[go: up one dir, main page]

EP0919769B1 - Device for protecting the injection tip of a burner and heating device comprising it - Google Patents

Device for protecting the injection tip of a burner and heating device comprising it Download PDF

Info

Publication number
EP0919769B1
EP0919769B1 EP98402658A EP98402658A EP0919769B1 EP 0919769 B1 EP0919769 B1 EP 0919769B1 EP 98402658 A EP98402658 A EP 98402658A EP 98402658 A EP98402658 A EP 98402658A EP 0919769 B1 EP0919769 B1 EP 0919769B1
Authority
EP
European Patent Office
Prior art keywords
burner
heat shield
jacket
sio
burner according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP98402658A
Other languages
German (de)
French (fr)
Other versions
EP0919769A1 (en
Inventor
Benoít Loiselet
Philippe Beaudoin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA a Directoire et Conseil de Surveillance pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide SA, LAir Liquide SA a Directoire et Conseil de Surveillance pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Publication of EP0919769A1 publication Critical patent/EP0919769A1/en
Application granted granted Critical
Publication of EP0919769B1 publication Critical patent/EP0919769B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C5/00Disposition of burners with respect to the combustion chamber or to one another; Mounting of burners in combustion apparatus
    • F23C5/02Structural details of mounting
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D14/00Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/46Details, e.g. noise reduction means
    • F23D14/72Safety devices, e.g. operative in case of failure of gas supply
    • F23D14/76Protecting flame and burner parts

Definitions

  • the present invention relates to an output protection device ejection of a burner mounted through a wall of an oven, of the type comprising a peripheral heat shield and mounting means said heat shield around the burner ejection outlet.
  • the invention also relates to a heating device comprising a burner and a protection device of the aforementioned type.
  • the invention relates more particularly to a burner according to the preamble of claim 1.
  • the burners used are subject to strong attacks due on the one hand to thermal radiation and on the other hand to attacks chemicals caused by bodies resulting from the melting of cast iron.
  • these cooling means include a tubular protective member through which circulates cooling water. This tubular member is mounted axially at the end from the burner and protrudes inside the oven.
  • EP-A-582 521 discloses a burner provided with a thermal screen made of refractory material.
  • the object of the invention is to propose a burner comprising a device for protecting the burner ejection outlet and a heating device comprising such a burner, do not not having the disadvantages mentioned above, and which allows get rid of the existence of a bulky water circuit and source of malfunctions.
  • the invention relates to a burner according to the preamble of claim 1 , characterized in that the screen thermal includes a consumable structure of refractory material having the shape of a sleeve whose position can be adjusted and which always exceeds the ejection end of the burner by a same distance.
  • the invention further relates to a heating device comprising a burner associated with a protection device as defined above.
  • FIG. 1 a rotary furnace 10 for melting cast iron provided with a burner according to the invention.
  • the oven has an enclosure 12 with axis of horizontal revolution, noted X-X.
  • the enclosure 12 is delimited in its part running through a cylindrical wall 14 comprising, at each end 16, frustoconical obturation walls.
  • the oven has axially means 20 for introducing the metals to be melted. It comprises, at its other end, an outlet 22 for molten iron.
  • a burner 24 adapted to produce a flame 26 along the axis of the oven.
  • the burner 24 is carried by a shutter door 28 of the oven articulated around a vertical Y-Y axis.
  • the oven is supported in its running part by two crowns of rollers 30. It further comprises rotational drive means not shown.
  • the interior wall of the furnace is lined with a siliceous refractory lining 32 comprising approximately 95% by weight of SiO 2 and 4% by weight of Al 2 O 3 , the remainder consisting of impurities.
  • the door-mounted burner is shown on a larger scale in Figures 2 and 3.
  • the door has an outer metal wall 34 lined internally of a refractory material 36 similar to the coating 32 used for the interior wall of the oven.
  • the burner comprises, in a conventional manner, an envelope or body 38, generally of revolution.
  • This envelope is separated by a wall transverse 40 delimiting therein a fuel gas inlet chamber 42 arranged behind and an oxidizing gas inlet chamber 44.
  • the latter leads to the front end of the body, directly inside of the oven through an opening 46.
  • Each chamber 42, 44 is connected to a corresponding gas supply source, by a side connection, noted 42A and 44A respectively.
  • the fuel gas inlet chamber 42 communicates with three fuel injection rods 48. These rods pass through the wall 40 and are carried by it. They extend into the following envelope 38 the axis of the burner and protrude beyond the opening 46.
  • the burner casing 38 is fixedly connected to the plate 34 of the door by a support frame 50 shown schematically in the figures.
  • the burner is associated with a device 52 for protection of the burner injection outlet.
  • This device 52 essentially comprises a heat shield 54 carried by mounting means 56 of it on the cylindrical running part denoted 38A of the envelope.
  • the heat shield 54 is formed of a tubular member or sleeve. Thus, it has an external cylindrical surface denoted 54A and a passage internal cylindrical 54B. The diameter of the latter is constant and is very slightly greater than the external diameter of the current portion 38A of the burner body.
  • the sleeve passes through the lining 36 of the door through an opening cylindrical 36A.
  • a skirt 57 for protecting the heat shield formed of a tubular wall, extends the cylindrical opening 36A and projects outside the oven.
  • the skirt 57 is integral with the wall 34.
  • Sleeve 54 projects inside the oven at one front end at a distance of 7 cm. Its rear end projects outside the oven beyond plate 34 of the door. This rear end is integral mounting means 56.
  • the sleeve 54 is formed by an adobe having undergone, before assembly with the mounting means 56, a cooking step prior to a temperature above 1000 ° C.
  • the refractory material constituting the sleeve 54 is an aluminosilicate advantageously comprising by mass x% of SiO 2 and y% of Al 2 O 3 , the ratio x / y being between one third and two thirds and advantageously close to one half.
  • the sum x + y of the mass percentages of SiO 2 and Al 2 O 3 is greater than 90%.
  • the sleeve 54 In order to ensure good resistance of the sleeve 54 to the flame, as well good resistance to thermal shock, especially during phases shutdown and start-up of the oven, the sleeve is made in the manner next.
  • the materials in the form of aggregates constituting the structure of the sleeve are arranged in a cylindrical mold defining the shape of the sleeve to make an adobe.
  • tamping or clamping the adobe in the mold is made with care, in particular by adding successive layers 2 or 3 cm thick each packed with a pneumatic gland.
  • the cooking of the rammed earth is then carried out according to a standard profile of temperature rise specific to adobe to a temperature of 1350 ° C.
  • the rammed earth After cooking and demoulding, the rammed earth has the following characteristics: Basic constituent fireclay Average expansion between 0 and 1000 ° C 3.10 6 Physical characteristics Density after heating to 1000 ° C 2.3 T / m 3 Conductivity coefficient in Kcal m 2 h ° C to 600 ° C 0.7 800 ° C 0.7 1200 ° C 1 Resistance to cold compression after heating to 1100 ° C 350 Kg / cm 2 Pyroscopic cone 36 Temperature limit for use 1500 ° C Slump under load of 2 bars 0.5% at 1200 ° C and 5% at 1340 ° C.
  • the mounting means 56 are adapted to ensure movement of the heat shield 54 relative to the wall of the oven enters at least two positions spaced along the axis of the burner. They include for this purpose a guide tube 58 with an inside diameter slightly greater than the diameter external of the current part 38A of the envelope.
  • the tube 58 comprises, at its front end, a transverse annular plate 60 provided with holes fixing the screen 54.
  • the latter comprises inking 62 the threaded ends of which are received through bores and held in place by nuts 64.
  • the tube 58 has an annular flange 66 drilled with a set of tapped holes. Against this flange is applied an additional flange 68 retained on the first flange 66 by screws 70 forming means for tightening the two flanges against each other according to the axis of the burner.
  • the flange 68 has at its internal diameter, on its face in contact with the first flange 66, a countersink 72 in which is received a clamping O-ring 74 whose diameter corresponds substantially to outside diameter of the current part 38A of the envelope. So the joint O-ring 74 is in contact with the lateral surface of the envelope.
  • the clamping means 70 hold the flange 68 against the flange 66, the seal 74 is compressed and exerts a friction force on the main part 38A of the envelope, ensuring that the position of the heat shield 54.
  • this length is of the order of 7 cm.
  • the sleeve 54 When the sleeve 54 is new, as shown in FIG. 2, it has a great length, for example equal to 40 cm. So, the mounting means 56 are held behind and most of the length of the sleeve 54 extends behind the lining 36.
  • the annular end face of the sleeve contained inside the oven gradually degrades, in particular under the chemical action of iron and manganese oxide molecules produced by the slag resulting from molten iron.
  • the erosion of the end front of the sleeve is carried out along a plane extending perpendicularly to the axis of it. So in order to keep constant the length of the part of the sleeve projecting from the lining 36, the user of the oven periodically advances the sleeve to compensate for the amount of material eroded at its end.
  • the low cost of the sleeve allows it to be replaced several times during the life of the oven without significantly increasing the cost operating it.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Vertical, Hearth, Or Arc Furnaces (AREA)
  • Muffle Furnaces And Rotary Kilns (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)
  • Gas Burners (AREA)
  • Pre-Mixing And Non-Premixing Gas Burner (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Cookers (AREA)
  • Blast Furnaces (AREA)

Description

La présente invention concerne un dispositif de protection d'une sortie d'éjection d'un brûleur monté au travers d'une paroi d'un four, du type comportant un écran thermique périphérique et des moyens de montage dudit écran thermique autour de la sortie d'éjection du brûleur.The present invention relates to an output protection device ejection of a burner mounted through a wall of an oven, of the type comprising a peripheral heat shield and mounting means said heat shield around the burner ejection outlet.

L'invention concerne également un dispositif de chauffe comportant un brûleur et un dispositif de protection du type précité. L'invention se rapporte plus particulièrement à un brûleur selon le préambule de la revendication 1.The invention also relates to a heating device comprising a burner and a protection device of the aforementioned type. The invention relates more particularly to a burner according to the preamble of claim 1.

Dans certaines applications, comme par exemple dans les fours rotatifs de fusion de fonte, les brûleurs mis en oeuvre subissent de fortes agressions dues d'une part au rayonnement thermique et d'autre part aux attaques chimiques provoquées par les corps résultant de la fusion de la fonte. Dans ce type de fours, il est connu de prévoir des moyens de refroidissement à l'eau de l'extrémité d'éjection du brûleur. Ces moyens de refroidissement comportent un organe tubulaire de protection dans lequel circule de l'eau de refroidissement. Cet organe tubulaire est monté axialement à l'extrémité du brûleur et fait saillie à l'intérieur du four.In some applications, such as in rotary ovens melting of cast iron, the burners used are subject to strong attacks due on the one hand to thermal radiation and on the other hand to attacks chemicals caused by bodies resulting from the melting of cast iron. In this type of oven, it is known to provide cooling means with water from the burner discharge end. These cooling means include a tubular protective member through which circulates cooling water. This tubular member is mounted axially at the end from the burner and protrudes inside the oven.

Un tel agencement est peu pratique puisqu'il nécessite la mise en place d'un équipement coûteux et encombrant adapté pour assurer la circulation de l'eau dans l'organe de protection. De plus, la présence d'un circuit d'eau présente un risque de rupture du circuit en cas d'arrêt du four lorsque la température est inférieure à 0°C.Such an arrangement is impractical since it requires the implementation costly and bulky equipment suitable for circulation water in the protective device. In addition, the presence of a circuit of water presents a risk of circuit breakage if the oven stops when the temperature is below 0 ° C.

Il est connu de EP-A-582 521 un brûleur muni d'un écran thermique en matériau réfractaire.EP-A-582 521 discloses a burner provided with a thermal screen made of refractory material.

L'invention a pour but de proposer un brûleur comportant un dispositif de protection de la sortie d'éjection du brûleur et un dispositif de chauffe comportant un tel brûleur, ne présentant pas les inconvénients mentionnés ci-dessus, et qui permette de s'affranchir de l'existence d'un circuit d'eau encombrant et source de dysfonctionnements.The object of the invention is to propose a burner comprising a device for protecting the burner ejection outlet and a heating device comprising such a burner, do not not having the disadvantages mentioned above, and which allows get rid of the existence of a bulky water circuit and source of malfunctions.

A cet effet, l'invention a pour objet un brûleur selon le préambule de la revendication 1 , caractérisé en ce que l'écran thermique comporte une structure consommable en matériau réfractaire ayant la forme d'un manchon dont la position peut être ajustée et qui dépasse toujours l'extrémité d'éjection du brûleur d'une même distance.To this end, the invention relates to a burner according to the preamble of claim 1 , characterized in that the screen thermal includes a consumable structure of refractory material having the shape of a sleeve whose position can be adjusted and which always exceeds the ejection end of the burner by a same distance.

Suivant des modes particuliers de réalisation, le brûleur comporte l'une ou plusieurs des caractéristiques suivantes :

  • les moyens de montage sont disposés entre le brûleur et l'écran thermique, de sorte que l'écran thermique est porté par le brûleur ;
  • le brûleur comporte une enveloppe renfermant des conduites d'acheminement du combustible et du comburant, laquelle enveloppe est tubulaire sur au moins une partie de sa longueur, et les moyens de déplacement comportent un organe de guidage emmanché sur la partie tubulaire de l'enveloppe, afin d'assurer le coulissement de l'écran thermique sur l'enveloppe ;
  • l'organe de guidage est muni de deux brides accouplées, enserrant un joint torique de serrage appliqué contre la surface extérieure de la partie tubulaire de l'enveloppe, ainsi que de moyens de serrage des deux brides l'une sur l'autre, afin de comprimer le joint torique assurant ainsi un maintien en position de l'écran thermique par rapport à l'enveloppe du brûleur ;
  • le matériau réfractaire constituant ladite structure est un aluminosilicate comportant en masse x % de SiO2 et y % de Al2O3 avec un rapport x/y compris entre un tiers et deux tiers et notamment voisin de un demi ;
  • la somme x + y des pourcentages en masse de SiO2 et de Al2O3 est supérieure à 90 % ; et
  • ladite structure est un pisé ayant subi, avant montage, une étape de cuisson à une température supérieure à 1000°C.
According to particular embodiments, the burner has one or more of the following characteristics:
  • the mounting means are arranged between the burner and the heat shield, so that the heat shield is carried by the burner;
  • the burner comprises a casing containing fuel and oxidant transport pipes, which casing is tubular over at least part of its length, and the displacement means comprise a guide member fitted on the tubular part of the casing, to ensure the sliding of the heat shield on the envelope;
  • the guide member is provided with two coupled flanges, enclosing a tightening O-ring applied against the external surface of the tubular part of the envelope, as well as means for tightening the two flanges one on the other, so compressing the O-ring thus ensuring that the heat shield is held in position relative to the burner casing;
  • the refractory material constituting said structure is an aluminosilicate comprising by mass x% of SiO 2 and y% of Al 2 O 3 with a ratio x / including between a third and two thirds and in particular close to a half;
  • the sum x + y of the mass percentages of SiO 2 and Al 2 O 3 is greater than 90%; and
  • said structure is an adobe having undergone, before assembly, a cooking step at a temperature above 1000 ° C.

L'invention a en outre pour objet un dispositif de chauffe comportant un brûleur associé à un dispositif de protection tel que défini ci-dessus.The invention further relates to a heating device comprising a burner associated with a protection device as defined above.

L'invention sera mieux comprise à la lecture de la description qui va suivre, donnée uniquement à titre d'exemple et faite en se référant aux dessins sur lesquels :

  • la figure 1 est une vue schématique en coupe longitudinale d'un four rotatif de fusion de fonte muni d'un brûleur selon l'invention ;
  • la figure 2 est une vue en coupe longitudinale d'un brûleur associé à un dispositif neuf de protection selon l'invention ; et
  • la figure 3 est une vue en coupe longitudinale du brûleur de la figure 1 associé à un dispositif de protection selon l'invention ayant déjà subi une longue période de fonctionnement.
The invention will be better understood on reading the description which follows, given solely by way of example and made with reference to the drawings in which:
  • Figure 1 is a schematic longitudinal sectional view of a rotary smelting furnace provided with a burner according to the invention;
  • Figure 2 is a longitudinal sectional view of a burner associated with a new protection device according to the invention; and
  • Figure 3 is a longitudinal sectional view of the burner of Figure 1 associated with a protection device according to the invention having already undergone a long period of operation.

Sur la figure 1 est représenté un four rotatif 10 de fusion de fonte muni d'un brûleur selon l'invention. Le four comporte une enceinte 12 à axe de révolution horizontal, noté X-X. L'enceinte 12 est délimitée dans sa partie courante par une paroi cylindrique 14 comportant, à chaque extrémité 16, des parois d'obturation tronconiques. A une extrémité 18, le four comporte axialement des moyens 20 d'introduction des métaux à fondre. Il comporte, à son autre extrémité, une sortie 22 pour la fonte en fusion.In Figure 1 is shown a rotary furnace 10 for melting cast iron provided with a burner according to the invention. The oven has an enclosure 12 with axis of horizontal revolution, noted X-X. The enclosure 12 is delimited in its part running through a cylindrical wall 14 comprising, at each end 16, frustoconical obturation walls. At one end 18, the oven has axially means 20 for introducing the metals to be melted. It comprises, at its other end, an outlet 22 for molten iron.

Suivant l'axe X-X est disposé, à l'opposé de l'extrémité 18 d'arrivée des matériaux à fondre, un brûleur 24 adapté pour produire une flamme 26 suivant l'axe du four. Le brûleur 24 est porté par une porte 28 d'obturation du four articulée autour d'un axe Y-Y vertical. Le four est supporté dans sa partie courante par deux couronnes de galets 30. Il comporte en outre des moyens d'entraínement en rotation non représentés.Along the axis X-X is arranged, opposite the end 18 of arrival materials to be melted, a burner 24 adapted to produce a flame 26 along the axis of the oven. The burner 24 is carried by a shutter door 28 of the oven articulated around a vertical Y-Y axis. The oven is supported in its running part by two crowns of rollers 30. It further comprises rotational drive means not shown.

La paroi intérieure du four est tapissée d'un revêtement réfractaire siliceux 32 comportant environ 95 % en poids de SiO2 et 4 % en poids de Al2O3, le reste étant constitué d'impuretés.The interior wall of the furnace is lined with a siliceous refractory lining 32 comprising approximately 95% by weight of SiO 2 and 4% by weight of Al 2 O 3 , the remainder consisting of impurities.

Le brûleur monté sur la porte est représenté à plus grande échelle sur les figures 2 et 3.The door-mounted burner is shown on a larger scale in Figures 2 and 3.

La porte comporte une paroi métallique extérieure 34 garnie intérieurement d'un matériau réfractaire 36 analogue au revêtement 32 utilisé pour la paroi intérieure du four.The door has an outer metal wall 34 lined internally of a refractory material 36 similar to the coating 32 used for the interior wall of the oven.

Le brûleur comporte, de manière classique, une enveloppe ou corps 38, généralement de révolution. Cette enveloppe est séparée par une paroi transversale 40 délimitant dans celle-ci une chambre d'arrivée du gaz combustible 42 disposée en arrière et une chambre d'arrivée du gaz comburant 44. Cette dernière débouche à l'extrémité avant du corps, directement à l'intérieur du four par une ouverture 46. Chaque chambre 42, 44 est reliée à une source d'alimentation en gaz correspondante, par un piquage latérale, noté 42A et 44A respectivement.The burner comprises, in a conventional manner, an envelope or body 38, generally of revolution. This envelope is separated by a wall transverse 40 delimiting therein a fuel gas inlet chamber 42 arranged behind and an oxidizing gas inlet chamber 44. The latter leads to the front end of the body, directly inside of the oven through an opening 46. Each chamber 42, 44 is connected to a corresponding gas supply source, by a side connection, noted 42A and 44A respectively.

La chambre 42 d'arrivée du gaz combustible communique avec trois cannes 48 d'injection du gaz combustible. Ces cannes traversent la paroi 40 et sont portées par celle-ci. Elles s'étendent dans l'enveloppe 38 suivant l'axe du brûleur et font saillie au-delà de l'ouverture 46.The fuel gas inlet chamber 42 communicates with three fuel injection rods 48. These rods pass through the wall 40 and are carried by it. They extend into the following envelope 38 the axis of the burner and protrude beyond the opening 46.

L'enveloppe 38 du brûleur est reliée fixement à la plaque 34 de la porte par un bâti de support 50 représenté schématiquement sur les figures.The burner casing 38 is fixedly connected to the plate 34 of the door by a support frame 50 shown schematically in the figures.

En outre, selon l'invention, le brûleur est associé à un dispositif 52 de protection de la sortie d'injection du brûleur. Ce dispositif 52 comporte essentiellement un écran thermique 54 porté par des moyens 56 de montage de celui-ci sur la partie courante cylindrique notée 38A de l'enveloppe.In addition, according to the invention, the burner is associated with a device 52 for protection of the burner injection outlet. This device 52 essentially comprises a heat shield 54 carried by mounting means 56 of it on the cylindrical running part denoted 38A of the envelope.

L'écran thermique 54 est formé d'un organe tubulaire ou manchon. Ainsi, il présente une surface cylindrique externe notée 54A et un passage cylindrique interne 54B. Le diamètre de ce dernier est constant et est très légèrement supérieur au diamètre externe de la partie courante 38A du corps de brûleur. La sortie d'éjection du brûleur où débouchent les extrémités des cannes 48 et de la chambre 44 est reçue dans le passage 54B, le manchon étant partiellement engagé sur la partie courante 38A du corps.The heat shield 54 is formed of a tubular member or sleeve. Thus, it has an external cylindrical surface denoted 54A and a passage internal cylindrical 54B. The diameter of the latter is constant and is very slightly greater than the external diameter of the current portion 38A of the burner body. The burner ejection outlet where the ends open rods 48 and chamber 44 is received in passage 54B, the sleeve being partially engaged on the current part 38A of the body.

Ainsi, le manchon traverse le garnissage 36 de la porte par une ouverture cylindrique 36A. Une jupe 57 de protection de l'écran thermique, formée d'une paroi tubulaire, prolonge l'ouverture cylindrique 36A et fait saillie en dehors du four. La jupe 57 est solidaire de la paroi 34.Thus, the sleeve passes through the lining 36 of the door through an opening cylindrical 36A. A skirt 57 for protecting the heat shield, formed of a tubular wall, extends the cylindrical opening 36A and projects outside the oven. The skirt 57 is integral with the wall 34.

Le manchon 54 fait saillie à l'intérieur du four à une extrémité avant suivant une distance de 7 cm. Son extrémité arrière fait saillie en dehors du four au-delà de la plaque 34 de la porte. Cette extrémité arrière est solidaire des moyens de montage 56.Sleeve 54 projects inside the oven at one front end at a distance of 7 cm. Its rear end projects outside the oven beyond plate 34 of the door. This rear end is integral mounting means 56.

Le manchon 54 est formé par un pisé ayant subi, avant assemblage avec les moyens de montage 56, une étape de cuisson préalable à une température supérieure à 1000°C.The sleeve 54 is formed by an adobe having undergone, before assembly with the mounting means 56, a cooking step prior to a temperature above 1000 ° C.

Le matériau réfractaire constituant le manchon 54 est un aluminosilicate comportant avantageusement en masse x % de SiO2 et y % de Al2O3, le rapport x/y étant compris entre un tiers et deux tiers et avantageusement voisin de un demi.The refractory material constituting the sleeve 54 is an aluminosilicate advantageously comprising by mass x% of SiO 2 and y% of Al 2 O 3 , the ratio x / y being between one third and two thirds and advantageously close to one half.

De plus, la somme x + y des pourcentages en masse de SiO2 et de Al2O3 est supérieur à 90 %.In addition, the sum x + y of the mass percentages of SiO 2 and Al 2 O 3 is greater than 90%.

Le tableau qui suit décrit, à titre d'exemple, la composition du manchon 54 analysée par une méthode de fluorescence X. Le manchon a été analysé après usage dans un four. La composition a été déterminée en trois points distincts du manchon localisés comme suit :

  • EXTRADOS : partie du manchon faisant saillie dans le four, hors face d'extrémité avant ;
  • INTRADOS : partie courante du manchon, notamment dans la zone arrière de celui-ci ;
  • CRASSE : face d'extrémité avant du manchon, c'est-à-dire la partie annulaire en cours de dégradation à l'avant du manchon.
  • ELEMENT RESULTATS EN % EXTRADOS INTRADOS CRASSE SiO2 47.20 47.38 30.43 Al2O3 45.97 46.23 37.58 Fe2O3 total 1.49 1.47 28.33 P2O5 2.50 2.18 1.19 TiO2 1.21 1.21 0.59 CaO 0.29 0.26 0.25 MgO 0.21 0.20 0.19 MnO 0.01 0.01 0.13 K2O 0.61 0.60 0.28 Na2O 0.11 0.10 0.06 ZnO --- --- 0.4 ZrO2 --- --- 0.10 Perte au feu 0.18 0.16 0.47 : gain au feu TOTAL 99.78 99.80 99.53 PHASES MINERALOGIQUES Sillimanite Sillimanite Al2O3,SiO2 Al2O3,SiO2 Cristobalite SiO2 Cristobalite SiO2 Andalousite Andalousite Al2O3,SiO2 Al2O3,SiO2 Quartz SiO2 (traces) Quartz SiO2 (traces) The following table describes, by way of example, the composition of the sleeve 54 analyzed by an X-ray fluorescence method. The sleeve was analyzed after use in an oven. The composition was determined at three distinct points on the sleeve located as follows:
  • EXTRADOS: part of the sleeve protruding into the oven, outside the front end face;
  • INTRADOS: running part of the sleeve, in particular in the rear area thereof;
  • CRASSE: front end face of the sleeve, that is to say the annular part in the process of degradation at the front of the sleeve.
  • ELEMENT RESULTS IN% EXTRADOS soffit DIRT SiO 2 47.20 47.38 30.43 Al 2 O 3 45.97 46.23 37.58 Fe 2 O 3 total 1.49 1.47 28.33 P 2 O 5 2.50 2.18 1.19 TiO 2 1.21 1.21 0.59 CaO 0.29 0.26 0.25 MgO 0.21 0.20 0.19 MnO 0.01 0.01 0.13 K 2 O 0.61 0.60 0.28 Na 2 O 0.11 0.10 0.06 ZnO --- --- 0.4 ZrO 2 --- --- 0.10 Fire loss 0.18 0.16 0.47: gain on fire TOTAL 99.78 99.80 99.53 MINERALOGICAL PHASES sillimanite sillimanite Al 2 O 3 , SiO 2 Al 2 O 3 , SiO 2 Cristobalite SiO 2 Cristobalite SiO 2 andalusite andalusite Al 2 O 3 , SiO 2 Al 2 O 3 , SiO 2 Quartz SiO 2 (traces) Quartz SiO 2 (traces)

    Afin d'assurer une bonne tenue du manchon 54 à la flamme, ainsi qu'une bonne résistance au choc thermique, notamment lors des phases d'arrêt et de mise en marche du four, le manchon est réalisé de la manière suivante.In order to ensure good resistance of the sleeve 54 to the flame, as well good resistance to thermal shock, especially during phases shutdown and start-up of the oven, the sleeve is made in the manner next.

    Les matériaux sous forme de granulats constituant la structure du manchon sont disposés dans un moule cylindrique définissant la forme du manchon afin de réaliser un pisé. The materials in the form of aggregates constituting the structure of the sleeve are arranged in a cylindrical mold defining the shape of the sleeve to make an adobe.

    Pour assurer un frittage correct, le damage ou serrage du pisé dans le moule est réalisé avec soin, notamment par ajout de couches successives de 2 ou 3 cm d'épaisseur chacune damée avec un fouloir pneumatique.To ensure correct sintering, tamping or clamping the adobe in the mold is made with care, in particular by adding successive layers 2 or 3 cm thick each packed with a pneumatic gland.

    La cuisson du pisé est ensuite réalisée selon un profil standard de montée en température propre aux pisés jusqu'à une température de 1350°C.The cooking of the rammed earth is then carried out according to a standard profile of temperature rise specific to adobe to a temperature of 1350 ° C.

    Après cuisson et démoulage, le pisé présente les caractéristiques suivantes : Constituant de base Chamotte Dilatation moyenne entre 0 et 1000°C 3.106 Caractéristiques physiques Densité après chauffage à 1000°C 2.3 T/m3 Coefficient de conductibilité en Kcal m2h°C à 600°C 0.7          800°C 0.7          1200°C 1 Résistance à la compression à froid après chauffe à 1100°C 350 Kg/cm2 Cône pyroscopique 36 Température limite d'emploi 1500°C Affaissement sous charge de 2 bars 0.5 % à 1200°C et 5 % à 1340°C. After cooking and demoulding, the rammed earth has the following characteristics: Basic constituent fireclay Average expansion between 0 and 1000 ° C 3.10 6 Physical characteristics Density after heating to 1000 ° C 2.3 T / m 3 Conductivity coefficient in Kcal m 2 h ° C to 600 ° C 0.7 800 ° C 0.7 1200 ° C 1 Resistance to cold compression after heating to 1100 ° C 350 Kg / cm 2 Pyroscopic cone 36 Temperature limit for use 1500 ° C Slump under load of 2 bars 0.5% at 1200 ° C and 5% at 1340 ° C.

    Les moyens de montage 56 sont adaptés pour assurer un déplacement de l'écran thermique 54 par rapport à la paroi du four entre au moins deux positions espacées suivant l'axe du brûleur. Ils comportent à cet effet un tube de guidage 58 de diamètre intérieur légèrement supérieur au diamètre externe de la partie courante 38A de l'enveloppe. Le tube 58 comporte, à son extrémité avant, une plaque annulaire transversale 60 munie de perçages de fixation de l'écran 54. A cet effet, celui-ci comporte des encrages 62 dont les extrémités filetées sont reçues au travers des perçages et maintenues en place par des écrous 64.The mounting means 56 are adapted to ensure movement of the heat shield 54 relative to the wall of the oven enters at least two positions spaced along the axis of the burner. They include for this purpose a guide tube 58 with an inside diameter slightly greater than the diameter external of the current part 38A of the envelope. The tube 58 comprises, at its front end, a transverse annular plate 60 provided with holes fixing the screen 54. For this purpose, the latter comprises inking 62 the threaded ends of which are received through bores and held in place by nuts 64.

    A son extrémité arrière, le tube 58 comporte une bride annulaire 66 percée d'un ensemble de trous taraudés. Contre cette bride est appliquée une bride complémentaire 68 retenue sur la première bride 66 par des vis 70 formant des moyens de serrage des deux brides l'une contre l'autre suivant l'axe du brûleur.At its rear end, the tube 58 has an annular flange 66 drilled with a set of tapped holes. Against this flange is applied an additional flange 68 retained on the first flange 66 by screws 70 forming means for tightening the two flanges against each other according to the axis of the burner.

    La bride 68 comporte au niveau de son diamètre intérieur, sur sa face en contact avec la première bride 66, un lamage 72 dans lequel est reçu un joint torique de serrage 74 dont le diamètre correspond sensiblement au diamètre extérieur de la partie courante 38A de l'enveloppe. Ainsi, le joint torique 74 est en contact avec la surface latérale de l'enveloppe.The flange 68 has at its internal diameter, on its face in contact with the first flange 66, a countersink 72 in which is received a clamping O-ring 74 whose diameter corresponds substantially to outside diameter of the current part 38A of the envelope. So the joint O-ring 74 is in contact with the lateral surface of the envelope.

    On comprend que, lorsque les moyens de serrage 70 sont desserrés, le joint torique 74 n'étant pas comprimé, le tube 58 est libre de coulisser axialement le long de la partie courante 38A de l'enveloppe depuis une position reculée représentée sur la figure 2 jusqu'à une position avancée représentée sur la figure 3. Il entraíne avec lui l'écran thermique 54.It is understood that, when the clamping means 70 are released, the O-ring 74 not being compressed, the tube 58 is free to slide axially along the current part 38A of the envelope from a position retracted shown in Figure 2 to an advanced position shown in Figure 3. It carries with it the heat shield 54.

    Au contraire, lorsque les moyens de serrage 70 maintiennent la bride 68 contre la bride 66, le joint 74 est comprimé et exerce une force de frottement sur la partie courante 38A de l'enveloppe, assurant un maintien en position de l'écran thermique 54. Ainsi, en fonction de la longueur du manchon 54, la position de l'écran thermique peut être ajustée, de sorte que le manchon 54 fasse saillie par rapport au garnissage 36 sur une longueur prédéterminée. Avantageusement, cette longueur est de l'ordre de 7 cm.On the contrary, when the clamping means 70 hold the flange 68 against the flange 66, the seal 74 is compressed and exerts a friction force on the main part 38A of the envelope, ensuring that the position of the heat shield 54. Thus, as a function of the length of the sleeve 54, the position of the heat shield can be adjusted, so that the sleeve 54 protrudes from lining 36 over a length predetermined. Advantageously, this length is of the order of 7 cm.

    Lorsque le manchon 54 est neuf, comme représenté sur la figure 2, celui-ci présente une grande longueur, par exemple égale à 40 cm. Ainsi, les moyens de montage 56 sont maintenus en arrière et l'essentiel de la longueur du manchon 54 s'étend en arrière de la garniture 36.When the sleeve 54 is new, as shown in FIG. 2, it has a great length, for example equal to 40 cm. So, the mounting means 56 are held behind and most of the length of the sleeve 54 extends behind the lining 36.

    Pendant le fonctionnement du brûleur, la face annulaire d'extrémité du manchon contenue à l'intérieur du four se dégrade progressivement, notamment sous l'action chimique des molécules d'oxydes de fer et de manganèse produites par le laitier résultant de la fonte en fusion.During burner operation, the annular end face of the sleeve contained inside the oven gradually degrades, in particular under the chemical action of iron and manganese oxide molecules produced by the slag resulting from molten iron.

    Avec la composition et la structure retenues pour le matériau réfractaire constituant le manchon 54, on constate que l'érosion de l'extrémité avant du manchon s'effectue suivant un plan s'étendant perpendiculairement à l'axe de celui-ci. Ainsi, afin de maintenir constante la longueur de la partie du manchon faisant saillie par rapport à la garniture 36, l'utilisateur du four avance périodiquement le manchon pour compenser la quantité de matière érodée à son extrémité.With the composition and structure chosen for the refractory material constituting the sleeve 54, it can be seen that the erosion of the end front of the sleeve is carried out along a plane extending perpendicularly to the axis of it. So in order to keep constant the length of the part of the sleeve projecting from the lining 36, the user of the oven periodically advances the sleeve to compensate for the amount of material eroded at its end.

    Comme représenté sur la figure 3, après un certain temps de fonctionnement, les moyens de montage 56 sont pratiquement totalement reçus à l'intérieur de la jupe 57 et la longueur restante du manchon est réduite à l'épaisseur du garnissage 36 et à la longueur faisant saillie par rapport à celui-ci à l'intérieur du four.As shown in Figure 3, after a certain period of operation, mounting means 56 are almost completely received inside the skirt 57 and the remaining length of the sleeve is reduced to the thickness of the lining 36 and the length projecting from this inside the oven.

    On conçoit qu'avec un tel dispositif, l'extrémité du brûleur est en permanence correctement protégée, l'écran thermique dépassant toujours l'extrémité d'éjection du brûleur d'une même distance.It is understood that with such a device, the end of the burner is permanently properly protected, the heat shield always protruding beyond the end the same distance from the burner.

    Bien que le matériau constituant le manchon 54 subisse une érosion, celle-ci est suffisamment lente pour permettre qu'un réglage périodique de la position de l'écran thermique suffise pour éviter une dégradation de l'extrémité du brûleur.Although the material constituting the sleeve 54 undergoes erosion, this is slow enough to allow periodic adjustment of the position of the heat shield is sufficient to avoid degradation of the end of the burner.

    Enfin, le faible coût du manchon permet qu'il soit remplacé plusieurs fois au cours de la vie du four sans qu'il grève considérablement le coût d'exploitation de celui-ci.Finally, the low cost of the sleeve allows it to be replaced several times during the life of the oven without significantly increasing the cost operating it.

    Claims (9)

    1. Burner comprising a jacket (38) containing pipes (34, 48) conveying the fuel and the oxidizing agent and equipped at its ejection outlet with a protective device of the heat shield type, characterized in that the heat shield (54) has a consumable structure made of refractory material in the form of a sleeve (54) the position of which can be adjusted so that it always protrudes by the same amount beyond the ejection end of the burner.
    2. Burner according to Claim 1, characterized in that it comprises means of moving the heat shield (54).
    3. Burner according to Claim 1 or 2, characterized in that it comprises mounting means (56) arranged between the body of the burner (24) and the heat shield (34), such that the heat shield is borne by the burner (24).
    4. Burner according to either of Claims 2 and 3, characterized in that the jacket (38) is tubular over at least part of its length, and in that the movement means comprise a guide member (58) pushed over the tubular part (38A) of the jacket, so as to allow the heat shield (54) to slide along the jacket (38).
    5. Burner according to Claim 4, characterized in that the guide member (58) is equipped with two coupled flanges (66, 68) trapping a gripping O-ring (74) pressed against the exterior surface of the tubular part (38A) of the jacket (38), and means (70) of clamping the two flanges together so as to compress the O-ring (74), thus keeping the heat shield (54) in position relative to the jacket (38) of the burner.
    6. Burner according to any one of the preceding claims, characterized in that the refractory material of which the said structure is made is an aluminosilicate containing, by mass, x% of SiO2 and y% of Al2O3 with an x/y ratio of between one third and two thirds and, in particular, close to one half.
    7. Burner according to Claim 6, characterized in that the sum x + y of the percentages by mass of SiO2 and Al2O3 exceeds 90%.
    8. Burner according to Claim 6 or 7, characterized in that the said structure is a ramming mass which, prior to mounting, has been baked at a temperature in excess of 1000°C.
    9. Heating device comprising a burner (24) according to any one of the preceding claims, designed to be mounted through the wall (28) of a furnace.
    EP98402658A 1997-12-01 1998-10-26 Device for protecting the injection tip of a burner and heating device comprising it Expired - Lifetime EP0919769B1 (en)

    Applications Claiming Priority (2)

    Application Number Priority Date Filing Date Title
    FR9715089 1997-12-01
    FR9715089A FR2771799B1 (en) 1997-12-01 1997-12-01 PROTECTION DEVICE FOR THE INJECTION END OF A BURNER AND HEATING DEVICE COMPRISING SAME

    Publications (2)

    Publication Number Publication Date
    EP0919769A1 EP0919769A1 (en) 1999-06-02
    EP0919769B1 true EP0919769B1 (en) 2003-07-02

    Family

    ID=9514002

    Family Applications (1)

    Application Number Title Priority Date Filing Date
    EP98402658A Expired - Lifetime EP0919769B1 (en) 1997-12-01 1998-10-26 Device for protecting the injection tip of a burner and heating device comprising it

    Country Status (12)

    Country Link
    US (1) US6089858A (en)
    EP (1) EP0919769B1 (en)
    JP (1) JPH11229009A (en)
    KR (1) KR19990062680A (en)
    AR (1) AR017774A1 (en)
    BR (1) BR9805317A (en)
    DE (1) DE69816000T2 (en)
    ES (1) ES2203908T3 (en)
    FR (1) FR2771799B1 (en)
    PL (1) PL330003A1 (en)
    PT (1) PT919769E (en)
    WO (1) WO1999028676A1 (en)

    Families Citing this family (5)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    US6688881B1 (en) * 2002-08-09 2004-02-10 Fitel Usa Corp. Torch mount for high deposition glass torches
    US6884064B1 (en) 2003-11-12 2005-04-26 Khd Humboldt Wedag Ag Burner mechanism for a rotary kiln
    CN104846162A (en) * 2015-05-11 2015-08-19 夏云美 Flame jetting pipe for quenching
    CN109595547A (en) * 2017-09-30 2019-04-09 山东博研粉体技术装备有限公司 A kind of double thorax kiln spray guns
    RU2755239C1 (en) 2021-03-02 2021-09-14 Общество с ограниченной ответственностью "ЭР ЛИКИД" Fuel-oxygen burner for melting furnace, system and method for controlling the ignition and flame control of such burner

    Family Cites Families (8)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    US1930812A (en) * 1931-11-13 1933-10-17 Gilbert & Barker Mfg Co Oil burner
    US4726763A (en) * 1982-09-24 1988-02-23 Gte Products Corporation Dual insulated ceramic burner
    US4952218A (en) * 1988-08-26 1990-08-28 The Dow Chemical Company Two-fluid nozzle for atomizing a liquid solid slurry and protecting nozzle tip
    US4986748A (en) * 1989-12-15 1991-01-22 Corning Incorporated Wide range oxy-fuel burner and furnace operation
    US5267850A (en) * 1992-06-04 1993-12-07 Praxair Technology, Inc. Fuel jet burner
    FR2694623B1 (en) * 1992-08-06 1994-09-16 Air Liquide Oxy-fuel burners.
    GB2280501B (en) * 1993-07-30 1996-10-23 Co Steel Sheerness Plc Burner mounting device
    US5785721A (en) * 1997-01-31 1998-07-28 Texaco Inc. Fuel injector nozzle with preheat sheath for reducing thermal shock damage

    Also Published As

    Publication number Publication date
    DE69816000D1 (en) 2003-08-07
    US6089858A (en) 2000-07-18
    PT919769E (en) 2003-11-28
    PL330003A1 (en) 1999-06-07
    DE69816000T2 (en) 2004-05-27
    EP0919769A1 (en) 1999-06-02
    FR2771799B1 (en) 1999-12-31
    BR9805317A (en) 1999-11-09
    ES2203908T3 (en) 2004-04-16
    WO1999028676A1 (en) 1999-06-10
    KR19990062680A (en) 1999-07-26
    JPH11229009A (en) 1999-08-24
    FR2771799A1 (en) 1999-06-04
    AR017774A1 (en) 2001-10-24

    Similar Documents

    Publication Publication Date Title
    EP0296032B1 (en) Burning system with high exhaust gas exit speed
    EP0624051A1 (en) Microwave oven in particular for rapid heating at high temperatures
    EP0919769B1 (en) Device for protecting the injection tip of a burner and heating device comprising it
    CA2070506A1 (en) Cooling device for the distribution chute of a shaft kiln charging installation
    EP0646751A1 (en) Burner and use of same in a glass furnace
    EP0875319B1 (en) Tundish provided with at least one plasma torch for reheating molten metal
    EP0622140A1 (en) Casting device with controlled flow of materials smolten in a cold crucible furnace
    EP0921350A1 (en) Oxy-fuel burner
    FR2597578A1 (en) BURNER APPARATUS, IN PARTICULAR WATER HEATER, HAVING A BLOWER
    WO1998040671A1 (en) Cremating method and cremator
    EP0069654B1 (en) Apparatus for lighting a flare stack
    FR2676799A1 (en) PARTIAL SEALING DEVICE BETWEEN THE INTERIOR AND EXTERIOR OF AN ARC FURNACE.
    EP0082073A1 (en) Method and apparatus for sintering refractory walls
    EP0252843B1 (en) Plasma-heated rotary drum furnace mechanically fed with materials to be treated
    EP0073168A2 (en) Torch for cutting, welding or heating
    EP0495764B1 (en) Preheating device for a molten metal casting nozzle
    EP0302040B1 (en) Improvement for ladles to cast metal
    FR2649850A1 (en) PLASMA TORCH
    EP0750450B1 (en) Plasma torch having an essentially axisymmetrical general structure
    EP0406208B1 (en) Preheating device for a molten metal casting nozzle and metal casting installation comprising such device
    FR2683896A1 (en) Apparatus for high-temperature heat treatment of a divided solid body
    EP0015351B2 (en) Joining duct between the inside and the outside of a furnace
    FR2750140A1 (en) SPRAYING SYSTEM WITH EROSION PROTECTION MEANS
    FR2632056A1 (en) Method and device for protecting heat exchanger tubes against rust
    FR2547395A1 (en) Burner device for metallurgical fusion furnace

    Legal Events

    Date Code Title Description
    PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

    Free format text: ORIGINAL CODE: 0009012

    AK Designated contracting states

    Kind code of ref document: A1

    Designated state(s): BE CH DE ES IT LI NL PT

    AX Request for extension of the european patent

    Free format text: AL;LT;LV;MK;RO;SI

    17P Request for examination filed

    Effective date: 19991202

    AKX Designation fees paid

    Free format text: BE CH DE ES IT LI NL PT

    17Q First examination report despatched

    Effective date: 20011017

    RAP1 Party data changed (applicant data changed or rights of an application transferred)

    Owner name: L'AIR LIQUIDE, S.A. A DIRECTOIRE ET CONSEIL DE SUR

    GRAH Despatch of communication of intention to grant a patent

    Free format text: ORIGINAL CODE: EPIDOS IGRA

    GRAH Despatch of communication of intention to grant a patent

    Free format text: ORIGINAL CODE: EPIDOS IGRA

    GRAA (expected) grant

    Free format text: ORIGINAL CODE: 0009210

    AK Designated contracting states

    Designated state(s): BE CH DE ES IT LI NL PT

    REG Reference to a national code

    Ref country code: CH

    Ref legal event code: EP

    REF Corresponds to:

    Ref document number: 69816000

    Country of ref document: DE

    Date of ref document: 20030807

    Kind code of ref document: P

    REG Reference to a national code

    Ref country code: ES

    Ref legal event code: FG2A

    Ref document number: 2203908

    Country of ref document: ES

    Kind code of ref document: T3

    PLBE No opposition filed within time limit

    Free format text: ORIGINAL CODE: 0009261

    STAA Information on the status of an ep patent application or granted ep patent

    Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

    26N No opposition filed

    Effective date: 20040405

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: CH

    Payment date: 20131021

    Year of fee payment: 16

    REG Reference to a national code

    Ref country code: CH

    Ref legal event code: PL

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: CH

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20141031

    Ref country code: LI

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20141031

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: DE

    Payment date: 20161020

    Year of fee payment: 19

    Ref country code: NL

    Payment date: 20161019

    Year of fee payment: 19

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: PT

    Payment date: 20161024

    Year of fee payment: 19

    Ref country code: IT

    Payment date: 20161024

    Year of fee payment: 19

    Ref country code: BE

    Payment date: 20161019

    Year of fee payment: 19

    Ref country code: ES

    Payment date: 20161011

    Year of fee payment: 19

    REG Reference to a national code

    Ref country code: DE

    Ref legal event code: R119

    Ref document number: 69816000

    Country of ref document: DE

    REG Reference to a national code

    Ref country code: NL

    Ref legal event code: MM

    Effective date: 20171101

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: DE

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20180501

    Ref country code: PT

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20180426

    Ref country code: NL

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20171101

    REG Reference to a national code

    Ref country code: BE

    Ref legal event code: MM

    Effective date: 20171031

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: BE

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20171031

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: IT

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20171026

    REG Reference to a national code

    Ref country code: ES

    Ref legal event code: FD2A

    Effective date: 20181221

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: PT

    Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

    Effective date: 20181106

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: ES

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20171027