EP3426919A1 - Modular power generator - Google Patents
Modular power generatorInfo
- Publication number
- EP3426919A1 EP3426919A1 EP17764170.1A EP17764170A EP3426919A1 EP 3426919 A1 EP3426919 A1 EP 3426919A1 EP 17764170 A EP17764170 A EP 17764170A EP 3426919 A1 EP3426919 A1 EP 3426919A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- shape memory
- memory alloy
- alloy member
- amount
- pressurized fluid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000007246 mechanism Effects 0.000 claims abstract description 40
- 229910001000 nickel titanium Inorganic materials 0.000 claims abstract description 18
- 229910001285 shape-memory alloy Inorganic materials 0.000 claims description 113
- 239000012530 fluid Substances 0.000 claims description 59
- 230000007704 transition Effects 0.000 claims description 55
- 238000000034 method Methods 0.000 claims description 36
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- 229910001069 Ti alloy Inorganic materials 0.000 claims description 8
- 238000006073 displacement reaction Methods 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 5
- 229920000431 shape-memory polymer Polymers 0.000 claims description 5
- WCERXPKXJMFQNQ-UHFFFAOYSA-N [Ti].[Ni].[Cu] Chemical compound [Ti].[Ni].[Cu] WCERXPKXJMFQNQ-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 238000003306 harvesting Methods 0.000 abstract description 53
- HLXZNVUGXRDIFK-UHFFFAOYSA-N nickel titanium Chemical compound [Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni] HLXZNVUGXRDIFK-UHFFFAOYSA-N 0.000 abstract description 9
- 238000004146 energy storage Methods 0.000 abstract description 6
- 238000010248 power generation Methods 0.000 description 10
- 229910045601 alloy Inorganic materials 0.000 description 9
- 239000000956 alloy Substances 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 238000005381 potential energy Methods 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- KHYBPSFKEHXSLX-UHFFFAOYSA-N iminotitanium Chemical compound [Ti]=N KHYBPSFKEHXSLX-UHFFFAOYSA-N 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 230000003446 memory effect Effects 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
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- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 2
- 230000000712 assembly Effects 0.000 description 2
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- 239000002243 precursor Substances 0.000 description 2
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- 229910002058 ternary alloy Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 108010053481 Antifreeze Proteins Proteins 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000925 Cd alloy Inorganic materials 0.000 description 1
- 229910001257 Nb alloy Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- -1 aluminum-copper-zinc Chemical compound 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- WJCRZORJJRCRAW-UHFFFAOYSA-N cadmium gold Chemical compound [Cd].[Au] WJCRZORJJRCRAW-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
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- 238000001704 evaporation Methods 0.000 description 1
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- 230000006870 function Effects 0.000 description 1
- 230000010365 information processing Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002069 magnetite nanoparticle Substances 0.000 description 1
- 229910000734 martensite Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- RJSRQTFBFAJJIL-UHFFFAOYSA-N niobium titanium Chemical compound [Ti].[Nb] RJSRQTFBFAJJIL-UHFFFAOYSA-N 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
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- 229920000642 polymer Polymers 0.000 description 1
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- 238000004544 sputter deposition Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F03—MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
- F03G—SPRING, WEIGHT, INERTIA OR LIKE MOTORS; MECHANICAL-POWER PRODUCING DEVICES OR MECHANISMS, NOT OTHERWISE PROVIDED FOR OR USING ENERGY SOURCES NOT OTHERWISE PROVIDED FOR
- F03G7/00—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for
- F03G7/06—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for using expansion or contraction of bodies due to heating, cooling, moistening, drying or the like
- F03G7/061—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for using expansion or contraction of bodies due to heating, cooling, moistening, drying or the like characterised by the actuating element
- F03G7/0614—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for using expansion or contraction of bodies due to heating, cooling, moistening, drying or the like characterised by the actuating element using shape memory elements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F03—MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
- F03G—SPRING, WEIGHT, INERTIA OR LIKE MOTORS; MECHANICAL-POWER PRODUCING DEVICES OR MECHANISMS, NOT OTHERWISE PROVIDED FOR OR USING ENERGY SOURCES NOT OTHERWISE PROVIDED FOR
- F03G7/00—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for
- F03G7/06—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for using expansion or contraction of bodies due to heating, cooling, moistening, drying or the like
- F03G7/061—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for using expansion or contraction of bodies due to heating, cooling, moistening, drying or the like characterised by the actuating element
- F03G7/0614—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for using expansion or contraction of bodies due to heating, cooling, moistening, drying or the like characterised by the actuating element using shape memory elements
- F03G7/06143—Wires
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F03—MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
- F03G—SPRING, WEIGHT, INERTIA OR LIKE MOTORS; MECHANICAL-POWER PRODUCING DEVICES OR MECHANISMS, NOT OTHERWISE PROVIDED FOR OR USING ENERGY SOURCES NOT OTHERWISE PROVIDED FOR
- F03G7/00—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for
- F03G7/06—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for using expansion or contraction of bodies due to heating, cooling, moistening, drying or the like
- F03G7/064—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for using expansion or contraction of bodies due to heating, cooling, moistening, drying or the like characterised by its use
- F03G7/0641—Motors; Energy harvesting or waste energy recovery
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F03—MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
- F03G—SPRING, WEIGHT, INERTIA OR LIKE MOTORS; MECHANICAL-POWER PRODUCING DEVICES OR MECHANISMS, NOT OTHERWISE PROVIDED FOR OR USING ENERGY SOURCES NOT OTHERWISE PROVIDED FOR
- F03G7/00—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for
- F03G7/06—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for using expansion or contraction of bodies due to heating, cooling, moistening, drying or the like
- F03G7/064—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for using expansion or contraction of bodies due to heating, cooling, moistening, drying or the like characterised by its use
- F03G7/0646—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for using expansion or contraction of bodies due to heating, cooling, moistening, drying or the like characterised by its use for pumping or compressing fluids
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F03—MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
- F03G—SPRING, WEIGHT, INERTIA OR LIKE MOTORS; MECHANICAL-POWER PRODUCING DEVICES OR MECHANISMS, NOT OTHERWISE PROVIDED FOR OR USING ENERGY SOURCES NOT OTHERWISE PROVIDED FOR
- F03G7/00—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for
- F03G7/008—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for characterised by the actuating element
- F03G7/012—Electro-chemical actuators
- F03G7/0121—Electroactive polymers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F03—MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
- F03G—SPRING, WEIGHT, INERTIA OR LIKE MOTORS; MECHANICAL-POWER PRODUCING DEVICES OR MECHANISMS, NOT OTHERWISE PROVIDED FOR OR USING ENERGY SOURCES NOT OTHERWISE PROVIDED FOR
- F03G7/00—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for
- F03G7/025—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for characterised by its use
- F03G7/0252—Motors; Energy harvesting or waste energy recovery
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F03—MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
- F03G—SPRING, WEIGHT, INERTIA OR LIKE MOTORS; MECHANICAL-POWER PRODUCING DEVICES OR MECHANISMS, NOT OTHERWISE PROVIDED FOR OR USING ENERGY SOURCES NOT OTHERWISE PROVIDED FOR
- F03G7/00—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for
- F03G7/06—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for using expansion or contraction of bodies due to heating, cooling, moistening, drying or the like
- F03G7/061—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for using expansion or contraction of bodies due to heating, cooling, moistening, drying or the like characterised by the actuating element
- F03G7/0612—Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for using expansion or contraction of bodies due to heating, cooling, moistening, drying or the like characterised by the actuating element using polymers
Definitions
- nitinol is one of several alloys that are known as either shape memory alloys (SMA) or thermoelastic materials, and has been leverage in conventional heat engines. Yet, some of the conventional heat engines that leverage nitinol may require that power be consumed in order to generate energy. Some other ones of the conventional heat engines may require that the generated power to be used upon generation. Still some other ones of the conventional heat engines that leverage SMAs can convert low grade heat into mechanical energy utilizing multiple shape memory springs.
- SMA shape memory alloys
- FIG. 1 illustrates a perspective view of an example of a modular power generator in accordance with one or more embodiments of the disclosure.
- FIG. 2 illustrates a perspective view of an example of a module that can be utilized in a modular power generator in accordance with one or more embodiments of the disclosure.
- FIG. 3 illustrates a perspective view of another example of a module that can be utilized in a modular power generator in accordance with one or more embodiments of the disclosure.
- FIG. 4 illustrates a perspective view of another example module that can be utilized in a modular power generator in accordance with one or more embodiments of the disclosure.
- FIG. 5 illustrates of an example of a multi-module assembly that can be utilized in a modular power generator in accordance with one or more embodiments of the disclosure.
- FIG. 6 illustrates an example of a multi-module assembly that can be utilized in a modular power generator in accordance with at least one or more embodiments of the disclosure.
- FIG. 7 illustrates another example of a multi-module assembly that can be utilized in a modular power generator in accordance with one or more embodiments of the disclosure.
- FIGS. 8-9 illustrate perspective views other example modules that can be utilized in a modular power generator in accordance with one or more embodiments of the disclosure.
- FIG. 10 illustrates perspective views of yet another example module that can be utilized in a modular power generator in accordance with one or more embodiments of the disclosure.
- FIG. 11 illustrates an example of a modular power generator in accordance with one or more embodiments of the disclosure.
- FIG. 12 illustrates an example method for power generation in accordance with one or more embodiments of the disclosure.
- nitinol is one of several alloys that are known as either shape memory alloys (SMA) or thermoelastic materials.
- SMAs work because of the presence of multiple solid state phases or crystal structures that have dramatically different properties. Usually, one structure will have bonds that can rotate easily without being broken and the other will be very rigid. The existence of these two structures allow for a restoration of an apparently plastic deformation just by changing the temperature of the material. Stated in other words, a shape memory alloy or a thermoelastic material in a heat engine can convert low-grade thermal energy into high-grade mechanical energy.
- the disclosure provides modular power generators that utilize shaper memory alloy members or other thermoelastic material members that can produce a linear output for the generation of thermodynamic work.
- the modular power generators of this disclosure permit or otherwise facilitate the decoupling of power generation elements from energy transfer elements and energy storage elements.
- the modular power generators can include control mechanisms that permit or otherwise facilitate the utilization of generated power on demand.
- the disclosure provides apparatuses, systems, and/or techniques for power generation based on modular power generators that leverage shape memory alloys and/or other thermoelastic materials.
- the disclosure provides a module for the collection (or harvesting) of elastic energy from a shape memory alloy or a thermoelastic material in response to a transition from a first tensile state to a second tensile state of the material.
- the elastic energy can be converted to mechanical energy at a hydraulic cylinder or another type of mechanism that can retain potential energy (e.g., restorative potential energy, gravitational potential energy, or the like).
- the mechanical energy retained in a pressurized fluid can be accumulated or otherwise retained in a storage module, such as a pressure storage vessel (including for example, hydraulic accumulators, bladders, and the like). While aspects of modular power generators of this disclosure are illustrated with reference to shape memory alloys, the disclosure is not limited in this respect and a member (e.g., a rod, a wire, or another type of member elongated along a defined axis) formed from a thermoelastic material can be utilized or otherwise leveraged.
- a member e.g., a rod, a wire, or another type of member elongated along a defined axis
- thermoelastic materials that can be utilized include binary alloys that exhibit shape memory effect, such as gold-cadmium alloys, titanium-niobium alloys; ternary alloys that exhibit shape memory effect, such as aluminum-copper-zinc; polymers that exhibit shape memory effect (which are generally referred to as shape memory polymers (SMPs)), such as light-induced SMPs, electro-active SMPs (carbon nanotubes, magnetite nanoparticles, or the like), and the like.
- SMPs shape memory polymers
- harvesting module(s) and storage module(s), for example can be implemented in accordance with aspects described herein.
- Embodiments of the disclosure can provide numerous improvements over conventional power generators that utilize shape memory alloys or other thermoelastic materials.
- One example improvement is that modular power generators of the disclosure have greater mechanical efficiency because frictional losses and other losses are reduced by reducing the number of parts or other components present in the generators.
- Another example improvement includes the decoupling of the energy harvesting mechanism from the power generation mechanism.
- power can be generated steadily, e.g. at an even continuous rate, rather than in bursts associated with the shape memory effect that permits the conversion of thermal energy into elastic energy.
- power can be controllably utilized.
- Yet another improvement includes the scalability and straightforward customization of a modular power generator to a defined application.
- FIG. 1 presents a perspective view of an example of a modular power generator 100 in accordance with at least certain embodiments of the disclosure.
- the modular power generator 100 can include a harvesting module 1 10 that includes a shape memory alloy member 120 having a proximal end and an opposing distal end. As illustrated, the shape memory alloy member 120 can be elongated along a
- the shape memory alloy member 120 can be crystalline and the longitudinal axis oriented along a (1,0,0) crystalline direction or any other crystallographic direction of the shape memory alloy member 120. In some embodiments, the shape memory alloy member 120 can have cylindrical symmetric or other types of symmetry about the longitudinal axis.
- the shape memory alloy member 120 can be embodied in a rod having a diameter in the range from about 1.0 mm to about 8.0 mm, and wherein the rod has a length in the range from about 100.0 mm to about 500.0 mm (e.g., 100.0 mm, 175.0 mm, 200.0 mm, 300.0 mm, 400.0 mm, 500.0 mm).
- the disclosure is not limited to such example lengths, and the shape memory alloy member 120 can have shorter or longer lengths.
- the modular power generator 100 can leverage or can otherwise rely on a transition to a tensile state of the shape alloy member 120 for generation of power in accordance with aspects of this disclosure.
- the shape memory alloy member 120 can have constituents and respective concentrations that can yield at least one transition to a respective tensile state of the shape memory alloy member 120.
- a transition of the at least one transition (or, in some embodiments, each of the at least one transition) can correspond to a
- thermodynamic phase transition between a first specific atomic structure to a second defined atomic structure each of such atomic structures having a tensile state (which can include, in some instances, an essentially relaxed state, e.g., a zero-strain state).
- the transition can cause the shape memory alloy member to transition from a first tensile state to a second tensile state, resulting in a contraction of the shape memory alloy member 120.
- the contraction can correspond to a defined percentage of the length of the shape memory alloy member 120 along the longitudinal axis thereof.
- such a contraction corresponds to a reduction, by the defined percentage, of a lattice parameter along the crystalline direction (e.g., (1,0,0) or, in some other embodiments, a general direction (k,l,m), where k, /, m can be Miller indices) of the shape memory alloy member 120.
- a lattice parameter along the crystalline direction e.g., (1,0,0
- a general direction (k,l,m) where k, /, m can be Miller indices
- Constituents and respective concentrations of an alloy that forms or is otherwise included in the shape memory alloy member 120 can determine transition temperatures at which the shape memory alloy member 120 can transition between tensile states.
- the shape memory alloy member 120 can be configured to transition to a tensile state at a defined transition temperature.
- the shape memory alloy member 120 can be formed from or can include a nickel -titanium alloy. Adjusting the concentrations of Ni and Ti can yield, for example, a transition temperature in a range from about -100 degrees Celsius to about 160 degrees Celsius, with a thermal hysteresis ranging from eleven to more than one hundred degrees Celsius.
- such concentrations can be adjusted to yield transition temperatures that can range from about 5 degrees Celsius to about 30 degrees Celsius.
- a first Ni-Ti alloy may be utilized in the shape memory alloy member 120 to permit power generation during an Antarctic winter, with temperatures below about -50 degrees Celsius
- a second Ni-Ti alloy may be utilized to permit power generation in some deserts where temperatures as elevated as 80 degrees Celsius in direct sunlight.
- concentrations of Ni and Ti can leverage concentrations of Ni and Ti that yield a transition temperature in a range from about 5 degrees Celsius to about 30 degrees Celsius.
- the shape memory alloy member 120 can be formed from or can include a nickel-copper-titanium alloy. For instance, copper can substitute nickel and the
- concentration of copper can be at most about 20 at%.
- Such ternary alloys can provide greater flexibility in achieving a desired transition temperature, altering thermal properties of the material, and/or altering the mechanical properties of the material.
- a first end (which may be referred to a distal end) of the shape memory alloy member 120 can be mechanically coupled to the harvesting module 1 10.
- the harvesting module 1 10 includes a mechanism mechanically coupled (e.g., soldiered, bolted, or otherwise affixed) to a second end (which may be referred to a proximal end) of the shape memory alloy member 120.
- a second end can move along the longitudinal axis of the shape memory alloy member 120. More specifically, as illustrated in FIG.
- the harvesting module 1 10 includes a rigid support member, where a first ring terminal 1 15a is rigidly affixed to an end of the rigid support member and a second ring terminal 1 15b is rigidly affixed to the second end of the shape memory alloy member 120.
- the rigid support member in some instances, can be machined or otherwise manufacture from a plastic or metal.
- the first ring terminal 1 15a can include a titanium alloy and can be laser soldered to the first end of the shape memory alloy member 120 and to the rigid support member.
- the second ring terminal 115b can include a titanium alloy and can be laser soldered to the second end of the shape memory alloy member 120.
- FIG. 2 illustrates the harvesting module 110.
- FIG. 3 illustrates an example harvesting module 300 that can be assembled in the modular power generator 100 or other type of modular power generators in accordance with aspects of the disclosure.
- the example harvesting module 300 includes a rigid support member 310, which can be machined or otherwise manufactured from a plastic or metal.
- an end 315a (which may be referred to a distal end) of a shape memory alloy member 320 (e.g., a nitinol rod or another Ni-Ti alloy rod) can be rigidly affixed (e.g., laser soldered) to the rigid support member 310.
- a shape memory alloy member 320 e.g., a nitinol rod or another Ni-Ti alloy rod
- a second end 315b of the shape memory alloy member 320 can be rigidly affixed (e.g., laser soldered) or otherwise mechanically coupled to a mechanism included within a hydraulic cylinder 340.
- the second end 315 opposes the first end 315a and can move along a longitudinal axis of the shape memory alloy member 320.
- the mechanism can be included in a hydraulic cylinder 130 (which can be embodied in a single-acting hydraulic cylinder) and can include a piston (or, in some embodiments, a plate or a slab; not depicted) configured to move in response to the shape memory alloy member 120 transitioning to a tensile state at a defined transition temperature.
- the movement of the piston can reduce a volume of an amount of fluid within the hydraulic cylinder, resulting in a first amount of pressurized fluid within the hydraulic cylinder 130.
- the modular power generator 100 can include a vessel 170 (or another type of enclosure or reservoir) that can supply unpressurized fluid to the hydraulic cylinder 130.
- the modular power generator 100 can include a valve 140a coupled (e.g., mechanically and fluidically coupled) to the vessel 170.
- the valve 140a can be configured to release an amount (metered or otherwise) of unpressurized fluid to the hydraulic cylinder 130.
- the piston of the mechanism included in the hydraulic cylinder 130 can transfer the elastic energy associated with the deformation (e.g., contraction) of the shape memory alloy member 120 to the amount of pressurized fluid.
- the fluid within the hydraulic cylinder 130 can be utilized as a medium to transfer the thermodynamic work generated by the shape memory alloy member 120 to energy storage.
- the modular power generator 100 can include a pressure storage vessel 150 configured to receive at least a portion of the amount of pressurized fluid.
- the pressure storage vessel 150 can be embodied in, for example, a hydraulic accumulator and can contain pressurized fluid at a defined operating pressure (e.g., about 15,000 psi).
- the pressure storage vessel 150 can receive at least a portion of the amount of pressurized fluid via an inlet opening (not depicted) of such a vessel.
- the inlet opening can be mechanically coupled and/or fluidically coupled to a valve 140b via a conduit, such as a pipe, a hose, or other flexible or non-flexible tubing.
- the valve 140b also can be mechanically and/or fluidically coupled to an outlet opening (not depicted) of the hydraulic cylinder 130, the valve 140b configured to release the amount of pressurized fluid.
- the modular power generator 100 also can include a valve 160 that can release pressurized fluid to an electric power generator 180 (e.g., a DC generator coupled to a hydraulic motor).
- the pressurized fluid can be released controllably in response to, for example, a power consumption criterion being satisfied.
- a control unit e.g., a programmable logic controller or another type of computing device; not depicted
- the control unit can implement logic (e.g., execute computer-accessible instructions) to determine that the power consumption criterion is satisfied.
- the control unit can direct or otherwise cause the valve 160 to open for the release of pressurized fluid.
- a mechanism can passively control the opening (and shutting) of the valve for the release of the second amount of pressurized fluid.
- the pressure storage vessel 150, the valve 140b, and/or the valve 160 can embody or can constitute an energy storage module within the modular power generator 100.
- the energy storage module can supply a steady non-pulsed stream of usable power to the electric generator 180.
- the separation between energy collection, energy transfer, and energy storage, and associated modularity of the modular power generator 100 becomes readily apparent.
- such a separation permits generation of power without consumption of the generated power upon generation thereof.
- the elastic energy that can be collected from the cyclical structural transitions (e.g., martensitic transformations) in the shape memory alloy member 120 can be stored for consumption on- demand.
- FIG. 4 illustrates an example harvesting module 400 having five shape memory alloy members 420 mounted to or otherwise integrated into a rigid support member 410. Similar to other rigid support members in accordance with this disclosure, the rigid support member 410 can be machined or otherwise manufacture from plastic or metal.
- multiple harvesting modules can be assembled in a modular power generator. As illustrated in FIG. 5, three harvesting modules can be assembled in series, the harvesting modules having respective shape memory alloy members 520a-520c.
- each of the shape memory alloy members 520a-520c having a first end rigidly affixed to a rigid support member (e.g., rigid support member 510a, rigid support member 510b, or rigid support member 510c), and a second end rigidly affixed to a mechanism integrated into a hydraulic cylinder (e.g., hydraulic cylinder 530a, hydraulic cylinder 530b, or hydraulic cylinder 530c).
- a rigid support member e.g., rigid support member 510a, rigid support member 510b, or rigid support member 510c
- a mechanism integrated into a hydraulic cylinder e.g., hydraulic cylinder 530a, hydraulic cylinder 530b, or hydraulic cylinder 530c.
- such second ends can move along the longitudinal axis of their respective shape memory alloy members.
- FIGS. 6-7 illustrate two harvesting modules that can be utilized or otherwise leveraged in a modular power generator in accordance with embodiments of this disclosure. While the multi-module assemblies 600 and 700 include two harvesting modules, the disclosure is not so limited and, in some embodiments, multi-module assemblies having more than two harvesting modules also can be contemplated and included in modular power generators in accordance with this disclosure. As shown in FIG. 6, the two modules 610a and 610b can be arranged in series, which each module configured to receive unpressurized fluid via a conduit 640, and further configured to supply pressurized fluid to a conduit 650.
- the harvesting module 610a can include a shape memory alloy member 612a having a first end 616 (which also may be referred to as proximal end) and an opposing end 614 (which also may be referred to as distal end), the shape memory alloy member 612a configured to transition to a tensile state at a defined transition temperature in accordance with aspects described herein.
- the end 614 of the shape memory alloy member 612a can be rigidly affixed (e.g., soldered, laser soldered, bolted, punched, or the like) to a rigid support member 618a of the harvesting module 610a.
- the harvesting module 610a also includes a mechanism mechanically coupled to the end 616 of the shape memory alloy member 612a, the mechanism configured to move a piston (or, in some embodiments, a plate or slab) in a hydraulic cylinder 620 in response to the shape memory alloy member 612a transitioning to the tensile state. As described herein, movement of the piston can yield an amount of pressurized fluid within the hydraulic cylinder 620, wherein the amount of pressurized fluid can be released via the conduit 650.
- the example multi-module assembly 600 also includes a harvesting module 610b having a shape memory alloy member 612b having a first end 624 (which also may be referred to as a proximal end) and an opposing end 622 (which also may be referred to as distal end), the shape memory alloy member 612b configured to transition to a tensile state at a defined transition temperature in accordance with aspects described herein.
- the end 622 of the shape memory alloy member 612b can be rigidly affixed (e.g., soldered, laser soldered, bolted, punched, or the like) to a rigid support member 618b of the harvesting module 610b.
- the harvesting module 610b also includes a mechanism mechanically coupled to the end 624 of the shape memory alloy member 612b, the mechanism configured to move a piston (or, in some embodiments, a plate or slab) in a hydraulic cylinder 630 in response to the shape memory alloy member 612b transitioning to the tensile state. As described herein, movement of the piston can yield an amount of pressurized fluid within the hydraulic cylinder 630, wherein the amount of pressurized fluid can be released via the conduit 650.
- the transition temperature of the shape memory alloy member 612b in the harvesting module 610b can be different from or the same as the other transition temperature of the other shape memory alloy member 612a included in the harvesting module 610a.
- an example multi-module assembly can include the two harvesting modules 610a and 610b arranged in parallel.
- the harvesting module 610a can be configured to receive unpressurized fluid via a conduit 640.
- the harvesting module 610b can receive unpressurized fluid from a conduit that couples respective hydraulic cylinders of the harvesting modules 610a and 610b.
- the harvesting module 610a can supply pressurized fluid via a hydraulic cylinder 620 of the module 610a to a second hydraulic cylinder 630 of the harvesting module 610b.
- the second hydraulic cylinder 630 also can supply pressurized fluid to a pressure storage vessel (e.g., a hydraulic accumulator) via the conduit 650.
- a pressure storage vessel e.g., a hydraulic accumulator
- FIG. 8 illustrates an example harvesting module 800 that can store elastic energy without reliance on a hydraulic cylinder or a pressure storage vessel.
- the example harvesting module 800 includes a spring 850 to store at least a portion of the elastic energy that can be generated in response to a deformation of a shape memory alloy member 820.
- the example harvesting module 800 can include a ratchet mechanism 840 configured to transfer the elastic energy from the shape memory alloy member 820 to the spring 850.
- the shape memory alloy member 820, the ratchet mechanism 840, and the spring 850 can be assembled in a single rigid support member 810. While the spring 850 is shown for the sake of illustration, it is noted that the disclosure is not limited in that respect and other elastic members (e.g., flexible bars) can be contemplated.
- the ratchet mechanism 840 can permit energy transfer and/or storage.
- the shape memory alloy 920 can be fixed at one end to the rigid support member 810.
- the free end of the nitinol element can be attached to the ratchet mechanism 840 so that each time the shape memory alloy member 820 cycles, the ratchet mechanism 840 moves.
- the motion of the ratchet mechanism 840 can be either linear or rotary. As described herein, the ratchet mechanism 840 can be attached to the spring 850 to gradually compress the spring responsive to successive transformation cycles. In some embodiments, the ratchet mechanism 840 can be configured to elevate a mass in response to a transition from a first tensile state to a second tensile state of the shape memory alloy member 820. The potential energy stored in the spring 850 can be released in response to the a consumption criterion being satisfied, as described herein, providing work output through the use of clutches, brakes, or the like.
- a biasing mechanism (not depicted) can stretch or otherwise restore the shape memory alloy member 820 and can reset the ratchet mechanism 840 for another transition between tensile states that yield a contraction of the shape memory alloy member 820.
- FIG. 9 illustrates an example harvesting module 900 that can that can store elastic energy without reliance on a hydraulic cylinder or a pressure storage vessel and can be utilized in a modular power generator in accordance with one or more embodiments of the disclosure.
- example harvesting module 900 can include a shape memory alloy member 920 having an end that is rigidly attached to a rack gear 930.
- the rack gear 930 is mechanically coupled to a pinion gear 940 configured to transfer at least a portion of the elastic energy generated in a deformation of the shape memory alloy member 920 to an elevated mass 950.
- the deformation (e.g., a contraction) can be responsive to a transition from a first tensile state to a second tensile state of the shape memory alloy member 920.
- the pinion gear 940 can transfer the linear movement of the shape memory alloy 920 to rotary movement that can change the position of the elevated mass 950, accumulating the at least a portion of the elastic energy in gravitational potential energy of the elevated mass 950.
- work transmitted by rotary motion can be stored via a flywheel, spring, or the like.
- a rigid support member 910 can hold the shape memory alloy 920, the rack gear 930, and the pinion gear 940. When needed, work can be extracted from these storage mechanisms through the use of brakes, clutches, etc.
- a modular power generator that utilizes or otherwise relies on the example harvesting module 800 and the example harvesting module 900, a pneumatic bladder or cylinder built inside of the rigid support member 910.
- the end of the bladder can be attached to the end of the shape memory alloy member 920 that opposes the end mechanically coupled to the ratchet 840 or the rack gear 930, thus providing a extension force to reset a shape memory cycle.
- a shape memory alloy member e.g., a nitinol rod or a nitinol wire
- a surface of a harvesting module can be coated at least in part with an absorptive material.
- the absorptive material can absorb light in a defined portion of the electromagnetic radiation spectrum, and can be deposited in a number of ways having different complexity.
- the surface can be coated via evaporation or sputtering with the absorptive material or precursors thereof.
- the surface can oppose a second surface of the shape memory alloy member and, in response to illumination of the coated surface, the atmosphere in the vicinity of the shape memory alloy member can attain or exceed a transition temperature for such a member.
- Sunlight and/or a specific light source can illuminate of the coated surface.
- the light source can be integrated into or otherwise assembled in the harvesting module. For instance, the light source can be attached to the harvesting module in a manner that illuminates the coated surface. Accordingly, regardless of the type of illumination, in some aspects, the shape memory alloy member can be caused to transition from a first tensile state to a second tensile state, resulting in a contraction of the shape memory alloy member in accordance with aspects described herein.
- FIG. 10 illustrates views of an example harvesting module 1000 that can be utilized in a modular power generator in accordance with one or more embodiments of the disclosure.
- the example harvesting module 1000 can include a movable enclosure 1010 having a surface 1020 coated at least in part with an absorptive material, such as carbon black or any other of the absorptive materials described herein.
- the movable enclosure 1010 defines an opening at an end of the movable enclosure 1010.
- the movable enclosure 1010 can heat a gas surrounding a shape memory alloy member (not depicted) included in the example harvesting module 1000.
- a temperature of the gas can attain or exceed a transition temperature for transformation of the shape memory alloy member, such a member can transition to a tensile state and, thus, can contract, moving a piston included in a hydraulic cylinder 1030 and transferring at least a portion of the elastic energy associated with the contraction, in accordance with aspects described herein.
- the movable enclosure 1010 is configured to move along a direction in which the rigid support member extends from the proximal end to the opposing distal end. The movement of the movable enclosure is responsive to the transition to the tensile state, and thus, the movable enclosure 1010 can open a releasing the heated gas, cooling the
- the movable enclosure can be mechanically coupled, e.g., attached via a rigid or semi-rigid member, to a movable end of the hydraulic cylinder 1030. Therefore, the movable enclosure 1010 can move in response to movement of the shape memory alloy member (not depicted) associated with a deformation (e.g., a contraction) responsive to a deformation transition associated with a transition to the tensile state.
- a deformation e.g., a contraction
- FIG. 11 illustrates an example of modular power generator 1 100 in accordance with one or more embodiments of the disclosure.
- the modular power generator 1 100 includes four plastic harvesting modules 1 120a, 1 120b, 1 120c, and 1 120d, each having a nitinol wire and a hydraulic cylinder at an end of the harvesting module.
- Each of the nitinol wires can have at least one defined transition temperature associated with a respective transition between tensile states of the nitinol wire.
- four hydraulic cylinders 1 130a, 1 130b, 1 130c, and 1 130d are included in the modular power generator 1 100.
- tubing 1 150 protrudes from each of the hydraulic cylinders 1 130a, 1 130b, 1 130c, and 1 130d, forming tubing 1 150.
- the tubing 1 150 can be mechanically coupled and/or fluidically coupled to the conduit 1 160a, which can include a valve in accordance with aspects described herein.
- the modular power generator 1 100 includes a vessel 1 1 10 configured to supply unpressurized fluid (e.g., oil, which can be biodegradable or otherwise) to each of the hydraulic cylinders 1 130a, 1 130b, 1 130c, and 1 130d.
- unpressurized fluid e.g., oil, which can be biodegradable or otherwise
- the vessel 1 1 10 can be mechanically coupled and/or fluidically to a conduit 1 180 via another conduit 1 170, where the conduit 1 180 is configured to release or otherwise transport an amount of unpressurized fluid to at least one of the hydraulic cylinders 1 130a, 1 130b, 1 130c, and 1 130d.
- the modular power generator 1 100 includes a hydraulic accumulator 1 140 configured to receive pressurized fluid from at least one of the hydraulic cylinders 1 130a, 1 130b, 1 130c, and 1 130d.
- the hydraulic accumulator 1 140 also is configured to supply an amount of pressurized fluid via the conduit 1 160b, which can include a valve, in accordance with aspects described herein.
- the modular power generator 1 100 also includes includes stability shafts, each of which can be bolted to a plastic stability frame coupled to a region proximate to an end of the hydraulic accumulator 1 140.
- stability shafts each of which can be bolted to a plastic stability frame coupled to a region proximate to an end of the hydraulic accumulator 1 140.
- the disclosed techniques are not limited by the order of blocks and associated actions or operations, as some blocks may occur in different orders and/or concurrently with other blocks from that are shown and described herein.
- the various techniques of the disclosure can be alternatively represented as a series of interrelated states or events, such as in a state diagram.
- not all illustrated blocks, and associated action(s) or operation(s) may be required to implement a technique in accordance with one or more aspects of the disclosure.
- two or more of the disclosed techniques can be implemented in combination with each other, to accomplish one or more features and/or advantages described herein.
- At least a portion of the techniques of the disclosure can be retained on an article of manufacture, or computer- readable storage medium in order to permit or facilitate transporting and transferring such techniques to a computing device (such as a microcontroller, a programmable logic controller, a programmable logic relay, and the like) for execution, and thus implementation, by a processor of the computing device or for storage in a memory thereof or functionally coupled thereto.
- a computing device such as a microcontroller, a programmable logic controller, a programmable logic relay, and the like
- one or more processors such as processor(s) that implement (e.g., execute) one or more of the disclosed techniques, can be employed to execute instructions retained in a memory, or any computer-readable or machine-readable storage medium, to implement the techniques described herein.
- the instructions can embody or can constitute at least a portion of the techniques, and thus can provide a computer-executable or machine- executable framework to implement the techniques described herein.
- FIG. 12 presents a flowchart of an example of a method 1200 for power generation according with at least some embodiments of the disclosure.
- a portion of the example method 1200 can be implemented by a modular power generator in accordance with this disclosure (e.g., modular power generator 100 and/or power modular generator 1 100).
- a thermoelastic material member can be arranged in a configuration corresponding to a first tensile state of the termoelastic material.
- the thermoelastic material member can be embodied in or can include a rod, a wire, or any other type of member that can be oriented in a defined crystallographic orientation that can favor the presence of uniaxial strain in the member.
- thermoelastic material can be embodied in or can include a shape memory alloy, such as a nickel-titanium alloy, a nickel-copper-titanium alloy (where at least an amount of nickel in a precursor nickel -titanium alloy have been replaced with copper), and the like.
- a shape memory alloy such as a nickel-titanium alloy, a nickel-copper-titanium alloy (where at least an amount of nickel in a precursor nickel -titanium alloy have been replaced with copper), and the like.
- the thermoelastic material member is caused to transition to a second tensile state, resulting in a contraction of thermoelastic material member.
- causing the transition to the second tensile state include increasing the temperature heating the thermoelastic material member to a temperature equal to or greater than a defined transition temperature.
- a linear displacement of a piston in a hydraulic cylinder can be caused, for example, in response to the contraction of the thermoelastic material member (e.g., a rod formed from or otherwise including nitinol).
- the thermoelastic material member e.g., a rod formed from or otherwise including nitinol
- an end of the thermoeleastic material member can be mechanically coupled to the piston.
- the mechanical coupling can be accomplished via a nearly rigid member that displaces the piston along an longitudinal axis of the thermoelastic material member in response to the contraction.
- an amount of fluid in the hydraulic cylinder can be pressurized in response to the linear displacement.
- the fluid can include a gas, a liquid, or a combination thereof.
- the amount of fluid can be pressurized in response to reducing a volume occupied by the fluid within the piston.
- at least a portion of the amount of pressurized fluid can be supplied to a pressure storage vessel (e.g., a hydraulic accumulator).
- the hydraulic cylinder can include an outlet opening fluidically coupled to the hydraulic accumulator, which can be configured to receive pressurized fluid. Rigid or flexible tubing and/or other types of conduits can provide such a coupling.
- the pressure storage vessel can receive the amount of pressurized fluid via an inlet opening of such a vessel.
- a second amount of pressurized fluid can be released from the pressure storage vessel.
- a valve can be coupled (e.g., mechanically coupled and/or fluidically coupled) to the pressure storage vessel and configured to be open in response to a release criterion (e.g., a power consumption criterion or rule) being satisfied.
- the second amount of pressurized fluid can be released via, for example, an outlet opening of the pressure storage vessel.
- a control unit e.g., a programmable logic controller or another type of computing device
- a control unit can implement logic to determine that the release criterion is satisfied and, in response, can open the valve for the release of the second amount of pressurized fluid.
- a mechanism can passively control the opening (and shutting) of the valve for the release of the second amount of pressurized fluid.
- Such an entity may be either hardware, software, software in execution, or a combination thereof.
- a component can be an apparatus that provides specific functionality by means of mechanical parts, without reliance on electronic or
- a component may be an apparatus with specific functionality provided by mechanical parts operated by electric or electronic circuitry that is controlled by a software application or firmware application executed by a processor, wherein the processor can be internal or external to the apparatus and can execute at least a part of the software or firmware application.
- the terms "component,” “environment,” “system,” “platform,” “architecture,” “interface,” “unit,” “module” can be utilized interchangeably and can be referred to collectively as functional elements.
- Conditional language such as, among others, "can,” “could,” “might,” or “may,” unless specifically stated otherwise, or otherwise understood within the context as used, is generally intended to convey that certain implementations could include, while other implementations do not include, certain features, elements, and/or operations. Thus, such conditional language generally is not intended to imply that features, elements, and/or operations are in any way required for one or more implementations or that one or more implementations necessarily include logic for deciding, with or without user input or prompting, whether these features, elements, and/or operations are included or are to be performed in any particular implementation.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
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- General Engineering & Computer Science (AREA)
- Connection Of Motors, Electrical Generators, Mechanical Devices, And The Like (AREA)
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Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US15/067,051 US10352307B2 (en) | 2014-09-04 | 2016-03-10 | Modular power generator |
PCT/US2017/021745 WO2017156371A1 (en) | 2016-03-10 | 2017-03-10 | Modular power generator |
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EP3426919A1 true EP3426919A1 (en) | 2019-01-16 |
EP3426919A4 EP3426919A4 (en) | 2020-04-15 |
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EP17764170.1A Withdrawn EP3426919A4 (en) | 2016-03-10 | 2017-03-10 | Modular power generator |
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JP (1) | JP2019513202A (en) |
CN (1) | CN109312725A (en) |
CA (1) | CA3017145C (en) |
WO (1) | WO2017156371A1 (en) |
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DE202023100127U1 (en) | 2023-01-11 | 2023-02-03 | Rüdiger Schloo | Electricity and heat generation using so-called shape memory alloys by using the ambient temperature |
WO2024195148A1 (en) * | 2023-03-22 | 2024-09-26 | ソニーグループ株式会社 | Linear actuator |
Family Cites Families (15)
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JPS56156978U (en) * | 1980-04-23 | 1981-11-24 | ||
JPS62121877A (en) * | 1985-11-22 | 1987-06-03 | Matsushita Electric Works Ltd | Thermal drive pump |
JPH02149773A (en) * | 1988-10-17 | 1990-06-08 | Zutsuun Rin | Internal energy-engine |
US4922718A (en) * | 1989-10-10 | 1990-05-08 | Armada Corporation | Thermal energy scavenger |
US4945727A (en) * | 1989-12-11 | 1990-08-07 | Whitehead Charles A | Hydraulic shape memory alloy actuator |
KR100199844B1 (en) * | 1994-10-31 | 1999-06-15 | 배길훈 | Hydraulic Pump Using Shape Memory Alloy |
JP3137594B2 (en) * | 1997-03-31 | 2001-02-26 | ババカル ンゴム | Power generation mechanism |
EP2290238A1 (en) * | 2002-10-09 | 2011-03-02 | Abbott Diabetes Care Inc. | Plunger pump actuated by a shape memory element |
WO2010062049A2 (en) * | 2008-11-03 | 2010-06-03 | Lee Jae In | Power generating apparatus using shape memory alloy |
US9145903B2 (en) * | 2010-07-22 | 2015-09-29 | Cameron International Corporation | Shape memory alloy powered hydraulic accumulator having actuation plates |
US8938965B1 (en) * | 2011-05-27 | 2015-01-27 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Thermal powered reciprocating-force motor |
US9909573B2 (en) * | 2013-01-15 | 2018-03-06 | The University Of Akron | Thermal energy harvesting system |
GB201310512D0 (en) * | 2013-06-13 | 2013-07-24 | Exergyn Ltd | Pressure Relief System and Method in an Energy Recovery Device |
DE102014006505A1 (en) * | 2014-05-03 | 2015-11-05 | Stefan Hagge | Apperatur for generating mechanical or electrical energy by the use of a low in relation to the prior art temperature difference |
GB201409679D0 (en) * | 2014-05-30 | 2014-07-16 | Exergyn Ltd | Slotted bundle holder for use in an energy recovery device |
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- 2017-03-10 JP JP2018567020A patent/JP2019513202A/en not_active Ceased
- 2017-03-10 EP EP17764170.1A patent/EP3426919A4/en not_active Withdrawn
- 2017-03-10 WO PCT/US2017/021745 patent/WO2017156371A1/en active Application Filing
- 2017-03-10 CN CN201780027466.2A patent/CN109312725A/en active Pending
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CN109312725A (en) | 2019-02-05 |
JP2019513202A (en) | 2019-05-23 |
CA3017145C (en) | 2020-01-28 |
CA3017145A1 (en) | 2017-09-14 |
WO2017156371A1 (en) | 2017-09-14 |
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