EP1326952B1 - Composition a base de polysaccharide anionique pour le soin du linge - Google Patents

Composition a base de polysaccharide anionique pour le soin du linge Download PDF

Info

Publication number: EP1326952B1
Authority: EP; European Patent Office
Prior art keywords: anionic polysaccharide; process according; anionic; formulation; composition
Prior art date: 2000-10-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

EP01978549A

Other languages

German (de)

English (en)

French (fr)

Other versions

EP1326952A1 (fr

Inventor

Ian Harrison

Eric Aubay

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Rhodia Chimie SAS

Original Assignee

Rhodia Chimie SAS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2000-10-18

Filing date

2001-10-17

Publication date

2008-01-02

2001-10-17 Application filed by Rhodia Chimie SAS filed Critical Rhodia Chimie SAS

2003-07-16 Publication of EP1326952A1 publication Critical patent/EP1326952A1/fr

2008-01-02 Application granted granted Critical

2008-01-02 Publication of EP1326952B1 publication Critical patent/EP1326952B1/fr

2021-10-17 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 129
229920001586 anionic polysaccharide Polymers 0.000 title claims abstract description 62
150000004836 anionic polysaccharides Chemical class 0.000 title claims abstract description 62
239000004753 textile Substances 0.000 title claims abstract description 37
238000009472 formulation Methods 0.000 claims abstract description 72
238000005406 washing Methods 0.000 claims abstract description 51
239000003599 detergent Substances 0.000 claims abstract description 46
239000000654 additive Substances 0.000 claims abstract description 31
230000000996 additive effect Effects 0.000 claims abstract description 22
229920000742 Cotton Polymers 0.000 claims abstract description 19
239000007787 solid Substances 0.000 claims abstract description 15
239000007788 liquid Substances 0.000 claims abstract description 12
125000000129 anionic group Chemical group 0.000 claims abstract description 11
238000010409 ironing Methods 0.000 claims abstract description 11
-1 alkyl radical Chemical group 0.000 claims description 52
125000004432 carbon atom Chemical group C* 0.000 claims description 25
238000010790 dilution Methods 0.000 claims description 21
239000012895 dilution Substances 0.000 claims description 21
238000000034 method Methods 0.000 claims description 21
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
239000004744 fabric Substances 0.000 claims description 19
229920001282 polysaccharide Polymers 0.000 claims description 15
239000005017 polysaccharide Substances 0.000 claims description 15
150000004804 polysaccharides Chemical class 0.000 claims description 15
150000003254 radicals Chemical class 0.000 claims description 14
229920000926 Galactomannan Polymers 0.000 claims description 11
229910052799 carbon Inorganic materials 0.000 claims description 10
239000006185 dispersion Substances 0.000 claims description 10
125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 9
SHZGCJCMOBCMKK-UHFFFAOYSA-N D-mannomethylose Natural products CC1OC(O)C(O)C(O)C1O SHZGCJCMOBCMKK-UHFFFAOYSA-N 0.000 claims description 8
238000006467 substitution reaction Methods 0.000 claims description 8
PNNNRSAQSRJVSB-UHFFFAOYSA-N L-rhamnose Natural products CC(O)C(O)C(O)C(O)C=O PNNNRSAQSRJVSB-UHFFFAOYSA-N 0.000 claims description 7
229910052783 alkali metal Inorganic materials 0.000 claims description 7
239000007864 aqueous solution Substances 0.000 claims description 7
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 6
150000001340 alkali metals Chemical class 0.000 claims description 6
125000003118 aryl group Chemical group 0.000 claims description 6
239000004094 surface-active agent Substances 0.000 claims description 6
238000012986 modification Methods 0.000 claims description 5
230000004048 modification Effects 0.000 claims description 5
239000011343 solid material Substances 0.000 claims description 5
WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 claims description 4
IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 claims description 4
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 4
SHZGCJCMOBCMKK-PQMKYFCFSA-N L-Fucose Natural products C[C@H]1O[C@H](O)[C@@H](O)[C@@H](O)[C@@H]1O SHZGCJCMOBCMKK-PQMKYFCFSA-N 0.000 claims description 4
SHZGCJCMOBCMKK-DHVFOXMCSA-N L-fucopyranose Chemical compound C[C@@H]1OC(O)[C@@H](O)[C@H](O)[C@@H]1O SHZGCJCMOBCMKK-DHVFOXMCSA-N 0.000 claims description 4
WQZGKKKJIJFFOK-DHVFOXMCSA-N L-galactose Chemical compound OC[C@@H]1OC(O)[C@@H](O)[C@H](O)[C@@H]1O WQZGKKKJIJFFOK-DHVFOXMCSA-N 0.000 claims description 4
PNNNRSAQSRJVSB-BXKVDMCESA-N aldehydo-L-rhamnose Chemical group C[C@H](O)[C@H](O)[C@@H](O)[C@@H](O)C=O PNNNRSAQSRJVSB-BXKVDMCESA-N 0.000 claims description 4
125000000217 alkyl group Chemical group 0.000 claims description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 claims description 4
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
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150000002402 hexoses Chemical group 0.000 claims description 4
239000000463 material Substances 0.000 claims description 4
230000007935 neutral effect Effects 0.000 claims description 4
239000001301 oxygen Substances 0.000 claims description 4
229910052760 oxygen Inorganic materials 0.000 claims description 4
OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 claims description 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
229910019142 PO4 Inorganic materials 0.000 claims description 3
150000001408 amides Chemical class 0.000 claims description 3
AEMOLEFTQBMNLQ-UHFFFAOYSA-N beta-D-galactopyranuronic acid Natural products OC1OC(C(O)=O)C(O)C(O)C1O AEMOLEFTQBMNLQ-UHFFFAOYSA-N 0.000 claims description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims description 2
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 2
AEMOLEFTQBMNLQ-DTEWXJGMSA-N D-Galacturonic acid Natural products O[C@@H]1O[C@H](C(O)=O)[C@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-DTEWXJGMSA-N 0.000 claims description 2
SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 claims description 2
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 2
229920002324 Galactoglucomannan Polymers 0.000 claims description 2
SRBFZHDQGSBBOR-OWMBCFKOSA-N L-ribopyranose Chemical compound O[C@H]1COC(O)[C@@H](O)[C@H]1O SRBFZHDQGSBBOR-OWMBCFKOSA-N 0.000 claims description 2
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 2
229920002310 Welan gum Polymers 0.000 claims description 2
229920002000 Xyloglucan Polymers 0.000 claims description 2
IAJILQKETJEXLJ-RSJOWCBRSA-N aldehydo-D-galacturonic acid Chemical compound O=C[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)C(O)=O IAJILQKETJEXLJ-RSJOWCBRSA-N 0.000 claims description 2
AEMOLEFTQBMNLQ-WAXACMCWSA-N alpha-D-glucuronic acid Chemical compound O[C@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-WAXACMCWSA-N 0.000 claims description 2
PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 claims description 2
125000003710 aryl alkyl group Chemical group 0.000 claims description 2
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
150000007942 carboxylates Chemical class 0.000 claims description 2
125000000753 cycloalkyl group Chemical group 0.000 claims description 2
AEMOLEFTQBMNLQ-YBSDWZGDSA-N d-mannuronic acid Chemical group O[C@@H]1O[C@@H](C(O)=O)[C@H](O)[C@@H](O)[C@H]1O AEMOLEFTQBMNLQ-YBSDWZGDSA-N 0.000 claims description 2
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
239000010452 phosphate Substances 0.000 claims description 2
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
229920001285 xanthan gum Polymers 0.000 claims description 2
244000007835 Cyamopsis tetragonoloba Species 0.000 claims 2
FEBUJFMRSBAMES-UHFFFAOYSA-N 2-[(2-{[3,5-dihydroxy-2-(hydroxymethyl)-6-phosphanyloxan-4-yl]oxy}-3,5-dihydroxy-6-({[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}methyl)oxan-4-yl)oxy]-3,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl phosphinite Chemical compound OC1C(O)C(O)C(CO)OC1OCC1C(O)C(OC2C(C(OP)C(O)C(CO)O2)O)C(O)C(OC2C(C(CO)OC(P)C2O)O)O1 FEBUJFMRSBAMES-UHFFFAOYSA-N 0.000 claims 1
229920002305 Schizophyllan Polymers 0.000 claims 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
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HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
229920000609 methyl cellulose Polymers 0.000 description 1
WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
239000001923 methylcellulose Substances 0.000 description 1
235000010981 methylcellulose Nutrition 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
239000011707 mineral Substances 0.000 description 1
QUSNBJAOOMFDIB-UHFFFAOYSA-N monoethyl amine Natural products CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 1
235000011929 mousse Nutrition 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000003921 oil Substances 0.000 description 1
238000011017 operating method Methods 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
230000002186 photoactivation Effects 0.000 description 1
229920001983 poloxamer Polymers 0.000 description 1
229920001281 polyalkylene Polymers 0.000 description 1
108010064470 polyaspartate Proteins 0.000 description 1
229920005646 polycarboxylate Polymers 0.000 description 1
238000006068 polycondensation reaction Methods 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920002643 polyglutamic acid Polymers 0.000 description 1
229920001721 polyimide Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229920006324 polyoxymethylene Polymers 0.000 description 1
239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
235000019422 polyvinyl alcohol Nutrition 0.000 description 1
239000003531 protein hydrolysate Substances 0.000 description 1
DNXIASIHZYFFRO-UHFFFAOYSA-N pyrazoline Chemical compound C1CN=NC1 DNXIASIHZYFFRO-UHFFFAOYSA-N 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
230000035945 sensitivity Effects 0.000 description 1
238000004513 sizing Methods 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
235000019832 sodium triphosphate Nutrition 0.000 description 1
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
NWPMTMCXJZTLSO-UHFFFAOYSA-M sodium;4-acetyloxybenzenesulfonate Chemical compound [Na+].CC(=O)OC1=CC=C(S([O-])(=O)=O)C=C1 NWPMTMCXJZTLSO-UHFFFAOYSA-M 0.000 description 1
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000009987 spinning Methods 0.000 description 1
238000005507 spraying Methods 0.000 description 1
238000010186 staining Methods 0.000 description 1
239000008107 starch Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
239000001384 succinic acid Substances 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
238000006277 sulfonation reaction Methods 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
229910021653 sulphate ion Inorganic materials 0.000 description 1
239000003826 tablet Substances 0.000 description 1
229940095064 tartrate Drugs 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
KWXLCDNSEHTOCB-UHFFFAOYSA-J tetrasodium;1,1-diphosphonatoethanol Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P(=O)([O-])C(O)(C)P([O-])([O-])=O KWXLCDNSEHTOCB-UHFFFAOYSA-J 0.000 description 1
229930192474 thiophene Natural products 0.000 description 1
150000003577 thiophenes Chemical class 0.000 description 1
238000012549 training Methods 0.000 description 1
GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
150000003626 triacylglycerols Chemical class 0.000 description 1
GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
239000001993 wax Substances 0.000 description 1
238000009941 weaving Methods 0.000 description 1
150000003751 zinc Chemical class 0.000 description 1
239000002888 zwitterionic surfactant Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/226—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin esterified
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups

Definitions

the subject of the present invention is a composition comprising an anionic polysaccharide for the care of articles made of textile fibers ("textile care"), especially made from cotton, colored in particular.
Care is particularly concerned with textile fiber articles, in particular textiles, the protection of the latter against physical or chemical deterioration phenomena, in particular the protection of the colors of the colored articles, and / or the contribution to those benefits such as softening and / or anti-creasing properties.
the document US 5612475 discloses fiber treatment compositions comprising a carboxymethyl guar.
the treated fibers are not textiles, they are not assembled by weaving, knitting or other form constituting linen.
Such compositions are not detergent formulations, rinse and / or softening formulations for laundry, drying additives, or prespotters, and are clearly not suitable for these uses.
the document EP072971 discloses agglomerates of zeolites comprising a carboxymethyl guar. D3 gives little training on the use of these agglomerates, except the need for zeolites for washing machine compositions. D3 does not mention washing clothes (it could be washing dishes - builder like zeolites are used in dishwasher products). This document does not disclose compositions which are detergent formulations, rinse and / or fabric softener formulations, drying additives, or prespotters.
compositions comprising a carboxymethyl guar.
Such compositions are not detergent formulations, rinse and / or softening formulations for laundry, drying additives, or prespotters, and are clearly not suitable for these uses.
compositions for the treatment of textile articles especially cotton-based, colored in particular, certain anionic polysaccharides of high molecular mass soluble in the conditions of use ("working conditions” ) in aqueous or wet medium of said compositions prevented the degradation of these articles, used to protect the colors and / or provided them with anti-crease and / or softening properties.
Such compositions may in particular be compositions for washing and / or rinsing and / or softening the laundry, for staining the laundry before washing ("prespotting"), for drying wet clothes in a tumble dryer or for ironing clothes.
the molar mass by weight of said anionic polysaccharides may be up to 2,000,000.
the molar mass by weight Mw of said anionic polysaccharides can be measured by size exclusion chromatography. The measurement is carried out in water at pH 9-10 containing 0.1 M LiCl and 2/10000 N 3 Na. The molar mass by weight Mw is established in known manner directly via the light scattering values.
the degree of substitution or modification DSi corresponds to the average number of hydroxyl functions of the anhydrohexose and / or anhydropentose units substituted or modified by the said anionic or anionizable group or groups, per anhydrohexose unit and / or anhydropentose unit.
Said ionic or ionizable groups are bonded to the carbon atoms of the sugar backbone either directly or via -O- bonds.
said anionic polysaccharide may also have at least one nonionic group.
the said nonionic groups are bonded to the carbon atoms of the sugar skeleton either directly or via -O- bonds.
the degree of substitution or modification by all of the anionic or anionizable and nonionic groups is less than 3 by definition.
the number of moles of substitution MS is theoretically not limited; it can for example go up to 6, preferably up to 2.
carboxy groups --COO - Na + directly attached to a carbon atom of the sugar skeleton carboxymethyl (salt of sodium) -CH 2 -COO - Na + linked to a carbon atom of the sugar skeleton via an -O- bond.
the hexose units (similar or different) of the main backbone of the native skeleton can be D-glucose, D-or L-galactose, D-mannose, D- or L-fucose, L-rhamnose, etc.
the neutral or anionic pentose and / or hexose (similar or different) units of the native backbone branches may be D-xylose ..., L- or D-arabinose, D-glucose, D- or L-galactose, D-xylose units.
galactomannans As examples of the native skeleton, there may be mentioned galactomannans, galactoglucomannans, xyloglucans, xanthan gums, scleroglucannes, succinoglycans, rhamsans, welan gums, etc.
the native skeleton is a galactomannan.
Galactomannans are macromolecules comprising a main chain of ⁇ (1-4) -linked D-mannopyranose units substituted with D-galactopyranose units in the ⁇ (1-6) position.
⁇ (1-4) -linked D-mannopyranose units substituted with D-galactopyranose units in the ⁇ (1-6) position.
gums guar, carob, tara there may be mentioned gums guar, carob, tara.
the native skeleton is a guar gum.
Guar gums have a mannose / galactose ratio of 2.
the anionic polysaccharides according to the invention can be obtained in known manner.
a second object of the invention consists of a method for treating textile fiber articles, by treating them with a composition, in an aqueous or wet medium, comprising at least one anionic polysaccharide according to the invention.
a third object of the invention is the use, in a composition for the treatment of textile fiber articles in aqueous or wet medium of at least one anionic polysaccharide according to the invention, as a care agent for textile articles.
compositions and the conditions of use (or treatment) can be multiple.
composition of the invention is particularly well suited to the care of linen, especially cotton-based, in particular containing at least 35% cotton. It is particularly suitable for the care of colored linen.
anionic polysaccharides according to the invention are soluble under the conditions of use ("working conditions") in an aqueous or wet medium of said composition.
Said anionic polysaccharides are considered as soluble when more than 50%, preferably more than 70% of their weight are soluble in the aqueous or wet medium of use of the composition of the invention, that is to say in particular in the temperature and pH conditions of said medium.
the amount of anionic polysaccharide present in the care composition according to the invention may range from 0.05 to 10% by dry weight of said composition in dry state, and this according to the desired application.
said anionic polysaccharide (PA) can be implemented as follows: % of (PA) (in sec) in a care composition according to the invention used as 0.05 - 5 preferably 0.1 - 3 detergent formulation 0.05-3 preferably 0.1-2 rinse and / or softening formulation 0.05 - 10 drying additive 0.05-10 preferably 0.1-5 ironing formulation 0.05-10 preferably 0.1-5 washing additive
compositions may contain at least one surfactant and / or a detergent and / or rinsing and / or softening additive for textile fiber articles and / or a solid support (textile in particular) of said anionic polysaccharide.
surfactant and / or a detergent and / or rinsing and / or softening additive for textile fiber articles and / or a solid support (textile in particular) of said anionic polysaccharide.
a detergent and / or rinsing and / or softening additive for textile fiber articles and / or a solid support (textile in particular) of said anionic polysaccharide.
solid support textile in particular
the detergent formulation may comprise surfactants in an amount corresponding to about 3 to 40% by weight, based on the detergent formulation, surfactants such as
Builder builders improving the properties of surfactants can be used in amounts of about 5-50%, preferably about 5-30% by weight for liquid detergent formulations or about 10% by weight. -80%, preferably 15-50% by weight for powder detergent formulations, detergency builders such as:
the detergent formulation may further comprise at least one oxygen-releasing bleaching agent comprising a percompound, preferably a persalt.
Said bleaching agent may be present in an amount corresponding to about 1 to 30%, preferably 4 to 20% by weight, based on the detergent formulation.
per-compounds which may be used as bleaching agents particular mention should be made of perborates such as sodium perborate monohydrate or tetrahydrate; peroxygen compounds such as sodium carbonate peroxyhydrate, pyrophosphate peroxyhydrate, urea peroxyhydrate, sodium peroxide, sodium persulfate.
perborates such as sodium perborate monohydrate or tetrahydrate
peroxygen compounds such as sodium carbonate peroxyhydrate, pyrophosphate peroxyhydrate, urea peroxyhydrate, sodium peroxide, sodium persulfate.
the preferred bleaching agents are sodium perborate, mono- or tetrahydrate and / or sodium carbonate peroxyhydrate.
Said agents are generally associated with a bleaching activator generating in situ in the detergent medium, a peroxy carboxylic acid, in an amount corresponding to about 0.1 to 12%, preferably 0.5 to 8% by weight relative to the detergent formulation.
a bleaching activator generating in situ in the detergent medium, a peroxy carboxylic acid, in an amount corresponding to about 0.1 to 12%, preferably 0.5 to 8% by weight relative to the detergent formulation.
these activators mention may be made of tetraacetylethylenediamine, tetraacetylmethylenediamine, tetraacetylglycoluryl, sodium p-acetoxybenzenesulphonate, pentaacetylglucose and octaacetyllactose.
Non-oxygenated bleaches acting by photoactivation in the presence of oxygen agents such as aluminum phthalocyanines and / or sulphonated zinc.
the detergent formulation may further comprise soil release, anti-redeposition, chelant, dispersant, fluorescence, suds suppressor, softener, enzyme and other miscellaneous additives.
They can be used in amounts of about 0.01-10%, preferably about 0.1-5%, and more preferably of the order of 0.2-3% by weight.
the chelating agents of iron and magnesium may be present in amounts of the order of 0.1-10%, preferably of the order of 0.1-3% by weight.
agents such as: stilbene derivatives, pyrazoline, coumarin, fumaric acid, cinnamic acid, azoles, methinecyanines, thiophenes ...
stilbene derivatives pyrazoline, coumarin, fumaric acid, cinnamic acid, azoles, methinecyanines, thiophenes ...
agents such as clays.
the detergent formulation may be used, especially in a washing machine, in a proportion of from 0.5 g / l to 20 g / l, preferably from 2 g / l to 10 g / l for carrying out washing operations at a rate of temperature of the order of 25 to 90 ° C.
a second embodiment of the care composition of the invention consists of an aqueous liquid formulation for rinsing and / or softening the laundry.
a third embodiment of the care composition of the invention consists of a laundry drying additive in a suitable drying machine.
Said additive comprises a flexible solid support constituted for example by a woven or non-woven textile strip, a cellulose sheet, impregnated with said anionic polysaccharide; said additive is introduced on drying in the wet laundry to be dried at a temperature of the order of 50 to 80 ° C for 10 to 60 minutes.
Said additive may further comprise cationic softening agents (up to 99%) and anti-color transfer agents (up to 80%) such as those mentioned above.
a fourth embodiment of the care composition of the invention consists of an ironing formulation which can be sprayed directly onto the dry cloth before the ironing operation.
Said formulation may further contain silicone-based polymers (from 0.2 to 5%), nonionic surfactants (from 0.5 to 5%) or anionic surfactants (from 0.5 to 5%), perfumes (0.1 to 3%), cellulose derivatives (0.1 to 3%) such as starch; spraying said formulation on the laundry makes it easier to iron and to limit the creasing of the laundry when worn.
a fifth embodiment of the care composition of the invention consists of a washing additive ("prespotter”) in the form of an aqueous solution or dispersion or of a solid (stick). .
the anionic polysaccharide used in the following examples is a carboxymethyl guar having a degree of substitution of 1.6 and a molar mass by weight of 1 400 000 determined as follows by size exclusion chromatography.
Formulation (A) with P (B) color without P (C) without P constituents % in weight % in weight % in weight NaTPP 40 Zeolite 4A 0 25 25 Silicate 2 SiO 2 , Na 2 O 5 5 5 Sodium carbonate 5 15 15 15 Sokalan CP5 Acrylate / Maleate Copolymer (BASF) 0 5 5 Sodium sulphate 8 21 8 CMC blanose 7MXF (HERCULES) 1 1 1 Perborate monohydrate 15 0 15 Pelletized TAED 5 0 5 Anionic surfactant Laurylbenzene sulfate (Nansa) 6 8 6 Nonionic surfactant Symperonic A3 (ethoxylated alcohol 3 OE_ -_ICI) 3 5 3 Symperonic A9 nonionic surfactant (ethoxylated alcohol 9 OE_ICI) 9 11 9 Enzymes (Esterases, Amylases, Cellulase, Protease) 0.5 0.5 0.5 Perfume 1 1
a washing operation is carried out in a laboratory apparatus Tergotometer well known in the art of detergent composition formulators.
the device simulates the mechanical and thermal effects of American pulsator-type washing machines, but thanks to the presence of 6 washing pots, it allows for simultaneous series of tests with appreciable time saving.
Unwrapped cotton test pieces measuring 25 x 25 cm are cut.
the cotton test pieces are first ironed in order to have all the same level of creasing before washing.
a color digital photograph is then taken of the dry specimens, which is then transformed into 256 gray levels (gray scale from 0 to 255).
the standard deviation ⁇ of the distribution of the gray level is measured.
⁇ 1 corresponds to the standard deviation obtained with the detergent formulation containing no anionic polysaccharide.
⁇ 2 corresponds to the standard deviation obtained with the detergent formulation containing the anionic polysaccharide.
the performance values obtained are as follows: Formulation (AT) (B) (VS) - ⁇ 3.5 4 4.5
These positive values of - ⁇ are representative of an anti-crease property provided by the detergent formulation comprising the anionic polysaccharide according to the invention.
Washing temperature 40 ° C Duration: about 67 minutes Number of wash: 10 Laundry load: 3 kg dry (4 towels + 6 tea towels + colored fabrics) Volume of the bath: 13 liters ⁇ 1 liter Water hardness : about 23 ° TH french Concentration detergent formula: 5 ⁇ 0.1g / l
⁇ E * ⁇ The * 2 + ⁇ at * 2 + ⁇ b * 2
the performance of the polysaccharide relative to the reference is measured as the difference of ⁇ E * between the formulas without and with polysaccharide.
a detergent formulation (F) is prepared by adding 1 part of anionic polysaccharide to 100 parts of the composition (C) below (expressed in parts by weight): sodium lauryl alkyl benzene sulfonate 19.2 Rhodia Nabion 15 (cogranules of sodium silicate and calcium carbonate) 48.6 sodium carbonate 10.3 sodium sulphate 13.5 Sokalan CP5 6.4 Phosphonate Dequest 2016 2 This formulation (F) and the composition without anionic polysaccharide (C) are tested as described above.

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Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Emergency Medicine (AREA)
Engineering & Computer Science (AREA)
Molecular Biology (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Polysaccharides And Polysaccharide Derivatives (AREA)
Cosmetics (AREA)

EP01978549A 2000-10-18 2001-10-17 Composition a base de polysaccharide anionique pour le soin du linge Expired - Lifetime EP1326952B1 (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
FR0013334		2000-10-18
FR0013334A FR2815355B1 (fr)	2000-10-18	2000-10-18	Composition a base de polysaccharide anionique pour le soin du linge
PCT/FR2001/003210 WO2002033034A1 (fr)	2000-10-18	2001-10-17	Composition a base de polysaccharide anionique pour le soin du linge

Publications (2)

Publication Number	Publication Date
EP1326952A1 EP1326952A1 (fr)	2003-07-16
EP1326952B1 true EP1326952B1 (fr)	2008-01-02

Family

ID=8855465

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP01978549A Expired - Lifetime EP1326952B1 (fr)	2000-10-18	2001-10-17	Composition a base de polysaccharide anionique pour le soin du linge

Country Status (10)

Country	Link
US (4)	US20040107505A1 (pt)
EP (1)	EP1326952B1 (pt)
JP (1)	JP2004511681A (pt)
AT (1)	ATE382672T1 (pt)
AU (1)	AU2002210655A1 (pt)
BR (1)	BR0114624A (pt)
CA (1)	CA2426695C (pt)
DE (1)	DE60132225T2 (pt)
FR (1)	FR2815355B1 (pt)
WO (1)	WO2002033034A1 (pt)

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- 2001-10-17 WO PCT/FR2001/003210 patent/WO2002033034A1/fr active IP Right Grant
2007
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Also Published As

Publication number	Publication date
WO2002033034A1 (fr)	2002-04-25
US20080263788A1 (en)	2008-10-30
AU2002210655A1 (en)	2002-04-29
JP2004511681A (ja)	2004-04-15
ATE382672T1 (de)	2008-01-15
US20070191254A1 (en)	2007-08-16
CA2426695A1 (fr)	2002-04-25
DE60132225D1 (de)	2008-02-14
US8128712B2 (en)	2012-03-06
EP1326952A1 (fr)	2003-07-16
FR2815355A1 (fr)	2002-04-19
US20040107505A1 (en)	2004-06-10
FR2815355B1 (fr)	2003-03-14
US20110028376A1 (en)	2011-02-03
DE60132225T2 (de)	2008-12-18
BR0114624A (pt)	2003-12-23
CA2426695C (fr)	2011-11-29

Publication	Publication Date	Title
EP1345970B1 (fr)	2008-04-16	Utilisation de polysaccharide amphotere pour le soin des articles en fibres textiles
EP1326952B1 (fr)	2008-01-02	Composition a base de polysaccharide anionique pour le soin du linge
EP1360364B1 (fr)	2010-03-31	Utilisation de polysaccharide non-ionique dans une composition pour le soin des articles en fibres textiles
FR2813313A1 (fr)	2002-03-01	Composition a base de nanoparticules ou de nanolatex de polymeres pour le soin du linge
EP0882117B1 (fr)	2002-11-13	Agent antisalissure et procede de traitement des articles a base de coton tisse
FR2740779A1 (fr)	1997-05-09	Composition a base d'enzyme et de sophorolipide sous forme lactone et son utilisation dans les formulations detergentes pour le lavage du linge
US5820637A (en)	1998-10-13	Method of pretreating stained fabrics with pretreater or laundry additive compositions containing hydrophobically modified polar polymers
WO1999041347A1 (fr)	1999-08-19	Compositions detergentes contenant un silicone amine et un polymere antitransfert de couleur
EP1272601B1 (en)	2008-07-02	Laundry wash compositions
EP1419231B1 (fr)	2005-10-19	Additif preformule pour composition de traitement des articles en fibres textiles et utilisation dudit additif comme agent de soin
FR2813312A1 (fr)	2002-03-01	Composition a base de nanolatex de polymeres pour le soin du linge
EP1485459B1 (fr)	2006-09-27	Copolyesteramides et leur utilisation comme agent antisalissure
EP1019474B1 (fr)	2004-03-31	Procede de preparation d'un systeme a base d'un agent tensioactif non-ionique et d'un silicate de metal alcalin
WO1998046717A1 (fr)	1998-10-22	Utilisation d'un systeme anti-oxydant enrobe en detergence et compositions obtenues
KR20220117884A (ko)	2022-08-24	재침착 억제 중합체 및 이를 함유하는 세제 조성물
FR2824841A1 (fr)	2002-11-22	Utilisation, dans une composition pour le traitement des articles en fibres textiles, d'un polyorganosiloxane a fonctions(s) piperidinyle (s) comme agent anti-salissure ("soil release")
WO1999041345A1 (fr)	1999-08-19	Compositions detergentes solides a base de silicate de sodium et de silicone amine

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