EP1708829A1 - Verfahren zur entfernung einer schicht - Google Patents
Verfahren zur entfernung einer schichtInfo
- Publication number
- EP1708829A1 EP1708829A1 EP05700980A EP05700980A EP1708829A1 EP 1708829 A1 EP1708829 A1 EP 1708829A1 EP 05700980 A EP05700980 A EP 05700980A EP 05700980 A EP05700980 A EP 05700980A EP 1708829 A1 EP1708829 A1 EP 1708829A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- removal area
- removal
- component
- damage
- area
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 51
- 230000007797 corrosion Effects 0.000 claims abstract description 51
- 238000005260 corrosion Methods 0.000 claims abstract description 51
- 150000003839 salts Chemical class 0.000 claims abstract description 15
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 4
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 claims abstract description 3
- 238000002485 combustion reaction Methods 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 11
- 239000000758 substrate Substances 0.000 claims description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000004140 cleaning Methods 0.000 claims description 8
- 239000010941 cobalt Substances 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 6
- 230000035939 shock Effects 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 238000005488 sandblasting Methods 0.000 claims description 4
- 229910000601 superalloy Inorganic materials 0.000 claims description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 2
- 229940044175 cobalt sulfate Drugs 0.000 claims description 2
- 229910000361 cobalt sulfate Inorganic materials 0.000 claims description 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 230000032798 delamination Effects 0.000 claims description 2
- 230000005674 electromagnetic induction Effects 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 2
- 150000002910 rare earth metals Chemical class 0.000 claims description 2
- -1 salt sodium sulfate Chemical class 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims 2
- 230000008018 melting Effects 0.000 claims 2
- 238000010306 acid treatment Methods 0.000 claims 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract description 3
- 239000007832 Na2SO4 Substances 0.000 abstract 1
- 238000007796 conventional method Methods 0.000 abstract 1
- 230000035484 reaction time Effects 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 15
- 239000002253 acid Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000009413 insulation Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000011241 protective layer Substances 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 238000009419 refurbishment Methods 0.000 description 2
- 229910000679 solder Inorganic materials 0.000 description 2
- 239000012720 thermal barrier coating Substances 0.000 description 2
- 238000006424 Flood reaction Methods 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005566 electron beam evaporation Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B7/00—Cleaning by methods not provided for in a single other subclass or a single group in this subclass
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
Definitions
- the invention relates to a method for removing a layer according to claim 1.
- Turbine blades for example, have corrosion products such as e.g. Oxides, sulfides, nitrides, carbides, phosphates, etc., which form a layer.
- Such components can be used again after their use, if, among other things. the corrosion products have been removed.
- the complete removal of the corrosion products is done, for example, by sandblasting, but this can damage the substrate.
- US Pat. No. 5,575,858 describes a method for removing a removal area, in particular a corrosion product of a component, in which the removal area is pretreated before final cleaning, so that the removal area is damaged, so that an erosion rate in the final cleaning of the removal area is greater than without damaging the range.
- the object is achieved by a method according to claim 1.
- FIG. 1 shows a component with a corrosion product
- FIG. 6 shows a gas turbine
- FIG. 7 a combustion chamber
- Figure 8 is a turbine blade
- Figure 9 is a steam turbine.
- Figure 1 shows a component 1, which with the invention
- the component 1 consists of a ceramic or metallic substrate 4 (base body) which, for example, is a cobalt, iron or nickel-based superalloy, in particular for turbines.
- Component 1 is, for example, a guide vane or rotor blade 120 (FIGS. 6, 8), a gas 100 (FIG. 6), a steam turbine 300, 303 (FIG. 9), or an aircraft turbine, a combustion chamber lining 155 (FIG. 7) or another component of a turbine subjected to hot gas.
- the component 1 can either be newly manufactured or remanufactured.
- Refurbishment means that components 1 may be separated from layers (thermal insulation layer) after their use, and corrosion and oxidation products removed. Cracks may still need to be repaired. Such a component 1 can then be coated again; this is particularly advantageous since the base body is very expensive.
- the component 1 can have at least one ceramic or metallic layer on the surface 13 for use, such as an MCrAlX layer and / or a thermal insulation layer lying thereon, which can be roughly removed in a first process step.
- the MCrAlX layer can also represent the removal area 10, which is treated with the method according to the invention.
- the removal area 10 is considered as a corrosion product 10 (corrosion layer 10).
- the removal area 10 can also be a functional layer without corrosion products.
- the removal area 10 can be a metallic and / or ceramic layer, wherein the layer can be metallic and has corrosion products.
- the corrosion product 10 for example an oxide, a sulfide, a nitride, a phosphide or a carbide etc., can be present on a surface 13 of the component 1 or in a crack 7 of the component 1.
- the corrosion products 10 must be removed from the crack 7 or from the surface 13 so that the crack 7 can be filled with a solder or weld metal and the surface 13 can be coated again. Corrosion products 10 would otherwise have good solder adhesion or renewed adhesion Prevent or at least reduce the coating.
- the corrosion product 10 according to the prior art has a certain removal rate (mass per time) when it is cleaned, for example, by the FIC method.
- this removal rate is too low and can even be zero after a certain time.
- FIG. 2 shows schematically the implementation of the method according to the invention.
- a material 16 for example a salt 16 is applied, which can react chemically with the corrosion product 10 in order to damage the removal area 10.
- Na 2 S0 4 (sodium sulfate) and / or CoS0 (cobalt sulfate) is preferably used as the salt.
- Other salts or combinations are conceivable.
- the corrosion products aluminum oxide and / or cobalt oxide and / or titanium oxide of the metals titanium, aluminum and / or cobalt, which are contained in the alloy (for example superalloy) of the substrate 4, can be removed very well.
- a molten salt can be applied directly in the crack 7 or on the corrosion product 10 or the component 1 is immersed in a molten salt.
- the salt 16 can, for example, be locally heated, for example by means of a laser 19 and its laser beams 22, so that a chemical reaction of the salt 16 with the corrosion product 10 or a thermal shock takes place.
- the heating can also be carried out by electromagnetic induction, in particular when the substrate 4 is metallic.
- the component 1 can be heated locally by means of induction or by means of a light source, for example using a laser, for example, in that the laser 19 only radiates into the crack 7 with the laser beam 22.
- Local heating can also be carried out using tunable microwaves. Tunable means that, among other things, the wavelength and intensity can be changed.
- FIG. 3 shows a component 1 with a corrosion product 10 after the corrosion product 10 has been damaged by a pretreatment according to the invention.
- the pretreatment produces cracks 25 which extend from the surface 14 of the layer 10 in the direction of the substrate 4, so that there is a larger contact surface of the corrosion product 10 with the acid and / or the fluorine ions etc.
- Such cracks 25 can also be produced by means of laser jets, high pressure water jets, sand blasting, in particular with coarse grains.
- the intensity and duration of the sandblasting treatment must be set so that the substrate 4 is not reached and the corrosion product 10 is only partially removed.
- component 1 is subjected to a final cleaning by means of an acid or fluorine ion treatment, which is carried out to completely remove the
- Corrosion product 10 leads because the damage to the corrosion product 10 significantly increases the rate of removal in the FIC or another method and there is no significant reduction in the rate of removal over time.
- FIG. 4 shows a further possibility of damaging the corrosion product 10.
- the corrosion product 10, which rests on a surface 13 of the substrate 4, is subjected to a thermal shock.
- the thermal shock can be done by immersion in a hot metal or salt bath or by rapid heating using electron beams or a laser 28.
- the corrosion product 10 can also be partially melted.
- FIG. 5 shows further damage in the corrosion product 10 according to the method according to the invention. If, for example, the material of the corrosion product 10 has been melted, the material contracts again when it cools down, so that mechanical stresses occur which may lead to crack formation.
- cracks 31 can also be generated within the corrosion product 10.
- delaminations 34 can form between the corrosion product 10 and a surface 13 on which the corrosion product 10 rests.
- FIG. 6 shows an example of a gas turbine 100 in a partial longitudinal section.
- the gas turbine 100 has on the inside a rotor 103 which is rotatably mounted about an axis of rotation 102 and is also referred to as a turbine rotor.
- Combustion chamber 110 in particular ring combustion chamber 106, with multiple ren coaxially arranged burners 107, a turbine 108 and the exhaust housing 109.
- the annular combustion chamber 106 communicates with an annular hot gas channel 111, for example.
- annular hot gas channel 111 for example.
- turbine stages 112 connected in series form the turbine 108.
- Each turbine stage 112 is formed from two blade rings. Seen in the flow direction of a working medium 113, a row 125 of guide vanes is followed by a row 125 formed from rotor blades 120 in the hot gas channel 111.
- the guide vanes 130 are fastened to an inner housing 138 of a stator 143, whereas the rotor blades 120 of a row 125 are attached to the rotor 103, for example by means of a turbine disk 133.
- a generator or a work machine (not shown) is coupled to the rotor 103.
- the compressor 105 draws in and compresses air 135 through the intake housing 104.
- the compressed air provided at the turbine end of the compressor 105 is led to the burners 107 and mixed there with a fuel.
- the mixture is then burned in the combustion chamber 110 to form the working medium 113.
- the working medium 113 flows along the hot gas channel 111 past the guide vanes 130 and the moving blades 120.
- the working medium 113 relaxes in a pulse-transmitting manner on the moving blades 120, so that the rotating blades 120 drive the rotor 103 and the working machine coupled to it ,
- the components exposed to the hot working medium 113 are subject to thermal loads during the operation of the gas turbine 100.
- the guide vanes 130 and rotor blades 120 of the first turbine stage 112, as seen in the flow direction of the working medium 113, are next to the annular combustion chamber 106 lining heat shield stones most thermally stressed.
- the substrates can have a directional structure, ie they are single-crystal (SX structure) or only have longitudinal grains (DS structure). Iron, nickel or cobalt-based super alloys are used as the material.
- the blades 120, 130 can have coatings against corrosion (MCrAlX; M is at least one element from the group iron (Fe), cobalt (Co), nickel (Ni), X stands for yttrium (Y) and / or at least one element of the rare Earth) and heat through a thermal barrier coating.
- the thermal barrier coating is, for example, Zr0 2 , Y 2 0 4 -Zr0 2 , ie it is not, partially or completely stabilized by yttrium oxide and / or calcium oxide and / or magnesium oxide.
- Appropriate coating processes such as electron beam evaporation (EB-PVD) produce stalk-shaped grains in the thermal insulation layer.
- EB-PVD electron beam evaporation
- corrosion products 10 can form on the component.
- the corrosion products must be removed using the method according to the invention if the component is to be newly coated.
- the guide vane 130 has a guide vane foot (not shown here) facing the inner casing 138 of the turbine 108 and a guide vane head opposite the guide vane foot.
- the guide vane head faces the rotor 103 and is fixed to a fastening ring 140 of the stator 143.
- FIG. 7 shows a combustion chamber 110 of a gas turbine.
- the combustion chamber 110 is configured, for example, as a so-called annular combustion chamber, in which a plurality of burners 102 arranged in the circumferential direction around the turbine shaft 103 open into a common combustion chamber space.
- combustion chamber 110 is configured in its entirety as an annular structure which is positioned around the turbine shaft 103.
- the combustion chamber 110 is designed for a comparatively high temperature of the working medium M of approximately 1000 ° C. to 1600 ° C.
- the combustion chamber wall 153 is provided on its side facing the working medium M with an inner lining formed from heat shield elements 155.
- Each heat shield element 155 is equipped on the working medium side with a particularly heat-resistant protective layer or is made of high-temperature resistant material. Due to the high temperatures inside the combustion chamber 110, a cooling system is also provided for the heat shield elements 155 or for their holding elements.
- the materials of the combustion chamber wall and their coatings can be similar to the turbine blades 120, 130.
- the combustion chamber 110 is designed in particular for the detection of losses of the heat shield elements 155.
- a number of temperature sensors 158 are positioned between the combustion chamber wall 153 and the heat shield elements 155.
- FIG. 8 "' shows a perspective view of a blade 120, 130 which extends along a longitudinal axis 121.
- the blade 120, 130 has, in succession along the longitudinal axis 121, a fastening area 400, one on it adjacent vane platform 403 and an airfoil area 406.
- a blade root 183 is formed in the fastening area 400 and serves to fasten the moving blades 120, 130 to the shaft.
- the blade root 183 is designed as a hammer head. Other configurations, for example as a fir tree or dovetail foot, are possible.
- solid metal materials are used in all areas 400, 403, 406 of the rotor blades 120, 130.
- the rotor blade 120, 130 can be manufactured by a casting process, a forging process, a milling process or combinations thereof.
- FIG. 9 shows an example of a steam turbine 300, 303 with a turbine shaft 309 extending along an axis of rotation 306.
- the steam turbine has a high-pressure sub-turbine 300 and a medium-pressure sub-turbine 303, each with an inner housing 312 and an outer housing 315 enclosing this.
- the high-pressure turbine section 300 is, for example, of a pot design.
- the medium pressure turbine section 303 is designed with two passages. It is also possible for the medium-pressure turbine section 303 to be single-flow.
- a bearing 318 is arranged along the axis of rotation 306 between the high-pressure sub-turbine 300 and the medium-pressure sub-turbine 303, the turbine shaft 309 having a bearing region 321 in the bearing 318.
- the turbine shaft 309 is supported on a further bearing 324 next to the high-pressure sub-turbine 300.
- the high-pressure turbine section 300 has a shaft seal 345.
- the turbine shaft 309 is sealed off from the outer housing 315 of the medium-pressure turbine part 303 by two further shaft seals 345.
- the turbine shaft 309 in the high-pressure sub-turbine 300 has the high-pressure rotor blades 354, 357.
- This high pressure barrel inspection Filling 354, 357 with the associated blades, not shown, represents a first blading area 360.
- the medium-pressure turbine section 303 has a central steam inflow area 333.
- the turbine shaft 309 Associated with the steam inflow region 333, the turbine shaft 309 has a radial-mechanical shaft shield 363, a cover plate, on the one hand for dividing the steam flow into the two floods of the medium-pressure turbine section 303 and for preventing direct contact of the hot steam with the turbine shaft 309.
- the turbine shaft 309 has a second blading area 366 with the medium-pressure rotor blades 354, 342 in the medium-pressure turbine part 303.
- the hot steam flowing through the second blading region 366 flows from the medium-pressure sub-turbine 303 from an outflow connection 369 to a low-pressure sub-turbine, not shown, which is connected downstream in terms of flow technology.
- the components of the steam turbine 300, 303 also have protective layers and / or corrosion products 10 which are removed using the method according to the invention before the components can be reprocessed.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05700980A EP1708829B1 (de) | 2004-01-30 | 2005-01-17 | Verfahren zur entfernung einer schicht |
EP07010914A EP1818112A3 (de) | 2004-01-30 | 2005-01-17 | Verfahren zur Entfernung einer Schicht |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04002158A EP1559485A1 (de) | 2004-01-30 | 2004-01-30 | Verfahren zur Entfernung einer Schicht |
EP05700980A EP1708829B1 (de) | 2004-01-30 | 2005-01-17 | Verfahren zur entfernung einer schicht |
PCT/EP2005/000405 WO2005072884A1 (de) | 2004-01-30 | 2005-01-17 | Verfahren zur entfernung einer schicht |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07010914A Division EP1818112A3 (de) | 2004-01-30 | 2005-01-17 | Verfahren zur Entfernung einer Schicht |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1708829A1 true EP1708829A1 (de) | 2006-10-11 |
EP1708829B1 EP1708829B1 (de) | 2009-03-11 |
Family
ID=34639430
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04002158A Withdrawn EP1559485A1 (de) | 2004-01-30 | 2004-01-30 | Verfahren zur Entfernung einer Schicht |
EP07010914A Withdrawn EP1818112A3 (de) | 2004-01-30 | 2005-01-17 | Verfahren zur Entfernung einer Schicht |
EP05700980A Expired - Lifetime EP1708829B1 (de) | 2004-01-30 | 2005-01-17 | Verfahren zur entfernung einer schicht |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04002158A Withdrawn EP1559485A1 (de) | 2004-01-30 | 2004-01-30 | Verfahren zur Entfernung einer Schicht |
EP07010914A Withdrawn EP1818112A3 (de) | 2004-01-30 | 2005-01-17 | Verfahren zur Entfernung einer Schicht |
Country Status (5)
Country | Link |
---|---|
US (1) | US20070170150A1 (de) |
EP (3) | EP1559485A1 (de) |
CN (1) | CN1929931A (de) |
DE (1) | DE502005006806D1 (de) |
WO (1) | WO2005072884A1 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN117758275A (zh) * | 2023-12-18 | 2024-03-26 | 深圳美荣达技术有限公司 | 钛铝复合材料镭雕后去除镭雕灰的清洗剂和其制备方法及应用,以及清洗方法 |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1559485A1 (de) * | 2004-01-30 | 2005-08-03 | Siemens Aktiengesellschaft | Verfahren zur Entfernung einer Schicht |
DE102004061269A1 (de) * | 2004-12-10 | 2006-06-14 | Siemens Ag | Verfahren zum Reinigen eines Werkstückes mit Halogenionen |
DE102006030364A1 (de) * | 2006-06-27 | 2008-01-03 | Siemens Ag | Verfahren zum Entfernen einer Schutzbeschichtung von einem Bauteil |
KR100840902B1 (ko) | 2007-03-20 | 2008-06-24 | 주식회사 에이팩 | 마이크로웨이브를 이용한 광디스크의 반사층 박리장치 |
PL2147138T3 (pl) | 2007-05-24 | 2015-11-30 | Oerlikon Textile Gmbh & Co Kg | Zespół mechanizmu rozciągowego, bądź mechanizm rozciągowy, i sposób jego eksploatacji |
DE102008005168A1 (de) * | 2008-01-19 | 2009-07-23 | Mtu Aero Engines Gmbh | Verfahren zum zumindest selektiven Entfernen einer ersten Schicht von einem Triebwerksbauteil |
ES2367855T3 (es) * | 2008-12-17 | 2011-11-10 | Saab Ab | Restauración de la fuerza y de la resistencia al desgaste de un compuesto de matriz metálica (mmc). |
SG165202A1 (en) * | 2009-03-25 | 2010-10-28 | United Technologies Corp | Method and apparatus for cleaning a component using microwave radiation |
EP2327813A1 (de) * | 2009-11-11 | 2011-06-01 | Siemens Aktiengesellschaft | Verstärkte Fluor-Ionen-Reinigung von verunreinigten Rissen |
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-
2005
- 2005-01-17 DE DE502005006806T patent/DE502005006806D1/de not_active Expired - Fee Related
- 2005-01-17 US US10/587,702 patent/US20070170150A1/en not_active Abandoned
- 2005-01-17 EP EP07010914A patent/EP1818112A3/de not_active Withdrawn
- 2005-01-17 WO PCT/EP2005/000405 patent/WO2005072884A1/de active Application Filing
- 2005-01-17 EP EP05700980A patent/EP1708829B1/de not_active Expired - Lifetime
- 2005-01-17 CN CNA2005800079667A patent/CN1929931A/zh active Pending
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CN117758275A (zh) * | 2023-12-18 | 2024-03-26 | 深圳美荣达技术有限公司 | 钛铝复合材料镭雕后去除镭雕灰的清洗剂和其制备方法及应用,以及清洗方法 |
Also Published As
Publication number | Publication date |
---|---|
EP1818112A3 (de) | 2007-09-12 |
DE502005006806D1 (de) | 2009-04-23 |
WO2005072884A1 (de) | 2005-08-11 |
EP1708829B1 (de) | 2009-03-11 |
EP1818112A2 (de) | 2007-08-15 |
CN1929931A (zh) | 2007-03-14 |
US20070170150A1 (en) | 2007-07-26 |
EP1559485A1 (de) | 2005-08-03 |
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