQUIER OTRO METAL QUE SE OXIDE MAS FACILMENTE QUE EL COBRE. EL COMPUESTO SE PREPARA POR LA OXIDACION DE LA ALEACION DE COBRE Y DEL SUSTRATO SIMULTANEAMENTE, DE FORMA QUE SE FORME UNA PELICULA IMPERMEABLE AL OXIGENO, POR EJEMPLO UNA CAPA DE OXIDO DE CROMO FORMADA EN UNA ALEACION DE CROMO CON NIQUEL, HIERRO Y/O COBALTO. EL COMPUESTO PUEDE SER UTILIZADO COMO SUSTRATO DEL ANODO PARA EL RECIBRIMIENTO DE OXIFLUORURO DE CERIO UTILIZADO EN LA OBTENCION DE ALUMINIO POR EL PROCESO ELECTROLITICO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP87810503 | 1987-09-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2052688T3 true ES2052688T3 (es) | 1994-07-16 |
Family
ID=8198416
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES198888201854T Expired - Lifetime ES2039594T3 (es) | 1987-09-02 | 1988-08-30 | Electrolisis de sales fundidas con anodos no consumibles. |
ES88201851T Expired - Lifetime ES2052688T3 (es) | 1987-09-02 | 1988-08-30 | Material compuesto ceramico-metalico. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES198888201854T Expired - Lifetime ES2039594T3 (es) | 1987-09-02 | 1988-08-30 | Electrolisis de sales fundidas con anodos no consumibles. |
Country Status (11)
Country | Link |
---|---|
US (3) | US5069771A (es) |
EP (4) | EP0306101A1 (es) |
CN (1) | CN1042737A (es) |
AU (4) | AU2428988A (es) |
BR (2) | BR8807682A (es) |
CA (3) | CA1328243C (es) |
DD (1) | DD283655A5 (es) |
DE (2) | DE3879819T2 (es) |
ES (2) | ES2039594T3 (es) |
NO (1) | NO302904B1 (es) |
WO (4) | WO1989001991A1 (es) |
Families Citing this family (71)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4966674A (en) * | 1986-08-21 | 1990-10-30 | Moltech Invent S. A. | Cerium oxycompound, stable anode for molten salt electrowinning and method of production |
WO1989001991A1 (en) * | 1987-09-02 | 1989-03-09 | Moltech Invent S.A. | A ceramic/metal composite material |
ES2072427T3 (es) * | 1989-03-07 | 1995-07-16 | Moltech Invent Sa | Soporte de anodo recubierto con oxicompuestos de tierras raras. |
US5131776A (en) * | 1990-07-13 | 1992-07-21 | Binney & Smith Inc. | Aqueous permanent coloring composition for a marker |
SG70558A1 (en) * | 1991-06-11 | 2000-02-22 | Qualcomm Inc | Variable rate vocoder |
US5279715A (en) * | 1991-09-17 | 1994-01-18 | Aluminum Company Of America | Process and apparatus for low temperature electrolysis of oxides |
US5254232A (en) * | 1992-02-07 | 1993-10-19 | Massachusetts Institute Of Technology | Apparatus for the electrolytic production of metals |
US5725744A (en) * | 1992-03-24 | 1998-03-10 | Moltech Invent S.A. | Cell for the electrolysis of alumina at low temperatures |
US5284562A (en) * | 1992-04-17 | 1994-02-08 | Electrochemical Technology Corp. | Non-consumable anode and lining for aluminum electrolytic reduction cell |
AU669407B2 (en) * | 1994-01-18 | 1996-06-06 | Brooks Rand, Ltd. | Non-consumable anode and lining for aluminum electrolytic reduction cell |
US5510010A (en) * | 1994-03-01 | 1996-04-23 | Carrier Corporation | Copper article with protective coating |
US5510008A (en) * | 1994-10-21 | 1996-04-23 | Sekhar; Jainagesh A. | Stable anodes for aluminium production cells |
US5566011A (en) * | 1994-12-08 | 1996-10-15 | Luncent Technologies Inc. | Antiflector black matrix having successively a chromium oxide layer, a molybdenum layer and a second chromium oxide layer |
JP3373076B2 (ja) * | 1995-02-17 | 2003-02-04 | トヨタ自動車株式会社 | 耐摩耗性Cu基合金 |
US5904828A (en) * | 1995-09-27 | 1999-05-18 | Moltech Invent S.A. | Stable anodes for aluminium production cells |
IT1291604B1 (it) * | 1997-04-18 | 1999-01-11 | De Nora Spa | Anodo per l'evoluzione di ossigeno in elettroliti contenenti fluoruri o loro derivati |
US6821312B2 (en) * | 1997-06-26 | 2004-11-23 | Alcoa Inc. | Cermet inert anode materials and method of making same |
US6162334A (en) * | 1997-06-26 | 2000-12-19 | Alcoa Inc. | Inert anode containing base metal and noble metal useful for the electrolytic production of aluminum |
US6423195B1 (en) | 1997-06-26 | 2002-07-23 | Alcoa Inc. | Inert anode containing oxides of nickel, iron and zinc useful for the electrolytic production of metals |
US6423204B1 (en) | 1997-06-26 | 2002-07-23 | Alcoa Inc. | For cermet inert anode containing oxide and metal phases useful for the electrolytic production of metals |
US6372119B1 (en) | 1997-06-26 | 2002-04-16 | Alcoa Inc. | Inert anode containing oxides of nickel iron and cobalt useful for the electrolytic production of metals |
US6217739B1 (en) | 1997-06-26 | 2001-04-17 | Alcoa Inc. | Electrolytic production of high purity aluminum using inert anodes |
US6416649B1 (en) | 1997-06-26 | 2002-07-09 | Alcoa Inc. | Electrolytic production of high purity aluminum using ceramic inert anodes |
CA2212471C (en) * | 1997-08-06 | 2003-04-01 | Tony Addona | A method of forming an oxide ceramic anode in a transferred plasma arc reactor |
CN1055140C (zh) * | 1997-11-19 | 2000-08-02 | 西北有色金属研究院 | 一种用于稀土熔盐电解的陶瓷阳极及其制备方法 |
US6365018B1 (en) * | 1998-07-30 | 2002-04-02 | Moltech Invent S.A. | Surface coated non-carbon metal-based anodes for aluminium production cells |
ES2230828T3 (es) * | 1998-01-20 | 2005-05-01 | Moltech Invent S.A. | Anodos de base metalica sin carbono para celdas de produccion de aluminio. |
WO1999036592A1 (en) * | 1998-01-20 | 1999-07-22 | Moltech Invent S.A. | Electrocatalytically active non-carbon metal-based anodes for aluminium production cells |
CA2317595A1 (en) * | 1998-01-20 | 1999-07-22 | Moltech Invent S.A. | Surface coated non-carbon metal-based anodes for aluminium production cells |
US6113758A (en) * | 1998-07-30 | 2000-09-05 | Moltech Invent S.A. | Porous non-carbon metal-based anodes for aluminium production cells |
DE69933854T2 (de) * | 1998-01-20 | 2007-05-31 | Moltech Invent S.A. | Aufschlämmung zum beschichten von kohlenstofffreien anoden auf metallbasis für zellen zur aluminiumherstellung |
US6103090A (en) * | 1998-07-30 | 2000-08-15 | Moltech Invent S.A. | Electrocatalytically active non-carbon metal-based anodes for aluminium production cells |
WO2000006802A1 (en) * | 1998-07-30 | 2000-02-10 | Moltech Invent S.A. | Cells for the electrowinning of aluminium having dimensionally stable metal-based anodes |
US6248227B1 (en) * | 1998-07-30 | 2001-06-19 | Moltech Invent S.A. | Slow consumable non-carbon metal-based anodes for aluminium production cells |
EP1109952B1 (en) * | 1998-07-30 | 2004-10-27 | MOLTECH Invent S.A. | Multi-layer non-carbon metal-based anodes for aluminium production cells |
US6372099B1 (en) * | 1998-07-30 | 2002-04-16 | Moltech Invent S.A. | Cells for the electrowinning of aluminium having dimensionally stable metal-based anodes |
US6425992B1 (en) | 1998-07-30 | 2002-07-30 | Moltech Invent S.A. | Surface coated non-carbon metal-based anodes |
US6083362A (en) * | 1998-08-06 | 2000-07-04 | University Of Chicago | Dimensionally stable anode for electrolysis, method for maintaining dimensions of anode during electrolysis |
CA2393426A1 (en) * | 1999-12-09 | 2001-06-14 | Moltech Invent S.A. | Metal-based anodes for aluminium electrowinning cells |
US6419813B1 (en) | 2000-11-25 | 2002-07-16 | Northwest Aluminum Technologies | Cathode connector for aluminum low temperature smelting cell |
US6419812B1 (en) | 2000-11-27 | 2002-07-16 | Northwest Aluminum Technologies | Aluminum low temperature smelting cell metal collection |
RU2283372C2 (ru) * | 2001-03-07 | 2006-09-10 | Мольтех Инвент С.А. | Электролизер для электрохимического получения алюминия, работающий с анодами на основе металла |
DE60202455T2 (de) * | 2001-04-12 | 2005-06-02 | Moltech Invent S.A. | Anoden auf basis von metallen für aluminium-elektrogewinnungszellen |
US6741061B2 (en) * | 2001-05-24 | 2004-05-25 | Comair Rotron, Inc. | Efficient stator |
US6537438B2 (en) | 2001-08-27 | 2003-03-25 | Alcoa Inc. | Method for protecting electrodes during electrolysis cell start-up |
US6692631B2 (en) | 2002-02-15 | 2004-02-17 | Northwest Aluminum | Carbon containing Cu-Ni-Fe anodes for electrolysis of alumina |
US7077945B2 (en) * | 2002-03-01 | 2006-07-18 | Northwest Aluminum Technologies | Cu—Ni—Fe anode for use in aluminum producing electrolytic cell |
US6558525B1 (en) | 2002-03-01 | 2003-05-06 | Northwest Aluminum Technologies | Anode for use in aluminum producing electrolytic cell |
US6723222B2 (en) | 2002-04-22 | 2004-04-20 | Northwest Aluminum Company | Cu-Ni-Fe anodes having improved microstructure |
EP1495160B1 (en) * | 2002-04-16 | 2005-11-09 | MOLTECH Invent S.A. | Non-carbon anodes for aluminium electrowinning and other oxidation resistant components with slurry-applied coatings |
AU2002348943A1 (en) * | 2002-09-11 | 2004-04-30 | Moltech Invent S.A. | Non-carbon anodes for aluminium electrowinning and other oxidation resistant components with iron oxide-containing coatings |
US7033469B2 (en) * | 2002-11-08 | 2006-04-25 | Alcoa Inc. | Stable inert anodes including an oxide of nickel, iron and aluminum |
US6758991B2 (en) | 2002-11-08 | 2004-07-06 | Alcoa Inc. | Stable inert anodes including a single-phase oxide of nickel and iron |
US7811425B2 (en) * | 2004-03-18 | 2010-10-12 | Moltech Invent S.A. | Non-carbon anodes with active coatings |
CA2557957C (en) * | 2004-03-18 | 2012-05-15 | Moltech Invent S.A. | Non-carbon anodes |
WO2007105125A2 (en) * | 2006-03-10 | 2007-09-20 | Moltech Invent S.A. | Aluminium electrowinning cell with enhanced crust |
US20070278107A1 (en) * | 2006-05-30 | 2007-12-06 | Northwest Aluminum Technologies | Anode for use in aluminum producing electrolytic cell |
US7718319B2 (en) | 2006-09-25 | 2010-05-18 | Board Of Regents, The University Of Texas System | Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries |
US20080172861A1 (en) * | 2007-01-23 | 2008-07-24 | Holmes Alan G | Methods for manufacturing motor core parts with magnetic orientation |
JP5271896B2 (ja) * | 2007-04-20 | 2013-08-21 | 三井化学株式会社 | 電気分解装置、それに用いる電極および電気分解方法 |
US20090016948A1 (en) * | 2007-07-12 | 2009-01-15 | Young Edgar D | Carbon and fuel production from atmospheric CO2 and H2O by artificial photosynthesis and method of operation thereof |
MY153924A (en) * | 2008-09-08 | 2015-04-15 | Rio Tinto Alcan Int Ltd | Metallic oxygen evolving anode operating at high current density for aluminium reduction cells. |
US7888283B2 (en) * | 2008-12-12 | 2011-02-15 | Lihong Huang | Iron promoted nickel based catalysts for hydrogen generation via auto-thermal reforming of ethanol |
WO2011140209A2 (en) * | 2010-05-04 | 2011-11-10 | The George Washington University | Processes for iron and steel production |
US8764962B2 (en) * | 2010-08-23 | 2014-07-01 | Massachusetts Institute Of Technology | Extraction of liquid elements by electrolysis of oxides |
CN103014769A (zh) * | 2012-11-26 | 2013-04-03 | 中国铝业股份有限公司 | 一种铝电解用合金惰性阳极及其制备方法 |
CN103540960B (zh) * | 2013-09-30 | 2016-08-17 | 赣南师范学院 | 一种稀土镁镍基储氢合金的制备方法 |
CN104131315B (zh) * | 2014-08-20 | 2017-11-07 | 赣南师范大学 | 一种稀土镁镍基储氢合金电解共析合金化方法 |
CN106435324A (zh) * | 2016-10-31 | 2017-02-22 | 张家港沙工科技服务有限公司 | 一种机械设备用低电阻复合管 |
CN109811368B (zh) * | 2019-03-20 | 2021-03-16 | 武汉大学 | 用于熔盐电解体系的锂离子强化型惰性阳极及其制备方法 |
EP3839084A1 (en) * | 2019-12-20 | 2021-06-23 | David Jarvis | Metal alloy |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2548514A (en) * | 1945-08-23 | 1951-04-10 | Bramley Jenny | Process of producing secondaryelectron-emitting surfaces |
US3804740A (en) * | 1972-02-01 | 1974-04-16 | Nora Int Co | Electrodes having a delafossite surface |
US4024294A (en) * | 1973-08-29 | 1977-05-17 | General Electric Company | Protective coatings for superalloys |
US4173518A (en) * | 1974-10-23 | 1979-11-06 | Sumitomo Aluminum Smelting Company, Limited | Electrodes for aluminum reduction cells |
US4157943A (en) * | 1978-07-14 | 1979-06-12 | The International Nickel Company, Inc. | Composite electrode for electrolytic processes |
FR2434213A1 (fr) * | 1978-08-24 | 1980-03-21 | Solvay | Procede pour la production electrolytique d'hydrogene en milieu alcalin |
GB2069529A (en) * | 1980-01-17 | 1981-08-26 | Diamond Shamrock Corp | Cermet anode for electrowinning metals from fused salts |
US4399008A (en) * | 1980-11-10 | 1983-08-16 | Aluminum Company Of America | Composition for inert electrodes |
US4374050A (en) * | 1980-11-10 | 1983-02-15 | Aluminum Company Of America | Inert electrode compositions |
US4374761A (en) * | 1980-11-10 | 1983-02-22 | Aluminum Company Of America | Inert electrode formulations |
CA1181616A (en) * | 1980-11-10 | 1985-01-29 | Aluminum Company Of America | Inert electrode compositions |
US4478693A (en) * | 1980-11-10 | 1984-10-23 | Aluminum Company Of America | Inert electrode compositions |
GB8301001D0 (en) * | 1983-01-14 | 1983-02-16 | Eltech Syst Ltd | Molten salt electrowinning method |
US4484997A (en) * | 1983-06-06 | 1984-11-27 | Great Lakes Carbon Corporation | Corrosion-resistant ceramic electrode for electrolytic processes |
US4620905A (en) * | 1985-04-25 | 1986-11-04 | Aluminum Company Of America | Electrolytic production of metals using a resistant anode |
BR8707791A (pt) * | 1986-08-21 | 1989-10-03 | Moltech Invent Sa | Material de cermet,corpo de cermet e processo de fabricacao |
WO1989001991A1 (en) * | 1987-09-02 | 1989-03-09 | Moltech Invent S.A. | A ceramic/metal composite material |
-
1988
- 1988-08-30 WO PCT/EP1988/000785 patent/WO1989001991A1/en unknown
- 1988-08-30 US US07/350,475 patent/US5069771A/en not_active Expired - Fee Related
- 1988-08-30 EP EP88201853A patent/EP0306101A1/en not_active Withdrawn
- 1988-08-30 EP EP88201851A patent/EP0306099B1/en not_active Expired - Lifetime
- 1988-08-30 BR BR888807682A patent/BR8807682A/pt not_active Application Discontinuation
- 1988-08-30 US US07/350,480 patent/US4960494A/en not_active Expired - Lifetime
- 1988-08-30 DE DE8888201854T patent/DE3879819T2/de not_active Expired - Fee Related
- 1988-08-30 AU AU24289/88A patent/AU2428988A/en not_active Abandoned
- 1988-08-30 WO PCT/EP1988/000787 patent/WO1989001993A1/en unknown
- 1988-08-30 ES ES198888201854T patent/ES2039594T3/es not_active Expired - Lifetime
- 1988-08-30 EP EP88201854A patent/EP0306102B1/en not_active Expired - Lifetime
- 1988-08-30 AU AU24243/88A patent/AU615002B2/en not_active Ceased
- 1988-08-30 AU AU23200/88A patent/AU2320088A/en not_active Abandoned
- 1988-08-30 BR BR888807683A patent/BR8807683A/pt not_active Application Discontinuation
- 1988-08-30 ES ES88201851T patent/ES2052688T3/es not_active Expired - Lifetime
- 1988-08-30 WO PCT/EP1988/000788 patent/WO1989001994A1/en unknown
- 1988-08-30 AU AU23276/88A patent/AU614995B2/en not_active Ceased
- 1988-08-30 US US07/350,477 patent/US4956068A/en not_active Expired - Lifetime
- 1988-08-30 DE DE8888201851T patent/DE3875040T2/de not_active Expired - Fee Related
- 1988-08-30 EP EP88201852A patent/EP0306100A1/en not_active Withdrawn
- 1988-08-30 WO PCT/EP1988/000786 patent/WO1989001992A1/en unknown
- 1988-09-01 CA CA000576279A patent/CA1328243C/en not_active Expired - Fee Related
- 1988-09-01 CA CA000576282A patent/CA1306148C/en not_active Expired - Fee Related
- 1988-09-01 CA CA000576281A patent/CA1306147C/en not_active Expired - Fee Related
- 1988-11-18 CN CN88107981A patent/CN1042737A/zh active Pending
-
1989
- 1989-03-02 DD DD89326219A patent/DD283655A5/de not_active IP Right Cessation
-
1990
- 1990-03-01 NO NO900995A patent/NO302904B1/no unknown
Also Published As
Publication number | Publication date |
---|---|
NO900995D0 (no) | 1990-03-01 |
DE3875040T2 (de) | 1993-02-25 |
DE3879819D1 (de) | 1993-05-06 |
WO1989001991A1 (en) | 1989-03-09 |
EP0306102A1 (en) | 1989-03-08 |
AU2428988A (en) | 1989-03-31 |
NO302904B1 (no) | 1998-05-04 |
WO1989001993A1 (en) | 1989-03-09 |
DE3879819T2 (de) | 1993-07-08 |
DD283655A5 (de) | 1990-10-17 |
EP0306099A1 (en) | 1989-03-08 |
EP0306100A1 (en) | 1989-03-08 |
CA1306147C (en) | 1992-08-11 |
WO1989001992A1 (en) | 1989-03-09 |
US4960494A (en) | 1990-10-02 |
CA1328243C (en) | 1994-04-05 |
CN1042737A (zh) | 1990-06-06 |
EP0306102B1 (en) | 1993-03-31 |
CA1306148C (en) | 1992-08-11 |
US4956068A (en) | 1990-09-11 |
BR8807683A (pt) | 1990-06-26 |
EP0306099B1 (en) | 1992-09-30 |
ES2039594T3 (es) | 1993-10-01 |
BR8807682A (pt) | 1990-06-26 |
AU2424388A (en) | 1989-03-31 |
WO1989001994A1 (en) | 1989-03-09 |
AU2327688A (en) | 1989-03-31 |
AU615002B2 (en) | 1991-09-19 |
AU614995B2 (en) | 1991-09-19 |
AU2320088A (en) | 1989-03-31 |
US5069771A (en) | 1991-12-03 |
EP0306101A1 (en) | 1989-03-08 |
NO900995L (no) | 1990-03-01 |
DE3875040D1 (de) | 1992-11-05 |
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