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EP1162155A2 - Verschlusskappe mit federnder Scharnieranordnung und Verpackungseinheit mit einer solchen Kappe - Google Patents

Verschlusskappe mit federnder Scharnieranordnung und Verpackungseinheit mit einer solchen Kappe Download PDF

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Publication number
EP1162155A2
EP1162155A2 EP01401277A EP01401277A EP1162155A2 EP 1162155 A2 EP1162155 A2 EP 1162155A2 EP 01401277 A EP01401277 A EP 01401277A EP 01401277 A EP01401277 A EP 01401277A EP 1162155 A2 EP1162155 A2 EP 1162155A2
Authority
EP
European Patent Office
Prior art keywords
capsule
container
product
valve
outlet orifice
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP01401277A
Other languages
English (en)
French (fr)
Other versions
EP1162155B1 (de
EP1162155A3 (de
Inventor
Guilhem Rousselet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LOreal SA filed Critical LOreal SA
Publication of EP1162155A2 publication Critical patent/EP1162155A2/de
Publication of EP1162155A3 publication Critical patent/EP1162155A3/de
Application granted granted Critical
Publication of EP1162155B1 publication Critical patent/EP1162155B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D51/00—Closures not otherwise provided for
    • B65D51/16—Closures not otherwise provided for with means for venting air or gas
    • B65D51/1633—Closures not otherwise provided for with means for venting air or gas whereby venting occurs by automatic opening of the closure, container or other element
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D47/00—Closures with filling and discharging, or with discharging, devices
    • B65D47/04—Closures with discharging devices other than pumps
    • B65D47/20—Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge
    • B65D47/2018—Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge comprising a valve or like element which is opened or closed by deformation of the container or closure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2205/00—Venting means

Definitions

  • the present invention relates to a capsule intended to equip a container used commonly used for the packaging of certain products, in particular cosmetics (shampoos, after shampoos, etc.) or care products (body milks, moisturizers, sunscreens, etc.).
  • cosmetics shampoos, after shampoos, etc.
  • care products body milks, moisturizers, sunscreens, etc.
  • such products are packaged in walled containers deformable, in particular in polypropylene or polyethylene, and surmounted by a neck with a free edge defining an opening.
  • a capsule comprising a body slammed on the neck of the container.
  • a wall transverse of the body is crossed by an outlet, in communication with the container.
  • the capsule also includes a hinged lid on the body via a so-called “spring effect” joint.
  • the cover includes a portion, in particular in the form of a suitable pin, in the closed position of the cover, to come in engagement with the exit orifice of the capsule to close it so waterproof.
  • a spring effect joint designates a joint allowing the passage of the cover from a first position, called “closing” to a second position called “maximum opening”, by pivoting around an axis (defined for example by a film hinge), the transition from the first position to the second, and / or conversely, accompanied by the passage through an intermediate position, of unstable equilibrium in which the elastic deformation (bending, compression, stretching, etc.) of at least part of the capsule, in particular of a connection connecting the body of the capsule to the cover, passes through a maximum value.
  • the crossing of this unstable equilibrium position, at the opening and / or at the closure results from an elastic restoring force generated by the element (s) deformed elastically, in particular by the connecting element connecting the body to cover.
  • the connecting element can be under shape of a kneepad, consisting of an elbow whose opening is maximum in passing through said intermediate position.
  • Another type of effect joint spring in which the connecting element consists of a deforming strip in elongation, is described in patent EP 0 147 423.
  • Yet another type articulation with spring effect is described in patent EP 0 56 469.
  • the connecting elements deform little or not. It’s the capsule body, and / or the cover which deforms passing through the unstable equilibrium position.
  • a valve configured so as to move apart under the pressure of the product inside the container, to authorize the distribution of the product, and to return to its closed position when the pressure stops.
  • a valve allows prevent (at least during a normal container overturning period) the liquid in the container will flow by gravity.
  • it allows better control the distribution of the product, in response to the deformation of the walls of the container.
  • such a valve must close sufficiently to prevent entry of liquid (especially water) into the container, from outside.
  • such a valve may allow air to enter the interior of the container, especially after each distribution, to compensate for the volume of product distributed.
  • Such a valve must be sufficiently flexible and flexible to allow a easy product distribution.
  • the material must also withstand multiple bends in one direction and in the other, with each distribution of the product.
  • the joint connecting the valve to the body must not break after some uses. She must also keep her ability to return elastically in the closed position after each use, and this throughout the Product life.
  • the material flexibility requirements are even larger when the valve must, returning to its closed position, allow an air intake inside the container. Indeed, the valve is subjected to deflections also repeated, but at a maximum angle which may be more important.
  • a first solution consists in molding the capsule equipped with a joint at spring effect by means of a rigid material, in particular polypropylene, and make the closing valve of the outlet orifice, in an elastomeric material.
  • the closing valve is made of an identical material to the material forming the capsule body, and is molded in one piece with this last.
  • the material used is of relatively low rigidity, so that meet the requirements for proper operation of the valve.
  • the cover is made, meanwhile, separate from the body of the capsule, and is mounted tightly or screwed onto the container. In other words, the articulation function spring effect is deleted.
  • this solution is not satisfactory from the point of view of cost.
  • the cover not hinged on the body of the capsule, can be lost if do not take care to replace it immediately after each use.
  • the snap-fastening of such a capsule, produced in relatively low stiffness material can be problematic for strength that he authorizes.
  • a third solution it has been proposed to produce the capsule in a single piece, with a cover hinged to a body by means of an effect hinge spring.
  • the capsule is made of a rigid material meeting the requirements required for the proper functioning of the joint.
  • no valve is disposed in the outlet.
  • It is yet another object of the invention to produce a capsule comprising a spring effect articulation, and equipped with a selective closing valve, opening in response to the pressure inside the container, and allowing a air intake inside the container, especially after each dispensing.
  • a capsule intended for equip a container said capsule comprising a) a body comprising means capable of mounting the capsule on the container, said body being crossed by an outlet; b) a shut-off valve mounted in said orifice outlet, and able to flex in response to pressure exerted by the product at the interior of the container so as to clear the outlet for the distribution of the product, and to return to its initial position when the pressure ceases ; and c) a cover mounted on the body by means of an effect articulation spring, and intended to removably cover said outlet orifice, for sealing the container, the valve being obtained by molding with the body, from a material identical to that forming the effect joint spring.
  • a spring effect articulation means a articulation allowing the passage of the cover from a first position, called “de closing "to a second position called” maximum opening ", pivoting around an axis (defined for example by a film hinge), the passage of the first position to the second, and / or vice versa, accompanied by the passage by a intermediate position, of unstable equilibrium, in which the elastic deformation (flexion, compression, stretching, etc.) of at least part of the capsule, in particular a connecting element connecting the body of the capsule to the cover, goes through a maximum value. Crossing this position of equilibrium unstable, upon opening and / or closing, results from an elastic restoring force generated by the elastically deformed element (s), in particular by the connecting element connecting the body to the cover.
  • the joint comprises a connecting element in the form of a strip of material connecting the body of the capsule to the cover.
  • a connecting strip On either side of the connecting strip are arranged two film hinges defining an axis of articulation.
  • the connecting strip In the closed position of the capsule, the connecting strip is located side of the hinge pin.
  • the connecting strip In the open position of the capsule, the connecting strip is on the other side of the hinge pin. Going from the open position to the closed position, and vice versa, the connecting strip passes through a position intermediate of maximum elongation in which it intersects the axis of articulation.
  • the connecting strip can, as described in the patent US-A-4,386,714, to be produced in the form of a kneepad.
  • the valve is configured so that, returning to said position initial, it allows an air intake inside the container so as to compensate for the volume of product distributed. So after each distribution, in resuming its initial position, the valve can go slightly beyond its position closing, so as to let air pass in the direction of the container. AT pressure balance it returns to its closed position of the outlet. This re-entering movement of the closing valve is however not necessary, in function in particular of the greater or lesser space existing between the edge device of the valve and the edge delimiting the outlet orifice.
  • the distance between the peripheral edge of the valve and the edge interior delimiting the outlet is of the order of 0.2 mm.
  • the capsule is preferably obtained by molding a polypropylene, homopolymer or copolymer.
  • the closing valve is connected to the body of the capsule by the minus a hinge material bridge. More preferably still, the valve of closure is connected to the body of the capsule by two bridges of material arranged at non-zero distance from each other.
  • the outlet orifice is formed at the bottom of a recess delimited by the body, said recess, on the side of the valve, opposite to that adjacent to the hinge bridge (s) having a profile which, in moving away from the outlet orifice, converges, preferably gradually, in direction of an axis of the latter.
  • a profile ensures flow substantially vertical to the orifice, of the product dispensed.
  • means in particular in the form of a pin, can be expected to come into engagement with the recess in which is formed the outlet orifice, so as to perfect the tightness to the closure, overall.
  • the mounting means are means able to cooperate with corresponding means of the container so as to allow the attachment of the capsule to the container by snap-fastening or by screwing. Snap-fastening is however a preferred solution.
  • an assembly is also produced for the packaging and distribution of a product, in particular a cosmetic product, comprising a container containing the product, said container having an edge free delimiting an opening equipped with a capsule according to the invention.
  • the container has walls capable of deforming in response to a pressure exerted perpendicular to their surface and to resume their shape initial when the pressure stops.
  • a container can be made in polypropylene or polyethylene.
  • Such an assembly is particularly suitable for packaging and distribution of a cosmetic product, in particular a shampoo, a conditioner, a styling gel, a milk, or a care product.
  • a cosmetic product in particular a shampoo, a conditioner, a styling gel, a milk, or a care product.
  • the assembly 100 on which the capsule 1 according to the invention is mounted consists of a bottle 101, for example, of polyethylene or polypropylene.
  • the bottle 101 has a body 102 closed by a bottom 103.
  • the body 102 is elongated cross section and is formed by two large faces 104, 105, "elastically" deformable under the effect of pressure perpendicular to the long sides of the bottle.
  • a capsule 1 is slammed onto the neck of the bottle.
  • Capsule 1 has a body 2 on which a cover 3 is hinged, via a hinge or hinge spring effect 30.
  • the body 2 of the capsule 1 has a transverse wall 4 in which is formed a recess 5 at the bottom of which is formed an orifice outlet 6.
  • the cover 3 On its face intended to come opposite the transverse wall 4, the cover 3 carries a pin 7 capable of sealingly engaging in the recess 5 so as to ensure a good seal upon closing.
  • such a capsule is obtained from one-piece molding, made of a homopolymer polypropylene having a module bending of 1450 MPa (measured with tests the conditions of which are given in ISO 178 standard, at 2 mm / min).
  • This capsule will be described more detailed with reference to the figures which follow.
  • the body 2 of the capsule comprises a covering skirt 8 of oblong cross section. Skirt 8 is opened in one end and closed at the other end by a transverse wall 4.
  • the transverse wall 4 forms a recessed part 9, oriented perpendicularly to the major axis of the capsule 1, and intended to receive the cover 3 in position closed of the latter.
  • a recess 5 In the recessed portion 9 of the wall 4, is formed a recess 5 at the bottom of which is an orifice 6 for the outlet of the product.
  • the product outlet orifice 6 is arranged along an axis X distinct from the axis Y of the capsule, which coincides with the axis of the container 101 intended to receive the capsule 1.
  • a sealing skirt 11 carried by the transverse wall 4, is formed all around of the recess 5, and centered on the Y axis of the capsule. This sealing skirt is intended to fit tightly inside the neck of the container 101.
  • skirt 12, 13 each carrying, in the vicinity of their free end, a bead 14, 15, able to cooperate by snap-fastening with a corresponding bead formed on the outer surface of the neck of the container 101.
  • a valve 20 is disposed in the outlet orifice 6, and connected to an edge delimiting said orifice by two bridges of material 21, 22, arranged so as to form a hinge, to allow the valve 20 to pivot in response to pressure from the product contained in the container 101.
  • the valve 20 is dimensioned so that that, in the closed position, there remains an annular passage 23 between the edge device of the valve 20 and the edge delimiting the outlet orifice 6, so as to authorize a return of air inside the container 101.
  • the outlet orifice 6 has a diameter of 4 mm.
  • the valve closure 20 has a diameter of 3.6 mm, and connected to the edge delimiting the orifice outlet 6 by two material bridges 21, 22, each 0.5 mm wide and 0.25 mm thick.
  • the thickness of the closing valve 20 is 0.7 mm.
  • the two material bridges 21, 22 are separated by an angular distance about 25 °. All these parameters are of course adjusted according to the material used, product to be distributed and comfort sought after distribution, including the inertia of the system.
  • valve 20 when the pressures are balanced, the valve 20 is in the closed position. shown in solid lines. In this position, the degree of closure is sufficient for one hand, when the container is turned upside down, at least for a relatively short time, prevent the product contained in the container to drain due to its weight, and on the other hand prevent any untimely entry of liquid, especially water, inside the container. In however, the annular passage 23 formed around the valve 20 allows recovery of air inside the container 101.
  • the user presses on the deformable walls 104, 105 of the container 101 so as to pressurize the product.
  • the product under pressure causes the valve 20 to flex in the opposite direction to the container 101 so as to release the outlet orifice 6, and to allow the outlet of the product.
  • the valve 20 is then in the position shown in broken lines.
  • the valve 20 returns to its closed position, letting through the container 101, via the annular passage 23, a volume of air corresponding to the volume of product distributed.
  • the body 2 of the capsule 1 is connected to a cover 3 via an effect articulation spring 30 of the toggle type.
  • a joint 30 comprises an element of connection in the form of an elbow 31 connected on the one hand to the body 2 of the capsule and on the other hand to the cover 3.
  • two film hinges 32, 34 On either side of the elbow 31 are formed two film hinges 32, 34 defining a pivot axis of the cover 3 by relative to the body 2.
  • the elbow 31 passes through an intermediate position in which its opening is maximum. After crossing this unstable equilibrium position, he recalls resiliently the cover, either in the closed position or in the maximum opening.
  • the functioning of such joints is well known, and therefore, does not require any additional detailed description.
  • a pin 7 which, in the closed position of the cover is capable of coming into engagement inside the recess 5 of so as to perfect the seal upon closing.
  • Figure 4 illustrates a variant of Figures 2 and 3.
  • the shape cylindrical of the recess 5 at the bottom of which the outlet orifice 6 is formed is replaced by a particular profile capable of promoting the flow, vertically of the outlet orifice 6, for the product flowing through the latter.
  • the recess 5 has a profile 40 which, moving away from the orifice of outlet 6, gradually converges towards the X axis of the latter.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Closures For Containers (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Pens And Brushes (AREA)
EP01401277A 2000-06-09 2001-05-16 Verschlusskappe mit federnder Scharnieranordnung und Verpackungseinheit mit einer solchen Kappe Expired - Lifetime EP1162155B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0007445 2000-06-09
FR0007445A FR2810017B1 (fr) 2000-06-09 2000-06-09 Capsule a articulation du type a effet ressort, et ensemble de conditionnement equipe d'une telle capsule

Publications (3)

Publication Number Publication Date
EP1162155A2 true EP1162155A2 (de) 2001-12-12
EP1162155A3 EP1162155A3 (de) 2001-12-19
EP1162155B1 EP1162155B1 (de) 2004-08-18

Family

ID=8851166

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01401277A Expired - Lifetime EP1162155B1 (de) 2000-06-09 2001-05-16 Verschlusskappe mit federnder Scharnieranordnung und Verpackungseinheit mit einer solchen Kappe

Country Status (8)

Country Link
US (1) US6575330B2 (de)
EP (1) EP1162155B1 (de)
JP (1) JP2002037286A (de)
AT (1) ATE273864T1 (de)
CA (1) CA2349697C (de)
DE (1) DE60104938T2 (de)
ES (1) ES2227084T3 (de)
FR (1) FR2810017B1 (de)

Cited By (1)

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Publication number Priority date Publication date Assignee Title
WO2018232066A1 (en) * 2017-06-15 2018-12-20 Illinois Tool Works Inc. Pouch flip-top for bubble valve applications

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US6948643B1 (en) * 2004-01-22 2005-09-27 Owens-Illinois Closure Inc. Fill-through container and closure package
US20050205618A1 (en) * 2004-03-18 2005-09-22 International Paper Company Container fitment having ellipsoidal opening
US20060006129A1 (en) * 2004-07-02 2006-01-12 L'oreal Dispenser head configured to be snap-fastened, a device including such a dispenser head, and a packaging device including such a dispenser head
FR2872491B1 (fr) * 2004-07-02 2007-10-05 Oreal Dispositif de conditionnement comportant une tete de distribution fixee par encliquetage
US7152763B2 (en) * 2004-07-08 2006-12-26 Stull Technologies, Inc. Container closure and method of assembly
US7387220B2 (en) * 2004-08-30 2008-06-17 Scholle Corporation Cap assembly and container used therewith
US7510095B2 (en) 2005-03-11 2009-03-31 Berry Plastics Corporation System comprising a radially aligned container and closure
USD530203S1 (en) 2005-05-13 2006-10-17 Webb Business Promotions, Incorporated Bottle cap
ITMO20060043A1 (it) * 2006-02-10 2007-08-11 Sacmi Mezzi a capsula
US20070262078A1 (en) * 2006-05-15 2007-11-15 Sheffler Robert J Spice dispensing closure with positive seal
USD574711S1 (en) 2006-10-26 2008-08-12 Robert Lederman Container with closure
EP2402261B1 (de) * 2009-02-27 2015-08-12 Taisei Kako Co., Ltd. Verschlusskappe und behälter mit verschlusskappe
NZ598818A (en) * 2009-09-11 2014-05-30 Kraft Foods Group Brands Llc Containers and methods for dispensing multiple doses of a concentrated liquid, and shelf stable concentrated liquids
USD663202S1 (en) 2011-10-03 2012-07-10 Drug Plastics & Glass Company, Inc. Bottle closure
CN102497557B (zh) * 2011-12-30 2014-10-22 旭曜科技股份有限公司 基于2x2编码单元的影像压缩、解压缩方法及系统
US11013248B2 (en) 2012-05-25 2021-05-25 Kraft Foods Group Brands Llc Shelf stable, concentrated, liquid flavorings and methods of preparing beverages with the concentrated liquid flavorings
WO2016063039A1 (en) * 2014-10-20 2016-04-28 Rieke Packaging Systems Limited Dispenser with valved nozzle closure
JP6406643B2 (ja) * 2015-04-30 2018-10-17 株式会社吉野工業所 液吐出容器
GB201517754D0 (en) * 2015-10-07 2015-11-18 Rieke Packaging Systems Ltd Liquid dosing devices
JP6752512B2 (ja) * 2016-07-28 2020-09-09 株式会社吉野工業所 吐出容器
JP6589158B1 (ja) * 2019-05-23 2019-10-16 株式会社ベッセル・ジャパン エアーバックレス構造
CH717976A9 (de) * 2020-10-16 2022-08-15 Alpla Werke Alwin Lehner Gmbh & Co Kg Behälterverschluss.
JP7672910B2 (ja) * 2021-08-03 2025-05-08 サーモス株式会社 キャップユニット及び飲料用容器
US20250326537A1 (en) * 2024-04-17 2025-10-23 Universal Trim Supply Co., Ltd. Control valve and related container kit

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EP0056469A1 (de) 1981-01-21 1982-07-28 ZELLER PLASTIK Koehn, Gräbner & Co. Schnappscharnier aus Kunststoff
US4386714A (en) 1980-10-02 1983-06-07 Louise Roberto Container cover assembly
EP0147423A1 (de) 1983-06-10 1985-07-10 Alfatechnic Ag Kunststoffverschluss.
FR2558140A3 (fr) 1984-01-14 1985-07-19 Finke Robert Kg Dispositif de fermeture a clapet
DE8616037U1 (de) 1986-06-13 1986-07-31 Twardy GmbH Biol. pharm. Fabrikation, 5012 Bedburg Verpackungsschachtel mit Originalitätsgarantie für den Inhalt
FR2599340A1 (fr) 1986-05-29 1987-12-04 Socar Emballage equipe d'un couvercle pouvant etre ferme de facon provisoire ou de facon definitive et inviolable
EP0499916A1 (de) 1991-02-15 1992-08-26 Seetal Papier Ag Aufrichteschachtel

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US4386714A (en) 1980-10-02 1983-06-07 Louise Roberto Container cover assembly
EP0056469A1 (de) 1981-01-21 1982-07-28 ZELLER PLASTIK Koehn, Gräbner & Co. Schnappscharnier aus Kunststoff
EP0147423A1 (de) 1983-06-10 1985-07-10 Alfatechnic Ag Kunststoffverschluss.
FR2558140A3 (fr) 1984-01-14 1985-07-19 Finke Robert Kg Dispositif de fermeture a clapet
FR2599340A1 (fr) 1986-05-29 1987-12-04 Socar Emballage equipe d'un couvercle pouvant etre ferme de facon provisoire ou de facon definitive et inviolable
DE8616037U1 (de) 1986-06-13 1986-07-31 Twardy GmbH Biol. pharm. Fabrikation, 5012 Bedburg Verpackungsschachtel mit Originalitätsgarantie für den Inhalt
EP0499916A1 (de) 1991-02-15 1992-08-26 Seetal Papier Ag Aufrichteschachtel

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018232066A1 (en) * 2017-06-15 2018-12-20 Illinois Tool Works Inc. Pouch flip-top for bubble valve applications
CN110997513A (zh) * 2017-06-15 2020-04-10 伊利诺斯工具制品有限公司 用于泡阀应用的袋翻转顶部
US10988295B1 (en) 2017-06-15 2021-04-27 Illinois Tool Works Inc. Pouch flip-top for bubble valve applications
CN110997513B (zh) * 2017-06-15 2021-10-15 伊利诺斯工具制品有限公司 用于泡阀应用的袋翻转顶部

Also Published As

Publication number Publication date
DE60104938D1 (de) 2004-09-23
EP1162155B1 (de) 2004-08-18
FR2810017B1 (fr) 2002-09-06
EP1162155A3 (de) 2001-12-19
ATE273864T1 (de) 2004-09-15
CA2349697A1 (fr) 2001-12-09
FR2810017A1 (fr) 2001-12-14
US6575330B2 (en) 2003-06-10
ES2227084T3 (es) 2005-04-01
US20020017535A1 (en) 2002-02-14
CA2349697C (fr) 2005-12-06
DE60104938T2 (de) 2005-08-11
JP2002037286A (ja) 2002-02-06

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