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EP0851038B2 - Steel and process for forming a steel article by cold plastic working - Google Patents

Steel and process for forming a steel article by cold plastic working Download PDF

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Publication number
EP0851038B2
EP0851038B2 EP97402978A EP97402978A EP0851038B2 EP 0851038 B2 EP0851038 B2 EP 0851038B2 EP 97402978 A EP97402978 A EP 97402978A EP 97402978 A EP97402978 A EP 97402978A EP 0851038 B2 EP0851038 B2 EP 0851038B2
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EP
European Patent Office
Prior art keywords
cold
steel
plastic deformation
component
rolled product
Prior art date
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Expired - Lifetime
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EP97402978A
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German (de)
French (fr)
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EP0851038B1 (en
EP0851038A1 (en
Inventor
Claude Pichard
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Ascometal France Holding SAS
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Ascometal SA
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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32Ferrous alloys, e.g. steel alloys containing chromium with boron
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires

Definitions

  • the invention relates to a use of a steel and a method for the manufacture of a steel part shaped by cold plastic deformation.
  • the steel used has a carbon content of between 0.2% and 0.42% (by weight). It is combined with either chromium, chromium - molybdenum, nickel - chromium or nickel - chromium - molybdenum or, finally, with manganese - chromium, so as to be sufficiently soaking to obtain after quenching a structure. martensitique, structure necessary to obtain after income the desired mechanical characteristics which are on the one hand a high tensile strength, on the other hand a good ductility.
  • the steel In order to be able to be cold-formed, the steel must first be subjected to a heat treatment of globulization or "maximum softening" consisting of holding at a temperature above 650 ° C. for a long time that can reach several dozens of hours. This treatment gives the steel a pearlitic structure globulized, easy to deform cold.
  • This technique has the disadvantage, in particular, of requiring three heat treatments, which complicates the manufacture and increases costs.
  • the document JP-A-50 655 40 discloses a method of manufacturing a high strength bolt of composition by weight:
  • the object of the present invention is to overcome this disadvantage by providing a means for manufacturing, by forming by cold plastic deformation, a high-grade steel mechanical part, without the need to do or treatment. maximum heat transfer or softening temperature or heat treatment of income.
  • the subject of the invention is a use of a steel according to claim 1.
  • the invention also relates to a method for the manufacture of a steel part shaped by cold plastic deformation which comprises for heat treatment only, quenching.
  • quenching is used, here and throughout, in the broad sense, that is to say that it is a fast enough cooling to obtain a structure which is practically not ferrito-pearlite and which is not essentially martensitic either.
  • the process consists in hot rolling a half-product made of steel to obtain a hot-rolled product, possibly cutting a slug in the hot-rolled product, and shaping the slug or slab by cold plastic deformation. rolled product.
  • Quenching which is intended to give the part an essentially bainitic structure, can be carried out both before and after the cold forming.
  • quenching can be carried out both directly in the hot rolling mill and after reheating austenitization over AC 3 .
  • quenching is performed after austenitization by reheating above AC 3 .
  • the invention relates to a cold-formed steel part according to claim 8.
  • the chemical composition of steel must satisfy the relationship: Mn + 0.9 x Cr + 1.3 x Mo + 1.6 x V ⁇ 2.2% which ensures that the combination of the manganese, chromium, molybdenum and vanadium contents makes it possible to obtain the desired strength characteristics and an essentially bainitic structure.
  • This steel has the advantage of having a very good ability to cold plastic deformation and to obtain, without the need for income, a bainitic type structure having excellent ductility and high characteristics mechanical.
  • the ductility can be measured by the necking Z which is greater than 45%, and even greater than 50%.
  • the tensile strength Rm is greater than 650 MPa and can exceed 1200 MPa.
  • a semi-finished steel product having the above-mentioned composition is supplied and hot-rolled after reheating above 940 ° C to obtain a hot-rolled product such as a bar , a billet, or a wire rod.
  • the hot rolling is finished at a temperature of between 900 ° C. and 1050 ° C. and the hot-rolled product is immersed directly in the hot rolling mill by cooling with the blown air, at oil, mist, water or water with polymers, according to its section.
  • the product thus obtained is then cut into pieces and then shaped in the cold form, for example by cold forging or cold forging.
  • the final mechanical characteristics, obtained directly after cold forming result, in particular, the work hardening generated by the cold forming operation.
  • the rolled product is quenched after austenitization and then cut into pieces which are shaped by cold plastic deformation, or the slugs are cut before the quenching and then the setting in cold form.
  • the austenitization consists of a heating between AC 3 and 970 ° C
  • the quenching is carried out by cooling with the blown air, the oil, the fog, the water or the water added with polymers, depending on the product section.
  • the final mechanical characteristics, obtained directly after cold forming result, in particular, the work hardening generated by the forming operation.
  • the end-of-rolling conditions are not of particular importance.
  • the cold forming operation is performed on a cut slug in the hot rolled product and quenching is carried out after cold forming.
  • the quenching is carried out after heating between AC 3 and 970 ° C and by cooling with blown air, oil, mist, water or water containing polymers.
  • the end-of-rolling conditions are also not of particular importance.
  • the invention intended more particularly for the manufacture of mechanical parts is also applicable to the manufacture of cold drawn bars, wire drawn and machine son unwound, cold drawing, drawing and unwinding being modes. particular shaping by cold plastic deformation.
  • Drawn bars and machine or drawn wire may be peeled, shaved or ground to a flawless surface condition.
  • the term "cold-formed steel part” covers all these products, and the term “slug” covers, in particular, any section of bar or wire; in some cases, the bars or wires are not cut into pieces before being cold-formed.
  • the invention may, finally, be used to manufacture pretreated bars or pretreated yarns, or more generally pretreated steel products, intended to be used in the state for the manufacture of parts by cold forming without additional heat treatment .
  • These steel products are quenched after hot rolling either directly in the hot rolling or after austenitization, in order to have a substantially bainitic structure (bainite ⁇ 50%). They can be peeled or shaved to have a flawless surface condition.
  • the cold tensile-torsion test consists of subjecting a specimen to 3 turns of cold twisting to simulate the shaping by plastic deformation, before performing a tensile test at ambient temperature.
  • the increase in resistance corresponds to the relative increase in resistance between the hardened state (after 3 turns of torsion) and the normal state (before the 3 turns of torsion).
  • the results obtained show that, even after a large cold deformation (three turns of torsion), the necking remains greater than 50%, and that the tensile strength can exceed 1200 MPa.
  • the work hardening capacity, measured by the increase in resistance after deformation by cold twisting, is high in all cases.
  • the rounds were subjected to cold forging shaping tests consisting of the measurement of the Limited Crush Rate (T.E.L.) by crushing rolled cylinders along a generator.
  • the Crush Rate Limit expressed in%, is the crush rate above which appears the first crack by cold press forging in the notch made following the generatrix of the cylinder.
  • This steel according to the prior art had previously been subjected to a globularization annealing of the perlite to make it suitable for cold deformation.
  • the steel used according to the invention has a cold forging shaping capacity substantially greater than the steel according to the prior art, despite a higher hardness, and this whatever the level of resistance, even if it is high (treatment F).
  • these steels were hot-rolled in the form of bars of diameter 28 mm. After rolling and before cold forming, the bars were subjected to a warm oil quenching treatment at 50 ° C after austenitization at 950 ° C. The bars were cut to obtain pieces from which the pieces were shaped by cold stamping at the deformation rate of 60%.
  • cold forming ability is excellent since, despite high initial strength levels and high cold deformation (60%), cold-worked parts have been found to be free of internal defects. external.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Thermotherapy And Cooling Therapy Devices (AREA)
  • Control Of Metal Rolling (AREA)
  • Inert Electrodes (AREA)
  • Metal Rolling (AREA)

Description

L'invention est relative à une utilisation d'un acier et un procédé pour la fabrication d'une pièce en acier mise en forme par déformation plastique à froid.The invention relates to a use of a steel and a method for the manufacture of a steel part shaped by cold plastic deformation.

De nombreuses pièces en acier, et en particulier des pièces de mécanique à hautes caractéristiques, sont fabriquées par forge à froid ou frappe à froid, et plus généralement par déformation plastique à froid de lopins d'acier laminé à chaud. L'acier utilisé a une teneur en carbone comprise entre 0,2 % et 0,42 % (en poids). Il est allié soit au chrome, soit au chrome - molybdène, soit nickel-chrome, soit au nickel - chrome - molybdène, soit, enfin, au manganèse - chrome, de façon à être suffisamment trempant pour permettre d'obtenir après trempe une structure martensitique, structure nécessaire pour obtenir après revenu les caractéristiques mécaniques souhaitées qui sont d'une part une résistance à la traction élevée, d'autre part une bonne ductilité. Pour pouvoir être mis en forme à froid, l'acier doit, au préalable, être soumis à un traitement thermique de globulisation ou "d'adoucissement maximal" consistant en un maintien à température supérieure à 650 °C pendant un temps long pouvant atteindre plusieurs dizaines d'heures. Ce traitement confère à l'acier une structure perlitique globulisée, facile à déformer à froid. Cette technique présente l'inconvénient, notamment, de nécessiter trois traitements thermiques, ce qui complique les fabrication et augmente les coûts.Many steel parts, and in particular mechanical parts with high characteristics, are manufactured by cold forging or cold forging, and more generally by cold plastic deformation of hot rolled steel slabs. The steel used has a carbon content of between 0.2% and 0.42% (by weight). It is combined with either chromium, chromium - molybdenum, nickel - chromium or nickel - chromium - molybdenum or, finally, with manganese - chromium, so as to be sufficiently soaking to obtain after quenching a structure. martensitique, structure necessary to obtain after income the desired mechanical characteristics which are on the one hand a high tensile strength, on the other hand a good ductility. In order to be able to be cold-formed, the steel must first be subjected to a heat treatment of globulization or "maximum softening" consisting of holding at a temperature above 650 ° C. for a long time that can reach several dozens of hours. This treatment gives the steel a pearlitic structure globulized, easy to deform cold. This technique has the disadvantage, in particular, of requiring three heat treatments, which complicates the manufacture and increases costs.

Le document EP-A-0 775 756 , cité au titre de l'Art.54(3) CBE, décrit un acier pour la fabrication de pièces forgées de composition en poids : C = 0,08% ; Si = 0,40% ; Mn = 1,30% ; Cr = 0,092 % ; Mo = 0.1% ; Cu = 0,22% ; Ni = 0,095% ; Ti = 0,023% ; Al = 0,032% ; N = 0,0075% ; B = 0,0028% ; P = 0,015% ; S = 0,072%.The document EP-A-0 775 756 , cited under Art.54 (3) EPC, describes a steel for the manufacture of forgings of composition by weight: C = 0.08%; Si = 0.40%; Mn = 1.30%; Cr = 0.092%; Mo = 0.1%; Cu = 0.22%; Ni = 0.095%; Ti = 0.023%; Al = 0.032%; N = 0.0075%; B = 0.0028%; P = 0.015%; S = 0.072%.

Le document JP-A-62 483 41 décrit un acier à haute résistance et ténacité de composition en poids C = 0,05-0,25% ; Si = 0,10-1,00% ; Mn = 0,50-3,00% ; P ≤ 0,025% ; Cr = 0,30-3,00% ; Mo ≤ 1,00% ; B = 0,0005-0,0050% ; Ti = 0,01-0,1% ; Al = 0,01-0,10% ; N ≤ 0,02%, le reste étant du fer et des impuretés, déformé à chaud, et auquel on confère une structure bainitique. Il est ensuite déformé à froid à moins de 10% puis revenu à 50-300°C pendant plus de 10 minutes.The document JP-A-62 483 41 discloses a high strength steel and tenacity of composition by weight C = 0.05-0.25%; Si = 0.10-1.00%; Mn = 0.50-3.00%; P ≤ 0.025%; Cr = 0.30-3.00%; Mo ≤ 1.00%; B = 0.0005-0.0050%; Ti = 0.01-0.1%; Al = 0.01-0.10%; N ≤ 0.02%, the remainder being iron and impurities, hot deformed, and to which a bainitic structure is imparted. It is then cold deformed to less than 10% and then returned to 50-300 ° C for more than 10 minutes.

Le document JP-A-50 655 40 décrit un procédé de fabrication d'un boulon à haute résistance de composition en poids :The document JP-A-50 655 40 discloses a method of manufacturing a high strength bolt of composition by weight:

C = 0,04-0,15% ; Si = 0,05-1,5% ; Mn = 0,5-1,5% ; Cr = 0,1-1,5% ; B = 0,0003-0,005% ; Ti = 0,01-0,04% ; Al = 0,01 - 0,06% le reste étant du fer et des impuretés. Après avoir été obtenu par déformation à froid, le boulon est chauffé au-dessus de Ac3, puis refroidi à moins de 400°C à plus de 1°C/s et durci pour obtenir une structure à base de martensite et/ou de bainite.C = 0.04-0.15%; Si = 0.05-1.5%; Mn = 0.5-1.5%; Cr = 0.1-1.5%; B = 0.0003-0.005%; Ti = 0.01-0.04%; Al = 0.01 - 0.06% the remainder being iron and impurities. After being cold-formed, the bolt is heated above Ac 3 , then cooled to less than 400 ° C to above 1 ° C / sec and cured to a martensite-based structure and / or bainite.

Le document EP-A-0 747 496 décrit des tôles laminées à chaud à haute résistance et haute emboutissabilité de composition en poids C ≤ 0,12% ; Mn = 0,5-1,5% ; Si ≤ 0,3% ; P ≤ 0,1% ; S ≤ 0,05% ; Al = 0,01-0,1% ; Cr ≤ 1%; Tieff = 0,03-0,15% ; Nb ≤ 0,05%, dont la structure comprend au moins 75% de ferrite durcie par précipitation de carbures ou carbonitrures de Ti ou Ti et Nb, le reste de la structure comprenant au moins 10% de martensite et éventuellement de la bainite et de l'austénite résiduelle.The document EP-A-0 747 496 discloses hot rolled sheets with high strength and high drawability of composition by weight C ≤ 0.12%; Mn = 0.5-1.5%; If ≤ 0.3%; P ≤ 0.1%; S ≤ 0.05%; Al = 0.01-0.1%; Cr ≤ 1%; Ti eff = 0.03-0.15%; Nb ≤ 0.05%, the structure of which comprises at least 75% of ferrite hardened by precipitation of carbides or carbonitrides of Ti or Ti and Nb, the remainder of the structure comprising at least 10% of martensite and optionally bainite and residual austenite.

Le but de la présente invention est de remédier à cet inconvénient en proposant un moyen pour fabriquer, par mise en forme par déformation plastique à froid, une pièce de mécanique en acier à hautes caractéristiques, sans qu'il soit nécessaire de faire ni un traitement thermique de globulisation ou d'adoucissement maximal ni un traitement thermique de revenu.The object of the present invention is to overcome this disadvantage by providing a means for manufacturing, by forming by cold plastic deformation, a high-grade steel mechanical part, without the need to do or treatment. maximum heat transfer or softening temperature or heat treatment of income.

A cet effet, l'invention a pour objet une utilisation d'un acier selon la revendication 1.For this purpose, the subject of the invention is a use of a steel according to claim 1.

L'invention concerne également un procédé pour la fabrication d'une pièce en acier mise en forme par déformation plastique à froid qui comporte pour seul traitement thermique, une trempe. Le terme "trempe" est utilisé, ici et dans toute la suite, au sens large, c'est à dire qu'il s'agit d'un refroidissement suffisamment rapide pour obtenir une structure qui n'est pratiquement pas ferrito-perlitique et qui n'est pas non plus essentiellement martensitique.The invention also relates to a method for the manufacture of a steel part shaped by cold plastic deformation which comprises for heat treatment only, quenching. The term "quenching" is used, here and throughout, in the broad sense, that is to say that it is a fast enough cooling to obtain a structure which is practically not ferrito-pearlite and which is not essentially martensitic either.

Outre la trempe, le procédé consiste à laminer à chaud un demi produit en acier pour obtenir un produit laminé à chaud, éventuellement à découper un lopin dans le produit laminé à chaud, et à mettre en forme par déformation plastique à froid le lopin ou le produit laminé.In addition to quenching, the process consists in hot rolling a half-product made of steel to obtain a hot-rolled product, possibly cutting a slug in the hot-rolled product, and shaping the slug or slab by cold plastic deformation. rolled product.

La trempe, qui est destinée à conférer à la pièce une structure essentiellement bainitique, peut être effectuée aussi bien avant qu'après la mise en forme à froid. Lorsqu'elle est effectuée avant la mise en forme à froid, la trempe peut être réalisée aussi bien directement dans la chaude de laminage qu'après austénitisation par réchauffage au dessus de AC3. Lorsqu'elle est effectuée après la mise en forme à froid, la trempe est réalisée après austénitisation par réchauffage au dessus de AC3.Quenching, which is intended to give the part an essentially bainitic structure, can be carried out both before and after the cold forming. When carried out before cold forming, quenching can be carried out both directly in the hot rolling mill and after reheating austenitization over AC 3 . When performed after cold forming, quenching is performed after austenitization by reheating above AC 3 .

L'invention concerne, enfin, une pièce en acier obtenue par mise en forme à froid selon la revendication 8.Finally, the invention relates to a cold-formed steel part according to claim 8.

L'invention va maintenant être décrite plus en détails et illustrée par les exemples qui suivent.The invention will now be described in more detail and illustrated by the following examples.

La composition chimique de l'acier utilisé dans le cadre de l'invention comprend, en % en poids :

  • de 0,03 % à 0,16 %, et, de préférence, de 0,06 % à 0,12 % de carbone pour obtenir une importante aptitude à l'écrouissage lors de la mise en forme à froid, éviter la formation de gros carbures défavorables à la ductilité, et permettre d'effectuer une mise en forme à froid sans qu'il soit nécessaire de réaliser un recuit de globulisation ou d'adoucissement maximal ;
  • de 0,5 % à 2 %, et, de préférence, de 0,8 % à 1,7 % de manganèse, pour assurer une bonne coulabilité, obtenir une trempabilité suffisante et les caractéristiques mécaniques souhaitées ;
  • de 0,1 % à 0,35 % de silicium, élément nécessaire pour assurer la désoxydation de l'acier, en particulier lorsque la teneur en aluminium est faible, mais, qui, en trop forte quantité, favorise un durcissement préjudiciable à l'aptitude à la mise en forme à froid et à la ductilité ;
  • de 0 % à 1,8 %, et, de préférence, de 0,1 % à 1,5 % de chrome pour ajuster la trempabilité et les caractéristiques mécaniques au niveau souhaité pour les pièces, sans dépasser une valeur qui durcirait trop l'acier à l'état brut de laminage ou conduirait à la formation de martensite préjudiciable à l'aptitude à la mise en forme à froid et à la ductilité;
  • de 0 % à 0,25 %, et, de préférence, de 0,07 % à 0,15 % de molybdène pour, en synergie avec le bore, assurer une trempabilité homogène dans les diverses sections de la pièce ;
  • éventuellement, de 0 % à 0,15 %, et de préférence, moins de 0,1 % de vanadium pour obtenir de hautes caractéristiques mécaniques (résistance à la traction) lorsque celles-ci sont recherchées ;
  • de 0,0005 % à 0,005 %, et, de préférence, de 0,001 % à 0,004 % de bore pour augmenter la trempabilité nécessaire ;
  • de 0 % à 0,05 %, et, de préférence, de 0,001 % à 0,035 % d'aluminium, et de 0 % à 0,05 %, et, de préférence, de 0,001 % à 0,03 % de titane, la somme des teneurs en aluminium et en titane devant être supérieure ou égale à 3,5 fois la teneur en azote, afin d'obtenir un grain fin nécessaire pour une bonne aptitude à la mise en forme à froid et une bonne ductilité;
  • de 0,004 % à 0,012 %, et, de préférence, de 0,006 % à 0,01 % d'azote, pour contrôler la taille du grain par formation de nitrures d'aluminium, de titane ou de vanadium, sans former de nitrures de bore ;
  • plus de 0,001 % de soufre afin d'assurer un minimum d'aptitude à l'usinage pour permettre d'effectuer des retouches finales sur les pièces, mais moins de 0,09 % pour garantir une bonne aptitude à la mise en forme à froid ; l'aptitude à l'usinage combinée avec une bonne aptitude à la mise en forme par déformation plastique à froid peut être améliorée soit par une addition de calcium jusqu'à 0,005 %, soit par une addition de tellure jusqu'à 0,01 %, il est alors préférable que le rapport Te/S reste voisin de 0,1, soit par une addition de sélénium jusqu'à 0,05 %, il est alors préférable que la teneur en sélénium reste voisine de la teneur en soufre, soit, enfin, par une addition de plomb jusqu'à 0,3 %, dans ce cas, la teneur en soufre doit être réduite ;
le reste est du fer et des impuretés résultant de l'élaboration.The chemical composition of the steel used in the context of the invention comprises, in% by weight:
  • from 0.03% to 0.16%, and preferably from 0.06% to 0.12% carbon to obtain a high work hardening ability during cold forming, to avoid the formation of large carbides disadvantageous to ductility, and allow cold forming without the need to perform a globulization annealing or maximum softening;
  • from 0.5% to 2%, and preferably from 0.8% to 1.7% of manganese, to ensure good flowability, to obtain sufficient quenchability and the desired mechanical characteristics;
  • from 0.1% to 0.35% of silicon, which element is necessary to ensure the deoxidation of the steel, in particular when the aluminum content is low, but which, in excessive amounts, favors a hardening which is detrimental to ability to cold form and ductility;
  • from 0% to 1.8%, and preferably from 0.1% to 1.5% of chromium to adjust the quenchability and mechanical characteristics to the desired level for the pieces, without exceeding a value which would harden too much steel in the raw state of rolling or would lead to the formation of martensite detrimental to the ability to cold forming and ductility;
  • from 0% to 0.25%, and preferably from 0.07% to 0.15% molybdenum for, in synergy with boron, to ensure homogeneous quenchability in the various sections of the room;
  • optionally from 0% to 0.15%, and preferably less than 0.1% vanadium to obtain high mechanical characteristics (tensile strength) when these are sought;
  • from 0.0005% to 0.005%, and preferably from 0.001% to 0.004% boron to increase the necessary quenchability;
  • from 0% to 0.05%, and preferably from 0.001% to 0.035% aluminum, and from 0% to 0.05%, and preferably from 0.001% to 0.03% titanium, the sum of aluminum and titanium contents to be greater than or equal to 3.5 times the nitrogen content, in order to obtain a fine grain necessary for good cold forming ability and good ductility;
  • from 0.004% to 0.012%, and preferably from 0.006% to 0.01% nitrogen, to control grain size by forming aluminum, titanium or vanadium nitrides, without forming boron nitrides ;
  • more than 0.001% sulfur to ensure a minimum of machinability to allow final touch-ups on parts, but less than 0.09% to ensure good cold forming ability ; Combined machinability with good formability by cold plastic deformation can be improved either by adding calcium up to 0.005% or by adding tellurium up to 0.01%. , it is then preferable that the Te / S ratio remains close to 0.1, or by adding selenium up to 0.05%, it is preferable for the selenium content to remain close to the sulfur content, ie finally, by adding lead up to 0.3%, in which case the sulfur content must be reduced;
the rest is iron and impurities resulting from the elaboration.

Les impuretés sont, notamment:

  • le phosphore, dont la teneur doit rester, de préférence, inférieure ou égale à 0,02 % pour garantir une bonne ductilité pendant et après mise en forme à froid ;
  • le cuivre et le nickel, considérés comme des résiduels, dont la teneur doit, de préférence, rester inférieure à 0,25 % pour chacun.
The impurities are, in particular:
  • phosphorus, the content of which must remain preferably less than or equal to 0.02% to ensure good ductility during and after cold forming;
  • copper and nickel, considered as residuals, the content of which should preferably remain below 0.25% for each.

Enfin, la composition chimique de l'acier doit satisfaire la relation :

        Mn + 0,9 x Cr + 1,3 x Mo + 1,6 x V ≥ 2,2%

qui assure que la combinaison des teneurs en manganèse, chrome, molybdène et vanadium permet d'obtenir les caractéristiques de résistance souhaitées et une structure essentiellement bainitique.
Finally, the chemical composition of steel must satisfy the relationship:

Mn + 0.9 x Cr + 1.3 x Mo + 1.6 x V ≥ 2.2%

which ensures that the combination of the manganese, chromium, molybdenum and vanadium contents makes it possible to obtain the desired strength characteristics and an essentially bainitic structure.

Cet acier présente l'avantage d'avoir une très bonne aptitude à la déformation plastique à froid et de permettre d'obtenir, sans qu'il soit nécessaire de faire un revenu, une structure du type bainitique ayant une excellente ductilité et de hautes caractéristiques mécaniques. En particulier, la ductilité peut être mesurée par la striction Z qui est supérieure à 45 %, et même supérieure à 50 %. La résistance à la traction Rm est supérieure à 650 MPa et peut dépasser 1200 MPa. Ces caractéristiques peuvent être obtenues aussi bien lorsque la trempe est effectuée dans la chaude de laminage avant mise en forme à froid, que lorsqu'elle est effectuée après austénitisation par chauffage au dessus de AC3, avant ou après mise en forme à froid.This steel has the advantage of having a very good ability to cold plastic deformation and to obtain, without the need for income, a bainitic type structure having excellent ductility and high characteristics mechanical. In particular, the ductility can be measured by the necking Z which is greater than 45%, and even greater than 50%. The tensile strength Rm is greater than 650 MPa and can exceed 1200 MPa. These characteristics can be obtained both when the quenching is carried out in the hot rolling before cold forming, and when it is carried out after austenitization by heating above AC 3 , before or after cold forming.

Pour fabriquer une pièce mise en forme à froid, on approvisionne un demi-produit en acier ayant la composition citée et on le lamine à chaud après réchauffage au dessus de 940 °C afin d'obtenir un produit laminé à chaud tel qu'une barre, une billette, ou un fil machine.To manufacture a cold-formed part, a semi-finished steel product having the above-mentioned composition is supplied and hot-rolled after reheating above 940 ° C to obtain a hot-rolled product such as a bar , a billet, or a wire rod.

Dans un premier mode de réalisation, le laminage à chaud est terminé à une température comprise entre 900 °C et 1050 °C et le produit laminé à chaud est trempé directement dans la chaude de laminage par refroidissement à l'air soufflé, à l'huile, au brouillard, à l'eau ou à l'eau additionnée de polymères, selon sa section. Le produit ainsi obtenu est alors découpé en lopins, puis mis en forme à froid, par exemple par forge à froid ou par frappe à froid. Les caractéristiques mécaniques finales, obtenues directement après mise en forme à froid, résultent, notamment, de l'écrouissage engendré par l'opération de mise en forme à froid.In a first embodiment, the hot rolling is finished at a temperature of between 900 ° C. and 1050 ° C. and the hot-rolled product is immersed directly in the hot rolling mill by cooling with the blown air, at oil, mist, water or water with polymers, according to its section. The product thus obtained is then cut into pieces and then shaped in the cold form, for example by cold forging or cold forging. The final mechanical characteristics, obtained directly after cold forming, result, in particular, the work hardening generated by the cold forming operation.

Dans un deuxième mode de réalisation, après laminage à chaud, soit le produit laminé est trempé après austénitisation puis découpé en lopins qu'on met en forme par déformation plastique à froid, soit on découpe les lopin avant d'effectuer la trempe puis la mise en forme à froid. Dans les deux cas, l'austénitisation consiste en un chauffage entre AC3 et 970 °C, et la trempe est effectuée par refroidissement à l'air soufflé, à l'huile, au brouillard, à l'eau ou à l'eau additionnée de polymères, selon la section du produit. Les caractéristiques mécaniques finales, obtenues directement après mise en forme à froid, résultent, notamment, de l'écrouissage engendré par l'opération de mise en forme. Dans ce mode de réalisation les conditions de fin de laminage n'ont pas d'importance particulière.In a second embodiment, after hot rolling, the rolled product is quenched after austenitization and then cut into pieces which are shaped by cold plastic deformation, or the slugs are cut before the quenching and then the setting in cold form. In both cases, the austenitization consists of a heating between AC 3 and 970 ° C, and the quenching is carried out by cooling with the blown air, the oil, the fog, the water or the water added with polymers, depending on the product section. The final mechanical characteristics, obtained directly after cold forming, result, in particular, the work hardening generated by the forming operation. In this embodiment, the end-of-rolling conditions are not of particular importance.

Dans un troisième mode de réalisation, l'opération de mise en forme à froid est effectuée sur un lopin découpé dans le produit laminé à chaud et la trempe est effectuée après mise en forme à froid. Comme dans le cas précédant, la trempe est effectuée après chauffage entre AC3 et 970 °C et par refroidissement à l'air soufflé, à l'huile, au brouillard, à l'eau ou à l'eau additionnée de polymères. Les conditions de fin de laminage n'ont pas, non plus, d'importance particulière.In a third embodiment, the cold forming operation is performed on a cut slug in the hot rolled product and quenching is carried out after cold forming. As in the preceding case, the quenching is carried out after heating between AC 3 and 970 ° C and by cooling with blown air, oil, mist, water or water containing polymers. The end-of-rolling conditions are also not of particular importance.

L'invention destinée plus particulièrement à la fabrication de pièces de mécanique, s'applique également à la fabrication de barres étirées à froid, de fils tréfilés et de fils machine déroulés, l'étirage à froid, le tréfilage et le déroulage étant des modes particuliers de mise en forme par déformation plastique à froid. Les barres étirées et les fils machine ou tréfilés peuvent être écroûtés, rasés ou rectifiés de façon à présenter un état de surface exempt de défauts. Le terme "pièce en acier mise en forme à froid" recouvre tous ces produits, et le terme "lopin" recouvre, notamment, tout tronçon de barre ou fil ; dans certains cas, les barres ou fils ne sont pas découpés en lopins avant d'être mis en forme à froid.The invention intended more particularly for the manufacture of mechanical parts, is also applicable to the manufacture of cold drawn bars, wire drawn and machine son unwound, cold drawing, drawing and unwinding being modes. particular shaping by cold plastic deformation. Drawn bars and machine or drawn wire may be peeled, shaved or ground to a flawless surface condition. The term "cold-formed steel part" covers all these products, and the term "slug" covers, in particular, any section of bar or wire; in some cases, the bars or wires are not cut into pieces before being cold-formed.

L'invention peut, enfin, être utilisée pour fabriquer des barres prétraitées ou des fils prétraités, ou plus généralement des produits sidérurgiques prétraités, destinés à être utilisés en l'état pour la fabrication de pièces par mise en formes à froid sans traitement thermique supplémentaire. Ces produits sidérurgiques sont trempés après laminage à chaud soit directement dans la chaude de laminage, soit après austénitisation, afin de présenter une structure essentiellement bainitique (bainite ≥ 50 %). Ils peuvent être écroûtés ou rasés pour présenter un état de surface exempt de défauts.The invention may, finally, be used to manufacture pretreated bars or pretreated yarns, or more generally pretreated steel products, intended to be used in the state for the manufacture of parts by cold forming without additional heat treatment . These steel products are quenched after hot rolling either directly in the hot rolling or after austenitization, in order to have a substantially bainitic structure (bainite ≥ 50%). They can be peeled or shaved to have a flawless surface condition.

L'invention va maintenant être illustrée par des exemples.The invention will now be illustrated by examples.

1 er exemple : 1st example :

On a élaboré un acier dont la composition chimique comprenait en poids :

        C = 0,065 %

        Mn = 1,33 %

        Si = 0,34 %

        S = 0,003 %

        P = 0,014 %

        Ni = 0,24%

        Cr = 0.92 %

        Mo = 0,081 %

        Cu = 0,23 %

        V = 0,003 %

        Al = 0,02 %

        Ti = 0,02 %

        N = 0,008,%

        B = 0,0035 %

remplissant donc les conditions

        Mn + 0,9 x Cr + 1,3 x Mo + 1,6 x V = 0,27% ≥ 2,2%

et

        Al + Ti = 0,040% ≥ 3,5 x N = 0,028%

A steel was developed whose chemical composition included by weight:

C = 0.065%

Mn = 1.33%

If = 0.34%

S = 0.003%

P = 0.014%

Ni = 0.24%

Cr = 0.92%

Mo = 0.081%

Cu = 0.23%

V = 0.003%

Al = 0.02%

Ti = 0.02%

N = 0.008,%

B = 0.0035%

fulfilling the conditions

Mn + 0.9 x Cr + 1.3 x Mo + 1.6 x V = 0.27% ≥ 2.2%

and

Al + Ti = 0.040% ≥ 3.5 x N = 0.028%

Avec cet acier on a fabriqué des billettes qui ont été laminées à chaud après réchauffage au dessus de 940 °C pour former des ronds (ou barres) de diamètre 16 mm, 25,5 mm et 24,8 mm.With this steel billets were manufactured which were hot rolled after reheating above 940 ° C to form rounds (or bars) of diameter 16 mm, 25.5 mm and 24.8 mm.

1) ronds de 16 mm de diamètre : 1) rounds of 16 mm in diameter:

Le laminage des ronds de diamètre 16 mm a été terminé à 990 °C et les ronds ont été trempés dans la chaude de laminage dans les trois conditions suivantes (conformes à l'invention) :

  1. A : refroidissement à la vitesse de 5,3°C/s équivalent à une trempe à l'air soufflé,
  2. B : refroidissement à la vitesse de 26°C/s équivalent à une trempe à l'huile,
  3. C : refroidissement à la vitesse de 140°C/s équivalent à une trempe à l'eau.
The rolling of rounds with a diameter of 16 mm was completed at 990 ° C. and the rounds were soaked in hot rolling under the following three conditions (in accordance with the invention):
  1. A: cooling at a speed of 5.3 ° C / s equivalent to blown air quenching,
  2. B: cooling at 26 ° C / s equivalent to oil quenching,
  3. C: Cooling at a rate of 140 ° C / s equivalent to quenching with water.

Les caractéristiques mécaniques avant mise en forme à froid des ronds trempés et leur aptitude à la mise en forme par déformation plastique à froid ont été évaluées par des essais de traction et par des essais de torsion à rupture à froid (les résultats des essais de torsion sont exprimés en "nombre de tours avant rupture de l'éprouvette"). Les résultats ont été les suivants : Condtions de trempe Dureté du rond avant torsion (HV) Résistance avant torsion(MPa) Striction Z avant torsion (%) Nombre de tours à rupture A 234 734 69 4,7 B 318 1001 73 5,2 C 350 1103 69 Mechanical characteristics prior to cold forming of hardened rounds and their ability to form by cold plastic deformation were evaluated by tensile tests and cold-break torsion tests (torsion test results). are expressed in "number of revolutions before failure of the specimen"). The results were as follows: Quenching conditions Hardness of the round front torsion (HV) Resistance before torsion (MPa) Striction Z before torsion (%) Number of laps to break AT 234 734 69 4.7 B 318 1001 73 5.2 VS 350 1103 69

La dureté et la résistance à la traction, qui varient considérablement avec les conditions de trempe, sont d'autant plus grandes que la vitesse de refroidissement est élevée. Néanmoins, dans tous les cas, la ductilité et la capacité de déformation à froid sont excellentes puisque la striction Z est toujours sensiblement supérieure à 50 %, et le nombre de tours à rupture est toujours nettement supérieur à 3.The hardness and the tensile strength, which vary considerably with the quenching conditions, are all the greater as the cooling rate is high. Nevertheless, in all cases, the ductility and cold deformation capacity are excellent since the necking Z is always substantially greater than 50%, and the number of turns to failure is still significantly greater than 3.

Afin de déterminer les caractéristiques mécaniques qu'il est possible d'obtenir sur des pièces fabriquées par mise en forme par déformation plastique à froid à partir de ces mêmes ronds, on a effectué des essais de torsion-traction à froid dont les résultats ont été les suivants : Conditions de trempe Résistance après 3 tours de torsion (MPa) Striction après 3 tours de torsion Z (%) Augmentation de la résistance après 3 tours de torsion (%) A 919 66 25% B 1189 67 19% C 1245 68 13% In order to determine the mechanical characteristics that can be obtained on parts made by forming by cold plastic deformation from these same rounds, cold tensile torsion tests were carried out, the results of which were The following : Quenching conditions Resistance after 3 turns of torsion (MPa) Striction after 3 turns of twist Z (%) Increase in resistance after 3 turns of torsion (%) AT 919 66 25% B 1189 67 19% VS 1245 68 13%

L'essai de torsion-traction à froid consiste à soumettre une éprouvette à 3 tours de torsion à froid pour simuler la mise en forme par déformation plastique, avant d'effectuer un essai de traction à température ambiante. L'augmentation de la résistance, correspond à l'accroissement relatif de résistance entre l'état écroui (après 3 tours de torsion) et l'état normal (avant les 3 tours de torsion).The cold tensile-torsion test consists of subjecting a specimen to 3 turns of cold twisting to simulate the shaping by plastic deformation, before performing a tensile test at ambient temperature. The increase in resistance corresponds to the relative increase in resistance between the hardened state (after 3 turns of torsion) and the normal state (before the 3 turns of torsion).

Les résultats obtenus montrent que, même après une importante déformation à froid (trois tours de torsion), la striction reste supérieure à 50 %, et que la résistance à la traction peut dépasser 1200 MPa. La capacité d'écrouissage, mesurée par l'augmentation de résistance après déformation par torsion à froid, est élevée dans tous les cas.The results obtained show that, even after a large cold deformation (three turns of torsion), the necking remains greater than 50%, and that the tensile strength can exceed 1200 MPa. The work hardening capacity, measured by the increase in resistance after deformation by cold twisting, is high in all cases.

2) Ronds de 25,5 mm de diamètre :2) 25.5 mm diameter rounds :

Les ronds de diamètre 25,5 mm ont été trempés avant mise en forme à froid, après austénitisation à 950°C, dans les conditions suivantes (conformes à l'invention) :

  • D : refroidissement à l'air soufflé (vitesse de refroidissement moyenne de 3,3°C/s entre 950 °C et l'ambiante)
  • E : refroidissement à l'huile (vitesse de refroidissement moyenne de 22°C/s entre 950 °C et l'ambiante)
  • F : refroidissement à l'eau (vitesse de refroidissement moyenne de 86°C/s entre 950 °C et l'ambiante)
The rounds 25.5 mm in diameter were soaked before cold forming, after austenitization at 950 ° C., under the following conditions (in accordance with the invention):
  • D: blast chilling (average cooling rate of 3.3 ° C / s between 950 ° C and ambient)
  • E: oil cooling (average cooling rate of 22 ° C / s between 950 ° C and ambient)
  • F: water cooling (average cooling rate of 86 ° C / s between 950 ° C and ambient)

Les ronds ont été soumis à des essais de mise en forme par forgeage à froid consistant en la mesure du Taux d'Ecrasement Limite (T.E.L.) par écrasement de cylindres entaillés suivant une génératrice. Le Taux d'Ecrasement Limite, exprimé en %, est le taux d'écrasement au-dessus duquel apparaît la première fissure par forgeage à froid à la presse dans l'entaille pratiquée suivant la génératrice du cylindre.The rounds were subjected to cold forging shaping tests consisting of the measurement of the Limited Crush Rate (T.E.L.) by crushing rolled cylinders along a generator. The Crush Rate Limit, expressed in%, is the crush rate above which appears the first crack by cold press forging in the notch made following the generatrix of the cylinder.

A titre de comparaison, le T.E.L. a été mesuré également sur un acier pour forge à froid suivant l'art antérieur dont la composition était :

        C = 0,37%

        Mn = 0,75 %

        Si = 0,25 %

        S = 0,005 %

        Cr = 1 %

        Mo = 0,02 %

        Al = 0,02 %

By way of comparison, the TEL was also measured on a steel for cold forging according to the prior art whose composition was:

C = 0.37%

Mn = 0.75%

If = 0.25%

S = 0.005%

Cr = 1%

Mo = 0.02%

Al = 0.02%

Cet acier suivant l'art antérieur avait été préalablement soumis à un recuit de globulisation de la perlite pour le rendre apte à la déformation à froid.This steel according to the prior art had previously been subjected to a globularization annealing of the perlite to make it suitable for cold deformation.

Les résultats obtenus ont été les suivants : Acier Traitement thermique Dureté HV Résistance (MPa) Taux d'Ecrasement Limite % Acier suivant l'invention D 249 793 52 E 303 954 52 F 355 1115 52 Acier suivant l'art antérieur Recuit de globulisation 174 547 44 The results obtained were as follows: Steel Heat treatment HV hardness Resistance (MPa) Crush Rate Limit% Steel according to the invention D 249 793 52 E 303 954 52 F 355 1115 52 Steel according to the prior art Globulation annealing 174 547 44

Au vu des Taux d'Ecrasement Limite il apparaît que l'acier utilisé selon l'invention présente une aptitude à la mise en forme par forgeage à froid sensiblement plus importante que l'acier suivant l'art antérieur, malgré une dureté plus élevée, et ceci quel que soit le niveau de résistance, même si celui-ci est élevé (traitement F).In view of the Crush Rate Limit it appears that the steel used according to the invention has a cold forging shaping capacity substantially greater than the steel according to the prior art, despite a higher hardness, and this whatever the level of resistance, even if it is high (treatment F).

3) Ronds de 24,8 mm de diamètre :3) Rounds 24.8 mm in diameter :

Après laminage et avant mise en forme à froid, des ronds de 24,8 mm de diamètre ont été trempés après austénitisation à 930 °C dans les conditions suivantes conformément à l'invention :

  • G : trempe à l'air soufflé
  • H: trempe à l'huile
After rolling and before cold forming, rounds 24.8 mm in diameter were quenched after austenitization at 930 ° C. under the following conditions according to the invention:
  • G: air-blast quenching
  • H: oil quenching

Les ronds ainsi traités ont été forgés à froid pour fabriquer des fusées de roues d'automobile dont les caractéristiques mécaniques obtenues étaient les suivantes traitement Résistance (MPa) Striction Z (%) G 741 71 H 984 74 The rounds thus treated were cold-forged to make automobile wheel-flares whose mechanical characteristics were as follows: treatment Resistance (MPa) Striction Z (%) BOY WUT 741 71 H 984 74

Il ressort de ces résultats que, quel que soit le traitement initial, la ductilité obtenue sur pièce forgée à froid est très élevée (Z ≥ 50%), et, ceci, indépendamment du niveau de résistance.These results show that, regardless of the initial treatment, the ductility obtained on the cold forged part is very high (Z ≥ 50%), and this, independently of the level of resistance.

Par ailleurs, dans les deux cas les ronds étaient tout-à-fait aptes à la mise en forme par forgeage à froid puisque les pièces se sont révélées exemptes de tout défaut tant interne qu'externe.On the other hand, in both cases the rounds were entirely suitable for cold forging shaping since the parts proved to be free of any internal and external defect.

Avec d'autres ronds de 24,8 mm de diamètre (identiques aux précédents), on a fabriqué les mêmes fusées par forgeage à froid des ronds bruts de laminage en effectuant la trempe après l'opération de mise en forme à froid. La trempe a été effectuée à l'eau après austénitisation à 940°C.With other rounds 24.8 mm in diameter (identical to the previous ones), the same rockets were made by cold forging of the rough rolling rounds by quenching after the cold forming operation. Quenching was carried out with water after austenitization at 940 ° C.

Dans ces conditions, les caractéristiques obtenues sur fusées étaient les suivantes :

  • Rm = 1077 MPa
  • Z = 73%
Under these conditions, the characteristics obtained on rockets were as follows:
  • Rm = 1077 MPa
  • Z = 73%

Ces résultats montrent qu'avec l'acier utilisé selon l'invention en effectuant une trempe après forgeage à froid d'un rond brut de laminage à chaud, on peut obtenir une très bonne ductilité (Z ≥ 50%) malgré un niveau de résistance élevé. Par ailleurs l'acier suivant l'invention s'est révélé parfaitement apte à la mise en forme par forgeage à froid à l'état brut de laminage sans nécessiter de traitement préalable de globulisation comme cela est pratiqué avec les aciers selon l'art antérieur, les fusées se sont, en effet, révélées exemptes de tout défaut tant interne qu'externe.These results show that with the steel used according to the invention by performing a quenching after cold forging of a hot rolling round, one can obtain a very good ductility (Z ≥ 50%) despite a level of resistance. Student. Furthermore, the steel according to the invention has proved perfectly suitable for shaping by cold forging in the raw state of rolling without the need for prior treatment of globulization as is practiced with steels according to the prior art. the rockets have, in fact, been shown to be free from any defect, both internal and external.

A titre de comparaison, suivant l'art antérieur, on utilise pour fabriquer les mêmes fusées, un acier de composition

        C = 0,195%

        Mn = 1,25%

        Si = 0,25 %

        S = 0,005 %

        Ni = 0,25 %

        Cr = 1,15%

        Mo = 0,02 %

        Cu = 0,2 %

        Al = 0,02 %

By way of comparison, according to the prior art, a composition steel is used to manufacture the same rockets.

C = 0.195%

Mn = 1.25%

If = 0.25%

S = 0.005%

Ni = 0.25%

Cr = 1.15%

Mo = 0.02%

Cu = 0.2%

Al = 0.02%

Pour obtenir des caractéristiques mécaniques similaires à celles qui sont obtenues avec l'invention, il est nécessaire d'utiliser la gamme de fabrication suivante :

  • Recuit globulaire de l'acier pour le rendre apte à la mise en forme à froid.
  • Forgeage à froid des fusées.
  • Trempe à l'huile de l'acier suivant l'art antérieur.
  • Revenu de l'acier suivant l'art antérieur.
To obtain mechanical characteristics similar to those obtained with the invention, it is necessary to use the following manufacturing range:
  • Globular annealing of steel to make it suitable for cold forming.
  • Cold forging of rockets.
  • Oil quenching of the steel according to the prior art.
  • Steel income according to the prior art.

2 ème exemple : 2nd example :

On a également fabriqué par frappe à froid des pièces mécanique en utilisant les aciers 1 et 2 dont les compositions chimiques étaient en % poids : Acier 1 Acier 2 C = 0,061 % 0,062 % Mn = 1,6 % 1,57 % Si = 0,28 % 0,29 % S = 0,021 % 0,021 % P = 0,004 % 0,004 % Ni = 0,11 % 0,11 % Cr = 0,81 % 0,8 % Mo = 0,081 % 0,128 % Cu = 0,2 % 0,2 % Al = 0,028 % 0,025 % Ti = 0,017 % 0,016 % V = 0,002 % 0,084 % B = 0,0039 % 0,0038 % N = 0,007 % 0,008 % remplissant donc les conditions :Mechanical parts were also cold-worked using steel 1 and 2, the chemical compositions of which were in% by weight: Steel 1 Steel 2 C = 0.061% 0.062% Mn = 1.6% 1.57% If = 0.28% 0.29% S = 0.021% 0.021% P = 0.004% 0.004% Ni = 0.11% 0.11% Cr = 0.81% 0.8% Mo = 0.081% 0.128% Cu = 0.2% 0.2% Al = 0.028% 0.025% Ti = 0.017% 0.016% V = 0.002% 0.084% B = 0.0039% 0.0038% N = 0.007% 0.008% fulfilling the conditions:

Pour l'acier 1 :

        Mn + 0,9 x Cr + 1,3 x Mo + 1,6 x V = 2,43 ≥ 2,2 %

        Al + Ti = 0,045% ≥ 3,5 x N = 0,024%

For steel 1:

Mn + 0.9 x Cr + 1.3 x Mo + 1.6 x V = 2.43 ≥ 2.2%

Al + Ti = 0.045% ≥ 3.5 x N = 0.024%

Pour l'acier 2 :

        Mn + 0,9 x Cr + 1,3 x Mo + 1,6 x V = 2,59 ≥ 2,2 %

        Al + Ti = 0,041 % ≥ 3,5 x N = 0,028%

For steel 2:

Mn + 0.9 x Cr + 1.3 x Mo + 1.6 x V = 2.59 ≥ 2.2%

Al + Ti = 0.041% ≥ 3.5 x N = 0.028%

Conformément à l'invention, ces aciers ont été laminés à chaud sous forme de barres de diamètre 28 mm. Après laminage et avant mise en forme à froid, les barres ont été soumises à un traitement de trempe à l'huile tiède à 50°C après austénitisation à 950°C. Les barres ont été découpées pour obtenir des lopins à partir desquels les pièces ont été mises en forme par frappe à froid au taux de déformation de 60%. Les caractéristiques mécaniques obtenues sur les lopins avant frappe à froid et sur les pièces après frappe à froid étaient les suivantes : Acier Dureté HV avant frappe à froid Rm de l'acier avant frappe à froid (MPa) Rm sur pièce après frappe à froid (MPa) Z sur pièce après frappe à froid (%) Augmentation de Rm à la frappe (%) (*) 1 323 1019 1380 61 35 2 331 1038 1430 59 38 (*) = aptitude à l'écrouissage par mise en forme à froid. According to the invention, these steels were hot-rolled in the form of bars of diameter 28 mm. After rolling and before cold forming, the bars were subjected to a warm oil quenching treatment at 50 ° C after austenitization at 950 ° C. The bars were cut to obtain pieces from which the pieces were shaped by cold stamping at the deformation rate of 60%. The mechanical characteristics obtained on the plots before cold stamping and on the pieces after cold stamping were as follows: Steel HV hardness before cold stamping Rm of steel before cold knocking (MPa) Rm on piece after cold stamping (MPa) Z on piece after cold stamp (%) Rm increase on strike (%) (*) 1 323 1019 1380 61 35 2 331 1038 1430 59 38 (*) = work hardening ability by cold forming.

Ces résultats montrent que la ductilité est élevée (Z ≥ 50%) malgré un taux de déformation à froid très important, ceci indépendamment du niveau de résistance initial (avant frappe à froid) et final (après frappe à froid) de l'acier, même si le niveau de résistance final est très élevé. Ils montrent également que la capacité d'écrouissage, mesurée par l'augmentation de résistance à la frappe à froid, est importante.These results show that the ductility is high (Z ≥ 50%) despite a very high rate of cold deformation, this independently of the level of initial strength (before cold stamping) and final (after cold stamping) of the steel, even if the final resistance level is very high. They also show that the work hardening capacity, measured by the increase in resistance to cold striking, is important.

Par ailleurs, l'aptitude à la mise en forme par frappe à froid est excellente puisque, malgré des niveau de résistance initiaux élevés et une forte déformation (60%) à froid, les pièces frappées à froid se sont révélées exemptes de défauts tant internes qu'externes.In addition, cold forming ability is excellent since, despite high initial strength levels and high cold deformation (60%), cold-worked parts have been found to be free of internal defects. external.

Ces exemples montrent que l'acier et les procédés suivant l'invention permettent d'obtenir une très bonne ductilité (Z ≥ 50%) par la fabrication d'une pièce mise en forme par déformation plastique à froid, sans qu'il soit nécessaire d'effectuer un traitement coûteux de globulisation ni un traitement de revenu. Cette ductilité élevée (Z ≥ 50%) combinée à des caractéristiques mécaniques sur pièces très élevées (Rm ≥ 1200 MPa) peut être obtenue notamment grâce à l'importante capacité d'écrouissage de l'acier. Enfin, la très bonne aptitude à la mise en forme par forgeage ou frappe à froid s'observent même si le niveau de résistance (ou de dureté) initial de l'acier et le taux de déformation à froid sont élevés.These examples show that the steel and the processes according to the invention make it possible to obtain a very good ductility (Z ≥ 50%) by the manufacture of a workpiece shaped by cold plastic deformation, without it being necessary. to perform expensive treatment of globulization or treatment of income. This high ductility (Z ≥ 50%) combined with very high mechanical characteristics on parts (Rm ≥ 1200 MPa) can be obtained thanks to the high work hardening capacity of the steel. Finally, the very good fitness for shaping by cold forging or striking is observed even if the initial resistance level (or hardness) of the steel and the rate of cold deformation are high.

Claims (10)

  1. Use, for the manufacture of a steel component formed by cold plastic deformation, of a steel the chemical composition of which comprises, by weight:

            0.03% ≤ C ≤ 0.16%

            0.5% ≤ Mn ≤ 2%

            0.1% ≤ Si ≤ 0.35%

            0% ≤ Cr ≤ 1.8%

            0% ≤ Mo ≤ 0.25%

            0.001% ≤ Al ≤ 0.05%

            0.001% ≤ Ti ≤ 0.05%

            0% ≤ V ≤ 0.15%

            0.0005% ≤ B ≤ 0.005%

            0.004% ≤ N ≤ 0.012%

            0.001% ≤ S ≤ 0.09%

    - optionally up to 0.005% of calcium, up to 0.01% of tellurium, up to 0.04% of selenium and up to 0.3% of lead,
    the balance being iron and impurities resulting from the smelting, the chemical composition of the steel furthermore satisfying the relationships:

            Mn + 0.9 x Cr + 1.3 x Mo + 1.6 x V ≥ 2.2%

    and

            Al + Ti ≥ 3.5 x N,

    said cold plastic deformation consisting of cold forging, or cold striking or cold drawing, wire drawing or peeling.
  2. Use of a steel according to Claim 1, characterized in that the chemical composition of the steel is such that:

            0.06% ≤ C ≤ 0.12%

            0.8% ≤ Mn ≤ 1.7%

            0.1% ≤ Si ≤ 0 .35%

            0.1% ≤ Cr ≤ 1.5%

            0.07% ≤ Mo ≤ 0.15%

            0.001% ≤ Al ≤ 0.035%

            0.001% ≤ Ti ≤ 0.03%

            0% ≤ V ≤ 0.1%

            0.001% ≤ B ≤ 0.004%

            0.004% ≤ N ≤ 0.01%

            0.001% ≤ S ≤ 0.09%

    - optionally up to 0.005% of calcium, up to 0.01% of tellurium, up to 0.04% of selenium and up to 0.3% of lead,
    the balance being iron and impurities resulting from the smelting.
  3. Use of a steel according to Claim 2,
    characterized in that the impurity contents of the steel are such that:

            Ni ≤ 0.25%

            Cu ≤ 0.25%.

  4. Use of a steel according to Claim 2 or Claim 3, characterized in that the impurity content of the steel is such that:

            P ≤ 0.02%.

  5. Process for the manufacture of a steel component formed by cold plastic deformation,
    characterized in that:
    - a semi-finished product made of a steel having the composition cited in any one of Claims 1 to 4 is provided;
    - the semi-finished product is hot rolled after it has been reheated to a temperature above 940°C and the rolling is stopped at a temperature of between 900°C and 1050°C in order to obtain a rolled product;
    - the rolled product is quenched immediately, whilst still hot from rolling, so as to give it an essentially bainitic structure;
    - optionally, a blank is cut from the rolled product; and
    - the blank or the rolled product is formed by cold plastic deformation in order to obtain the component having its final mechanical properties, said cold plastic deformation consisting of cold forging or cold striking or cold drawing, wire drawing or peeling.
  6. Process for the manufacture of a steel component formed by cold plastic deformation, characterized in that: the
    - a semi-finished product made of a steel the composition cited in any one of Claims 1 to 4 is provided;
    - the semi-finished product is hot rolled so as to obtain a rolled product;
    - the rolled product is quenched after it has been reheated to above the AC3 point, so as to give it an essentially bainitic structure;
    - optionally, a blank is cut from the rolled product; and
    - the blank or the rolled product is formed by cold plastic deformation in order to obtain the component having its final mechanical properties, said cold plastic deformation consisting of cold forging or cold striking or cold drawing, wire drawing or peeling.
  7. Process for the manufacture of a steel component formed by cold plastic deformation, characterized in that:
    - a semi-finished product made of a steel having the composition cited in any one of Claims 1 to 4 is provided,
    - the semi-finished product is hot rolled so as to obtain a rolled product;
    - optionally, a blank is cut from the rolled product;
    - the blank or the rolled product is formed by cold plastic deformation in order to obtain the component; said cold plastic deformation consisting of cold forging or cold striking or cold drawing, wire drawing or peeling and
    - the component, after it has been reheated to above the AC3 point, is quenched so as to give it an essentially bainitic structure and its final mechanical properties.
  8. Cold-formed steel component, characterized in that it is made of a steel having the composition cited in any one of Claims 1 to 4, in that the reduction in section Z of the steel is greater than 45%, in that the tensile strength Rm of the steel is greater than 650 MPa and in that it is cold-formed by cold forging or cold striking or cold drawing or wire drawing or peeling.
  9. Component according to Claim 8, characterized in that the tensile strength Rm of the steel is greater than 1200 MPa.
  10. Component according to Claim 8 or Claim 9 , characterized in that it has an essentially bainitic structure.
EP97402978A 1996-12-31 1997-12-10 Steel and process for forming a steel article by cold plastic working Expired - Lifetime EP0851038B2 (en)

Applications Claiming Priority (2)

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FR9616254 1996-12-31
FR9616254A FR2757877B1 (en) 1996-12-31 1996-12-31 STEEL AND PROCESS FOR THE MANUFACTURE OF A SHAPED STEEL PART BY COLD PLASTIC DEFORMATION

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EP0851038B1 EP0851038B1 (en) 2003-03-26
EP0851038B2 true EP0851038B2 (en) 2007-11-07

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EP0851038B1 (en) 2003-03-26
KR19980064836A (en) 1998-10-07
US5919415A (en) 1999-07-06
AR011312A1 (en) 2000-08-16
NO321331B1 (en) 2006-04-24
ATE235579T1 (en) 2003-04-15
ES2196279T3 (en) 2003-12-16
JP2007284796A (en) 2007-11-01
PL191871B1 (en) 2006-07-31
HU9702515D0 (en) 1998-03-02
CN1195708A (en) 1998-10-14
RU2201468C2 (en) 2003-03-27
ES2196279T5 (en) 2008-05-01
CZ412897A3 (en) 1999-05-12
DE69720163T3 (en) 2008-03-06
SI9700323A (en) 1998-08-31
PL324075A1 (en) 1998-07-06
BR9705637A (en) 1999-08-03
DE69720163D1 (en) 2003-04-30
NO976099L (en) 1998-07-01
EP0851038A1 (en) 1998-07-01
DE69720163T2 (en) 2004-03-04
DK0851038T3 (en) 2003-07-21
DK0851038T4 (en) 2008-01-02
FR2757877B1 (en) 1999-02-05
NO976099D0 (en) 1997-12-29
PT851038E (en) 2003-07-31
HUP9702515A3 (en) 1999-06-28
HUP9702515A2 (en) 1998-07-28
JPH10204585A (en) 1998-08-04
CA2225782A1 (en) 1998-06-30
FR2757877A1 (en) 1998-07-03
JP3988095B2 (en) 2007-10-10

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