EP3893660A1 - Composition comprenant des proteines de legumineuses texturees - Google Patents
Composition comprenant des proteines de legumineuses textureesInfo
- Publication number
- EP3893660A1 EP3893660A1 EP19839402.5A EP19839402A EP3893660A1 EP 3893660 A1 EP3893660 A1 EP 3893660A1 EP 19839402 A EP19839402 A EP 19839402A EP 3893660 A1 EP3893660 A1 EP 3893660A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- legume
- proteins
- dry
- textured
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- 235000004348 Perilla frutescens Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 244000000231 Sesamum indicum Species 0.000 description 1
- 235000003434 Sesamum indicum Nutrition 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
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- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 description 1
- 230000036541 health Effects 0.000 description 1
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- 235000011477 liquorice Nutrition 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
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- 229920001282 polysaccharide Polymers 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J3/00—Working-up of proteins for foodstuffs
- A23J3/22—Working-up of proteins for foodstuffs by texturising
- A23J3/26—Working-up of proteins for foodstuffs by texturising using extrusion or expansion
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J3/00—Working-up of proteins for foodstuffs
- A23J3/14—Vegetable proteins
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J3/00—Working-up of proteins for foodstuffs
- A23J3/22—Working-up of proteins for foodstuffs by texturising
- A23J3/225—Texturised simulated foods with high protein content
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J3/00—Working-up of proteins for foodstuffs
- A23J3/22—Working-up of proteins for foodstuffs by texturising
- A23J3/225—Texturised simulated foods with high protein content
- A23J3/227—Meat-like textured foods
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L11/00—Pulses, i.e. fruits of leguminous plants, for production of food; Products from legumes; Preparation or treatment thereof
- A23L11/05—Mashed or comminuted pulses or legumes; Products made therefrom
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Definitions
- the present invention relates to a specific composition comprising textured pea proteins, as well as to its manufacturing process.
- the protein texturing technique in particular by cooking-extrusion, in order to prepare products with a fibrous structure intended for the production of meat and fish analogs, has been applied to numerous plant sources.
- the cooking-extrusion processes of proteins can be separated into two major families by the amount of water used during the process. When this quantity is greater than 30% by weight, we will speak of cooking-extrusion called “wet” and the products obtained will rather be intended for the production of finished products for immediate consumption, simulating animal meat for example beef steaks or else chicken nuggets. When this amount of water is less than 30% by weight, this is called “dry” cooking-extrusion: the products obtained are rather intended for use by food industry manufacturers, in order to formulate meat substitutes, by mixing them with other ingredients.
- the field of the present invention is that of "dry" extrusion cooking.
- the dry textured pea proteins will be placed in contact with an aqueous solution.
- the amount of water absorbed for rehydration is not effective enough and, without additional human intervention, it is only about 50% of the amount required for the following formulation steps.
- the present invention relates to a composition comprising dry-textured legume proteins characterized in that its water retention capacity measured by test A is greater than 3 g of water per g of dry proteins, preferably greater than 4 g of water per g of dry proteins, more preferably between 4 g and 5 g.
- the legume protein is chosen from the list consisting of faba beans and peas. Peas are particularly preferred.
- the dry matter of the dry textured legume protein according to the invention is greater than 80% by weight, preferably greater than 90% by weight.
- the present invention also relates to a process for the production of a legume protein composition as described above, characterized in that the process comprises the following steps:
- the powder comprising legume proteins and legume fibers used in step 1 can be prepared by mixing the said protein and fiber.
- the powder can consist mainly of legume proteins and legume fibers.
- the term “essentially constituted” means that the powder may comprise impurities linked to the process for the production of proteins and fibers, such as for example traces of starch.
- the protein and the legume fiber are chosen from the list consisting of faba beans and peas. Peas are particularly preferred.
- step 2 is carried out by baking-extrusion in a twin-screw extruder by applying a specific energy of between 20 and 30 kWh / kg to the powder mixture and by regulating the pressure at the outlet in a range between 70 and 90 bars.
- the twin-screw extruder is characterized by a length / diameter ratio of 60, with an outlet die with a diameter of 27mm.
- the temperature of the textured pea protein composition must be between 30 ° C and 50 ° C, preferably 40 ° C, during step 3 of compression.
- the compression of step 3 is characterized in that the textured protein has, after compression, a density of between 100 and 170 g / L, preferably between 130 g / L and 150 g / l.
- the compression carried out in step 3 is carried out on a dryer drum, in particular with a diameter of 300mm rotating at a speed between 10 and 20 revolutions / min, preferably 16 revolutions / min, equipped with 4 75mm satellite cylinders whose air gap with the main cylinder is between 0.5mm and 1.5mm, preferably 1mm.
- the present invention finally relates to the use of the dry textured legume protein composition as described above in industrial applications such as for example the human and animal food industry, industrial pharmacy or cosmetics.
- the present invention relates to a composition comprising dry-textured legume proteins, characterized in that its water retention capacity measured by test A is greater than 3 g of water per g of dry proteins, preferably greater than 4 g of water per g of dry proteins, more preferably between 4 g and 5 g.
- the legume protein is chosen from the list consisting of faba bean protein and pea protein.
- Pea protein is particularly preferred.
- legumes is considered here as the family of dicotyledonous plants of the order Fabales. It is one of the most important families of flowering plants, the third after Orchidaceae and Asteraceae by the number of species. It has about 765 genera comprising more than 19,500 species.
- Several legumes are important cultivated plants, including soybeans, beans, peas, faba beans, chickpeas, peanuts, lentils, cultivated alfalfa, different clovers, beans, carob, liquorice.
- pea being here considered in its widest sense and including in particular all varieties of “smooth pea” (“smooth pea”) and “wrinkled pea” (“wrinkled pea”), and all mutant varieties of “smooth pea” and “wrinkled pea”, regardless of the uses for which these varieties are generally intended (human food, animal nutrition and / or other uses).
- pea in the present application includes varieties of peas belonging to the genus Pisum and more particularly to the sativum and aestivum species. Said mutant varieties are in particular those called “mutants r”, “mutants rb”, “mutants rug 3”, “mutants rug 4”, “mutants rug 5” and “mutants lam” as described in the article by CL HEYDLEY and al. entitled “Developing novel pea starches” Proceedings of the Symposium of the Industrial Biochemistry and Biotechnology Group of the Biochemical Society, 1996, pp. 77-87.
- textured or “texturing” is meant in the present application any physical and / or chemical process aimed at modifying a composition comprising proteins in order to give it a specific ordered structure. In the context of the invention, the texturing of the protein aims to give the appearance of a fiber, as present in animal meats.
- test A In order to measure the water retention capacity, test A is used, the protocol of which is described below:
- drinking water is meant in the present invention, water that can be drunk or used for domestic and industrial purposes without risk to health.
- this water has a sulphate content of less than 250 mg / l, a chloride content of less than 200 mg / l, a potassium content of less than 12 mg / l, a pH of between 6.5 and 9 and a TH (Hydrometric Title, ie the hardness of water, which corresponds to the measurement of the content of water in calcium and magnesium ions) greater than 15 French degrees.
- drinking water should not have less than 60 mg / l of calcium or 36 mg / l of magnesium.
- the textured pea protein compositions of the prior art are already well known and used in the food industry, in particular in meat analogs.
- the necessary water content is at least 3 g per g of protein, 4 g being preferred.
- This rehydration will make it possible to prepare the fibers to be included in the formulation, by simulating the properties as well as possible. functional of meat fibers, and avoid the excessive presence of poorly rehydrated parts causing a feeling of hardness during final consumption. It is also known that this rehydration cannot be carried out in a single step.
- the shredding or "shredding" of proteins is a well-known solution but it adds a step, making the final formulation process more complex, generating an increase in costs.
- this shredding if it is poorly controlled will cause excessive destructuring of the fibers, causing a loss of the desired functional effects.
- the vegetable fibers having been shortened will simulate the meat fibers less well.
- the dry matter of the dry textured legume protein according to the invention is greater than 80% by weight, preferably greater than 90% by weight.
- Dry matter is measured by any method well known to those skilled in the art.
- the so-called "desiccation” method is used. It consists in determining the quantity of water evaporated by heating a known quantity of a sample of known mass.
- the protein content of the composition according to the invention is advantageously between 60% and 80%, preferably between 70% and 80% by weight on the total dry matter.
- any method well known to those skilled in the art can be used.
- the quantity of total nitrogen will be determined and this content will be multiplied by the coefficient 6.25. This method is particularly well known and used for vegetable proteins.
- the present invention also relates to a process for the production of a legume protein composition as described above, characterized in that the process comprises the following steps:
- the legume protein and fiber from step 1 are chosen from the list consisting of faba bean protein and pea protein. Pea protein is particularly preferred.
- the powder comprising legume proteins and legume fibers used in step 1 can be prepared by mixing said proteins and fibers.
- the powder can consist mainly of legume proteins and legume fibers.
- the term "essentially constituted" means that the powder may include impurities linked to the process for manufacturing proteins and fibers, such as for example traces of starch.
- the mixture consists in obtaining a dry mixture of the various constituents necessary for synthesizing the plant fiber during step 2.
- leg fibers any composition comprising polysaccharides which are little or not digestible by the human digestive system, extracted from legumes. Such fibers are extracted by any process well known to those skilled in the art.
- a commercial example of such a fiber is for example the Pea Fiber I50 fiber from the company Roquette.
- the mixing can be carried out upstream or else directly in the feed of step 2.
- additives well known to those skilled in the art can be added such as flavorings or colorings
- the fiber / protein mixture is naturally obtained by turboseparation of a legume flour.
- Legume seeds are cleaned, stripped of their external fibers and ground into flour.
- the flour is then turboseparated, which consists in the application of an ascending air stream allowing a separation of the different particles according to their density.
- Concentrais Such flours are called "concentrais”. These concentrates also contain between 10% and 20% of legume fibers.
- the dry mass ratio between proteins and fibers is advantageously between 70/30 and 90/10, preferably between 75/25 and 85/15.
- step 2 this mixture of powders will then be textured, which amounts to saying that the proteins and the fibers will undergo thermal destructuring and reorganization in order to form fibers, continuous elongation in parallel straight lines, simulating the fibers present in meats. Any process well known to those skilled in the art will be suitable, in particular by extrusion.
- Extrusion consists in forcing a product to flow through a small orifice, the die, under the action of pressures and high shear forces, thanks to the rotation of one or two screws d 'Archimedes.
- the resulting heating causes cooking and / or denaturing of the product, hence the sometimes used term "cooking-extrusion", then expansion by evaporation of the water at the outlet of the die.
- This technique makes it possible to develop products which are extremely diverse in their composition, their structure (expanded and honeycombed form of the product) and their functional and nutritional properties (denaturation of anti-nutritional or toxic factors, sterilization of food for example). Protein processing often leads to structural changes that take place result in obtaining products with a fibrous appearance, simulating the fibers of animal meats.
- Test B the protocol known as Test B is applied:
- step 2 is carried out by baking-extrusion in a twin-screw extruder by applying to the powder mixture a specific energy of between 20 and 30 kWh / kg and by regulating the pressure at the outlet in a range between 70 and 90 bars.
- the twin-screw extruder is characterized by a length / diameter ratio of 60, with a screw diameter of 27mm.
- water will also be introduced at a flow rate of between 5 and 7 kg / h, preferably between 5.5 and 6.5 kg / h .
- the preferred screw profile used will include the following elements:
- the temperature of the textured pea protein composition during compression step 3 must be between 30 ° C and 50 ° C, preferably 40 ° C.
- step 3 below cannot be carried out effectively.
- the compression of step 3 is characterized in that the textured protein has after compression a density between 100 and 170 g / L, preferably between 130 g / L and 150 g / l.
- Step 3 aims to compress by mechanical pressure the proteins extruded in step 2.
- this compression carried out on a textured protein whose density is between 40 and 120 g / L; preferably 60 and 90 g / L; allows obtaining a textured protein with optimal final retention, without shredding or shredding.
- a person skilled in the art should have expected, after compression, to completely destructure the textured protein by this mechanical compression, so that these functional capacities are destroyed. The Applicant has established that it was in fact the opposite, if the protocol described in this application is respected.
- the compression carried out in step 3 is carried out on a dryer drum, in particular with a diameter of 300mm rotating at a speed between 10 and 20 revolutions / min, preferably 16 revolutions / min, equipped with 4 75mm satellite cylinders whose air gap with the main cylinder is between 0.5mm and 1.5mm, preferably 1mm.
- a particularly preferred device is the Tummers Machinebrouw BV type 350323.
- the present invention finally relates to the use of the dry textured legume protein composition as described above in industrial applications such as for example the human and animal food industry, industrial pharmacy or cosmetics .
- a particular application relates to the use of the composition according to the invention for the manufacture of meat substitute, in particular minced meat.
- Example 1A Production of a dry textured legume protein composition according to the invention
- a powder mixture consisting of 87% NUTRALYS® F85M from the company ROQUETTE and 13% pea fiber I50M is produced.
- This mixture is introduced by gravity into a LEISTRITZ ZSE 27 MAXX extruder from the company LEISTRITZ.
- the mixture is introduced with a regulated flow rate of 35 kg / h. 5.5 kg / h of water is also introduced.
- the extrusion screw composed of 85% of conveying elements, 5% of kneading elements and 10% of elements with inverted pitch, is rotated at a speed between 1100 and 1200 revolutions / min and sends the mixture to a die.
- This particular line generates a machine torque of 42% with an outlet pressure of 91 bars.
- the specific energy of the system is around 24 KWh / Kg
- the product is directed out to a die consisting of a 3mm cylindrical hole, from which is expelled the textured protein which is cut into sections of about 1 mm using knives.
- a density measurement of the extruded protein using test B indicates a value of 59 g / L.
- the extruded protein thus produced is then deposited on top of the main cylinder (with a diameter of 300mm) of a Tummers MachineBouw BV type 3500323 drum dryer.
- the cylinder is rotated at a speed of 16 revolutions / min, said rotation also causing the 4 peripheral cylinders (with a diameter of 75mm).
- the air gap or distance between main cylinder and peripheral cylinders is 1 mm.
- the protein is deposited at a temperature of around 40 ° C and will be compressed between the different cylinders, then will fall to the bottom of the drum-dryer in a container.
- Example 1 B Production of a dry textured legume protein composition according to the invention
- a powder mixture consisting of 100% faba Protein faba bean concentrais, containing 65% protein and 15% fiber, is produced.
- This mixture is introduced by gravity into a COPERION ZSK 54 MV extruder from the company COPERION.
- the mixture is introduced with a regulated flow rate of 350 kg / h.
- a quantity of 65 kg / h of water is also introduced.
- the extrusion screw composed of 85% of conveying elements, 5% of kneading elements and 10% of elements with inverted pitch, is rotated at a speed between 950 and 1100 revolutions / min and sends the mixture to a die.
- This particular pipe generates a machine torque of 50 ⁇ 2% with an outlet pressure of 82 ⁇ 2 bars.
- the specific energy of the system is around 24 kWh / kg.
- the product is directed at the outlet to a die consisting of a 5mm cylindrical hole, from which the textured protein is expelled which is cut into sections of approximately 3cm using knives.
- a density measurement of the extruded protein using test B indicates a value of 84 g / L.
- the extruded protein thus produced is then deposited on top of the main cylinder (with a diameter of 300mm) of a Tummers MachineBouw B.V. drum dryer type 3500323.
- the cylinder is rotated at a speed of 16 revolutions / min, said rotation also causing the 4 peripheral cylinders (with a diameter of 75mm).
- the air gap or distance between main cylinder and peripheral cylinders is 1 mm.
- the protein is deposited at a temperature of around 40 ° C. and will be compressed between the different cylinders, then will fall to the bottom of the drum-dryer in a container.
- Example 2 Production of a dry textured legume protein composition according to the prior art
- a powder mixture consisting of 87% by weight of is produced.
- NUTRALYS® F85M from the company ROQUETTE and 13% by weight of pea fiber I50M.
- This mixture is introduced by gravity into a LEISTRITZ ZSE 27 MAXX extruder from the company LEISTRITZ.
- the mixture is introduced with a regulated flow rate of 35 kg / h.
- the extrusion screw composed of 85% of conveying elements, 5% of kneading elements and 10% of elements with inverted pitch, is rotated at a speed of between 1100 and 1200 revolutions / min and sends the mixture to a die.
- This particular pipe generates a machine torque of 41% with an outlet pressure of 70 bars.
- the specific energy of the system is around 220 kw / kg.
- the product is directed at the outlet to a die consisting of two 3mm cylindrical holes, from which the textured protein is expelled which is cut into sections of about 1 mm using knives.
- a density measurement of the extruded protein indicates a value of 100 g / L.
- Example 3 Comparison of the dry textured legume protein compositions obtained in the above examples and of compositions from the prior art
- compositions according to the prior art require a shredding or cutting step.
- Example 4 Application of a dry textured legume protein composition according to the invention in meat analogs
- the production procedure is as follows:
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Nutrition Science (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Botany (AREA)
- Meat, Egg Or Seafood Products (AREA)
- Seeds, Soups, And Other Foods (AREA)
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Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1872778A FR3089757B1 (fr) | 2018-12-12 | 2018-12-12 | Composition comprenant des proteines de legumineuses texturees |
PCT/FR2019/053049 WO2020120915A1 (fr) | 2018-12-12 | 2019-12-12 | Composition comprenant des proteines de legumineuses texturees |
Publications (1)
Publication Number | Publication Date |
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EP3893660A1 true EP3893660A1 (fr) | 2021-10-20 |
Family
ID=66166240
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19839402.5A Pending EP3893660A1 (fr) | 2018-12-12 | 2019-12-12 | Composition comprenant des proteines de legumineuses texturees |
Country Status (9)
Country | Link |
---|---|
US (1) | US20220046950A1 (fr) |
EP (1) | EP3893660A1 (fr) |
JP (1) | JP7604372B2 (fr) |
CN (1) | CN113329636A (fr) |
AU (1) | AU2019395875A1 (fr) |
BR (1) | BR112021010873A2 (fr) |
CA (1) | CA3122113A1 (fr) |
FR (1) | FR3089757B1 (fr) |
WO (1) | WO2020120915A1 (fr) |
Families Citing this family (8)
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FR3116698A1 (fr) * | 2020-12-01 | 2022-06-03 | Roquette Freres | Proteines de legumineuses texturees |
US20240180196A1 (en) * | 2021-03-12 | 2024-06-06 | Corn Products Development, Inc. | Extrusion cooked legume protein composition, uses and methods of manufacture |
EP4346422A1 (fr) * | 2021-05-25 | 2024-04-10 | Roquette Freres | Compositions protéiques de légumineuses ayant des propriétés de gélification acide améliorées |
FR3124359A1 (fr) * | 2021-06-28 | 2022-12-30 | Roquette Freres | Proteines de legumineuses texturees ayant une fermete amelioree |
WO2023208729A1 (fr) * | 2022-04-26 | 2023-11-02 | Dsm Ip Assets B.V. | Protéine végétale texturée |
FR3135875A1 (fr) * | 2022-05-31 | 2023-12-01 | Roquette Freres | Proteines de legumineuses texturees |
FR3139439A1 (fr) * | 2022-09-09 | 2024-03-15 | Roquette Freres | Proteines vegetales texturees |
WO2024079202A1 (fr) * | 2022-10-11 | 2024-04-18 | Cosucra Groupe Warcoing S.A. | Protéine végétale texturée et son utilisation |
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-
2018
- 2018-12-12 FR FR1872778A patent/FR3089757B1/fr active Active
-
2019
- 2019-12-12 WO PCT/FR2019/053049 patent/WO2020120915A1/fr unknown
- 2019-12-12 CA CA3122113A patent/CA3122113A1/fr active Pending
- 2019-12-12 AU AU2019395875A patent/AU2019395875A1/en active Pending
- 2019-12-12 US US17/309,632 patent/US20220046950A1/en active Pending
- 2019-12-12 BR BR112021010873-4A patent/BR112021010873A2/pt unknown
- 2019-12-12 EP EP19839402.5A patent/EP3893660A1/fr active Pending
- 2019-12-12 JP JP2021531012A patent/JP7604372B2/ja active Active
- 2019-12-12 CN CN201980084793.0A patent/CN113329636A/zh active Pending
Also Published As
Publication number | Publication date |
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WO2020120915A1 (fr) | 2020-06-18 |
BR112021010873A2 (pt) | 2021-08-31 |
JP2022514457A (ja) | 2022-02-14 |
FR3089757A1 (fr) | 2020-06-19 |
CN113329636A (zh) | 2021-08-31 |
CA3122113A1 (fr) | 2020-06-18 |
JP7604372B2 (ja) | 2024-12-23 |
US20220046950A1 (en) | 2022-02-17 |
AU2019395875A1 (en) | 2021-06-24 |
FR3089757B1 (fr) | 2021-11-19 |
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