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EP1541751B1 - Utilisation de polymères stabilisées au moyen de colloides protecteurs en tant que revêtements à point double - Google Patents

Utilisation de polymères stabilisées au moyen de colloides protecteurs en tant que revêtements à point double Download PDF

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Publication number
EP1541751B1
EP1541751B1 EP03028481A EP03028481A EP1541751B1 EP 1541751 B1 EP1541751 B1 EP 1541751B1 EP 03028481 A EP03028481 A EP 03028481A EP 03028481 A EP03028481 A EP 03028481A EP 1541751 B1 EP1541751 B1 EP 1541751B1
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EP
European Patent Office
Prior art keywords
vinyl
use according
polymer
acid
protective colloid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP03028481A
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German (de)
English (en)
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EP1541751A1 (fr
Inventor
Gertrud Dr. Schönmann
Peter Dr. Weiler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dr Th Boehme KG Chemie Fabrik GmbH and Co
Original Assignee
Dr Th Boehme KG Chemie Fabrik GmbH and Co
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Filing date
Publication date
Priority to EP03028481A priority Critical patent/EP1541751B1/fr
Application filed by Dr Th Boehme KG Chemie Fabrik GmbH and Co filed Critical Dr Th Boehme KG Chemie Fabrik GmbH and Co
Priority to ES03028481T priority patent/ES2259747T3/es
Priority to AT03028481T priority patent/ATE321909T1/de
Priority to DE50302798T priority patent/DE50302798D1/de
Priority to US10/582,072 priority patent/US20070128362A1/en
Priority to PCT/EP2004/013642 priority patent/WO2005059238A1/fr
Priority to KR1020067011386A priority patent/KR20060121165A/ko
Publication of EP1541751A1 publication Critical patent/EP1541751A1/fr
Application granted granted Critical
Publication of EP1541751B1 publication Critical patent/EP1541751B1/fr
Anticipated expiration legal-status Critical
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00—Producing multi-layer textile fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00—Producing multi-layer textile fabrics
    • D06M17/04—Producing multi-layer textile fabrics by applying synthetic resins as adhesives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0092—Non-continuous polymer coating on the fibrous substrate, e.g. plastic dots on fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00—Condition, form or state of the materials
    • D06N2205/02—Dispersion
    • D06N2205/023—Emulsion, aqueous dispersion, latex

Definitions

  • the invention relates to the use of a protective colloid-stabilized polymer for coating a carrier material.
  • such a material may be coated with a hot melt adhesive and then bonded to a second material placed thereon.
  • a hot melt adhesive is coated with a hot melt adhesive and then bonded to a second material placed thereon.
  • One possible coating is the so-called double dot coating.
  • a sub-item is first printed on the material to be coated. This printing can be done by rotary screen printing.
  • the sub-item is a paste comprising an aqueous dispersion of an emulsifier-stabilized polymer, thickener and, optionally, printing assistant.
  • hot melt glue is scattered. Excess powder is sucked off. Thereafter, the sub-item is first dried and sintered with the hot melt adhesive, or the hot melt adhesive is melted.
  • a coated sheet which comprises a coating carrier (also referred to herein as a carrier material), a base layer made thereon of a plastic compound (also referred to herein as a sub-point) and a second layer provided thereon (also referred to herein as a hot-melt adhesive) ,
  • the basecoat is made from a crosslinkable, aqueous polymer dispersion, emulsion and / or solution.
  • Self-crosslinking acrylic polymers, self-crosslinking polyvinyl esters or self-crosslinking styrene-acrylic or acrylic-vinyl ester copolymers have been used as polymer dispersions.
  • the polymers used preferably have a film-forming temperature of at least 5 ° C. and are usually acidified in the dispersion or emulsion form.
  • DE-A-3510109 describes the use of a protective colloid-stabilized polymer for the Punttberchichtung a carrier material.
  • the present invention is therefore based on the object to overcome these disadvantages.
  • this is achieved by the use of a protective colloid-stabilized polymer comprising a protective colloid and a polymer for the double-point coating of a carrier material.
  • a protective colloid stabilized polymer can be used to coat a support material, e.g. textile material, suitable to stick it then, was completely surprising for the expert.
  • Prerequisite for bonding textile materials is that the bond during washing or cleaning is not solved.
  • protective colloid-stabilized polymers would expect protective colloid-stabilized polymers to be soluble, thus dissolving the adhesions made therefrom with fabrics during washing. Surprisingly, however, this was not observed. Rather, it has even been found that the bonds obtainable using protective colloid-stabilized polymers are very resistant to washing and cleaning.
  • Emulsifiers are compounds which can be subsumed under the term "surfactants".
  • Surfactants are compounds which can be subsumed under the term "surfactants".
  • Protective colloids are surface-active substances, but they have very characteristic differences to surfactants.
  • a characteristic feature of surfactants and their solutions is micelle formation. As the surfactant concentration increases, the number of molecules increases at the interface until there is no room for more. Then the time for the formation of micelles is given.
  • the formation of micelles starts in a narrow range of concentration characteristic of each surfactant and depends on the molecular structure. It occurs at the concentration at which the surface is completely or substantially fully occupied and therefore the surface tension becomes independent of the increase in the concentration. By measuring the surface tension as a function of the concentration, the concentration at which the micelle formation begins can be determined in a simple manner. It is called the critical micelle concentration (CMC).
  • CMC critical micelle concentration
  • HLB value hydrophilic-lipophilic balance
  • Protective colloid-stabilized polymers are known to the person skilled in the art. They are commercially available or can be prepared by free-radically initiated polymerization of monomers below and optionally auxiliary monomers.
  • the free-radically initiated polymerization of the ethylenically unsaturated monomers can be carried out by suspension or emulsion polymerization. In suspension and emulsion polymerization, in the presence of surface-active substances of the composition, 100-51% of protective colloids and 0-49% of emulsifiers are polymerized.
  • Suitable emulsifiers are anionic, cationic and nonionic emulsifiers, for example anionic surfactants, such as alkyl sulfates having a chain length of 8 to 18 carbon atoms, alkyl or alkylaryl ether sulfates having 8 to 18 carbon atoms in the hydrophobic radical and up to 60 ethylene or Propylene oxide units, alkyl or alkylaryl sulfonates having 8 to 18 carbon atoms, esters and half esters of sulfosuccinic acid with monohydric alcohols or alkylphenols, or nonionic surfactants such as alkyl polyglycol ethers or alkylaryl polyglycol ethers having up to 60 ethylene oxide or propylene oxide units.
  • anionic surfactants such as alkyl sulfates having a chain length of 8 to 18 carbon atoms, alkyl or alkylaryl ether sulfates having 8 to 18 carbon atoms in the
  • protective colloids are modified natural polymers, such as O-methylcellulose, O- (2-hydroxyethyl) -cellulose, O- (2-hydroxy-propyl) -cellulose, O- (2-hydroxy-propyl) -O-methyl-cellulose, O- (2-hydroxy-butyl) -O-methyl-cellulose, carboxymethylcellulose (Na salt), starch ether, O- (2-hydroxy-propyl) starch and lignosulfonic acid, synthetic homo- and Copolymers such as poly (vinyl alcohol) [partially hydrolyzed poly (vinyl acetate)], poly (vinyl alcohol-co-ethylene), poly (methacrylic acid-sodium salts), poly [methacrylic acid-sodium-salt-co- (methacrylic acid-methyl ester)] ], Poly [acrylic acid-co-acrylic acid (2-ethyl-hexyl ester)], poly [methacrylic acid (hydroxyl-alkyl ester)],
  • the polymers of the protective colloid-stabilized polymer are explained in more detail below with reference to the monomers.
  • polymers are to be understood as meaning both homopolymers and copolymers.
  • the monomers may be ethylenically unsaturated monomers.
  • vinyl esters of unbranched or branched alkylcarboxylic acids having 1 to 18 carbon atoms acrylic esters or methacrylic esters of branched or unbranched alcohols or diols having 1 to 18 carbon atoms, C 2 -C 20 -mono- or di-carboxylic acids, their amides , N-methylolamides or nitriles, C2-C20-sulphonic acids, 3-20-membered heterocyclic compounds with oxygen, sulfur, selenium, tellurium, nitrogen, phosphorus, boron or aluminum as heteroatom, dienes with at least 4 C atoms, olefins with at least 2 C atoms, vinyl aromatics in particular with benzene or naphthalene as aromatic, and C2-C20 vinyl halides.
  • Preferred vinyl esters are those having 1 to 12 C atoms, in particular vinyl acetate, vinyl propionate, vinyl butyrate, vinyl 2-ethylhexanoate, vinyl laurate, 1-methylvinyl acetate, vinyl pivalate and vinyl esters of ⁇ -branched monocarboxylic acids having 9 to 13 C atoms.
  • the acrylic acid or methacrylic ester is an ester of unbranched or branched alcohols having 1 to 15 C atoms, in particular methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, n-butyl acrylate, n-butyl methacrylate, t-butyl acrylate, t-butyl methacrylate and 2-ethylhexyl acrylate, more particularly methyl acrylate, methyl methacrylate, n-butyl acrylate, t-butyl acrylate, and 2-ethylhexyl acrylate.
  • Preferred mono- and di-carboxylic acids, their amides, N-methylol amides and nitriles are selected from acrylic acid, methacrylic acid, fumaric acid, maleic acid, acrylamide, N-methylolacrylamide, N-methylolmethacrylamide and acrylonitrile.
  • the sulfonic acid is desirably selected from vinylsulfonic acid and 2-acrylamido-2-methylpropanesulfonic acid.
  • the preferred heterocyclic compounds are vinylpyrrolidone and vinylpyridine.
  • the vinyl aromatic is styrene, methyl styrene or vinyl toluene.
  • the vinyl halide is vinyl chloride.
  • the olefin is selected from ethylene and propylene.
  • Preferred dienes are selected from 1,3-butadiene and isoprene.
  • a plurality of different protective colloid-stabilized polymers can be used.
  • auxiliary monomers are copolymerized.
  • auxiliary monomers are ethylenically unsaturated C 2 -C 20 -mono- and dicarboxylic acids, preferably acrylic acid, methacrylic acid, fumaric acid and maleic acid; ethylenically unsaturated C 2 -C 20 -carboxylic acid amides and nitrites, preferably acrylamide and acrylonitrile; Mono- and diesters of fumaric acid and maleic acid, such as diethyl and diisopropyl esters, and maleic anhydride, ethylenically unsaturated C 2 -C 20 -sulfonic acids or their salts (alkali, alkaline earth and ammonium salts), preferably vinylsulfonic acid, 2-acryl
  • C2-C20 comonomers such as polyethylenically unsaturated comonomers, for example divinyl adipate, diallyl maleate, diallyl phthalate, allyl methacrylate or triallyl cyanurate, or post-crosslinking comonomers, for example acrylolyglycolic acid (AGA), methylacrylamidoglycolic acid methyl ester (MAGME), N-methylolacrylamide (NMA), N Methylolmethacrylamide, N-methylolallylcarbamate, C 2 -C 20 -alkyl ethers such as the isobutoxy ether or esters of N-methylolacrylamide, N-methylolmethacrylamide and N-methylolallylcarbamate.
  • AGA acrylolyglycolic acid
  • MAGME methylacrylamidoglycolic acid methyl ester
  • NMA N-methylolacrylamide
  • NMA N Methylolme
  • epoxide-functional C 2 -C 20 comonomers such as glycidyl methacrylate and glycidyl acrylate.
  • silicon-functional C 2 -C 20 comonomers such as acryloxypropyltri (alkoxy) - and methacryloxypropyltri (alkoxy) silanes, vinyltrialkoxysilanes and vinylmethyldialkoxysilanes, where as alkoxy groups, for example, ethoxy and ethoxypropylene glycol ether radicals may be present.
  • C 2 -C 20 -monomers having hydroxyl or CO groups for example methacrylic acid and acrylic acid hydroxyalkyl esters, such as hydroxyethyl, hydroxypropyl or hydroxybutyl acrylate or methacrylate, and also compounds such as diacetoneacrylamide and acetylacetoxyethyl acrylate or methacrylate.
  • the properties of the coatings can be favorably influenced.
  • the polymers are particularly preferably prepared from monomers or mixtures which contain one or more monomers from the group of vinyl acetate, vinyl esters of ⁇ -branched monocarboxylic acids having 9 to 13 C atoms, vinyl chloride, ethylene, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate , n-butyl acrylate, n-butyl methacrylate, 2-ethylhexyl acrylate or styrene.
  • mixtures of vinyl acetate with ethylene of vinyl acetate, ethylene and a vinyl ester of ⁇ -branched monocarboxylic acids having 9 to 13 carbon atoms; of n-butyl acrylate, 2-ethylhexyl acrylate and / or methyl methacrylate; of styrene with one or more monomers from the group of methyl acrylate, ethyl acrylate, propyl acrylate, n-butyl acrylate, 2-ethylhexyl acrylate; of vinyl acetate with one or more monomers from the group of methyl acrylate.
  • These blends have been found to be particularly beneficial because they exhibit excellent coating properties at low cost.
  • the monomer selection or the selection of the weight proportions of the comonomers can be carried out so that in general a glass transition temperature Tg of -50 ° C to + 120 ° C, preferably -30 ° C to + 95 ° C results.
  • the glass transition temperature Tg of the polymer can be determined in a known manner by means of differential scanning calorimetry (DSC).
  • Tgn the glass transition temperature in Kelvin of the homopolymer of the monomer n. Tg values for homopolymers are listed in Polymer Handbook 2nd edition, J. Wiley & Sons, New York (1975).
  • the polymerization of the above monomers and optionally auxiliary monomers to the polymer can be radicalized.
  • the free-radically initiated polymerization of the ethylenically unsaturated monomers can be carried out by suspension polymerization and emulsion polymerization.
  • the polymerization temperature may be 40 ° C to 100 ° C, preferably 60 ° C to 90 ° C.
  • gaseous comonomers such as ethylene, 1,3-butadiene or vinyl chloride
  • initiation of the polymerization can be carried out with the customary water-soluble or monomer-soluble initiators or redox initiator combinations take place. Examples of water-soluble initiators are the sodium.
  • monomer-soluble initiators are dicetyl peroxydicarbonate, dicyclohexyl peroxydicarbonate, dibenzoyl peroxide, tert-butyl peroxyneodecanoate, tert-butyl peroxy-2-ethylhexanoate and tert-butyl peroxypivalate.
  • the initiators mentioned are generally in an amount of 0.01 to 10.0 wt .-%. preferably 0.1 to 0.5 wt.%, in each case based on the total weight of the monomers, used as redox initiators, combinations of said initiators with reducing agents can be used.
  • Suitable reducing agents are the sulfites and bisulfites of the alkali metals and of ammonium, for example sodium sulfite, the derivatives of sulfoxylic acid, such as zinc or Alkaliformaldehydsulfoxylate, for example Natriumhydroxymethansulfinat, and ascorbic acid.
  • the amount of reducing agent is generally from 0.01 to 10.0 wt .-%, preferably 0.1 to 0.5 wt .-%, each based on the total weight of the monomers.
  • the monomers can be submitted in total, be metered in total or be introduced in portions and the remainder be added after the initiation of the polymerization.
  • the dosages can be carried out separately (spatially and temporally) or the components to be metered can be added all or partly pre-emulsified.
  • the present invention has a number of advantages. First of all, it has been found that, in comparison to other prior art coating processes, very small amounts of coating suffice for sufficiently good adhesion. As a result, a significant reduction in costs can be achieved, and the bonded textile materials have a pleasant soft touch. With the protective colloid-stabilized polymers used according to the invention, a very high adhesive strength of the bonded textiles is observed. The connection of the scattering powder to the sub-point is very good. The bonds obtained with the coating using a protective colloid-stabilized polymer are very good for washing and cleaning.
  • the sub-point obtained with the protective colloid-stabilized polymer does not penetrate into the textile substrate during the double-point coating, ie a very effective flashback is achieved. Furthermore, pastes containing the protective colloid-stabilized polymer and to Making the subpoint used in colon coatings, has a very good rheology and does not dry on the template.
  • the protective colloid-stabilized polymers can be used in the form of a paste.
  • a dispersion of the protective colloid-stabilized polymer in water is used.
  • the amount of water may be, for example, 70% by weight, based on the dispersion, and that of the protective-colloid-stabilized polymer 30% by weight, likewise based on the dispersion.
  • Thickeners and, if appropriate, printing assistants can then be added to these polymer dispersions, as a result of which pastes for coating are obtained.
  • These pastes can be applied, for example, in rotary screen printing on the substrate to be coated. In this way, a sub-point for the double-point coating can be produced. On the sub-point can then be sprinkled hot melt adhesive powder. Excess powder can subsequently be removed by suction. The sub-item can then be dried and sintered, or the litter powder can be melted.
  • the abovementioned polymer dispersions have the advantage that they are obtained by adding compounds having 2 or more epoxide, organo, halogen, hydroxyl, aziridine, carbodiimide, oxazoline, alcohol, amine, aminosilane, aminoformaldehyde, Isocyanate or N-2-hydroxyalkylamide residues can be crosslinked.
  • crosslinking of the polymer with the protective colloid shell and with the added additives also occurs. As a result, particularly high adhesive strengths are achieved.
  • Crosslinkers may also be present in the final formulation of the dispersion or paste, for example compounds containing two or more epoxy, organo, halogen, hydroxy, aziridine, carbodiimide, oxazoline, alcohol, amine, aminosilane, Amino-formaldehyde, isocyanate or N-2-hydroxyalkylamide residues.
  • the substrates that can be coated can be materials of any kind. It can be flexible, not very flexible or not flexible at all. Examples are textile materials of any kind, such as woven, knitted, woven knitted fabric, Raschelwaren (natural and synthetic fibers). Flies made of any material. Furthermore, films can be coated, in particular of plastics of any kind, as well as paper, synthetic leather, leather, foam and wood.
  • Tebelink® B-IC polysocyanate, modified, Dr. med. Th. Boehme KG Chem. Fabrik GmbH & Co.
  • Tebelink® MFA partially etherified, modified melamine-formaldehyde condensate, low in formaldehyde (0.3%), Dr. Ing. Th. Boehme KG Chem. Fabrik GmbH & Co.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Claims (17)

  1. Utilisation d'un polymère stabilisé par colloïdes de protection, comprenant un colloïde de protection et un polymère, pour le revêtement d'un matériau support, dans laquelle le revêtement est un revêtement à double point.
  2. Utilisation selon la revendication 1, dans laquelle le colloïde de protection est choisi parmi des polymères naturels modifiés, des homo- et des copolymères synthétiques, des polymères greffés et des produits de condensation.
  3. Utilisation selon l'une des revendications précédentes, dans laquelle le polymère peut être préparé à partir d'au moins un monomère insaturé éthylénique, qui est choisi parmi des esters de vinyle d'acides alkylcarboxyliques non ramifiés ou ramifiés avec 1 à 18 atomes de carbone, des esters de l'acide acrylique ou de l'acide méthacrylique ou des alcools ou des diols à 1 à 18 atomes de carbone, des acides mono- ou dicarboxyliques en C2 à C20 non ramifiés ou ramifiés, leurs amides, des N-méthylolamides, ou des nitriles, des acides sulfoniques en C2 à C20, des composés hétérocycliques à 3 à 20 membres avec comme hétéroatomes de l'oxygène, du soufre, du sélénium, du tellure, de l'azote, du phosphore, du bore ou de l'aluminium, des diènes avec au moins 4 atomes de carbone, des oléfines avec au moins 2 atomes de carbone, des composés vinyle aromatiques et des halogénures de vinyle en C2 à C20.
  4. Utilisation selon la revendication 3, dans laquelle l'ester de vinyle est choisi parmi l'acétate de vinyle, le propionate de vinyle, le butyrate de vinyle, l'hexanoate de vinyl-2-éthyle, le laurate de vinyle, l'acétate de 1-méthylvinyle, le pivalate de vinyle, et les esters de vinyle d'acides monocarboxyliques α-ramifiés avec 9 à 13 atomes de carbone.
  5. Utilisation selon la revendication 3, dans laquelle l'ester d'acide acrylique ou d'acide méthacrylique est choisi parmi l'acrylate de méthyle, le méthacrylate de méthyle, l'acrylate d'éthyle, le méthacrylate d'éthyle, l'acrylate de propyle, le méthacrylate de propyle, l'acrylate de n-butyle le méthacrylate de n-butyle, l'acrylate de t-butyle le méthacrylate de t-butyle, l'acrylate de 2-éthylhexyle.
  6. Utilisation selon la revendication 3, dans laquelle les acides mono- et dicarboxyliques, leurs amides, les n-méthylolamides, et les nitriles sont choisis parmi l'acide acrylique, l'acide méthacrylique, l'acide fumarique, l'acide maléique, l'acrylamide, le N-méthylolacrylamide, le N-méthylolméthacrylamide, et l'acrylonitrile.
  7. Utilisation selon la revendication 3, dans laquelle l'acide sulfonique est choisi parmi l'acide vinylsulfonique et l'acide 2-acrylamino-2-méthyl-propane sulfonique.
  8. Utilisation selon la revendication 3, dans laquelle le composé hétérocyclique est choisi parmi la vinylpyrrolidone et la vinylpyridine.
  9. Utilisation selon la revendication 3, dans laquelle le composé aromatique de vinyle est choisi parmi le styrène, le méthylstyrène et le vinyltoluène.
  10. Utilisation selon la revendication 3, dans laquelle l'halogénure de vinyle est du chlorure de vinyle.
  11. Utilisation selon la revendication 3, dans laquelle l'oléfine est choisie parmi l'éthylène et le propylène.
  12. Utilisation selon la revendication 3, dans laquelle le diène est choisi parmi le 1,3-butadiène et l'isoprène.
  13. Utilisation selon l'une des revendications précédentes, dans laquelle, pour la préparation du polymère, un monomère auxiliaire est utilisé en plus du monomère, en une quantité de 0,1 à 50 % en poids, rapportés au poids total du polymère.
  14. Utilisation selon l'une des revendications précédentes, dans laquelle le polymère présente une température de transition de verre de -50 °C à 120 °C.
  15. Utilisation selon l'une des revendications précédentes, dans laquelle le polymère stabilisé par colloïde de protection se présente sous forme d'une dispersion aqueuse.
  16. Utilisation selon l'une des revendications précédentes, dans laquelle le polymère stabilisé par colloïde de protection se présente sous forme d'une pâte.
  17. Utilisation selon l'une des revendications précédentes, dans laquelle l'enduction s'effectue par sérigraphie rotative.
EP03028481A 2003-12-12 2003-12-12 Utilisation de polymères stabilisées au moyen de colloides protecteurs en tant que revêtements à point double Expired - Lifetime EP1541751B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
ES03028481T ES2259747T3 (es) 2003-12-12 2003-12-12 Uso de polimeros estabilizados con coloides protectores para recubrimiento por puntos dobles.
AT03028481T ATE321909T1 (de) 2003-12-12 2003-12-12 Verwendung schutzkolloidstabilisierter polymere für doppelpunktbeschichtungen
DE50302798T DE50302798D1 (de) 2003-12-12 2003-12-12 Verwendung schutzkolloidstabilisierter Polymere für Doppelpunktbeschichtungen
EP03028481A EP1541751B1 (fr) 2003-12-12 2003-12-12 Utilisation de polymères stabilisées au moyen de colloides protecteurs en tant que revêtements à point double
US10/582,072 US20070128362A1 (en) 2003-12-12 2004-12-01 Use of protective colloids-stabilized polymers for double dot coatings
PCT/EP2004/013642 WO2005059238A1 (fr) 2003-12-12 2004-12-01 Utilisation de polymeres stabilises par un colloide protecteur pour revetements double-point
KR1020067011386A KR20060121165A (ko) 2003-12-12 2004-12-01 이중 도트 피복을 위한 보호 콜로이드 안정화 폴리머의사용방법

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Application Number Priority Date Filing Date Title
EP03028481A EP1541751B1 (fr) 2003-12-12 2003-12-12 Utilisation de polymères stabilisées au moyen de colloides protecteurs en tant que revêtements à point double

Publications (2)

Publication Number Publication Date
EP1541751A1 EP1541751A1 (fr) 2005-06-15
EP1541751B1 true EP1541751B1 (fr) 2006-03-29

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EP03028481A Expired - Lifetime EP1541751B1 (fr) 2003-12-12 2003-12-12 Utilisation de polymères stabilisées au moyen de colloides protecteurs en tant que revêtements à point double

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US (1) US20070128362A1 (fr)
EP (1) EP1541751B1 (fr)
KR (1) KR20060121165A (fr)
AT (1) ATE321909T1 (fr)
DE (1) DE50302798D1 (fr)
ES (1) ES2259747T3 (fr)
WO (1) WO2005059238A1 (fr)

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CN101910505A (zh) 2007-10-25 2010-12-08 库夫纳纺织品有限责任公司 可热密封的平面织物结构、其的制备和应用
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KR20060121165A (ko) 2006-11-28
EP1541751A1 (fr) 2005-06-15
DE50302798D1 (de) 2006-05-18
ES2259747T3 (es) 2006-10-16
US20070128362A1 (en) 2007-06-07
WO2005059238A1 (fr) 2005-06-30

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