EP2039786A1 - Cooling method of steel pipe - Google Patents
Cooling method of steel pipe Download PDFInfo
- Publication number
- EP2039786A1 EP2039786A1 EP07744417A EP07744417A EP2039786A1 EP 2039786 A1 EP2039786 A1 EP 2039786A1 EP 07744417 A EP07744417 A EP 07744417A EP 07744417 A EP07744417 A EP 07744417A EP 2039786 A1 EP2039786 A1 EP 2039786A1
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- EP
- European Patent Office
- Prior art keywords
- steel pipe
- cooling
- cooling water
- quenching
- flow rate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 162
- 239000010959 steel Substances 0.000 title claims abstract description 162
- 238000001816 cooling Methods 0.000 title claims abstract description 126
- 239000000498 cooling water Substances 0.000 claims abstract description 70
- 238000000034 method Methods 0.000 claims abstract description 17
- 238000005507 spraying Methods 0.000 claims abstract description 9
- 238000011144 upstream manufacturing Methods 0.000 claims abstract description 9
- 238000005452 bending Methods 0.000 abstract description 41
- 238000010791 quenching Methods 0.000 abstract description 37
- 230000000171 quenching effect Effects 0.000 abstract description 37
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 230000003247 decreasing effect Effects 0.000 abstract description 5
- 230000007423 decrease Effects 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 230000002093 peripheral effect Effects 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 2
- 239000008186 active pharmaceutical agent Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- 238000009863 impact test Methods 0.000 description 2
- 238000010583 slow cooling Methods 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910001563 bainite Inorganic materials 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910000734 martensite Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/62—Quenching devices
- C21D1/667—Quenching devices for spray quenching
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/08—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/02—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
- B21B45/0203—Cooling
- B21B45/0209—Cooling devices, e.g. using gaseous coolants
- B21B45/0215—Cooling devices, e.g. using gaseous coolants using liquid coolants, e.g. for sections, for tubes
- B21B2045/0227—Cooling devices, e.g. using gaseous coolants using liquid coolants, e.g. for sections, for tubes for tubes
Definitions
- This invention relates to a method of cooling a steel pipe capable of effectively suppressing bending of steel pipes which can easily occur particularly when quenching thin-walled steel pipes, thereby making it possible to manufacture steel pipes having mechanical properties of increased uniformity.
- Bending of steel pipes sometimes occurs at the time of quenching.
- "bending" of a steel pipe means curvature in the axial direction of the steel pipe.
- quenching-induced bending bending which is observed at the time of quenching
- Quenching-induced bending is caused by factors such as uneven cooling.
- the ratio (t/D) of the wall thickness (t) to the outer diameter (D) has a low value such as at most 0.07
- a large amount of quenching-induced bending which is considered a defect in quality, can easily occur.
- JP H02-7372 B (1990 ) discloses a heat treatment method which, during quenching of a metal pipe, suppresses quenching-induced bending by performing slow cooling in the initial stage of cooling the outer surface of the pipe so as to reduce the temperature difference over the entire surface of the pipe followed by usual rapid cooling.
- JP S61-4896 B (1986 ) a cooling method is disclosed in which a pipe is cooled by spraying water into the interior of the pipe from one end thereof while water sprayed from nozzles is allowed to impinge on the outer surface of the pipe over substantially the entire length thereof.
- the amount of water sprayed on the outer surface of the pipe is increased, or the timing of the start of outer surface cooling is made earlier, or the completion of outer surface cooling is delayed, whereby the entire pipe is uniformly cooled in a short period.
- This invention provides a method of cooling a steel pipe which can suppress quenching-induced bending during quenching of thin-walled steel pipes having a t/D ratio of at most 0.07 and which can solve the problems of the above-described prior art.
- the present invention is a method of cooling a steel pipe in which the inner surface and outer surface of a horizontally-disposed steel pipe are cooled while rotating the steel pipe in its circumferential direction, characterized in that the ratio of the wall thickness to the outer diameter of the steel pipe is preferably at most 0.07 and more preferably at most 0.06, cooling of the inner surface of the steel pipe is carried out by spraying cooling water inside the steel pipe and cooling of the outer surface of the steel pipe is carried out by making cooling water flow downwards in a planar shape in the axial direction onto the outer surface of a steel pipe from above at two locations approximately equally spaced from the uppermost portion of the steel pipe on both sides thereof, the flow rate of cooling water which flows downwards at a location on the upstream side in the direction of rotation of the steel pipe is equal to or greater than the flow rate of cooling water flowing downwards at a location on the downstream side in the rotational direction, and cooling of the inner surface of the steel pipe is commenced at least 7 seconds prior to cooling of the outer surface of the steel pipe.
- a method of cooling a steel pipe according to the present invention can effectively suppress quenching-induced bending of steel pipes without a decrease in the manufacturing efficiency of steel pipes even when quenching thin-walled steel pipes for which t/D is at most 0.07.
- the uniformity of cooling in both the circumferential and axial directions of a steel pipe is improved, leading to improvement in the uniformity of quenching and accordingly uniformity of the mechanical properties of a steel pipe.
- the steel pipe has improved toughness.
- Figure 1 is a vertical cross-sectional view schematically showing the structure of a cooling apparatus for carrying out a method of cooling a steel pipe according to this embodiment.
- a cooling apparatus 1 includes a pair of rotating rollers 3, 3 which support a horizontally-disposed steel pipe 2 and rotate it in its circumferential direction.
- the cooling apparatus 1 additionally includes an inner surface cooling nozzle (not shown) which is disposed near one end of the steel pipe 2 and which is designed to spray cooling water into the interior of the steel pipe 2, and an outer surface cooling nozzle 7 which is installed above the steel pipe 2.
- the inner surface cooling nozzle may be a conventional spraying nozzle.
- the outer surface cooling nozzle 7 has slit-shaped discharge ports 6a and 6b for allowing streams of cooling water 5a and 5b which have a planar shape in the pipe axial direction to flow downwards from above at two locations 4a and 4b which are approximately equally spaced from the uppermost (top) portion of the outer peripheral surface of the steel pipe 2 on both sides thereof (namely, at two locations which are approximately symmetric with respect to the uppermost portion).
- the discharge ports 6a and 6b preferably have a length extending over substantially the entire length of the steel pipe 2.
- the cooling water for cooling the outer surface preferably flows naturally downwards in a laminar flow from the discharge ports 6a and 6b of the nozzle 7, but it is also possible to apply pressure to the cooling water.
- a steel pipe 2 to which a cooling method according to this embodiment can be advantageously applied is a thin-walled steel pipe having a ratio t/D of the wall thickness t with respect to the outer diameter D of at most 0.07 with which a significant amount of quenching-induced bending which becomes a problem with respect to quality can easily occur.
- This cooling method can be applied particularly suitably to cooling of the inner and outer surfaces of line pipe made from low carbon steel which is of low strength and easily bends or line pipe of a grade not higher than API X60 (having a composition in mass percent of, for example, (a) C: 0.06%, Si: 0.26%, Mn: 1.24%, P: 0.013%, S: 0.001%, Cr: 0.16%, V: 0.06%, a remainder of Fe and impurities, with Ceq: 0.311%, or (b) C: 0.06%, Si: 0.40%, Mn: 1.60%, P: 0.020%, S: 0.003%, Cu: 0.30%, Ni: 0.50%, Cr: 0.28%, Mo: 0.23%, V: 0.08%, a remainder of Fe and impurities, with Ceq: 0.498%). Even when this cooling method is applied to a long steel pipe 2 with a length of at least 20 meters, it can effectively suppress the occurrence of quenching-induced bending.
- cooling a steel pipe 2 with the cooling apparatus 1 When cooling a steel pipe 2 with the cooling apparatus 1 according to this embodiment, first, the steel pipe 2 is rotated in its circumferential direction by rotating the rotating rollers 3, 3 in the direction of the arrows. Then, cooling of the inner surface of the steel pipe 2 is commenced by spraying cooling water from the unillustrated inner surface cooling nozzle into the interior of the steel pipe from one end thereof. The sprayed cooling water is discharged from the other end of the steel pipe 2. Cooling of the outer surface of the steel pipe 2 is then commenced by making cooling water 5a and 5b from the discharge ports 6a and 6b of the outer surface cooling nozzle 7 flow downwards towards the outer peripheral surface of the steel pipe 2. The cooling water may if necessary contain an additive such as a corrosion inhibitor as is well known in the art.
- the rotational speed of the steel pipe 2 is preferably at least 30 rpm and at most 80 rpm. If the rotational speed of the steel pipe 2 is less than 30 rpm, the condition of the steel pipe 2 after quenching can easily vary in the circumferential direction thereof. On the other hand, if the rotational speed of the steel pipe 2 exceeds 80 rpm, the necessary equipment becomes large in size and complicated and equipment costs increase.
- the rate at which cooling water is sprayed into the interior of the steel pipe 2 from the inner surface cooling nozzle is preferably at least 2,000 m 3 per hour and at most 6,500 m 3 per hour. If the flow rate of cooling water sprayed into the steel pipe 2 is less than 2,000 m 3 per hour, the cooling ability is inadequate, whereas if it exceeds 6,500 m 3 per hour, the necessary equipment becomes large in size and complicated and equipment costs increase.
- cooling of the inner surface of the steel pipe 2 begins at least 7 seconds before cooling of the outer surface of the steel pipe 2 for the following reasons.
- Figure 2 are graphs showing the results of numerical calculation of the surface temperature, the yield strength YS, and the axial stress ⁇ z of the steel pipe 2 when the inner surface and the outer surface of the steel pipe 2 were cooled.
- of the axial stress produced by thermal expansion and contraction of the steel pipe 2 in the initial stage after the start of cooling i.e., in the stage in which the surface temperature of the steel pipe 2 is 550° C or higher (the axial stress in the region indicated by symbol A in the graph of Figure 2(a) ), or that of the axial stress produced after the surface temperature of the steel pipe 2 decreases to lower than 550° C (the axial stress in the region shown by symbol B in the graph of Figure 2(a) ) and including the stress caused by bainite transformation or martensite transformation or the like is sometimes larger than the absolute value
- cooling is carried out not only on the inner surface but also on the outer surface of a steel pipe 2.
- at least in the initial stage of cooling in which the surface temperature of the steel pipe 2 is 550° C or higher, it is effective to begin cooling of the inner surface of the steel pipe 2 before cooling of the outer surface. Specifically, by making the advance time at least 7 seconds, the relationship
- the advance time of inner surface cooling exceeds 30 seconds, a long time is required for cooling of a steel pipe 2 and operating efficiency decreases. Therefore, the advance time is preferably at most 30 seconds.
- a certain amount of the cooling water 5b which flows down at position 4b on the downstream side in the direction of rotation, i.e., of the cooling water which runs down from discharge port 6b flows backwards against the direction of rotation of the steel pipe 2, but almost all of it flows to the downward side and then drops immediately after it flows down.
- the contribution to cooling of the outer surface of the steel pipe 2 is greater for cooling water 5a than for cooling water 5b.
- the flow rate of cooling water which flows down at location 4a on the upstream side in the rotational direction of the steel pipe 2 is made equal to or larger than the flow rate of cooling water 5b which flows down at location 4b on the downstream side in the rotational direction of the steel pipe 2.
- the flow rates of cooling water 5a and 5b can be set by adjusting the width of the slits of the discharge ports 6a and 6b, respectively.
- the amount of cooling water which flows in the rotational direction along the outer surface of the steel pipe 2 can be increased as needed, and the water film which accumulates between positions 4a and 4b on the outer surface of the steel pipe where cooling water streams 5a and 5b, respectively, flow down can be made a suitable thickness, thereby making it possible to further increase the cooling efficiency of the outer surface of the steel pipe 2.
- the ratio of the flow rate of cooling water 5b which flows down at location 4b on the downstream side in the rotational direction of the steel pipe 2 with respect to the flow rate of cooling water 5a which flows down at location 4a on the upstream side in the rotational direction of the steel pipe 2 is preferably in the range of 1 - 0.6 and more preferably in the range of 1 - 0.8.
- this ratio somewhat smaller than 1, the amount of bending can be decreased compared to when the ratio is 1 (namely, when the flow rates of cooling water streams 5a and 5b are the same).
- this ratio is too small, the amounts of cooling water on both sides of the outer peripheral surface of the steel pipe become significantly unequal and the amount of bending ends up increasing.
- the angle ⁇ between positions 4a and 4b where the two streams of cooling water 5a and 5b impact the outer peripheral surface of the steel pipe 2 as measured from the center of the steel pipe 2 is preferably at least 12° and at most 95°. If this angle ⁇ is less than 12°, the region formed by the water film on the surface of the steel pipe 2 (the region between positions 4a and 4b) becomes extremely narrow. If this angle exceeds 95°, except for the case in which the outer diameter of the steel pipe 2 is extremely large, it is difficult to supply a sufficient amount of water for cooling between positions 4a and 4b of cooling water 5a and 5b on the outer surface of the steel pipe, and cooling sometimes becomes insufficient particularly at the uppermost portion of the steel pipe 2.
- a third discharge port for cooling water which flows downwards in a planar shape may be installed preferably in a position immediately above the uppermost portion of the steel pipe 2.
- the flow rate of cooling water which flows down from this third discharge port is preferably smaller than the flow rates of cooling water from the discharge ports 6a and 6b on both sides.
- the cooling apparatus becomes complicated, it is possible to have two rows of third streams of cooling water in a planar shape.
- two pairs of two rows of discharge ports namely, an inner pair and an outer pair
- the flow rate of cooling water which flows down in a position on the upstream side in the rotational direction of the steel pipe 2 is preferably set to be equal to or greater than the flow rate of cooling water which flows down at a position on the downstream side in the rotational direction of the steel pipe 2.
- the amount of quenching-induced bending which develops when quenching a thin-walled steel pipe P for which the ratio t/D is at most 0.07 can be made such that the maximum overall bending in a lot of pipes is effectively suppressed without a decrease in the manufacturing efficiency of steel pipes.
- the quenched steel pipes have improved toughness.
- cooling of the outer surface can be carried out under the same conditions over the entire length of the steel pipe without varying the starting time and the ending time in the axial direction of the steel pipe, so complexity of the structure of equipment and of control can be avoided.
- the timing of start of cooling of the outer surface is delayed relative to cooling of the inner surface over the entire length of the steel pipe.
- cooling was carried out on API X60 grade steel pipes 2 (in mass %, C: 0.06%, Si: 0.26%, Mn: 1.24%, P: 0.013%, S: 0.001%, Cr: 0.16%, V: 0.06%, a remainder of Fe and impurities, and Ceq: 0.311%) having the outer diameter D, wall thickness t, ratio t/D, and length shown in Table 1 while rotating it at a rotational speed of 60 rpm with the inner surface flow rate (the flow rate of cooling water for cooling the inner surface), the total flow rate on the outer surface (the total flow rate of cooling water for cooling the outer surface), the inner surface advance time (the time interval from the start of inner surface cooling to the start of outer surface cooling), the separation between the streams of outer surface cooling water (the distance in the circumferential direction between 4a and 4b in Figure 1 ), and the angle ⁇ having the values shown in Table 1.
- the heating temperature of the steel pipe 2 prior to the start of cooling was 920° C
- cooling of the steel pipe 2 was carried out using one stream of cooling water which flowed downwards in a planar shape on the outer surface of the steel pipe 2.
- the discharge port for cooling water was disposed immediately above the uppermost portion of the steel pipe 2.
- the amount of quenching-induced bending which was produced in the steel pipe 2 after the completion of cooling (in unit of mm/10 m; determined by measuring the amount of bending (mm) with a thread stretched over the overall length of a pipe for the pipe having the largest amount of bending in a lot of pipes undergoing the same heat treatment, and converting this value into the amount of bending per 10 meters) and the maximum fracture appearance transition temperature vTs (the maximum value measured at 4 locations in the circumferential direction of the steel pipe) in a Charpy impact test were determined.
- Bending amounts of at most 10 mm are indicated by DOUBLE CIRCLE (o), bending amounts of greater than 10 mm and at most 20 mm are indicated by CIRCLE ( ⁇ ), bending amounts of greater than 20 mm and at most 30 mm are indicated by TRIANGLE ( ⁇ ), and bending amounts exceeding 30 mm are indicated by X.
- DOUBLE CIRCLE DOUBLE CIRCLE
- CIRCLE ⁇
- TRIANGLE ⁇
- X bending amounts exceeding 30 mm
- Runs Nos. 5 - 7, 10, 11, 14, and 15 in Table 1 are examples of carrying out cooling by the method according to the present invention (namely, there were two streams of outer surface cooling water, and inner surface cooling was carried out at least 7 seconds in advance).
- the amount of bending was CIRCLE or DOUBLE CIRCLE, and even with a thin-walled steel pipe having a t/D ratio of at most 0.07 (i.e., 0.031 to 0.058), quenching-induced bending could be effectively suppressed without decreasing the manufacturing efficiency of a steel pipe.
- the Charpy maximum fracture appearance transition temperature (maximum vTs) was -40° C or below, so the toughness was good.
- Runs Nos. 6 and 7 had the same cooling conditions as each other except that the distribution of the flow rate of the two streams of outer surface cooling water was different. Whereas the amount of quenching-induced bending was 10 mm for Run No. 6 in which the flow rates of the two streams of outer surface cooling water were the same, for Run No. 7 in which the flow rate for the stream on the upstream side in the rotational direction of the steel pipe was made larger than the flow rate for the stream on the downstream side, the amount of quenching-induced bending was further decreased to 6 mm.
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Abstract
Description
- This invention relates to a method of cooling a steel pipe capable of effectively suppressing bending of steel pipes which can easily occur particularly when quenching thin-walled steel pipes, thereby making it possible to manufacture steel pipes having mechanical properties of increased uniformity.
- Bending of steel pipes sometimes occurs at the time of quenching. In the context of the present invention, "bending" of a steel pipe means curvature in the axial direction of the steel pipe. Below, bending which is observed at the time of quenching will be referred to as "quenching-induced bending".
- Quenching-induced bending is caused by factors such as uneven cooling. In particular, when quenching a thin-walled steel pipe in which the ratio (t/D) of the wall thickness (t) to the outer diameter (D) has a low value such as at most 0.07, a large amount of quenching-induced bending, which is considered a defect in quality, can easily occur. There have been many proposals in the past concerning cooling methods intended to suppress this quenching-induced bending.
- For example,
JP H02-7372 B (1990 - In
JP S61-4896 B (1986 - In the method disclosed in
JP H02-7372 B - In the method disclosed in
JP S61-4896 B - This invention provides a method of cooling a steel pipe which can suppress quenching-induced bending during quenching of thin-walled steel pipes having a t/D ratio of at most 0.07 and which can solve the problems of the above-described prior art.
- The present invention is a method of cooling a steel pipe in which the inner surface and outer surface of a horizontally-disposed steel pipe are cooled while rotating the steel pipe in its circumferential direction, characterized in that the ratio of the wall thickness to the outer diameter of the steel pipe is preferably at most 0.07 and more preferably at most 0.06, cooling of the inner surface of the steel pipe is carried out by spraying cooling water inside the steel pipe and cooling of the outer surface of the steel pipe is carried out by making cooling water flow downwards in a planar shape in the axial direction onto the outer surface of a steel pipe from above at two locations approximately equally spaced from the uppermost portion of the steel pipe on both sides thereof, the flow rate of cooling water which flows downwards at a location on the upstream side in the direction of rotation of the steel pipe is equal to or greater than the flow rate of cooling water flowing downwards at a location on the downstream side in the rotational direction, and cooling of the inner surface of the steel pipe is commenced at least 7 seconds prior to cooling of the outer surface of the steel pipe.
- A method of cooling a steel pipe according to the present invention can effectively suppress quenching-induced bending of steel pipes without a decrease in the manufacturing efficiency of steel pipes even when quenching thin-walled steel pipes for which t/D is at most 0.07. In addition, the uniformity of cooling in both the circumferential and axial directions of a steel pipe is improved, leading to improvement in the uniformity of quenching and accordingly uniformity of the mechanical properties of a steel pipe. Thus, the steel pipe has improved toughness.
-
-
Figure 1 is a vertical cross-sectional view schematically showing the structure of a cooling apparatus for carrying out an embodiment of a method of cooling a steel pipe according to the present invention. -
Figure 2 shows graphs showing the results of numerical calculation of the surface temperature, the yield strength YS, and the axial stress σz of a steel pipe when the inner surface and the outer surface of the steel pipe are cooled.Figure 2(a) shows the case in which cooling of the inner surface and the outer surface of the steel pipe are started simultaneously (inner surface advance time = 0 seconds), andFigure 2(b) shows the case in which only cooling of the inner surface of the steel pipe is carried out (inner surface advance = ∞ seconds). - An embodiment of a method of cooling a steel pipe according to the present invention will be explained in detail while referring when suitable to the accompanying drawings.
-
Figure 1 is a vertical cross-sectional view schematically showing the structure of a cooling apparatus for carrying out a method of cooling a steel pipe according to this embodiment. - In
Figure 1 , a cooling apparatus 1 includes a pair of rotatingrollers steel pipe 2 and rotate it in its circumferential direction. The cooling apparatus 1 additionally includes an inner surface cooling nozzle (not shown) which is disposed near one end of thesteel pipe 2 and which is designed to spray cooling water into the interior of thesteel pipe 2, and an outersurface cooling nozzle 7 which is installed above thesteel pipe 2. The inner surface cooling nozzle may be a conventional spraying nozzle. The outersurface cooling nozzle 7 has slit-shaped discharge ports water 5a and 5b which have a planar shape in the pipe axial direction to flow downwards from above at twolocations 4a and 4b which are approximately equally spaced from the uppermost (top) portion of the outer peripheral surface of thesteel pipe 2 on both sides thereof (namely, at two locations which are approximately symmetric with respect to the uppermost portion). Thedischarge ports steel pipe 2. The cooling water for cooling the outer surface preferably flows naturally downwards in a laminar flow from thedischarge ports nozzle 7, but it is also possible to apply pressure to the cooling water. - A
steel pipe 2 to which a cooling method according to this embodiment can be advantageously applied is a thin-walled steel pipe having a ratio t/D of the wall thickness t with respect to the outer diameter D of at most 0.07 with which a significant amount of quenching-induced bending which becomes a problem with respect to quality can easily occur. This cooling method can be applied particularly suitably to cooling of the inner and outer surfaces of line pipe made from low carbon steel which is of low strength and easily bends or line pipe of a grade not higher than API X60 (having a composition in mass percent of, for example, (a) C: 0.06%, Si: 0.26%, Mn: 1.24%, P: 0.013%, S: 0.001%, Cr: 0.16%, V: 0.06%, a remainder of Fe and impurities, with Ceq: 0.311%, or (b) C: 0.06%, Si: 0.40%, Mn: 1.60%, P: 0.020%, S: 0.003%, Cu: 0.30%, Ni: 0.50%, Cr: 0.28%, Mo: 0.23%, V: 0.08%, a remainder of Fe and impurities, with Ceq: 0.498%). Even when this cooling method is applied to along steel pipe 2 with a length of at least 20 meters, it can effectively suppress the occurrence of quenching-induced bending. - When cooling a
steel pipe 2 with the cooling apparatus 1 according to this embodiment, first, thesteel pipe 2 is rotated in its circumferential direction by rotating therotating rollers steel pipe 2 is commenced by spraying cooling water from the unillustrated inner surface cooling nozzle into the interior of the steel pipe from one end thereof. The sprayed cooling water is discharged from the other end of thesteel pipe 2. Cooling of the outer surface of thesteel pipe 2 is then commenced by makingcooling water 5a and 5b from thedischarge ports surface cooling nozzle 7 flow downwards towards the outer peripheral surface of thesteel pipe 2. The cooling water may if necessary contain an additive such as a corrosion inhibitor as is well known in the art. - The rotational speed of the
steel pipe 2 is preferably at least 30 rpm and at most 80 rpm. If the rotational speed of thesteel pipe 2 is less than 30 rpm, the condition of thesteel pipe 2 after quenching can easily vary in the circumferential direction thereof. On the other hand, if the rotational speed of thesteel pipe 2 exceeds 80 rpm, the necessary equipment becomes large in size and complicated and equipment costs increase. - The rate at which cooling water is sprayed into the interior of the
steel pipe 2 from the inner surface cooling nozzle is preferably at least 2,000 m3 per hour and at most 6,500 m3 per hour. If the flow rate of cooling water sprayed into thesteel pipe 2 is less than 2,000 m3 per hour, the cooling ability is inadequate, whereas if it exceeds 6,500 m3 per hour, the necessary equipment becomes large in size and complicated and equipment costs increase. - In a cooling method according to this embodiment, cooling of the inner surface of the
steel pipe 2 begins at least 7 seconds before cooling of the outer surface of thesteel pipe 2 for the following reasons. -
Figure 2 are graphs showing the results of numerical calculation of the surface temperature, the yield strength YS, and the axial stress σz of thesteel pipe 2 when the inner surface and the outer surface of thesteel pipe 2 were cooled.Figure 2(a) shows the results when cooling of the inner surface and cooling of the outer surface of thesteel pipe 2 were commenced simultaneously (advance time for the inner surface = 0 seconds) andFigure 2(b) shows the results when only the inner surface of thesteel pipe 2 was cooled (advance time for the inner surface = ∞ seconds). The results shown in the graphs ofFigure 2(a) and 2(b) were observed under conditions in which the outer diameter of thesteel pipe 2 was 412.3 mm, the wall thickness was 8.30 mm, the length was 30 mm, the material of the pipe was low carbon steel, the flow rate of cooling water sprayed into thesteel pipe 2 from the inner surface cooling nozzle was 5,400 m3 per hour, the flow rate of cooling water which flowed downwards onto the outer surface of thesteel pipe 2 from the outersurface cooling nozzle 7 was 2,700 m3 per hour, and the rotational speed of thesteel pipe 2 was 65 rpm. - As shown in
Figure 2(a) , if cooling of the inner surface and cooling of the outer surface of a steel pipe P are commenced simultaneously, the absolute value |σz| of the axial stress produced by thermal expansion and contraction of thesteel pipe 2 in the initial stage after the start of cooling, i.e., in the stage in which the surface temperature of thesteel pipe 2 is 550° C or higher (the axial stress in the region indicated by symbol A in the graph ofFigure 2(a) ), or that of the axial stress produced after the surface temperature of thesteel pipe 2 decreases to lower than 550° C (the axial stress in the region shown by symbol B in the graph ofFigure 2(a) ) and including the stress caused by bainite transformation or martensite transformation or the like is sometimes larger than the absolute value |YS| of the yield stress. - In contrast, as shown in the graph of
Figure 2(b) , when only cooling of the inner surface of thesteel pipe 2 is carried out, the absolute value |σz| of the axial stress is always less than the absolute value |YS| of the yield stress from the start to the completion of cooling, namely, in the period until the surface temperature of thesteel pipe 2 decreases to room temperature. - The reason for this is thought to be that compared to outer surface cooling in which only the portion where the planar streams of cooling
water 5a and 5b flow down is cooled for an instant, in the case of inner surface cooling, it is possible to substantially uniformly cool thesteel pipe 2 over its entire periphery, so temperature unevenness of thesteel pipe 2 does not readily develop, and variation in the axial stress σz decreases. - In a cooling test performed on an
actual steel pipe 2 under the same conditions as were set for obtaining the results shown in the graphs ofFigures 2(a) and 2(b) , a significant amount of quenching-induced bending occurred when cooling of the inner surface and cooling of the outer surface were simultaneously carried out, whereas a significant amount of troublesome quenching-induced bending did not occur when only inner surface cooling was carried out. - Based on the above-described results from
Figures 2(a) and 2(b) and from the cooling test, it is thought that quenching-induced bending of asteel pipe 2 occurs when the absolute value |σz| of the axial stress is greater than the absolute value |YS| of the yield stress (i.w., |σz| > |YS|). Accordingly, quenching-induced bending of asteel pipe 2 can be suppressed by cooling asteel pipe 2 such that the relationship |σz| < |YS| is always established. As shown inFigure 2(b) , the relationship |σz| < |YS| is always established if only inner surface cooling is carried out. However, with only inner surface cooling, the cooling capacity of thesteel pipe 2 per unit time is inadequate and cooling takes a long time. As a result, the manufacturing efficiency of asteel pipe 2 decreases, or thesteel pipe 2 cannot be suficiently uniformly cooled due to the effect of recuperation of heat from thesteel pipe 2, whereby a steel pipe having uniform mechanical properties cannot be obtained. - Therefore, according to an embodiment of the present invention, in order to prevent a decrease in manufacturing efficiency and guarantee uniform quenching, cooling is carried out not only on the inner surface but also on the outer surface of a
steel pipe 2. In order to establish the relationship |σz| < |YS| at least in the initial stage of cooling in which the surface temperature of thesteel pipe 2 is 550° C or higher, it is effective to begin cooling of the inner surface of thesteel pipe 2 before cooling of the outer surface. Specifically, by making the advance time at least 7 seconds, the relationship |σz| < |YS| can be maintained throughout all the period of cooling thesteel pipe 2. - For the above-described reasons, in this embodiment, by starting cooling of the inner surface of the
steel pipe 2 at least 7 seconds in advance of cooling of the outer surface of thesteel pipe 2, i.e., by setting the timing of the start of spraying of cooling water from the inner surface cooling nozzle to be at least 7 seconds before the timing of the start of allowing coolingwater 5a and 5b to flow down from thedischarge ports - If the advance time of inner surface cooling exceeds 30 seconds, a long time is required for cooling of a
steel pipe 2 and operating efficiency decreases. Therefore, the advance time is preferably at most 30 seconds. - In order to increase the cooling efficiency of the outer surface of a
steel pipe 2, it is conceivable to increase both the flow rates of the coolingwater 5a and 5b which flows down from thedischarge ports water 5a and 5b are both too large, a water film which accumulates on the outer surface of thesteel pipe 2 between thelocations 4a and 4b where the coolingwater 5a and 5b runs down becomes thicker than necessary, and the rate of effective utilization of cooling water (the proportion of cooling water which contributes purely to cooling of the steel pipe 2) decreases, and cooling water no longer smoothly flows in the rotational direction of thesteel pipe 2. - A considerable portion of the cooling water 5a which flows down at
position 4a on the upstream side in the rotational direction of thesteel pipe 2, i.e., a considerable portion of the cooling water which runs down fromdischarge port 6a flows in the rotational direction on the outer surface of thesteel pipe 2 as it rotates. In contrast, a certain amount of the coolingwater 5b which flows down at position 4b on the downstream side in the direction of rotation, i.e., of the cooling water which runs down fromdischarge port 6b flows backwards against the direction of rotation of thesteel pipe 2, but almost all of it flows to the downward side and then drops immediately after it flows down. Namely, the contribution to cooling of the outer surface of thesteel pipe 2 is greater for cooling water 5a than for coolingwater 5b. - Therefore, in this embodiment, the flow rate of cooling water which flows down at
location 4a on the upstream side in the rotational direction of thesteel pipe 2 is made equal to or larger than the flow rate of coolingwater 5b which flows down at location 4b on the downstream side in the rotational direction of thesteel pipe 2. The flow rates of coolingwater 5a and 5b can be set by adjusting the width of the slits of thedischarge ports - As a result, the amount of cooling water which flows in the rotational direction along the outer surface of the
steel pipe 2 can be increased as needed, and the water film which accumulates betweenpositions 4a and 4b on the outer surface of the steel pipe where coolingwater streams 5a and 5b, respectively, flow down can be made a suitable thickness, thereby making it possible to further increase the cooling efficiency of the outer surface of thesteel pipe 2. - The ratio of the flow rate of cooling
water 5b which flows down at location 4b on the downstream side in the rotational direction of thesteel pipe 2 with respect to the flow rate of cooling water 5a which flows down atlocation 4a on the upstream side in the rotational direction of thesteel pipe 2 is preferably in the range of 1 - 0.6 and more preferably in the range of 1 - 0.8. By making this ratio somewhat smaller than 1, the amount of bending can be decreased compared to when the ratio is 1 (namely, when the flow rates of coolingwater streams 5a and 5b are the same). However, if this ratio is too small, the amounts of cooling water on both sides of the outer peripheral surface of the steel pipe become significantly unequal and the amount of bending ends up increasing. - The angle θ between
positions 4a and 4b where the two streams of coolingwater 5a and 5b impact the outer peripheral surface of thesteel pipe 2 as measured from the center of thesteel pipe 2 is preferably at least 12° and at most 95°. If this angle θ is less than 12°, the region formed by the water film on the surface of the steel pipe 2 (the region betweenpositions 4a and 4b) becomes extremely narrow. If this angle exceeds 95°, except for the case in which the outer diameter of thesteel pipe 2 is extremely large, it is difficult to supply a sufficient amount of water for cooling betweenpositions 4a and 4b of coolingwater 5a and 5b on the outer surface of the steel pipe, and cooling sometimes becomes insufficient particularly at the uppermost portion of thesteel pipe 2. - Particularly when the angle θ is large, a third discharge port for cooling water which flows downwards in a planar shape (not shown) may be installed preferably in a position immediately above the uppermost portion of the
steel pipe 2. The flow rate of cooling water which flows down from this third discharge port is preferably smaller than the flow rates of cooling water from thedischarge ports - Although the cooling apparatus becomes complicated, it is possible to have two rows of third streams of cooling water in a planar shape. For example, it is possible to install two pairs of two rows of discharge ports (namely, an inner pair and an outer pair) for cooling water which flows down on the outer peripheral surface of the steel pipe at roughly equal distances from the uppermost portion on both sides of the uppermost portion of the steel pipe. In this case, for the discharge ports of each pair, the flow rate of cooling water which flows down in a position on the upstream side in the rotational direction of the
steel pipe 2 is preferably set to be equal to or greater than the flow rate of cooling water which flows down at a position on the downstream side in the rotational direction of thesteel pipe 2. - In this manner, in this embodiment, the amount of quenching-induced bending which develops when quenching a thin-walled steel pipe P for which the ratio t/D is at most 0.07 can be made such that the maximum overall bending in a lot of pipes is effectively suppressed without a decrease in the manufacturing efficiency of steel pipes. As a result, the quenched steel pipes have improved toughness. In contrast to the method disclosed in
JP S61-4896 B - Using the cooling apparatus 1 shown in
Figure 1 , cooling was carried out on API X60 grade steel pipes 2 (in mass %, C: 0.06%, Si: 0.26%, Mn: 1.24%, P: 0.013%, S: 0.001%, Cr: 0.16%, V: 0.06%, a remainder of Fe and impurities, and Ceq: 0.311%) having the outer diameter D, wall thickness t, ratio t/D, and length shown in Table 1 while rotating it at a rotational speed of 60 rpm with the inner surface flow rate (the flow rate of cooling water for cooling the inner surface), the total flow rate on the outer surface (the total flow rate of cooling water for cooling the outer surface), the inner surface advance time (the time interval from the start of inner surface cooling to the start of outer surface cooling), the separation between the streams of outer surface cooling water (the distance in the circumferential direction between 4a and 4b inFigure 1 ), and the angle θ having the values shown in Table 1. The heating temperature of thesteel pipe 2 prior to the start of cooling was 920° C. Thedischarge ports - For comparison, cooling of the
steel pipe 2 was carried out using one stream of cooling water which flowed downwards in a planar shape on the outer surface of thesteel pipe 2. In this case, the discharge port for cooling water was disposed immediately above the uppermost portion of thesteel pipe 2. - The amount of quenching-induced bending which was produced in the
steel pipe 2 after the completion of cooling (in unit of mm/10 m; determined by measuring the amount of bending (mm) with a thread stretched over the overall length of a pipe for the pipe having the largest amount of bending in a lot of pipes undergoing the same heat treatment, and converting this value into the amount of bending per 10 meters) and the maximum fracture appearance transition temperature vTs (the maximum value measured at 4 locations in the circumferential direction of the steel pipe) in a Charpy impact test were determined. - Bending amounts of at most 10 mm are indicated by DOUBLE CIRCLE (ⓞ), bending amounts of greater than 10 mm and at most 20 mm are indicated by CIRCLE (○), bending amounts of greater than 20 mm and at most 30 mm are indicated by TRIANGLE (△), and bending amounts exceeding 30 mm are indicated by X. For the maximum fracture appearance transition temperature vTs in a Charpy impact test, a value of -40° C or below is indicated by CIRCLE, a value of greater than -40° C and at most 0° C is indicated by TRIANGLE, and a value exceeding 0° C is indicated by X. The overall evaluation was whichever of the above two evaluations was the worst, with the highest evaluation being CIRCLE. The results are shown in Table 1.
Table 1 Outer diameter D [mm] Wall thickness t [mm] t/D Length [m] Rotational speed [rpm] Inner surface flow rate [t/hr] Outer surfaces overall flow rate [t/hr] Inner surface cooling advance time [see] Amount of bending [mm/10m] Charpy max. vTs (°C) Outer surface cooling water in planar shape Overall evaluation Run No. Number of streams (flow rate ratio) Spacing [mm] Angle θ [°] 323.9 12.7 0.039 25 60 5400 2800 0 50(X) -30°C(△) 1 0 0 X 1 10 25(△) -30°C(△) 1 0 0 △ 2 20 15(o) -30°C(△) 1 0 0 △ 3 0 47(X) -50°C(○) 2 (1:1) 100 18 X 4 10 20(○) -50°C(○) 2 (1:1) 100 18 ○ 5 20 01(ⓞ) -50°C(○) 2 (1:1) 100 18 ○ 6 20 6(ⓞ) -50°C(○) 2 (5:4) 100 18 ○ 7 406.4 12.7 0.031 25 60 6500 2800 20 10(ⓞ) -30°C(△) 1 0 0 △ 8 5 65(X) -30°C(△) 2 (1:1) 100 14 X 9 7 20(X) -50°C(○) 2 (1:1) 100 14 ○ 10 20 9(ⓞ) -50°C(○) 2(1:1) 100 14 ○ 11 219.1 12.7 0.058 25 60 4500 2800 12 9(ⓞ) -30°C(△) 1 0 0 △ 12 4 17(o) -30°C(△) 2 (1:1) 100 26 △ 13 7 8(ⓞ) -50°C(○) 2 (1:1) 100 26 ○ 14 12 4(ⓞ) -50°C(○) 2 (1:1) 100 26 ○ 15 Note: Flow rate ratio = flow rate on upstream side: flow rate on downstream side - Runs Nos. 5 - 7, 10, 11, 14, and 15 in Table 1 are examples of carrying out cooling by the method according to the present invention (namely, there were two streams of outer surface cooling water, and inner surface cooling was carried out at least 7 seconds in advance). For each example, the amount of bending was CIRCLE or DOUBLE CIRCLE, and even with a thin-walled steel pipe having a t/D ratio of at most 0.07 (i.e., 0.031 to 0.058), quenching-induced bending could be effectively suppressed without decreasing the manufacturing efficiency of a steel pipe. In addition, the Charpy maximum fracture appearance transition temperature (maximum vTs) was -40° C or below, so the toughness was good.
- Runs Nos. 6 and 7 had the same cooling conditions as each other except that the distribution of the flow rate of the two streams of outer surface cooling water was different. Whereas the amount of quenching-induced bending was 10 mm for Run No. 6 in which the flow rates of the two streams of outer surface cooling water were the same, for Run No. 7 in which the flow rate for the stream on the upstream side in the rotational direction of the steel pipe was made larger than the flow rate for the stream on the downstream side, the amount of quenching-induced bending was further decreased to 6 mm.
- In contrast, in Run No. 1 in which there was one stream of outer surface cooling water and inner surface cooling and outer surface cooling were started simultaneously, the amount of quenching-induced bending was too large, and toughness was poor with a maximum vTs of -30° C. In Runs Nos. 2, 3, 8, and 12 in which inner surface cooling began earlier than outer surface cooling but there was one stream of outer surface cooling water, toughness was poor with a maximum vTs of -30° C. In Run No. 4 in which there were two streams of outer surface cooling water but inner surface cooling and outer surface cooling were started simultaneously, the amount of quenching-induced bending was too large. In Runs Nos. 9 and 13 in which there were two streams of outer surface cooling but the advance time of inner surface cooling was shorter than 7 seconds, the amount of quenching-induced bending was relatively large and the toughness was poor with a maximum vTs of -30° C.
Claims (2)
- A method of cooling a steel pipe in which the inner surface and the outer surface of a horizontally-disposed steel pipe are cooled while the steel pipe is rotated in its circumferential direction, characterized in that
cooling of the inner surface of the steel pipe is carried out by spraying cooling water inside the steel pipe,
cooling of the outer surface of the steel pipe is carried out by producing downwards flow of cooling water in a planar shape along the axial direction onto the outer surface of the steel pipe from above at two locations approximately equal distances from the uppermost portion of the steel pipe on both sides of the uppermost portion, wherein the flow rate of cooling water which flows downwards at a location on the upstream side in the rotational direction of the steel pipe is equal to or greater than the flow rate of cooling water which flows downwards at a location on the downstream side in the rotational direction, and
cooling of the inner surface of the steel pipe is started at least 7 seconds before cooling of the outer surface of the steel pipe. - A method of cooling a steel pipe as set forth in claim 1 wherein the ratio of the wall thickness to the outer diameter of the steel pipe is at most 0.07.
Applications Claiming Priority (2)
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JP2006150248A JP2007321178A (en) | 2006-05-30 | 2006-05-30 | Steel pipe cooling method |
PCT/JP2007/061004 WO2007139158A1 (en) | 2006-05-30 | 2007-05-30 | Cooling method of steel pipe |
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EP2039786A1 true EP2039786A1 (en) | 2009-03-25 |
EP2039786A4 EP2039786A4 (en) | 2010-04-07 |
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EP07744417.2A Active EP2039786B1 (en) | 2006-05-30 | 2007-05-30 | Cooling method of thin-walled steel pipe |
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US (1) | US20090183805A1 (en) |
EP (1) | EP2039786B1 (en) |
JP (1) | JP2007321178A (en) |
CN (1) | CN101490286A (en) |
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WO (1) | WO2007139158A1 (en) |
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JP5071537B2 (en) * | 2010-09-02 | 2012-11-14 | 住友金属工業株式会社 | Method of quenching steel pipe and method of manufacturing steel pipe using the same |
CN101962707B (en) * | 2010-10-28 | 2012-05-30 | 攀钢集团钢铁钒钛股份有限公司 | Method for producing 42CrMo steel seamless steel tube |
CN103146901B (en) * | 2013-03-27 | 2015-11-18 | 湖北新冶钢有限公司 | Steel pipe water quenching method |
JP6436473B2 (en) * | 2014-06-30 | 2018-12-12 | トピー工業株式会社 | Heat treatment system and heat treatment method |
CN104775079A (en) * | 2015-03-24 | 2015-07-15 | 天津市精成伟业机器制造有限公司 | Marine highly weldable, large caliber, thick wall and high steel grade seamless steel pipe and preparation technology thereof |
CN107262700A (en) * | 2017-08-03 | 2017-10-20 | 新兴铸管股份有限公司 | Cast tube cooling system |
CN109295294A (en) * | 2018-09-27 | 2019-02-01 | 烟台鲁宝钢管有限责任公司 | A kind of method and dedicated unit mitigating steel pipe heat treatment curvature |
CN111229845B (en) * | 2020-01-15 | 2020-12-29 | 燕山大学 | A large tube section annular cooling device |
CN111023651A (en) * | 2020-02-03 | 2020-04-17 | 江苏百利达钢丸有限公司 | Cooling device for steel shot production |
CN118345235B (en) * | 2024-06-17 | 2024-09-06 | 延津县通达铸钢工业制造有限公司 | Heat treatment equipment for producing steel castings and production process thereof |
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- 2007-05-30 MX MX2008015180A patent/MX2008015180A/en unknown
- 2007-05-30 WO PCT/JP2007/061004 patent/WO2007139158A1/en active Application Filing
- 2007-05-30 CN CNA2007800274724A patent/CN101490286A/en active Pending
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2008
- 2008-12-01 US US12/292,922 patent/US20090183805A1/en not_active Abandoned
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JPH01121628A (en) * | 1987-11-04 | 1989-05-15 | Matsushita Electric Ind Co Ltd | Ignition heater |
JPH08319516A (en) * | 1995-05-23 | 1996-12-03 | Sumitomo Metal Ind Ltd | Method and apparatus for cooling tubular body |
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JP2007321178A (en) | 2007-12-13 |
EP2039786B1 (en) | 2017-06-21 |
CN101490286A (en) | 2009-07-22 |
WO2007139158A1 (en) | 2007-12-06 |
MX2008015180A (en) | 2009-02-11 |
EP2039786A4 (en) | 2010-04-07 |
US20090183805A1 (en) | 2009-07-23 |
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