EP1837722B1 - Mikromechanisches Bauteil aus Isoliermaterial und Herstellungsverfahren dafür - Google Patents
Mikromechanisches Bauteil aus Isoliermaterial und Herstellungsverfahren dafür Download PDFInfo
- Publication number
- EP1837722B1 EP1837722B1 EP07104385.5A EP07104385A EP1837722B1 EP 1837722 B1 EP1837722 B1 EP 1837722B1 EP 07104385 A EP07104385 A EP 07104385A EP 1837722 B1 EP1837722 B1 EP 1837722B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- balance
- conductive material
- insulating material
- micro
- silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011810 insulating material Substances 0.000 title claims description 12
- 238000000034 method Methods 0.000 title description 7
- 238000004519 manufacturing process Methods 0.000 title description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000004020 conductor Substances 0.000 claims description 13
- 229910052710 silicon Inorganic materials 0.000 claims description 11
- 239000010703 silicon Substances 0.000 claims description 11
- 230000008021 deposition Effects 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 5
- 239000010931 gold Substances 0.000 claims description 5
- 229910052737 gold Inorganic materials 0.000 claims description 5
- 239000007769 metal material Substances 0.000 claims description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 229920001940 conductive polymer Polymers 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 229910052703 rhodium Inorganic materials 0.000 claims description 3
- 239000010948 rhodium Substances 0.000 claims description 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 2
- 238000000151 deposition Methods 0.000 description 6
- 238000004544 sputter deposition Methods 0.000 description 4
- 239000002131 composite material Substances 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000005468 ion implantation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- 238000001020 plasma etching Methods 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 238000005459 micromachining Methods 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000003631 wet chemical etching Methods 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B15/00—Escapements
- G04B15/14—Component parts or constructional details, e.g. construction of the lever or the escape wheel
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B17/00—Mechanisms for stabilising frequency
- G04B17/04—Oscillators acting by spring tension
- G04B17/06—Oscillators with hairsprings, e.g. balance
- G04B17/063—Balance construction
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B17/00—Mechanisms for stabilising frequency
- G04B17/04—Oscillators acting by spring tension
- G04B17/06—Oscillators with hairsprings, e.g. balance
- G04B17/066—Manufacture of the spiral spring
Definitions
- the present invention relates to a micro-mechanical part made of an insulating material, and more particularly to a fixed or mobile part of a watch movement whose proximity to other parts does not disturb the operation of a moving part, directly, or indirectly by the attraction of particles.
- Insulating materials such as silicon and its compounds, quartz, diamond, glass, ceramics or others are increasingly used to make micro-mechanical parts, whether fixed parts , such as plates or bridges, or moving parts for example part of the drive train, or the control system such as the balance spring, balance or exhaust.
- the document EP 1 422 436 discloses the manufacture of a spiral spring from the cutting of a monocrystalline silicon plate.
- the coil spring has a silicon oxide coating to minimize thermal drift.
- the document EP 1 482 282 discloses an electronic movement with a display means detecting means for automatically correcting undue movements of the display means.
- the present invention therefore aims to provide a solution to the problem mentioned above by providing a fixed or mobile micro-mechanical part made of an insulating material whose surface treatment avoids the risk of bonding.
- the invention relates to a micro-mechanical part made of an insulating material, such as silicon, and its compounds, diamond, glass, ceramic or other, all or part of its surface is coated with a thin deposit of an electrically conductive material such as a layer of a metallic material or a conductive non-metallic material.
- the conductive deposit preferably has a thickness of less than 50 nm. This very thin deposit invisible to the naked eye, but detectable by the current means of analysis eliminates the risk of attraction and bonding by a neighboring room, this attraction may be due to may be due to friction or tension that can create electrostatic charges in the room.
- This deposit may be performed on a piece of insulating material monoblock or composite, that is to say, at least the outer surface is of insulating material.
- the stainless and amagnetic metals such as gold, platinum, rhodium and palladium are preferably chosen.
- non-metallic conductive materials one will preferably choose one of the group comprising graphite, carbon, doped silicon, and conductive polymers. These metals can be deposited by known methods making it possible to control the thickness by adjusting the operating conditions, for example by sputtering, PVD, doping, ion implantation or by an electrolytic process. The same techniques can be used to deposit conductive non-metallic materials.
- said micro-mechanical part is a part of the kinematic chain of a watch movement, such as a hairspring, an anchor, an escape wheel or a toothed wheel, or any which other fixed part may for example be the bearing of the axis of a mobile.
- a hairspring which is the most sensitive part of a watch movement.
- the invention also relates to a timepiece incorporating such a micro-mechanical part.
- the invention will be more particularly illustrated by a sprung balance adjusting device shown in FIG. figure 1 , in which the spiral 1 is made, for example, of silicon, by adapting the micro-machining processes used in the manufacture of integrated circuits or accelerometers from a silicon wafer or other amorphous or crystalline insulating material.
- wet chemical etching, plasma dry machining or reactive ion etching (RIE) can be carried out using masks appropriate to the desired contour for the hairspring.
- the same silicon wafer makes it possible to manufacture a batch of spirals whose characteristics are determined by the thickness of the wafer and the shape of the masks, said characteristics being calculated for operation of the spiral in a plane.
- the turns 11 deviate from their normal position shown in dotted lines by being attracted by the cock 9 and can even stick to it, which obviously disturbs the normal walking, that is to say to say a march having only movements of extension / contraction in a plane.
- the material used is preferably a stainless and non-magnetic metal such as gold, platinum, rhodium, palladium, when it is a metallic conductive material.
- This deposition can be carried out by means of various known methods, such as sputtering, PVD deposition, ion implantation or electroplating.
- a gold deposit of 15 nm has been carried out by "sputtering", that is to say by performing a cathodic sputtering under vacuum, with a gold target, by applying a current of 60 mA for 15 seconds.
- a non-metallic conductive material When a non-metallic conductive material is deposited, it will preferably be chosen from the group comprising graphite, carbon, doped silicon, and conducting polymers and deposition techniques and thicknesses as mentioned above will be used.
- a silicon spiral has just been described, but other non-conductive amorphous or crystalline materials may also be used, as indicated above, and be treated with a surface metallization avoiding the risk of attraction or sticking.
- a composite material to produce for example a hairspring having a silicon core and a thick coating of silicon dioxide on which the deposition of conductive material of small thickness will be performed.
- a “composite material” may also include a metal core embedded in an insulating material.
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Micromachines (AREA)
Claims (8)
- Spirale, die aus wenigstens einem Isoliermaterial verwirklicht ist und dazu bestimmt ist, in ein Uhrwerk integriert zu werden, wobei das Isoliermaterial einen Siliciumkern enthält, auf dem eine Beschichtung aus Siliciumdioxid gebildet ist, die eine Dicke von mehr als 50 nm hat, dadurch gekennzeichnet, dass die Spirale auf ihrer gesamten Oberfläche oder auf einem Teil hiervon mit einer Ablagerung eines elektrisch leitenden Materials beschichtet ist.
- Spirale nach dem vorhergehenden Anspruch, dadurch gekennzeichnet, dass das elektrisch leitende Material ein metallisches Material ist.
- Spirale nach dem vorhergehenden Anspruch, dadurch gekennzeichnet, dass das metallische Material aus Gold, Platin, Rhodium und Palladium gewählt ist.
- Spirale nach Anspruch 1, dadurch gekennzeichnet, dass das elektrisch leitende Material ein nichtmetallisches Material ist.
- Spirale nach dem vorhergehenden Anspruch, dadurch gekennzeichnet, dass das nichtmetallische Material aus Graphit, Kohlenstoff, dotiertem Silicium und leitenden Polymeren gewählt ist.
- Spirale nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Ablagerung des elektrisch leitenden Materials eine Dicke von weniger als 50 nm hat.
- Spirale nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Ablagerung des elektrisch leitenden Materials eine Dicke im Bereich von 10 bis 20 nm hat.
- Zeitmessgerät, das eine Spirale nach einem der vorhergehenden Ansprüche enthält.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07104385.5A EP1837722B1 (de) | 2006-03-24 | 2007-03-19 | Mikromechanisches Bauteil aus Isoliermaterial und Herstellungsverfahren dafür |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06111727A EP1837721A1 (de) | 2006-03-24 | 2006-03-24 | Mikromechanisches Bauteil aus Isoliermaterial und Herstellungsverfahren dafür |
CH00595/06A CH707669B1 (fr) | 2006-04-10 | 2006-04-10 | Pièce de micro-mécanique en matériau électriquement isolant ou en silicium ou un de ses composés et son procédé de fabrication. |
EP07104385.5A EP1837722B1 (de) | 2006-03-24 | 2007-03-19 | Mikromechanisches Bauteil aus Isoliermaterial und Herstellungsverfahren dafür |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1837722A2 EP1837722A2 (de) | 2007-09-26 |
EP1837722A3 EP1837722A3 (de) | 2008-06-04 |
EP1837722B1 true EP1837722B1 (de) | 2016-02-24 |
Family
ID=38442240
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07104385.5A Active EP1837722B1 (de) | 2006-03-24 | 2007-03-19 | Mikromechanisches Bauteil aus Isoliermaterial und Herstellungsverfahren dafür |
Country Status (1)
Country | Link |
---|---|
EP (1) | EP1837722B1 (de) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008029429A1 (de) * | 2007-10-18 | 2009-04-23 | Konrad Damasko | Verfahren zum Herstellen von mechanischen Funktionselementen für Uhrwerke sowie nach diesem Verfahren hergestelltes Funktionselement |
CH699494B1 (fr) | 2007-11-28 | 2010-09-30 | Manuf Et Fabrique De Montres E | Oscillateur mécanique présentant un coefficient thermoélastique optimisé et procédé de fabrication d'un tel oscillateur. |
EP2104007A1 (de) | 2008-03-20 | 2009-09-23 | Nivarox-FAR S.A. | Monoblockspirale aus Material auf Siliziumbasis und ihr Herstellungsverfahren |
EP2104008A1 (de) | 2008-03-20 | 2009-09-23 | Nivarox-FAR S.A. | Monoblock-Regulierungsorgan und sein Herstellungsverfahren |
EP2104005A1 (de) | 2008-03-20 | 2009-09-23 | Nivarox-FAR S.A. | Composite-Unruh und Herstellungsverfahren dafür |
EP2104006B1 (de) | 2008-03-20 | 2010-07-14 | Nivarox-FAR S.A. | Monoblock-Doppelspirale und ihr Herstellungsverfahren |
EP2105807B1 (de) | 2008-03-28 | 2015-12-02 | Montres Breguet SA | Monoblockspirale zur Erhöhung der Kurve und ihr Herstellungsverfahren |
CH699882A2 (fr) | 2008-11-06 | 2010-05-14 | Montres Breguet Sa | Spiral à élévation de courbe en matériau micro-usinable. |
US10324419B2 (en) | 2009-02-06 | 2019-06-18 | Domasko GmbH | Mechanical oscillating system for a clock and functional element for a clock |
EP3101484A1 (de) * | 2009-02-06 | 2016-12-07 | DAMASKO GmbH | Mechanisches schwingsystem für uhren und verfahren zum herstellen eines mechanischen schwingsystems für uhren |
CH703172B1 (fr) | 2010-05-18 | 2014-11-14 | Montres Breguet Sa | Spiral à élévation de courbe en silicium. |
EP2920653A1 (de) | 2012-11-16 | 2015-09-23 | Nivarox-FAR S.A. | Resonator mit geringerer empfindlichkeit gegenüber klimatischen schwankungen |
EP2781968A1 (de) * | 2013-03-19 | 2014-09-24 | Nivarox-FAR S.A. | Resonator, der weniger empfindlich gegenüber klimatischen Schwankungen ist |
HK1209578A2 (en) | 2015-02-17 | 2016-04-01 | Master Dynamic Limited | Silicon hairspring |
JP6629854B2 (ja) | 2015-06-15 | 2020-01-15 | シチズン時計株式会社 | 時計の調速装置 |
EP3534222A1 (de) * | 2018-03-01 | 2019-09-04 | Rolex Sa | Herstellungsverfahren eines thermokompensierten oszillators |
EP3742237B1 (de) | 2019-05-23 | 2024-10-16 | Nivarox-FAR S.A. | Komponente, insbesondere für uhrwerk mit einer oberflächentopologie, und ihr herstellungsverfahren |
EP3859449A1 (de) * | 2020-01-30 | 2021-08-04 | ETA SA Manufacture Horlogère Suisse | Leitende schnur für spirale |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020060954A1 (en) * | 1999-04-21 | 2002-05-23 | Konrad Schafroth | Watch movement with a microgenerator and method for testing watch movements |
EP1482282A1 (de) * | 2002-03-04 | 2004-12-01 | Citizen Watch Co., Ltd. | Elektrische uhr |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2731715B1 (fr) * | 1995-03-17 | 1997-05-16 | Suisse Electronique Microtech | Piece de micro-mecanique et procede de realisation |
WO1999036941A2 (en) * | 1998-01-15 | 1999-07-22 | Cornell Research Foundation, Inc. | Trench isolation for micromechanical devices |
DE10055421A1 (de) * | 2000-11-09 | 2002-05-29 | Bosch Gmbh Robert | Verfahren zur Erzeugung einer mikromechanischen Struktur und mikromechanische Struktur |
KR100468853B1 (ko) * | 2002-08-30 | 2005-01-29 | 삼성전자주식회사 | 절연 물질에 구현된 mems 콤브 액추에이터와 그제조방법 |
AU2003205503A1 (en) * | 2002-09-25 | 2004-04-19 | Fore Eagle Co Ltd | Mechanical parts |
DE60206939T2 (de) * | 2002-11-25 | 2006-07-27 | Csem Centre Suisse D'electronique Et De Microtechnique S.A. | Spiraluhrwerkfeder und Verfahren zu deren Herstellung |
-
2007
- 2007-03-19 EP EP07104385.5A patent/EP1837722B1/de active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020060954A1 (en) * | 1999-04-21 | 2002-05-23 | Konrad Schafroth | Watch movement with a microgenerator and method for testing watch movements |
EP1482282A1 (de) * | 2002-03-04 | 2004-12-01 | Citizen Watch Co., Ltd. | Elektrische uhr |
Also Published As
Publication number | Publication date |
---|---|
EP1837722A3 (de) | 2008-06-04 |
EP1837722A2 (de) | 2007-09-26 |
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