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EP2882835B1 - Compositions liquides contenant des agents tensio-actifs dépourvues d'alcanolamines - Google Patents

Compositions liquides contenant des agents tensio-actifs dépourvues d'alcanolamines Download PDF

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Publication number
EP2882835B1
EP2882835B1 EP13747798.0A EP13747798A EP2882835B1 EP 2882835 B1 EP2882835 B1 EP 2882835B1 EP 13747798 A EP13747798 A EP 13747798A EP 2882835 B1 EP2882835 B1 EP 2882835B1
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EP
European Patent Office
Prior art keywords
liquid composition
acid
group
bleach
component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
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EP13747798.0A
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German (de)
English (en)
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EP2882835A1 (fr
Inventor
Johannes Himmrich
Hans Jürgen SCHOLZ
Wolfgang Walther
Joachim Erbes
Stefan RIEGELBECK
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Weylchem Switzerland AG
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Weylchem Switzerland AG
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3907—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • the invention relates to liquid compositions containing a high total concentration of anionic and nonionic surfactants but free from alkanolamines and their salts.
  • the liquid compositions can be used to wash and clean textiles and, in combination with bleaching systems, provide beneficial bleaching performance.
  • Liquid detergents are enjoying a rapidly increasing popularity in the market, because they can be dosed easily and without dust development, quickly release the washing-active ingredients during washing and also leave no residues on the laundry.
  • a trend towards increasingly concentrated liquid detergents has become established in order to be able to produce small, easy-to-handle packaging units and to reduce transport costs.
  • a major disadvantage of liquid detergents is their low compatibility with bleach systems and, as a result, their poor wash performance on bleachable soils.
  • liquid compositions are understood to mean all liquid or flowable administration forms.
  • Liquid or flowable in the context of the present invention are compositions which are pourable.
  • the viscosity can be measured by standard methods (for example Brookfield LVT-II at 20 revolutions / minute and 20 ° C.), the spindle 2 being used for the viscosity range 5 to ⁇ 1000 mPas, the spindle 3 for 1000 to ⁇ 5000 mPas, spindle 4 is used for 5000 to ⁇ 10 000 mPas and spindle 7 for 10 000 to 60 000 mPas.
  • the liquid compositions used according to the invention have viscosities of from 100 to 20,000 mPas, more preferably from 300 to 10,000 mPas, and especially preferably from 400 to 5,000 mPas.
  • the compositions used according to the invention may be gel-like or paste-like, they may be present as homogeneous solutions or as suspensions, they may be sprayable, be presented in so-called pouches or be made up in otherwise customary dosage forms.
  • compositions used in the invention contain one or more anionic surfactants selected from the group consisting of the surfactant classes of sulfonates, sulfates, carboxylates and phosphates and more preferably contain one or more anionic surfactants selected from the group consisting of the surfactant classes of sulfonates, sulfates and carboxylates ,
  • the counterions of the anionic surfactants are the cations of sodium, potassium, calcium and magnesium.
  • the compositions used according to the invention are free from alkanolamines and their salts. This means, for example, that this Substances also do not come as counterions of anionic surfactants into consideration.
  • Preferred sulfonates are secondary paraffin sulfonates.
  • the paraffin hydrocarbon chains are predominantly linear and only a minor proportion of 5% by weight or less branched paraffin chains having 8 to 22 carbon atoms.
  • secondary paraffin sulfonates having 13 to 17 carbon atoms in the paraffin group.
  • the preferred primary sulfonates contain linear alkyl or alkenyl chains of 9 to 25 carbon atoms, preferably 10 to 20 carbon atoms, and more preferably 13 to 17 carbon atoms.
  • olefin sulfonates which are obtained by sulfonation of C 12 -C 24 -, preferably C 14 -C 16 - ⁇ -olefins with sulfur trioxide and subsequent neutralization. Due to the preparation process, these olefin sulfonates may contain minor amounts of hydroxyalkanesulfonates and alkanedisulfonates.
  • alkenyl or alkylbenzenesulfonates are also preferred.
  • the alkenyl or alkyl group may be branched or linear and optionally substituted with a hydroxyl group.
  • the preferred alkyl benzene sulfonates contain linear alkyl chains of 9 to 25 carbon atoms, and preferably 10 to 13 carbon atoms.
  • M is a cation that forms a water-soluble salt with the ester sulfonate.
  • Particularly preferred are methyl ester sulfonates in which R 1 is C 10 -C 16 -alkyl and R is methyl.
  • Preferred sulfates are water-soluble salts of the formula ROSO 3 M, wherein R is a C 10 -C 24 -Kohtenwasserstoffrest, preferably an alkyl or hydroxyalkyl radical C 10 -C 20 -alkyl component, more preferably a C 12 -C 18 alkyl or hydroxyalkyl radical.
  • M is sodium, potassium, calcium, magnesium or a mixture thereof.
  • Preferred ether sulfates are water-soluble salts of the linear formula RO (A) m SO 3 M, wherein R is an unsubstituted C 10 -C 24 -hydrocarbon radical, preferably C 10 -C 24 -alkyl radical, or a hydroxyl-substituted C 10 -C 24- hydrocarbon radical, preferably a C 10 -C 24 -hydroxyalkyl radical, particularly preferably a C 12 -C 20 -alkyl or hydroxyalkyl radical, particularly preferably a C 12 -C 18 -alkyl or hydroxyalkyl radical.
  • R is an unsubstituted C 10 -C 24 -hydrocarbon radical, preferably C 10 -C 24 -alkyl radical, or a hydroxyl-substituted C 10 -C 24- hydrocarbon radical, preferably a C 10 -C 24 -hydroxyalkyl radical, particularly preferably a C 12 -C 20 -alkyl or hydroxy
  • A is an ethoxy (EO) or propoxy (PO) unit
  • m is a number greater than 0, preferably between 0.5 and 6, more preferably between 0.5 and 3
  • M is a cation such as.
  • C 12 to C 18 fatty alcohol ether sulfates wherein the content of EO is 1, 2, 2.5, 3 or 4 moles per 1 mole of the fatty alcohol ether sulfate, and in which M is sodium or potassium.
  • anionic surfactants are carboxylates, in particular. Fatty acid soaps.
  • the soaps may be saturated or unsaturated and may contain various substituents such as hydroxyl groups or ⁇ -sulfonate groups.
  • Preferred are linear saturated or unsaturated hydrocarbon radicals as hydrophobic moiety having 6 to 30 and preferably 10 to 18 carbon atoms.
  • the secondary paraffin sulfonates are particularly preferred.
  • compositions used according to the invention comprise one or more nonionic surfactants selected from the group consisting of the surfactant classes of the alkoxylated fatty alcohols, fatty acid amides, alkoxylated fatty acid amides, and alkyl polyglycosides.
  • the alkyl or alkenyl chain of the alkoxylated fatty alcohols may be linear or branched, primary or secondary, and generally contains from 8 to 22 carbon atoms. Particularly preferred are the condensation products of C 10 to C 20 alcohols with 2 to 18 moles of ethylene oxide per 1 mole of alcohol.
  • the alcohol ethoxylates may have a narrow range (“narrow range ethoxylates") or a broad homolog distribution of the ethylene oxide ("Broad Range Ethoxylates").
  • nonionic surfactants of this type are Tergitol® 15-S-9 (condensation product of a linear secondary C 11 -C 15 -alcohol with 9 moles of ethylene oxide), Tergitol® 24-L-NMW (condensation product of a linear primary C 12 -C 14- alcohol with 6 moles of ethylene oxide with a narrow molecular weight distribution). Also included in this product class are the Genapol® brands of Clariant.
  • fatty acid amides according to the formula (2) wherein R is an alkyl group having 7 to 21, preferably 9 to 17 carbon atoms and each radical R 1 is hydrogen, C 1 -C 4 alkyl, C 1 -C 4 hydroxyalkyl or (C 2 H 4 O), H, wherein x varies from 1 to 3.
  • R is an alkyl group having 7 to 21, preferably 9 to 17 carbon atoms and each radical R 1 is hydrogen, C 1 -C 4 alkyl, C 1 -C 4 hydroxyalkyl or (C 2 H 4 O), H, wherein x varies from 1 to 3.
  • C 8 -C 20 -amides, -monoethanolamides, -diethanolamides and -isopropanolamides are preferred.
  • alkyl polyglycosides of the formula RO (G) x , where R is a primary straight-chain or methyl-branched, especially in the 2-position methyl-branched, aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is a glycose unit having 5 or 6 carbon atoms , preferably glucose.
  • the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is preferably a number between 1 and 10, more preferably x is between 1.2 and 1.4.
  • the alkoxylated fatty alcohols are particularly preferred.
  • surfactants from the group of the polyethylene, polypropylene and polybutylene oxide condensates of alkylphenols can be used. These compounds include the condensation products of alkylphenols having a C 6 to C 20 alkyl group, which may be either linear or branched, with alkene oxides. These surfactants are used as alkylphenol alkoxylates, e.g. B. Alkylphenolethoxylate called.
  • water-soluble amine oxides of the formula (3) can be used: R here is an alkyl, hydroxyalkyl or alkylphenol group having a chain length of 8 to 22 carbon atoms, R 2 is an alkylene or hydroxyalkylene group having 2 to 3 carbon atoms or mixtures thereof, each R 1 is an alkyl or hydroxyalkyl group having 1 to 3 carbon atoms or a polyethylene oxide group having 1 to 3 ethylene oxide units and x represents a number from 0 to 10.
  • R 1 CO is an aliphatic acyl radical having 6 to 22 carbon atoms
  • R 2 is hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms
  • Z is a linear or branched polyhydroxyalkyl radical having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups.
  • compositions used according to the invention comprise the surfactants of components a) and b) in a total concentration of> 50% by weight and more preferably of from 50 to 80% by weight, based in each case on the total weight of the compositions according to the invention.
  • anionic surfactants of component a) and the nonionic surfactants of component b) in the compositions used according to the invention in a weight ratio of component a) to component b) of 3: 1 to 1: 3, and more preferably 2: 1 to 1: 2 in front.
  • amphoteric and cationic surfactants are amphoteric and cationic surfactants, bleaches, bleach activators, bleach catalysts, builders, co-builders, wash alkalis, enzymes, sequestering agents, soil release polymers, grayness inhibitors, dye transfer inhibitors, dye fixing agents, complexing agents, optical agents Whitening, softening components, dyes, fragrances, emulsifiers, hydrotropes, organic solvents, and water in the compositions used.
  • Suitable amphoteric or zwitterionic surfactants are alkylbetaines, alkylamidbetaines, aminopropionates, aminoglycinates or amphoteric imidazolinium compounds according to the formula (5) wherein R 1 is C 8 -C 22 alkyl or alkenyl, R 2 is hydrogen or CH 2 CO 2 M, R 3 is CH 2 CH 2 OH or CH 2 CH 2 OCH 2 CH 2 CO 2 M, R 4 is hydrogen, CH 2 CH 2 OH or CH 2 CH 2 COOM, Z CO 2 M or CH 2 CO 2 M, n is 2 or 3, preferably 2, M is hydrogen or a cation such as alkali metal, alkaline earth metal.
  • Preferred amphoteric surfactants of this formula are monocarboxylates and dicarboxylates. Examples of these are cocoamphocarboxypropionate, cocoamidocarboxypropionic acid, cocoamphocarboxyglycinate (also referred to as cocoamphodiacetate) and cocoamphoacetate.
  • amphoteric surfactants are alkyl dimethyl betaines and alkyl dipolyethoxy betaines having an alkyl group of 8 to 22 carbon atoms, which may be linear or branched, preferably having 8 to 18 carbon atoms and more preferably having 12 to 18 carbon atoms. These compounds are z. B. marketed by Clariant under the trade name Genagen® LAB.
  • compositions according to the invention contain one or more amphoteric surfactants, these are preferably present in an amount of 0.1-10% by weight and more preferably in an amount of 0.5-5% by weight, based in each case on the Total weight of the compositions according to the invention.
  • Suitable cationic surfactants are substituted or unsubstituted straight-chain or branched quaternary ammonium salts of the type R 1 N (CH 3 ) 3 ⁇ X ⁇ , R 1 R 2 N (CH 3 ) 2 ⁇ X ⁇ , R 1 R 2 R 3 N (CH 3 ) ⁇ X ⁇ or R 1 R 2 R 3 R 4 N ⁇ X ⁇ .
  • the radicals R 1 , R 2 , R 3 and R 4 may preferably be, independently of one another, unsubstituted alkyl having a chain length of 8 to 24 C atoms, in particular of 10 to 18 C atoms, hydroxyalkyl having 1 to 4 C atoms, phenyl, C 2 to C 18 alkenyl, C 7 to C 24 aralkyl, (C 2 H 4 O) x H, where x is from 1 to 3, one or more ester group-containing alkyl groups or cyclic quaternary ammonium salts.
  • X is a suitable anion.
  • Suitable cationic surfactants are quaternary alkylhydroxyalkylammonium salts according to the formula (6) wherein R 1 is a linear or branched, saturated or unsaturated alkyl group having 5 to 22 carbon atoms, preferably 8 to 18 carbon atoms, more preferably 8 to 14 carbon atoms, R 2 is a methyl group, R 3 is a methyl group or R 4 is a Group of the formula -A- (OA) n -OH, where A can be a -C 2 H 4 and / or -C 3 H 6 group and n can be a number from 0 to 20.
  • R 1 is a linear or branched, saturated or unsaturated alkyl group having 5 to 22 carbon atoms, preferably 8 to 18 carbon atoms, more preferably 8 to 14 carbon atoms
  • R 2 is a methyl group
  • R 3 is a methyl group
  • R 4 is a Group of the formula -A- (OA) n -OH
  • X can be any anion, for example, chloride, bromide, iodide, fluoride, sulfate, hydrogensulfate, carbonate, bicarbonate, acetate, citrate, phosphate, mono- and di-hydrogenphosphate, pyrophosphate, polyphosphate, metaphosphate, nitrate, methylsulfate, phosphonate, methylphosphonate , Methanedisulfonate, methylsulfonate, ethanesulfonate or an anion of the formulas R 6 SO 3 ⁇ , R 7 SO 4 ⁇ or R 6 COO ⁇ , where R 6 and R 7 are C 2 -C 20 -, preferably C 10 -C 18 - Alkyl, and R 7 additionally also C 1 -C 18 alkylphenyl mean.
  • compositions used according to the invention contain one or more cationic surfactants, these are preferably present in an amount of 0.1-15% by weight and more preferably in an amount of 0.5-7% by weight, in each case based on the total weight of the compositions.
  • compositions used in the invention contain one or more cationic surfactants
  • the weight ratio of the one or more cationic surfactants to the one or more anionic surfactants is preferably from 1 to 10 to 1 to 5.
  • Suitable bleaching agents are hydrogen peroxide and inorganic persalts, preferably percarbonates, perborates, persulfates and persilicates, in particular in the form of alkali metal salts.
  • Particularly preferred bleaching agents are hydrogen peroxide, sodium perborate (monohydrate and tetrahydrate) and / or Sodium percarbonate, particularly preferably sodium perborate (monohydrate and tetrahydrate) and / or sodium percarbonate.
  • compositions used according to the invention contain one or more of the bleaching agents just mentioned, they must not contain a bleach activator. In this case, they also preferably do not contain a bleach catalyst.
  • compositions used according to the invention comprise one or more bleaching agents, these are preferably present in an amount of from 1 to 25% by weight, more preferably from 5 to 20% by weight and especially preferably from 8 to 16% by weight, in each case on the total weight of the composition.
  • compositions used must not contain peracids or their salts.
  • compositions used in the invention contain no bleach, i. they are free of bleach.
  • compositions may contain one or more bleach activators.
  • compositions according to the invention may contain one or more substances selected from the following group: polyacylated alkylenediamines, in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxohexahydro-1,3,5-triazine (DADHT), acylated glycolurils, in particular tetraacetylglycoluril (TAGU), N-acylimides, in particular N-nonanoylsuccinimide (NOSI), acylated phenolsulphonates, in particular n-nonanoyloxy or n-lauroyloxybenzenesulphonate (NOBS or LOBS), acylated phenolcarboxylic acids, in particular nonanoyloxy or decanoyloxybenzoic acid (NOBA or DOBA), carboxylic acid anhydrides, in particular phthalic
  • Hydrophilic substituted acyl acetals and acyl lactams are also preferably used.
  • nitrile derivatives such as n-methyl-morpholinium-acetonitrile-methyl sulfate (MMA) or cyanomorpholine (MOR) can be used as bleach activators. Combinations of conventional bleach activators can also be used.
  • bleach activators are tetraacetylethylenediamine, decanoyloxybenzoic acid, n-nonanoyloxybenzenesulfonate or n-lauroyloxybenzenesulfonate.
  • compositions according to the invention comprise one or more bleach activators, these are preferably present in an amount of 1-10% by weight, more preferably in an amount of 1-6% by weight and more preferably in an amount of 2-5% by weight. -% ent, each based on the total weight of the composition of the invention.
  • compositions used in the invention do not contain a bleach activator, i. H. they are free of Bieicheptator.
  • compositions used according to the invention contain no bleach and no bleach activator.
  • Suitable bleach catalysts are preferably bleach-enhancing transition metal salts or complexes of manganese, iron, cobalt, ruthenium, molybdenum, titanium or vanadium.
  • Metal salts are especially preferred manganese salts in the oxidation states +2 or +3, for example manganese halides, the chlorides being preferred, manganese sulfates, manganese salts of organic acids such as manganese acetates, manganese acetylacetonates, manganese oxalates and manganese nitrates.
  • complexes of the iron in the oxidation state II or III and the manganese in the oxidation state II, III, IV or IV which preferably one or more macrocyclic ligand (s) with the donor functions N1 NR, PR, O and / or S included.
  • macrocyclic ligands are used which have nitrogen donor functions.
  • transition metal complexes which contain, as macromolecular ligands, 1,4,7-trimethyl-1,4,7-triazacyclononane (Me-TACN), 1,4,7-triazacyclononane (TACN), 1,5,9-trimethyl-1. [delta].
  • [theta] triazacyclododecane (Me-TACD), 2-methyl-1,4,7-trimethyl-1,4,7-triazacyclononane (MeMeTACN) and / or 2-methyl-1,4,7- triazacyclononane (Me / TACN) or bridged ligands such as 1,2-bis- (4,7-dimethyl-1,4,7-triazacyclonono-1-yl) ethane (Me4-DTNE) or derivatives of the cyclam or cyclene such as 1 , 8-dimethylcyclam, 1,7-dimethylcycles, 1,8-diethylcyclam, 1,7-diethylcycles, 1,8-dibenzylcyclam and 1,7-dibenzylcycles, as described e.g.
  • EP 0 458 397 EP 0458 398 .
  • EP 0 549 272 WO 96/06154 .
  • WO 96/06157 or WO 2006/125517 but also manganese complexes, as they are EP 1 445 305 .
  • EP 1 557 457 and WO 2011/095308 are known.
  • compositions used according to the invention contain one or more bleach catalysts, they are preferably present therein in an amount of 0.001 to 2% by weight, based on the total weight of the compositions.
  • ingredients which may be included in the compositions used include inorganic and / or organic builders and co-builders, so-called builders, to reduce the degree of hardness of the water.
  • Inorganic builders include for example, alkali metal, ammonium and alkanolammonium salts of polyphosphates such as tripolyphosphates, pyrophosphates and glassy polymeric metaphosphates, phosphonates, silicates, carbonates including bicarbonates and sesquicarbonates, sulfates and aluminosilicates.
  • silicate builders are the alkali metal silicates, in particular those having a SiO 2 : Na 2 O ratio of between 1.6: 1 and 3.2: 1, and also phyllosilicates, for example sodium layer silicates, as described in US Pat US 4,664,839 , available from Clariant under the SKS® brand.
  • SKS-6® is a particularly preferred phyllosilicate builder.
  • Aluminosilicate builders are particularly preferred. These are, in particular, zeolites of the formula Na z [(AlO 2 ) z (SiO 2 ) y ] -xH 2 O. where z and y are integers of at least 6, the ratio of z to y is 1.0 is 0.5 and x is an integer of 15 to 264.
  • Suitable aluminosilicate-based ion exchangers are commercially available. These aluminosilicates may be of crystalline or amorphous structure, and may be naturally occurring or synthetically produced.
  • zeolite A zeolite A
  • zeolite P zeolite P (B) (including those described in US Pat EP-A-0 384 070 disclosed)
  • zeolite X zeolite X
  • Suitable organic builders include polycarboxylic compounds such as, for example, ether polycarboxylates and oxydisuccinates, such as in U.S. Pat US 3,128,287 and US 3,635,830 described. Likewise on “TMS / TDS" equipment from US 4,663,071 to get expelled.
  • Suitable builders include the ether hydroxypolycarboxylates, copolymers of acrylic acid with maleic anhydride, maleic anhydride with ethylene or vinyl methyl ether, 1,3,5-trihydroxybenzene-2,4,6-trisulfonic acid and carboxymethyloxysuccinic acid, the alkali, ammonium and substituted Ammonium salts of polyacetic acids such. Ethylenediaminetetraacetic acid and nitrilotriacetic acid, and polycarboxylic acids such as mellitic acid, succinic acid, oxydisuccinic acid, polymaleic acid, benzene-1,3,5-tricarboxylic acid, carboxymethyloxysuccinic acid, and their soluble salts.
  • Citrate-based builders e.g. As citric acid and its soluble salts, in particular the sodium salt, are preferred polycarboxylic acid, which can also be used together with zeolites and / or phyllosilicates.
  • phosphorus based builders can be used, various alkali metal phosphates such as sodium tripolyphosphate, sodium pyrophosphate, and sodium orthophosphate can be used. Also, phosphonate builders such as ethane-1-hydroxy-1,1-diphosphonate and other known phosphonates such as those described in U.S. Pat US 3,159,581 . US 3,213,030 . US 3,422,021 . US 3,400,148 and US 3,422,137 are disclosed.
  • compositions used in the invention may contain wash alkalis which raise the pH of the composition.
  • compositions used according to the invention preferably comprise one or more enzymes selected from the group consisting of proteases, amylases, mannases, lipases, endolases, pectinases, cellulases, pullinases, cutinases and peroxidases.
  • proteases available are Liquanase® Ultra 2.0 XL, BLAP®, Opticlean®, Maxacal®, Maxapem®, Esperase®, Savinase®, Purafect®, OxP and / or Duraxym®.
  • amylases for example, Steinzyme® Plus 12L, Termamyl®, Amylase® LT, Maxamyl®, Duramyl® and / or Pruafect® Ox, Mannasen, for example, Mannaway 4.0 L, lipases, for example Lipex® 100 L, Lipolase®, Lipomax®, Lumafast® and / or Lipozym®, on endolases, for example Endolase® 5000L, on pectinases, for example Pectinex 3X L and / or Pectinex Ultra SPL and on cellulases, for example Carezyme 1000 L and / or Celluclast 1.5 L.
  • the compositions contain at least 0.001% by weight, more preferably 0.01 to 10% by weight, especially preferably 0.1 to 5% by weight and most preferably 1 to 3% by weight of one or more enzymes, each based on the total weight of the compositions.
  • Sequestering agents available are sodium tripolyphosphate (STPP), ethylenediaminetetraacetic acid (EDTA), salts, nitrilotriacetic acid (NTA), polyacrylate, phosphonate, oxalic acid, salt, citric acid, zeolite, condensed phosphates, carbonates, polycarbonates.
  • STPP sodium tripolyphosphate
  • EDTA ethylenediaminetetraacetic acid
  • NTA nitrilotriacetic acid
  • polyacrylate phosphonate
  • oxalic acid salt
  • citric acid citric acid
  • zeolite zeolite
  • condensed phosphates carbonates, polycarbonates.
  • Suitable for soil release polymers are polyesters obtainable by polymerization of the components selected from one or more sulfo-free aromatic dicarboxylic acids and / or their salts, one or more sulfo-containing dicarboxylic acids, one or more compounds of the formula R 1 O (CHR 2 CHR 3 O) n H, where R 1 is H, a linear or branched alkyl or alkenyl group having 1 to 22 C atoms, preferably for C 1 -C 4 alkyl and particularly preferably for methyl, R 2 and R 3 are independent each represent hydrogen or an alkyl group having 1 to 4 carbon atoms, preferably hydrogen and / or methyl, and n is a number from 1 to 100, one or more compounds of the formula H- (OCH 2 CH 2 ) m -SO 3 X, where m is a number from 1 to 100 and X is hydrogen or an alkali metal ion, and one or more crosslinking polyfunctional compounds.
  • SRPs soil release
  • the compositions used according to the invention contain one or more soil release polymers. If the compositions contain one or more soil release polymers, they are preferably present in an amount of from 0.1 to 10% by weight and more preferably in an amount of from 0.2 to 3% by weight, based in each case on Total weight of the compositions.
  • Suitable graying inhibitors are carboxymethyl cellulose, methyl cellulose, hydroxyalkyl cellulose, methyl hydroxyethyl cellulose, methyl hydroxypropyl cellulose, methyl carboxymethyl cellulose and polyvinyl pyrrolidone.
  • dye transfer inhibitors such as polyamine N-oxides such as poly (4-vinylpyridine-N-oxide), e.g. Chromabond S-400, Fa. ISP; Polyvinylpyrrolidone, e.g. Sokalan® HP 50, BASF and copolymers of N-vinylpyrrolidone with N-vinylimidazole and optionally other monomers.
  • polyamine N-oxides such as poly (4-vinylpyridine-N-oxide), e.g. Chromabond S-400, Fa. ISP
  • Polyvinylpyrrolidone e.g. Sokalan® HP 50, BASF and copolymers of N-vinylpyrrolidone with N-vinylimidazole and optionally other monomers.
  • compositions used may also contain color fixing agents, for example color fixing agents obtained by reacting diethylenetriamine, dicyandiamide and amidosulfuric acid, amines with epichlorohydrin, for example dimethylaminopropylamine and epichlorohydrin or dimethylamine and epichlorohydrin or dicyandiamide, formaldehyde and ammonium chloride, or dicyandiamide, ethylenediamine and formaldehyde or cyanamide with amines and formaldehyde or polyamines with cyanamides and amidosulfuric acid or cyanamides with aldehydes and ammonium salts, but also polyamine N-oxides such as poly (4-vinylpyridine-N-oxide), for.
  • color fixing agents obtained by reacting diethylenetriamine, dicyandiamide and amidosulfuric acid, amines with epichlorohydrin, for example dimethylaminopropylamine and epichlorohydrin or dimethylamine and
  • Chromabond S-400, Fa. ISP Polyvinylpyrrolidone, e.g. B. Sokalan® HP 50, BASF and copolymers of N-vinylpyrrolidone with N-vinylimidazole and optionally other monomers.
  • compositions used according to the invention may be complexing agents, for example aminocarboxylates, such as ethylenediaminetetraacetate, N-hydroxyethylethylenediaminetriacetate, nitrilotriacetate, ethylenediamine tetrapropionate, triethylenetetraaminehexaacetate, diethylenetriaminepentaacetate, cyclohexanediaminetetraacetate, phosphonates, for example azacycloheptanediphosphonate, Na salt, pyrophosphates, etidronic acid (1-hydroxyethylidene-1,1-diphosphonic acid, 1-hydroxyethyne-1,1-diphosphonic acid, acetophosphonic acid) and their salts, aminophosphonates such as ethylenediaminetetrakis (methylenephosphonate), diethylenetriaminepentakis (methylenephosphonate), aminotrimethylenephosphonic acid, cyclodextrins, and polyfunctionally
  • Cyclic hydrocarbons such as distyrylbenzenes, distyrylbiphenyls, diphenylstilbenes, triazinylaminostilbenes, stilbenyl-2H-triazoles, for example stilbenzyl-2H-naphthol [1,2-d] triazoles and bis (1,2,3-triazole-2 -yl) stilbenes, benzoxazoles, for example stilbenylbenzoxazole and bis (benzoxazole), furans, benzofurans and benzimidazoles, for example bis (benzo [b] furan-2-yl) biphenyl and cationic benzimidazoles, 1,3-diphenyl-2-pyrazoline, coumarin , Naphthalimides, 1,3,5-2-yl derivatives, methine cyanine and dibenzothiophene-5,5-oxide.
  • stilbenyl-2H-triazoles for example stilbenzyl-2H-naph
  • anionic optical brighteners in particular sulfonated compounds.
  • triazinylaminostilbenes distyrylbiphenyls, and mixtures thereof, 2- (4-styrylphenyl) -2H-naphtho [1,2-d] triazole, 4,4'-bis (1,2,3-triazole-2-) yl) stilbene, aminocoumarin, 4-methyl-7-ethylaminocoumarin, 1,2-bis (benzimidazol-2-yl) ethylene, 1,3-diphenylphrazoline, 2,5-bis (benzooxazol-2-yl) thiophene, 2- Strylnaphtho [1,2-d] oxazole, 2- (4-styryl-3-sulfophenyl) -2H-naphtho [1,2-d] triazole and 2- (stilben-4-yl) -2H-naphthol [ 1,2-d] triazole.
  • compositions used according to the invention comprise one or more optical brighteners, these are preferably present in amounts of from 0.001 to 2% by weight, more preferably in amounts of from 0.002 to 0.8% by weight and particularly preferably in amounts of from 0.003 to 0, 4 wt .-% therein, each based on the total weight of the compositions.
  • Examples thereof are distearyldimethylammonium chloride, ditallowalkyldimethylammonium chloride, ditallowalkylmethylhydroxypropylammonium chloride, cetyltrimethylammonium chloride or the corresponding benzyl derivatives such as dodecyldimethylbenzylammonium chloride. Cyclic quaternary ammonium salts such as alkyl morpholine derivatives can also be used.
  • imidazolinium compounds (1) and imidazoline derivatives (2) can be used.
  • R C 8 -C 24 n- or iso-alkyl, preferably C 10 -C 18 n-alkyl
  • X Bromide, chloride, iodide or methosulfate and
  • A -NH-CO-, -CO-NH-, -O-CO- or -CO-O- is.
  • ester quats are reaction products of alkanolamines and fatty acids, which are then quaternized with conventional alkylating or hydroxyalkylating agents.
  • esterquats are compounds of the formulas: wherein RCO is derived from C 8 -C 24 fatty acids, which may be saturated or unsaturated.
  • the index n is in the range of 0 to 10, preferably in the range of 0 to 3, and more preferably in the range of 0 to 1.
  • quaternization of the tertiary amino group may additionally be a radical R 3 , which may be C 1 -C 4 alkyl, preferably methyl, and a counterion X, which may be chloride, bromide, iodide or methyl sulfate, are introduced.
  • R 3 which may be C 1 -C 4 alkyl, preferably methyl
  • a counterion X which may be chloride, bromide, iodide or methyl sulfate.
  • Amidoaminoethoxylates or their quaternized secondary products are available under the trade names Varisoft® 510, Varisoft® 512, Rewopal® V 3340 and Rewoquat® W 222 LM.
  • compositions used in the invention preferably contain dyes and fragrances or perfumes.
  • Preferred dyes include Acid Red 18 (CI 16255), Acid Red 26, Acid Red 27, Acid Red 33, Acid Red 51, Acid Red 87, Acid Red 88, Acid Red 92, Acid Red 95, Acid Red 249 (CI). 18134, Acid Red 52 (CI45100), Acid Violet 126, Acid Violet 48, Acid Violet 54, Acid Yellow 1, Acid Yellow 3 (CI 47005), Acid Yellow 11, Acid Yellow 23 (CI 19140), Acid Yellow 3, Direct Blue 199 (CI 74190), Direct Yellow 28 (CI 19555), Food Blue 2 (CI 42090), Food Blue 5: 2 (CI 42051: 2), Food Red 7 (CI 16255), Food Yellow 13 (CI 47005) , Food Yellow 3 (CI 15985), Food Yellow 4 (CI 19140), Reactive Green 12, Solvent Green 7 (CI 59040).
  • Particularly preferred dyes are water-soluble acid dyes, for example, Food Yellow 13 (Acid Yellow 3, CI 47005), Food Yellow 4 (Acid Yellow 23, CI 19140), Food Red 7 (Acid Red 18, CI 16255), Food Blue 2 (Acid Blue 9, CI 42090), Food Blue 5 (Acid Blue 3, CI 42051), Acid Red 249 (CI 18134), Acid Red 52 (CI 45100), Acid Violet 126, Acid Violet 48, Acid Blue 80 (CI 61585), Acid Blue 182, Acid Blue 182, Acid Green 25 (CI 61570), Acid Green 81.
  • Food Yellow 13 Acid Yellow 3, CI 47005
  • Food Yellow 4 Acid Yellow 23, CI 19140
  • Food Red 7 Acid Red 18, CI 16255
  • Food Blue 2 Acid Blue 9, CI 42090
  • Food Blue 5 Acid Blue 3, CI 42051
  • Acid Red 249 CI 18134
  • Acid Red 52 CI 45100
  • Acid Violet 126 Acid Violet 48
  • Acid Blue 80 CI 61585
  • Acid Blue 182 Acid
  • Water-soluble direct dyes for example Direct Yellow 28 (CI 19555), Direct Blue 199 (CI 74190) and water-soluble reactive dyes, for example Reactive Green 12, as well as the dyes Food Yellow 3 (CI 15985), Acid Yellow 184 can also be used with preference ,
  • the concentration of the dye dispersions used for dyeing solutions or dispersions preferably being in the range from 0.1 to 50% by weight, particularly preferably in the range from 1 to 45% by weight. , more preferably in the range of 5 to 40 wt .-%, and most preferably in the range of 10 to 35 wt .-% is.
  • aqueous pigment dispersions contain, in addition to the pigments, dispersants and optionally further auxiliaries, for example biocides.
  • Suitable pigment dyes are Pigment Black 7 (CI 77266), Pigment Blue 15 (CI 74160), Pigment Blue 15: 1 (CI 74160), Pigment Blue 15: 3 (CI 74160), Pigment Green 7 (CI 74260). , Pigment Orange 5, Pigment Red 112 (CI 12370), Pigment Red 112 (CI 12370), Pigment Red 122 (CI 73915), Pigment Red 179 (CI 71130), Pigment Red 184 (CI 12487), Pigment Red 188 (CI 12467), Pigment Red 4 (CI 12085), Pigment Red 5 (CI 12490), Pigment Red 9, Pigment Violet 23 (CI 51319), Pigment Yellow 1 (CI 11680), Pigment Yellow 13 (CI 21100), Pigment Yellow 154 , Pigment Yellow 3 (CI 11710), Pigment Yellow 74, Pigment Yellow 83 (CI 21108), Pigment Yellow 97.
  • the following pigment dyes are used in the form of dispersions: Pigment Yellow 1 (CI 11680), Pigment Yellow 3 (CI 11710), Pigment Red 112 (CI 12370), Pigment Red 5 (CI 12490), Pigment Red 181 (CI 73360), Pigment Violet 23 (CI 51319), Pigment Blue 15: 1 (CI 74160), Pigment Green 7 (CI 74260), Pigment Black 7 (CI 77266).
  • water-soluble polymer dyes for example Liquitint.RTM., Liquitint Blue HP.RTM., Liquitint Blue 65.RTM., Liquitint Patent Blue.RTM., Liquitint Royal Blue.RTM., Liquitint Experimental Yellow 8949- 43.RTM., Liquitint Green HMC.RTM., Liquitint Yellow II.RTM. and mixtures thereof.
  • fragrance or perfume individual fragrance compounds, eg.
  • ethers, aldehydes, ketones, alcohols and hydrocarbons are used.
  • Fragrance compounds of the ester type are e.g. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate, phenylethylacetate, linalylbenzoate, benzylformate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate and benzylsalicylate.
  • the ethers include, for example, benzyl ethyl ether to the aldehydes z.
  • the linear alkanals having 8 to 18 carbon atoms citral, citronellal, citronellyloxyacetaldehyde, Hydroxycitronellal, Lilial and Bourgeonal, to the ketones z.
  • the alcohols include anethole, citronellol, eugenol, geranion, linalool, phenylethyl alcohol and terpineol
  • the hydrocarbons include mainly the terpenes and balsams.
  • mixtures of different fragrances are used, which together produce an attractive fragrance.
  • Perfume oils may also contain natural fragrance mixtures, such as those available from plant or animal sources, e.g. Pine, citrus, jasmine, lily, rose or ylang-ylang oil. Also essential oils of lower volatility, which are mostly used as aroma components, are suitable as perfume oils, eg. B. sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon oil, lime blossom oil and juniper berry oil.
  • solutions or emulsions of the abovementioned fragrances and perfume oils which can be prepared by customary methods.
  • Suitable emulsifiers are adducts of 0 to 30 moles of alkylene oxide, in particular ethylene, propylene and / or butylene oxide, to linear or branched, saturated or unsaturated fatty alcohols having 8 to 22 C atoms, to fatty acids having 12 to 22 C atoms, on alkylphenols having 8 to 15 C atoms in the alkyl group and on sorbitan esters; (C 12 -C 18 ) fatty acid mono- and diesters of addition products of 0 to 30 moles of ethylene oxide with glycerol; Glycerol mono- and diesters and sorbitan mono- and diesters of saturated and unsaturated fatty acids having 6 to 22 carbon atoms and optionally their ethylene oxide addition products; Addition products of 5 to 60 mol, preferably 15 to 60 mol, of ethylene oxide with castor oil and / or hydrogenated castor oil; Polyol and in particular polyglycerol esters, such as. Polygly
  • anionic emulsifiers such as ethoxylated and nonethoxylated mono-, di- or tri-phosphoric esters
  • cationic emulsifiers such as mono-, di- and tri-alkyl quats and their polymeric derivatives.
  • Suitable hydrotropes are xylene sulfonates, toluenesulfonates and cumene sulfonates in the form of their potassium or sodium salts or mixtures thereof.
  • compositions used according to the invention comprise one or more hydrotropes in an amount of 1-10% by weight, preferably in an amount of 1-6% by weight and more preferably in an amount of 2-5% by weight .-%, each based on the total weight of the compositions.
  • Preferred organic solvents are selected from the group of monohydric or polyhydric alcohols or glycol ethers.
  • the solvents are preferably selected from ethanol, n- or i-propanol, butanol, glycol, propane or butanediol, glycerol, diglycol, propyl- or butyldiglycol, hexylene glycol, ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, etheylene glycol mono-n-butyl ether, diethylene glycol methyl ether, Di-ethylene glycol ethyl ether, propylene glycol methyl, ethyl or propyl ether, dipropylene glycol methyl or ethyl ether, methoxy, ethoxy or butoxy triglycol, 1-butoxyethoxy-2-propanol, 3-methyl-3-methoxybutanol, propylene glycol-
  • compositions used according to the invention contain water.
  • the amount of water in the compositions used is 10 to 60 wt .-%, preferably 10 to 40 wt .-% and particularly preferably 10 to 20 wt .-%, each based on the total weight of the compositions.
  • the amount of water in the compositions used is ⁇ 10 wt .-%, preferably ⁇ 8 wt .-%, particularly preferably ⁇ 6 wt .-% and particularly preferably ⁇ 5 wt .-%, respectively based on the total weight of the compositions.
  • the minimum amount of water is preferably 3 wt .-%, based on the total weight of the compositions.
  • compositions used according to the invention have a pH of preferably 7 to 11, particularly preferably from 7.5 to 10 and particularly preferably from 7.5 to 8.5.
  • compositions used according to the invention having a water content of 40% by weight or greater apply directly and for compositions having a water content of ⁇ 40% by weight (based on the total weight the compositions) for a 1% by weight aqueous solution of the composition.
  • compositions used according to the invention can advantageously be used in the presence of one or more bleaches for cleaning textiles and in particular for removing bleachable stains on textiles.
  • the invention therefore relates to the use of one of the above-described compositions in the presence of one or more bleaches for cleaning textiles and, in particular, for removing bleachable stains on textiles.
  • compositions used show in particular a significantly greater cleaning power than comparable alkanolamine or alkanolamine salt-containing compositions.
  • compositions used may already contain one or more bleaching agents as described above.
  • the composition used can be combined with one or more bleaching agents which are used separately from the compositions. This may also be the case if the composition used already contains bleach.
  • the use takes place such that the composition used does not contain any bleaching agent but is combined in use with one or more bleaching agents.
  • Bleaching agents which can be combined with the composition according to the invention in the use according to the invention are, on the one hand, compounds which react with bleach activators and form peroxyacids which bleach much more effectively at low temperatures (eg ⁇ 70 ° C.) than the bleaches alone ,
  • Suitable bleaching agents are hydrogen peroxide and inorganic persalts, preferably percarbonates, perborates, persulfates and persilicates, in particular in the form of alkali metal salts.
  • Particularly preferred such bleaching agents are hydrogen peroxide, sodium perborate (monohydrate and tetrahydrate) and / or sodium percarbonate, particularly preferably sodium perborate (monohydrate and tetrahydrate) and / or sodium percarbonate.
  • Bleaching agents which may not be present in the composition according to the invention but which can be combined with the composition in the use according to the invention are, on the other hand, compounds which act without a bleach activator. Suitable such bleaching agents are peracids or their salts.
  • peracids or peracid salts are peroxycarboxylic acids and their salts according to the formula wherein R represents an alkyl group, aralkyl group, cycloalkyl group, aryl group or heterocyclic group, preferably a linear or branched, substituted or unsubstituted alkyl group, particularly preferably an alkyl group with 6 to 9 carbon atoms, and X + is a suitable counterion, preferably an H + , potassium or sodium ion. Preference is given to peroxyhexanoic acid, peroxyheptanoic acid, peroxyoctanoic acid, peroxynonanoic acid, peroxydecanoic acid and salts thereof.
  • peracids or peracid salts are peroxysulfonic acids and their salts according to the formula wherein R is an alkyl group, aralkyl group, cycloalkyl group, aryl group or heterocyclic group, preferably a linear or branched, substituted or unsubstituted alkyl group, particularly preferably an alkyl group having 6 to 9 carbon atoms, and X + is a suitable counterion, preferably H + , a potassium or sodium ion.
  • peracids or peracid salts are peroxophthalic acids and their salts, phthalimidoperacids and their salts, diperoxycarboxylic acids and their salts or peroxy-sulfuric acids and their salts.
  • the bleaching agents which have no bleach activator, particular preference is given to the peracids or their salts selected from the group consisting of monoperoxyphthalic acid and its salts, N, N-phthalimidoperhexanoic acid (PAP) and its salts, diperazelaic acid and its salts, diperdodecanedioic acid and their salts and monoperoxy-sulfuric acid and their salts, the salts preferably being selected from the sodium and / or potassium salts.
  • PAP N-phthalimidoperhexanoic acid
  • PAP N-phthalimidoperhexanoic acid
  • diperazelaic acid and its salts diperdodecanedioic acid and their salts
  • monoperoxy-sulfuric acid and their salts the salts preferably being selected from the sodium and / or potassium salts.
  • monoperoxy sulfuric acid and its salts in particular, the potassium peroxymonosulfate (available under the trade name Car
  • the one or more bleaches in an amount of preferably 1 to 25 wt .-%, particularly preferably 5 to 20 wt .-% and particularly preferably 8 to 16 wt .-%, based on the total weight of inventive composition used.
  • the stated amount of bleach is the total amount of bleach used in the present invention resulting from the amount of bleach in the composition used and the amount of bleach added separately from the composition.
  • the one or more bleaches may be used in the inventive use either without bleach activator or with one or more bleach activators.
  • this takes place in the presence of one or more bleach activators.
  • compositions used may already contain a bleach activator as described above.
  • the composition used can be combined with one or more bleach activators which are used separately from the composition. This may also be the case if the composition already contains bleach activator.
  • composition employed does not contain a bleach activator but is combined in use with one or more bleach activators.
  • bleach activator is used together with bleach in a physical mixture but separate from the liquid composition used.
  • the physical mixture of bleach activator and bleach is in solid form at 25 ° C. If, in the use according to the invention, bleach activators are used together with bleach in a physical mixture, the composition used preferably contains neither bleach nor bleach activator.
  • bleach activator is used separately from bleach and separately from the composition used according to the invention. If, in the use according to the invention, bleach activator is used separately from bleach and separately from the composition according to the invention, the composition according to the invention preferably contains neither bleach nor bleach activator.
  • bleach activators are used which are already mentioned above.
  • the bleach activators listed there as preferred are preferred in the use according to the invention. This applies both in the case where the one or more bleach activators are present in the composition according to the invention and in the case that they are added in the inventive use in addition to the liquid composition used.
  • bleach activators are used in the inventive use, they are used in such a way that, based on the total weight of the liquid compositions used, they are preferably in an amount of 1-10% by weight, more preferably in an amount of 1-6 Wt .-% and particularly preferably in an amount of 2-5 wt .-% present.
  • the stated amount of bleach activator is the total amount of bleach activator used in the inventive use, which consists of the amount of bleach activator in the liquid used Composition and added separately from the composition amount of bleach activator.
  • the wash liquor should have a pH of preferably from 8.0 to 11.0, more preferably from 8.5 to 10.5 and most preferably from 9.0 to 10.0 in order to achieve a sufficient bleaching result.
  • the increase in the pH in the wash liquor can be achieved by wash alkalis, for example sodium carbonate.
  • the washing temperature is preferably from 20 to 80 ° C, more preferably from 30 to 60 ° C and particularly preferably from 40 to 60 ° C.
  • composition % By weight (active substance) A Hostapur® SAS 93 20.5 Sec. Sodium paraffin sulfonate B Genapol® OX 070 (Clariant) C 12,15 -oxoalcohol, 7 EO 30.0 C Edenor® K 12-18 8.0 coconut fatty acid KOH (50% by weight in water) water ad 100 Monoethanolamine 5.0 D Genapol® LRO paste (Clariant) Active ingredient: lauryl ether sulfate, 2EO (EO: ethylene oxide unit), Na salt 8.4 Cublen® BIT 121 2.5 phosphonate Texcare® SRN 170 2.0 Nonionic polyester of polypropylene terephthalate, aqueous Leucophor® BOD liq. 0.5 Optical brightener propylene glycol 10.0 e ethanol 2.0 ® enzyme mix 2.0 Novozymes
  • composition % By weight (active substance) A Hostapur® SAS 93 20.5 Sec. Sodium paraffin sulfonate B Genapol® OX 070 (Clariant) C 12,15 -oxoalcohol, 7 EO 30.0 C Edenor® K 12-18 8.0 coconut fatty acid KOH (50% by weight in water) water ad 100 D Genapol® LRO paste (Clariant) Active ingredient: lauryl ether sulfate, 2EO (EO: ethylene oxide unit), Na salt 8.4 Cublen® BIT 121 2.5 phosphonate Texcare® SRN 170 2.0 Nonionic polyester of polypropylene terephthalate, aqueous Leucophor® BOD liq. 0.5 Optical brightener propylene glycol 10.0 e ethanol 2.0 ® enzyme mix 2.0 Novozymes
  • washing tests were carried out under the following conditions: Washing machine: Miele Novotronic W 927 WPS Program: Hot wash Coloureds Loading: 3 kg Temperature: 40 ° C Wash cycle: 3 times Amount of water: 12 liters
  • Formulation A1 and Formulation B1 30 g each of Formulation A and B were dissolved in 500 ml of water immediately before addition to the washing machine, and 2 g of TAED, 4 g of sodium percarbonate and 11 g of soda were added to each solution.
  • the resulting formulations are referred to below as Formulation A1 and Formulation B1.

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Claims (20)

  1. Utilisation d'une composition liquide ayant une viscosité de 100 à 20 000 mPas, mesurée avec le viscosimètre Brookfeld LVT-II à 20 tr/min et à 20 °C, contenant
    a) un ou plusieurs tensioactifs anioniques choisis dans le groupe constitué par les classes de tensioactifs des sulfonates, sulfates, carboxylates et phosphates et les contre-ions de tensioactifs anioniques du composant a) choisis dans le groupe constitué par les cations de sodium, potassium, calcium et magnésium, et
    b) un ou plusieurs tensioactifs non ioniques choisis dans le groupe constitué par les classes de tensioactifs des alcools gras alcoxylés, amides d'acides gras, amides d'acides gras alcoxylés et alkylpolyglycosides,
    la quantité totale de tensioactifs des composants a) et b) étant > 50 % en poids, par rapport au poids total de la composition liquide, et les tensioactifs anioniques du composant a) et les tensioactifs non ioniques du composant b) étant présents dans la composition liquide dans un rapport pondéral du composant a) sur le composant b) de 3:1 à 1:3, à condition que la composition soit exempte d'alcanolamines et de leurs sels, en présence d'un ou plusieurs agents de blanchiment pour le nettoyage de textiles.
  2. Utilisation selon la revendication 1, caractérisée en ce que la composition liquide contient un ou plusieurs tensioactifs anioniques du composant a) qui sont choisis parmi les sulfonates de paraffine secondaires.
  3. Utilisation selon l'une ou plusieurs des revendications 1 à 2, caractérisée en ce que la composition liquide contient un ou plusieurs tensioactifs anioniques du composant a) qui sont choisis dans le groupe constitué par les sels de l'acide laurique, de l'acide myristique, de l'acide palmitique, de l'acide stéarique, de l'acide béhénique, de l'acide érucique hydrogéné, de l'acide oléique, de l'acide linoléique, de l'acide linolénique et de leurs mélanges et les sels des acides gras ou des mélanges d'acides gras issus de graisses et d'huiles naturelles, de préférence d'huile de coco, d'huile de soja, d'huile de colza, d'huile de tournesol, d'huile de canola, d'huile de palme, d'huile de palmiste, d'huile d'olive et de graisse de suif.
  4. Utilisation selon l'une ou plusieurs des revendications 1 à 3, caractérisée en ce que la composition liquide contient un ou plusieurs tensioactifs non ioniques du composant b) qui sont choisis parmi les produits de condensation d'alcools en C10 à C20 avec 2 à 18 moles d'oxyde d'éthylène pour 1 mole d'alcool.
  5. Utilisation selon l'une ou plusieurs des revendications 1 à 4, caractérisée en ce que la composition liquide contient une ou plusieurs enzymes choisies dans le groupe constitué par les protéases, les amylases, les mannases, les lipases, les endolases, les pectinases, les cellulases, les pullinases, les cutinases et les peroxydases.
  6. Utilisation selon l'une ou plusieurs des revendications 1 à 5, caractérisée en ce que la composition liquide contient un ou plusieurs polymères anti-salissures.
  7. Utilisation selon l'une ou plusieurs des revendications 1 à 6, caractérisée en ce que la composition liquide contient de l'eau dans une quantité inférieure à 10 % en poids, par rapport au poids total de la composition liquide.
  8. Utilisation selon la revendication 1, caractérisée en ce que la composition liquide contient un ou plusieurs agents de blanchiment.
  9. Utilisation selon la revendication 1, caractérisée en ce que la composition liquide ne contient pas d'agent de blanchiment mais est combinée avec un ou plusieurs agents de blanchiment lors de l'utilisation.
  10. Utilisation selon l'une ou plusieurs des revendications 1 à 9, caractérisée en ce que lesdits un ou plusieurs agents de blanchiment sont choisis dans le groupe constitué par le perborate de sodium (monohydrate et tétrahydrate) et le percarbonate de sodium.
  11. Utilisation selon l'une ou plusieurs des revendications 1 à 10, caractérisée en ce que lesdits un ou plusieurs agents de blanchiment sont utilisés dans une quantité de 1 à 25 % en poids, par rapport au poids total de la composition liquide.
  12. Utilisation selon l'une ou plusieurs des revendications 1 à 11, caractérisée en ce qu'elle a lieu en présence d'un ou plusieurs activateurs de blanchiment.
  13. Utilisation selon la revendication 12, caractérisée en ce que l'activateur de blanchiment est utilisé conjointement avec l'agent de blanchiment dans un mélange physique mais séparément de la composition liquide, le mélange physique de l'activateur de blanchiment et de l'agent de blanchiment est présent sous forme solide à 25 °C et la composition liquide ne contient ni agent de blanchiment ni activateur de blanchiment.
  14. Utilisation selon la revendication 12, caractérisé en ce que l'activateur de blanchiment est utilisé séparément de l'agent de blanchiment et séparément de la composition liquide et la composition liquide ne contient ni agent de blanchiment ni activateur de blanchiment.
  15. Utilisation selon l'une ou plusieurs des revendications 12 à 14, caractérisée en ce que lesdits un ou plusieurs activateurs de blanchiment sont choisis dans le groupe constitué par la tétraacétyléthylènediamine, l'acide décanoyloxybenzoïque, le n-nonanoyloxybenzènesulfonate et le n-lauroyloxybenzènesulfonate.
  16. Composition liquide ayant une viscosité de 100 à 20 000 mPas, mesurée avec le viscosimètre Brookfeld LVT-II à 20 tr/min et à 20 °C, contenant
    a) un ou plusieurs tensioactifs anioniques choisis dans le groupe des sulfonates de paraffine secondaires et les contre-ions des tensioactifs anioniques du composant a) choisis dans le groupe constitué par les cations de sodium, potassium, calcium et magnésium, et
    b) un ou plusieurs tensioactifs non ioniques choisis dans le groupe constitué par les classes de tensioactifs des alcools gras alcoxylés, amides d'acides gras, amides d'acides gras alcoxylés et alkylpolyglycosides,
    la quantité totale de tensioactifs des composants a) et b) étant > 50 % en poids, par rapport au poids total de la composition liquide, et les tensioactifs anioniques du composant a) et les tensioactifs non ioniques du composant b) étant présents dans la composition liquide dans un rapport pondéral du composant a) sur le composant b) de 3:1 à 1:3, à condition que la composition soit exempte d'alcanolamines et de leurs sels, et
    la composition liquide contenant de 5 à 20 % en poids d'un ou plusieurs agents de blanchiment du groupe constitué par le peroxyde d'hydrogène et les persels inorganiques, par rapport au poids total de la composition liquide.
  17. Composition liquide selon la revendication 16, caractérisée en ce qu'elle contient un ou plusieurs tensioactifs non ioniques du composant b) qui sont choisis parmi les produits de condensation d'alcools en C10 à C20 avec 2 à 18 moles d'oxyde d'éthylène pour 1 mole d'alcool.
  18. Composition liquide selon la revendication 16 ou 17, caractérisée en ce qu'elle contient une ou plusieurs enzymes choisies dans le groupe constitué par les protéases, les amylases, les mannases, les lipases, les endolases, les pectinases, les cellulases, les pullinases, les cutinases et les peroxydases.
  19. Composition liquide selon l'une ou plusieurs des revendications 16 à 18, caractérisée en ce qu'elle contient un ou plusieurs polymères anti-salissures.
  20. Composition liquide selon l'une ou plusieurs des revendications 16 à 19, caractérisée en ce qu'elle contient de l'eau dans une quantité inférieure à 10 % en poids, par rapport au poids total de la composition liquide.
EP13747798.0A 2012-08-09 2013-08-07 Compositions liquides contenant des agents tensio-actifs dépourvues d'alcanolamines Not-in-force EP2882835B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102012015826.2A DE102012015826A1 (de) 2012-08-09 2012-08-09 Flüssige tensidhaltige Alkanolamin-freie Zusammensetzungen
PCT/EP2013/002367 WO2014023427A1 (fr) 2012-08-09 2013-08-07 Compositions liquides contenant des agents tensio-actifs dépourvues d'alcanolamines

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EP2882835A1 EP2882835A1 (fr) 2015-06-17
EP2882835B1 true EP2882835B1 (fr) 2018-10-24

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US (1) US9777249B2 (fr)
EP (1) EP2882835B1 (fr)
JP (1) JP2015531798A (fr)
DE (1) DE102012015826A1 (fr)
ES (1) ES2705248T3 (fr)
WO (1) WO2014023427A1 (fr)

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US10207491B2 (en) 2016-11-16 2019-02-19 Eastman Kodak Company Method for preparing flexographic printing plates
US10248025B2 (en) 2016-11-16 2019-04-02 Eastman Kodak Company Concentrated and working strength aqueous flexographic developers
US10216089B2 (en) 2016-11-16 2019-02-26 Eastman Kodak Company Methods of forming flexographic printing members
US11434454B2 (en) 2017-12-22 2022-09-06 Church & Dwight Co., Inc. Laundry detergent composition
PL3978590T3 (pl) * 2020-10-05 2025-01-07 The Procter & Gamble Company Rozpuszczalny w wodzie artykuł w dawce jednostkowej zawierający pierwszą niejonową substancję powierzchniowo czynną i drugą niejonową substancję powierzchniowo czynną
US20220298453A1 (en) * 2021-03-18 2022-09-22 Henkel IP & Holding GmbH Liquid Laundry Detergent Compositions Containing Soil Release Polymers

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Also Published As

Publication number Publication date
ES2705248T3 (es) 2019-03-22
WO2014023427A1 (fr) 2014-02-13
US9777249B2 (en) 2017-10-03
JP2015531798A (ja) 2015-11-05
US20150299624A1 (en) 2015-10-22
EP2882835A1 (fr) 2015-06-17
DE102012015826A1 (de) 2014-02-13

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