EP0789807B1 - Catalyst carrier element with internal insulation - Google Patents
Catalyst carrier element with internal insulation Download PDFInfo
- Publication number
- EP0789807B1 EP0789807B1 EP95936484A EP95936484A EP0789807B1 EP 0789807 B1 EP0789807 B1 EP 0789807B1 EP 95936484 A EP95936484 A EP 95936484A EP 95936484 A EP95936484 A EP 95936484A EP 0789807 B1 EP0789807 B1 EP 0789807B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- exhaust gas
- carrier body
- passages
- plastic deformation
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title abstract description 48
- 238000009421 internal insulation Methods 0.000 title description 3
- 239000007789 gas Substances 0.000 claims abstract description 44
- 238000000034 method Methods 0.000 claims abstract description 19
- 238000002485 combustion reaction Methods 0.000 claims abstract description 8
- 230000003197 catalytic effect Effects 0.000 claims description 23
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 238000004898 kneading Methods 0.000 claims description 2
- 238000005096 rolling process Methods 0.000 claims description 2
- 238000007493 shaping process Methods 0.000 claims 1
- 238000009413 insulation Methods 0.000 abstract description 7
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 230000002093 peripheral effect Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000011324 bead Substances 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003863 metallic catalyst Substances 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2839—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
- F01N3/2842—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration specially adapted for monolithic supports, e.g. of honeycomb type
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
- F01N3/2807—Metal other than sintered metal
- F01N3/281—Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
- F01N13/14—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having thermal insulation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2260/00—Exhaust treating devices having provisions not otherwise provided for
- F01N2260/08—Exhaust treating devices having provisions not otherwise provided for for preventing heat loss or temperature drop, using other means than layers of heat-insulating material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2450/00—Methods or apparatus for fitting, inserting or repairing different elements
- F01N2450/02—Fitting monolithic blocks into the housing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2450/00—Methods or apparatus for fitting, inserting or repairing different elements
- F01N2450/20—Methods or apparatus for fitting, inserting or repairing different elements by mechanical joints, e.g. by deforming housing, tube, baffle plate or parts thereof
Definitions
- the invention relates to a device for catalytic conversion of exhaust gases in an exhaust system, in particular in an exhaust system of internal combustion engines, with a catalyst carrier body, of a plurality of channels through which an exhaust gas can flow has and on a method for producing such a device.
- the catalyst must have a minimum temperature at which the catalytic conversion of the components of the exhaust gas take place can.
- the catalytic converter is in the cold start phase by the hot exhaust gas heated up. It is also known to at least support the catalyst carrier partially heated electrically. So that the pollutant emissions during the Cold start phase is as low as possible and for mechanical reasons therefore, it has been proposed to use a catalyst carrier body Form internal insulation to reduce heat loss to the housing and reduce the environment.
- DE 36 02 134 A1 describes a device for catalytic Implementation of exhaust gases in an exhaust system, especially in one Exhaust system of internal combustion engines, known to one in a metallic catalyst carrier body arranged in a housing having.
- the carrier body has a plurality of exhaust gases through which an exhaust gas can flow Channels on.
- the interior insulation of the catalyst carrier body According to the proposal of DE 36 02 134 A1, that in front of the catalyst carrier body a radially inward Collar is arranged, the collar height of 3-15% of the catalyst diameter, is at least 1 mm. Through this covenant a vortex zone is created in the exhaust gas flow, through which a direct admission an outer annular region with the hot exhaust gas is avoided.
- the DE G 87 12 267.7 U1 is a device for catalytic Implementation of exhaust gases in an exhaust system known.
- the device includes a catalyst carrier body having a plurality of flow channels for an exhaust gas and in a sleeve-shaped housing is inserted.
- the housing is opposite the catalyst carrier body thermally insulated.
- the insulation is achieved in that the Catalyst carrier body is arranged between end rings, which at least the outer layer of the metallic matrix body and thus the Seal the outer flow channels in this matrix. This creates in the outer area of the catalyst carrier body a closed, Air gap not flowed through by exhaust gas, which is used for thermal insulation.
- the present invention has for its object the known To further develop devices for the catalytic conversion of exhaust gases, that the production of a catalyst carrier body with a Internal insulation is simplified. Furthermore, a method of manufacture is said to such a device for the catalytic conversion of exhaust gases to be provided.
- the channels are preferably closed in the region of the exhaust gas inlet.
- the plastic deformation of the channels advantageously takes place before the application of a catalytically active layer on the catalyst carrier body.
- the coating and (washcoat) is usually by means of a applied suspension flowing through the catalyst support body. Of the Catalyst support body can be arranged so that the suspension flows into the channels closed on one side. The washcoat then fills the channels out. It forms thermal insulation. If you arrange that Catalyst carrier body so that the closed channels in the inlet area the suspension are in the catalyst carrier body, so the channels cannot be filled with the suspension. This improves the insulation, since the thermal conductivity of the catalyst support layer, that would fill the channel completely is better than that in the Channels contained atmosphere.
- the channels are advantageously in the Exhaust gas inlet and exhaust area closed. Should the plastic Deformation does not completely close off individual channels, this will through the subsequent coating that closes the small gaps, balanced.
- the channels in the catalyst carrier body are formed in layers one above the other, it is advantageous in up to five Layers of the channels should be closed by plastic deformation, preferably two. This is an advantageous compromise between the necessary catalytically active surface and thermal insulation achieved without that the catalyst carrier body in its outer dimensions essential must be enlarged.
- a method according to the invention for producing a device for catalytic conversion of exhaust gases in an exhaust system is carried out by the features of claim 5 specified.
- Advantageous further training the method are the subject of dependent claims 6 to 17.
- plastic deformation is proposed of the channels in an outer ring in the region of the catalyst carrier body the free flow cross section of the channels partly in the direction of flow to close the exhaust gas.
- the plastic deformation can in that the catalyst carrier body in a matrix is kicked in. When the catalyst carrier body is pushed in, the outer area of the support body deformed, thereby closing the channels will.
- the insertion die can be made with a conical or be provided with an annular wall.
- the plastic deformation of the channel walls also take place in that exerted a force on an outer ring area by means of a stamp which leads to the plastic deformation of the channel walls.
- a stamp which leads to the plastic deformation of the channel walls.
- the Stamp can be ring-shaped or with an oblique from the inside out outside wall be formed. Is the stamp with a wall that runs diagonally from the inside to the outside the free flow cross sections of the channels by bending the channel walls closed. In the case of an annular stamp, the channel walls bruised.
- Catalyst support bodies which are composed of a large number of themselves alternating structured and preferably smooth sheet metal layers exist.
- Such metallic catalyst carrier bodies are made by one Surround the casing tube. It is therefore proposed the plastic deformation of the casing tube and the channels in an outer ring area perform the catalyst carrier body so that the free flow cross section of the channels partly in the flow direction of the exhaust gas is closed.
- the plastic deformation of the casing tube and the Channels can be made in that at least one in the jacket tube inward circumferential bead is formed. The bead can also for connecting the catalyst carrier body to a housing be used.
- the plastic deformation is advantageously carried out by free molding.
- the plastic deformation is preferably carried out by rolling or kneading carried out.
- the catalyst carrier body 1 has a plurality of exhaust gases flow-through channels 2.
- the channels 2 are alternating Arrangement of structured sheet metal layers 12 and smooth sheet metal layers 13 educated. Each channel has a free flow cross section 4, the is limited by the channel walls 11.
- the canal walls are covered by the sheet metal layers 12, 13 formed.
- the catalyst carrier body 1 z. B. by means of not shown Clamping jaws held and pushed into the die 7 accordingly will.
- the honeycomb body 1 is by means of a tool 14 pushed into the die.
- an annular wall 8 is formed.
- the width of the ring corresponds the width of the channels to be closed in the honeycomb body 1.
- To the Wall 8 is followed by a jacket 15, the inner contour of which corresponds to the outer contour of the catalyst carrier body 1.
- FIG. 2 shows a second exemplary embodiment of a die 7 shown.
- the die 7 has a wall 8 which is conical is.
- a honeycomb body 1 is shown in FIG Die 7 was pushed in according to Figure 2. In the ring-shaped Area 3, channels 2 are closed. The edge area of the carrier body 1 is designed obliquely.
- FIG. 6 and 7 support bodies 1 are shown, in which Figure 6 shows a carrier body in section, in which in the outer In the ring area, the channels 2 have been closed by means of the stamp 9 are.
- FIG. 7 shows a carrier body in which a stamp 9 'according to FIG. 5 was used.
- the manufacture of the device for the catalytic conversion of Exhaust gases in an exhaust system, especially in an exhaust system for Internal combustion engines, with one surrounded by a casing tube 10 Catalyst carrier body 1, which has a plurality of channels 2 has, can be produced in that the plastic deformation of the casing tube 10 and the channels 2 in an outer ring region 3 takes place so that the free flow cross section 4 of the channels 2 partially is closed in the flow direction of the exhaust gas.
- the plastic one Deformation can take place by means of a tool 17.
- the tool 17 has a disk 18 which can be rotated about an axis 19 and which its outer edge region is essentially triangular Has cross section.
- the disc 18 is with a force against the Catalyst carrier body 1 and the jacket 10 pressed so that a plastic deformation of the casing tube 10 and the channel walls he follows. There is a circumferential bead 20 directed towards the carrier body 1 generated.
- the formation of the bead 20 can be done in stages, for which the tool 17 is delivered accordingly.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Exhaust Gas After Treatment (AREA)
- Catalysts (AREA)
Abstract
Description
Die Erfindung bezieht sich auf eine Vorrichtung zur katalytischen Umsetzung von Abgasen in einem Abgassystem, insbesondere in einem Abgassystem von Verbrennungskraftmaschinen, mit einem Katalysator-Trägerkörper, der eine Vielzahl von einem Abgas durchströmbarer Kanäle aufweist und auf ein Verfahren zur Herstellung einer solchen Vorrichtung.The invention relates to a device for catalytic conversion of exhaust gases in an exhaust system, in particular in an exhaust system of internal combustion engines, with a catalyst carrier body, of a plurality of channels through which an exhaust gas can flow has and on a method for producing such a device.
Um eine möglichst vollständige Umsetzung der in einer Verbrennungskraftmaschine enthaltenen Kohlenwasserstoffe und des Kohlenmonoxydes zu erreichen, muß der Katalysator eine Mindesttemperatur haben, bei der die katalytische Umsetzung der Komponenten des Abgases stattfinden kann. Im allgemeinen spricht man von einer sogenannten Anspringtemperatur. Der Katalysator wird in der Kaltstartphase durch das heiße Abgas aufgeheizt. Es ist auch bekannt, den Katalysator-Trägerkörper wenigstens teilweise elektrisch zu beheizen. Damit der Schadstoffausstoß während der Kaltstartphase möglichst gering ist und aus mechanischen Gründen, ist daher vorgeschlagen worden, den Katalysator-Trägerkörper mit einer Innenisolierung auszubilden, um den Wärmeverlust an das Gehäuse und die Umgebung zu verringern.To ensure the most complete implementation possible in an internal combustion engine contained hydrocarbons and carbon monoxide To achieve, the catalyst must have a minimum temperature at which the catalytic conversion of the components of the exhaust gas take place can. In general one speaks of a so-called light-off temperature. The catalytic converter is in the cold start phase by the hot exhaust gas heated up. It is also known to at least support the catalyst carrier partially heated electrically. So that the pollutant emissions during the Cold start phase is as low as possible and for mechanical reasons therefore, it has been proposed to use a catalyst carrier body Form internal insulation to reduce heat loss to the housing and reduce the environment.
Durch die DE 36 02 134 A1 ist eine Vorrichtung zur katalytischen Umsetzung von Abgasen in einem Abgassystem, insbesondere in einem Abgassystem von Verbrennungskraftmaschinen, bekannt, die einen in einem Gehäuse angeordneten metallischen Katalysator-Trägerkörper aufweist. Der Trägerkörper weist eine Vielzahl von einem Abgas durchströmbarer Kanäle auf. Die Innenisolierung des Katalysator-Trägerkörpers ist gemäß dem Vorschlag der DE 36 02 134 A1 dadurch zu verwirklichen, daß vor dem Katalysator-Trägerkörper ein radial nach innen weisender Bund angeordnet ist, dessen Bundhöhe 3-15% des Katalysator-Durchmessers, mindestens aber 1 mm beträgt. Durch diesen Bund wird im Abgasstrom eine Wirbelzone geschaffen, durch die eine direkte Beaufschlagung eines äußeren ringförmigen Bereichs mit dem heißen Abgas vermieden wird.DE 36 02 134 A1 describes a device for catalytic Implementation of exhaust gases in an exhaust system, especially in one Exhaust system of internal combustion engines, known to one in a metallic catalyst carrier body arranged in a housing having. The carrier body has a plurality of exhaust gases through which an exhaust gas can flow Channels on. The interior insulation of the catalyst carrier body According to the proposal of DE 36 02 134 A1, that in front of the catalyst carrier body a radially inward Collar is arranged, the collar height of 3-15% of the catalyst diameter, is at least 1 mm. Through this covenant a vortex zone is created in the exhaust gas flow, through which a direct admission an outer annular region with the hot exhaust gas is avoided.
Durch das DE G 87 12 267.7 U1 ist eine Vorrichtung zur katalytischen Umsetzung von Abgasen in einem Abgassystem bekannt. Die Vorrichtung umfaßt einen Katalysator-Trägerkörper, der eine Vielzahl von Strömungskanälen für ein Abgas aufweist und der in einem hülsenförmigen Gehäuse eingesetzt ist. Das Gehäuse ist gegenüber dem Katalysator-Trägerkörper thermisch isoliert. Die Isolierung wird dadurch erreicht, daß der Katalysator-Trägerkörper zwischen Stirnringen angeordnet ist, die mindestens die äußere Lage des metallische Matrixkörpers und damit die äußeren Strömungskanäle in dieser Matrix verschließen. Hierdurch entsteht im Außenbereich des Katalysator-Trägerkörpers ein abgeschlossener, nicht von Abgas durchströmter, Luftspalt, der zur Wärmeisolierung dient.DE G 87 12 267.7 U1 is a device for catalytic Implementation of exhaust gases in an exhaust system known. The device includes a catalyst carrier body having a plurality of flow channels for an exhaust gas and in a sleeve-shaped housing is inserted. The housing is opposite the catalyst carrier body thermally insulated. The insulation is achieved in that the Catalyst carrier body is arranged between end rings, which at least the outer layer of the metallic matrix body and thus the Seal the outer flow channels in this matrix. This creates in the outer area of the catalyst carrier body a closed, Air gap not flowed through by exhaust gas, which is used for thermal insulation.
Der vorliegenden Erfindung liegt die Aufgabe zugrunde, die bekannten Vorrichtungen zur katalytischen Umsetzung von Abgasen so weiterzubilden, daß die Herstellung eines Katalysator-Trägerkörpers mit einer Innenisolierung vereinfacht wird. Ferner soll ein Verfahren zur Herstellung einer solchen Vorrichtung zur katalytischen Umsetzung von Abgasen bereitgestellt werden. The present invention has for its object the known To further develop devices for the catalytic conversion of exhaust gases, that the production of a catalyst carrier body with a Internal insulation is simplified. Furthermore, a method of manufacture is said to such a device for the catalytic conversion of exhaust gases to be provided.
Diese Aufgabe wird durch eine Vorrichtung mit den Merkmalen nach
Anspruch 1 gelöst. Vorteilhafte Weiterbildungen sind Gegenstand der
Unteransprüche.This object is achieved by a device with the
Im Gegensatz zu den bekannten Vorrichtungen zur katalytischen Umsetzung von Abgasen wird ein im Außenbereich des Katalysator-Trägerkörpers abgeschlossener Luftspalt nicht durch zusätzliche Ringe oder desgleichen bewirkt, sondern dadurch, daß der freie Strömungsquerschnitt der Kanäle teilweise, d. h. in mindestens einem axialen Teilbereich, in Strömungsrichtung des Abgases durch plastische Verformung der Kanalwände verschlossen wird. Hierdurch vereinfacht sich die Herstellung der Vorrichtung, da nunmehr kein Bund oder Stirnring in das Gehäuse eingebracht werden muß. Besteht der Katalysator-Trägerkörper aus mehreren gewickelten Blechlagen, so kann die plastische Verformung bereits beim Wickeln erfolgen. Dies vereinfacht das Herstellungsverfahren gewikkelter Katalysatoren, da der Wickelvorgang und die plastische Verformung gleichzeitig erfolgen können.In contrast to the known devices for catalytic conversion Exhaust gases become in the outer area of the catalyst carrier body closed air gap not by additional rings or the like causes, but in that the free flow cross-section of the channels partially, d. H. in at least one axial section, in Flow direction of the exhaust gas due to plastic deformation of the duct walls is closed. This simplifies the manufacture of the Device, since now no collar or end ring in the housing must be introduced. The catalyst carrier body consists of several coiled sheet layers, the plastic deformation can already done while winding. This simplifies the manufacturing process more complicated Catalysts because of the winding process and the plastic deformation can be done simultaneously.
Vorzugsweise werden die Kanäle im Bereich des Abgaseintritts verschlossen. Die plastische Verformung der Kanäle erfolgt vorteilhafterweise vor der Aufbringung einer katalytischen wirksamen Schicht auf den Katalysator-Trägerkörper. Die Beschichtund (Washcoat) wird meist mittels einer den Katalysator-Trägerkörper durchfließenden Suspension aufgebracht. Der Katalysator-Trägerkörper kann so angeordnet werden, daß die Suspension in die einseitig verschlossenen Kanäle reinfließt. Der Washcoat füllt dann die Kanäle aus. Er bildet eine thermische Isolierung. Ordnet man den Katalysator-Trägerkörper so an, daß die verschlossenen Kanäle im Eintrittsbereich der Suspension in den Katalysator-Trägerkörper liegen, so können die Kanäle nicht mit der Suspension gefüllt werden. Dies verbessert die Isolation, da die Wärmeleitfähigkeit der Katalysator-Trägerschicht, die den Kanal vollständig ausfüllen würde besser ist als die der in den Kanälen enthaltenen Atmosphäre. Vorteilhafterweise sind die Kanäle im Abgaseintritts- und Abgasaustrittsbereich verschlossen. Sollte die plastische Verformung einzelne Kanäle nicht vollständig verschließen, so wird dies durch die nachträgliche Beschichtung, die kleine Spalte verschließt, ausgeglichen.The channels are preferably closed in the region of the exhaust gas inlet. The plastic deformation of the channels advantageously takes place before the application of a catalytically active layer on the catalyst carrier body. The coating and (washcoat) is usually by means of a applied suspension flowing through the catalyst support body. Of the Catalyst support body can be arranged so that the suspension flows into the channels closed on one side. The washcoat then fills the channels out. It forms thermal insulation. If you arrange that Catalyst carrier body so that the closed channels in the inlet area the suspension are in the catalyst carrier body, so the channels cannot be filled with the suspension. This improves the insulation, since the thermal conductivity of the catalyst support layer, that would fill the channel completely is better than that in the Channels contained atmosphere. The channels are advantageously in the Exhaust gas inlet and exhaust area closed. Should the plastic Deformation does not completely close off individual channels, this will through the subsequent coating that closes the small gaps, balanced.
Bei einer Vorrichtung, bei der die Kanäle im Katalysator-Trägerkörper lagenweise übereinander ausgebildet sind, ist es von Vorteil, in bis fünf Lagen der Kanäle durch plastische Verformung zu schließen, vorzugsweise zwei. Hierdurch wird ein vorteilhafter Kompromiß zwischen der notwendigen katalytisch aktiven Oberfläche und der Wärmeisolierung erzielt, ohne daß der Katalysator-Trägerkörper in seinen äußeren Abmessungen wesentlich vergrößert werden muß.In a device in which the channels in the catalyst carrier body are formed in layers one above the other, it is advantageous in up to five Layers of the channels should be closed by plastic deformation, preferably two. This is an advantageous compromise between the necessary catalytically active surface and thermal insulation achieved without that the catalyst carrier body in its outer dimensions essential must be enlarged.
Ein erfindungsgemäßes Verfahren zur Herstellung einer Vorrichtung zur katalytischen Umsetzung von Abgasen in einem Abgassystem wird durch die Merkmale des Anspruchs 5 angegeben. Vorteilhafte Weiterbildungen des Verfahrens sind Gegenstand der Unteransprüche 6 bis 17.A method according to the invention for producing a device for catalytic conversion of exhaust gases in an exhaust system is carried out by the features of claim 5 specified. Advantageous further training the method are the subject of dependent claims 6 to 17.
Gemäß dem Verfahren wird vorgeschlagen durch plastische Verformung der Kanäle in einem äußeren Ring im Bereich des Katalysator-Trägerkörpers den freien Strömungsquerschnitt der Kanäle teilweise in Strömungsrichtung des Abgases zu verschließen. Die plastische Verformung kann dadurch erfolgen, daß der Katalysator-Trägerkörper in eine Matrize eingestoßen wird. Beim Einstoßen des Katalysator-Trägerkörpers wird der äußere Bereich des Trägerkörpers deformiert, wodurch die Kanäle verschlossen werden. Die Einstoßmatrize kann mit einer konischen oder einer ringförmigen Wandung versehen sein. According to the method, plastic deformation is proposed of the channels in an outer ring in the region of the catalyst carrier body the free flow cross section of the channels partly in the direction of flow to close the exhaust gas. The plastic deformation can in that the catalyst carrier body in a matrix is kicked in. When the catalyst carrier body is pushed in, the outer area of the support body deformed, thereby closing the channels will. The insertion die can be made with a conical or be provided with an annular wall.
Statt den Katalysator-Trägerkörper in eine Matrize einzustoßen, kann die plastische Verformung der Kanalwände auch dadurch erfolgen, daß mittels eines Stempels auf einen äußeren Ringbereich eine Kraft ausgeübt wird, die zu der plastischen Verformung der Kanalwände führt. Der Stempel kann dabei ringförmig oder mit einer schräg von innen nach außen verlaufenden Wand ausgebildet sein. Ist der Stempel mit einer schräg von innen nach außen verlaufenden Wand versehen, so werden die freien Strömungsquerschnitte der Kanäle durch Biegen der Kanalwände geschlossen. Bei einem ringförmigen Stempel werden die Kanalwände gequetscht.Instead of pushing the catalyst carrier body into a die, the plastic deformation of the channel walls also take place in that exerted a force on an outer ring area by means of a stamp which leads to the plastic deformation of the channel walls. Of the Stamp can be ring-shaped or with an oblique from the inside out outside wall be formed. Is the stamp with a wall that runs diagonally from the inside to the outside the free flow cross sections of the channels by bending the channel walls closed. In the case of an annular stamp, the channel walls bruised.
Gemäß einem weiteren vorteilhaften Gedanken wird vorgeschlagen, während der plastischen Verformung den Katalysator-Trägerkörper an seinem der Krafteinleitung entgegengesetzem Ende gegenzuhalten. Dies hat den Vorteil, daß die einzelnen Lagen des Katalysator-Trägerkörpers gegeneinander nicht verschoben werden.According to a further advantageous idea, it is proposed that during the plastic deformation on the catalyst carrier body to hold its end opposite to the introduction of force. This has the advantage that the individual layers of the catalyst carrier body not be moved against each other.
Es sind Katalysator-Trägerkörper bekannt, die aus einer Vielzahl von sich abwechselnden strukturierten und vorzugsweise glatten Blechlagen bestehen. Solche metallischen Katalysator-Trägerkörper werden von einem Mantelrohr umgeben. Es wird daher vorgeschlagen, die plastische Verformung des Mantelrohres und der Kanäle in einem äußeren Ringbereich des Katalysator-Trägerkörpers durchzuführen, derart daß der freie Strömungsquerschnitt der Kanäle teilweise in Strömungsrichtung des Abgases verschlossen wird. Die plastische Verformung des Mantelrohres und der Kanäle kann dadurch erfolgen, daß in dem Mantelrohr wenigstens eine nach innen gerichtete umlaufende Sicke ausgebildet wird. Die Sicke kann auch zur Verbindung des Katalysator-Trägerkörpers mit einem Gehäuse genutzt werden. Catalyst support bodies are known which are composed of a large number of themselves alternating structured and preferably smooth sheet metal layers exist. Such metallic catalyst carrier bodies are made by one Surround the casing tube. It is therefore proposed the plastic deformation of the casing tube and the channels in an outer ring area perform the catalyst carrier body so that the free flow cross section of the channels partly in the flow direction of the exhaust gas is closed. The plastic deformation of the casing tube and the Channels can be made in that at least one in the jacket tube inward circumferential bead is formed. The bead can also for connecting the catalyst carrier body to a housing be used.
Die plastische Verformung erfolgt vorteilhafterweise durch Freiformen. Vorzugsweise wird die plastische Verformung durch Walzen oder Kneten durchgeführt.The plastic deformation is advantageously carried out by free molding. The plastic deformation is preferably carried out by rolling or kneading carried out.
Weitere Merkmale und Vorteile des Gegenstandes der Erfindung werden anhand von Ausführungsbeispielen erläutert, ohne daß eine Beschränkung auf diese Ausführungsbeispiele vorgenommen wird. Hierbei zeigt:
Figur 1- schematisch einen Katalysator-Trägerkörper und eine Matrize,
Figur 2- zeigt eine zweite Form einer Matrize,
- Figur 3
- zeigt schematisch einen Trägerkörper, welcher in eine Matrize
nach
Figur 2 eingestoßen wurde, - Figur 4
- zeigt einen Katalysator-Trägerkörper und einen Stempel im Schnitt,
- Figur 5
- ein zweites Ausführungsbeispiel eines Stempels,
- Figur 6
- zeigt einen plastisch deformierten Trägerkörper, entsprechend Figur 4,
Figur 7- einen plastisch deformierten Trägerkörper durch Deformation mit einem Stempel nach Figur 5 und
Figur 8- einen Trägerkörper im Teilschnitt.
- Figure 1
- schematically a catalyst support body and a matrix,
- Figure 2
- shows a second form of a die,
- Figure 3
- schematically shows a carrier body which was pushed into a die according to FIG. 2,
- Figure 4
- shows a catalyst carrier body and a stamp in section,
- Figure 5
- a second embodiment of a stamp,
- Figure 6
- shows a plastically deformed carrier body, corresponding to Figure 4,
- Figure 7
- a plastically deformed carrier body by deformation with a stamp according to Figure 5 and
- Figure 8
- a carrier body in partial section.
Der Katalysator-Trägerkörper 1 weist eine Vielzahl von einem Abgas
durchströmbarer Kanäle 2 auf. Die Kanäle 2 werden durch abwechselnde
Anordnung von strukturierten Blechlagen 12 und glatten Blechlagen 13
gebildet. Jeder Kanal weist einen freien Strömungsquerschnitt 4 auf, der
durch die Kanalwände 11 begrenzt wird. Die Kanalwände werden durch
die Blechlagen 12, 13 gebildet. Zur plastischen Verformung in einem
äußeren ringförmigen Bereich 3 des Katalysator-Trägerkörpers 1 wird
dieser, wie aus der Figur 1 ersichtlich, in eine Matrize 7 eingestoßen.
Hierzu kann der Katalysator-Trägerkörper 1 z. B. mittels nicht dargestellter
Spannbacken gehalten und entsprechend in die Matrize 7 eingestoßen
werden. In der Darstellung nach Figur 1 wird der Wabenkörper 1 mittels
eines Werkzeuges 14 in die Matrize eingestoßen. In der Matrize 7 ist
eine ringförmige Wandung 8 ausgebildet. Die Breite des Rings entspricht
der Breite der zu verschließenden Kanäle im Wabenkörper 1. An die
Wandung 8 schließt sich ein Mantel 15 an, dessen innere Kontur mit
der Außenkontur des Katalysator-Trägerkörpers 1 entspricht.The
In der Figur 2 ist ein zweites Ausführungsbeispiel einer Matrize 7
dargestellt. Die Matrize 7 hat eine Wandung 8, die konisch ausgebildet
ist.FIG. 2 shows a second exemplary embodiment of a
In der Figur 3 ist ein Wabenkörper 1 dargestellt, die in eine entsprechende
Matrize 7 nach Figur 2 eingestoßen wurde. In dem ringförmigen
Bereich 3 sind die Kanäle 2 verschlossen. Der Randbereich des Trägerkörpers
1 ist entsprechend schräg ausgebildet.A
Statt den Trägerkörper 1 in die Matrize 7 einzustoßen, wird vorgeschlagen,
die plastische Verformung der Kanäle 2 mittels eines Stempels 9
bzw. 9' zu verschließen. Der Stempel 9 bzw. 9' ist hin und her bewegbar
und weist einen ringförmigen Absatz 16 auf. Instead of pushing the
Der Stempel 9' unterscheidet sich vom Stempel 9 dadurch, daß dieser
eine schräg von innen nach außen verlaufende Wand 21 aufweist.The stamp 9 'differs from the
In den Figuren 6 und 7 sind Trägerkörper 1 dargestellt, wobei in der
Figur 6 ein Trägerkörper im Schnitt dargestellt ist, bei dem im äußeren
Ringbereich die Kanäle 2 mittels des Stempels 9 verschlossen worden
sind. In der Figur 7 ist ein Trägerkörper dargestellt, bei dem ein Stempel
9' nach Figur 5 verwendet wurde.6 and 7
Die Herstellung der Vorrichtung zur katalytischen Umsetzung von
Abgasen in einem Abgassystem, insbesondere in einem Abgassystem für
Verbrennungskraftmaschinen, mit einem von einem Mantelrohr 10 umgebenden
Katalysator-Trägerkörper 1, der eine Vielzahl von Kanälen 2
aufweist, kann dadurch hergestellt werden, daß die plastische Verformung
des Mantelrohres 10 und der Kanäle 2 in einem äußeren Ringbereich 3
erfolgt, so daß der freie Strömungsquerschnitt 4 der Kanäle 2 teilweise
in Strömungsrichtung des Abgases verschlossenn wird. Die plastische
Verformung kann mittels eines Werkzeuges 17 erfolgen. Das Werkzeug
17 weist eine um eine Achse 19 verdrehbare Scheibe 18 auf, die an
ihrem äußeren Randbereich im wesentlichen einen dreieckförmigen
Querschnitt aufweist. Die Scheibe 18 wird mit einer Kraft gegen den
Katalysator-Trägerkörper 1 und den Mantel 10 gedrückt, so daß eine
plastische Verformung des Mantelrohres 10 und der Kanalwandungen
erfolgt. Es wird eine umlaufende zum Trägerkörper 1 gerichtete Sicke 20
erzeugt. The manufacture of the device for the catalytic conversion of
Exhaust gases in an exhaust system, especially in an exhaust system for
Internal combustion engines, with one surrounded by a
Das Werkzeug 17 kann um den Katalysator-Trägerkörper 1 rotieren. Es
ist auch möglich, daß Werkzeug 17 stationär anzuordnen und den Katalysator-Trägerkörper
1 um seine Achse rotieren zu lassen.The
Die Ausbildung der Sicke 20 kann stufenweise erfolgen, wozu das Werkzeug
17 entsprechend zugestellt wird. The formation of the
- 11
- Katalysator-TrägerkörperCatalyst carrier body
- 22nd
- Kanälechannels
- 33rd
- RingbereichRing area
- 44th
- StrömungsquerschnittFlow cross-section
- 55
- Eintrittentry
- 66
- Austrittexit
- 77
- Matrizedie
- 88th
- WandungWall
- 9,9'9.9 '
- Stempelstamp
- 1010th
- MantelrohrCasing pipe
- 1111
- KanalwandCanal wall
- 12,1312.13
- BlechlageSheet layer
- 1414
- WerkzeugTool
- 1515
- Mantelcoat
- 1616
- Ringring
- 1717th
- WerkzeugTool
- 1818th
- Scheibedisc
- 1919th
- Achseaxis
- 2020th
- SickeSurround
- 2121
- Wandwall
Claims (17)
- Apparatus for the catalytic conversion of exhaust gases in an exhaust gas system, in particular in an exhaust gas system of internal combustion engines, comprising a catalytic converter carrier body (1) having a plurality of passages (2) through which an exhaust gas can flow, characterised in that in an outer annular region (3) of the catalytic converter carrier body (1) the free flow cross-section (4) of the passages (2) is closed at least in a portion in the direction of flow of the exhaust gas by plastic deformation of the passage walls (11).
- Apparatus according to claim 1 characterised in that the passages (2) are closed in the region of the exhaust gas inlet (5).
- Apparatus according to claim 2 characterised in that the passages (2) are additionally closed in the region of the exhaust gas outlet (6).
- Apparatus according to claim 1, claim 2 or claim 3 wherein the passages (2) are formed in layer-wise mutually superposed relationship characterised in that up to five layers, preferably two layers, of the passages (2) are plastically deformed.
- A process for producing an apparatus for the catalytic conversion of exhaust gases in an exhaust gas system, in particular in an exhaust gas system of internal combustion engines, comprising a catalytic converter carrier body (1) having a plurality of passages (2) through which an exhaust gas can flow, characterised by plastic deformation of the passages (2) in an outer annular region (3) of the catalytic converter carrier body (1) so that the free flow cross-section (4) of the passages (2) is closed at least in a portion in the exhaust gas flow direction.
- A process according to claim 5 wherein the catalytic converter carrier body (1) is pushed into a die (7) for deformation of the passages (2).
- A process according to claim 6 characterised in that the catalytic converter carrier body (1) is pushed into a die (7) with a wall (8) of a conical configuration.
- A process according to claim 6 characterised in that the catalytic converter carrier body (1) is pushed into a die (7) having an annular wall (8).
- A process according to claim 5 characterised in that deformation of the passages (2) is effected by a ram (9, 9').
- A process according to claim 9 characterised in that deformation is effected by an annular ram (9).
- A process according to claim 10 characterised in that the annular ram (9') has a wall (21) which extends inclinedly from the inside outwardly.
- A process according to one or more of claims 5 to 11 characterised in that the catalytic converter carrier body (1) is counter-held during the plastic deformation.
- A process for producing an apparatus for the catalytic conversion of exhaust gas in an exhaust gas system, in particular in an exhaust gas system of internal combustion engines, comprising a catalytic converter carrier body (1) which is enclosed by a tubular casing (10) and which has a plurality of passages through which an exhaust gas can flow, characterised by plastic deformation of the tubular casing (10) and the passages (2) in an outer annular region (3) of the catalytic converter carrier body (1) in such a way that the free flow cross-section (4) of the passages (2) is closed at least in a portion in the exhaust gas flow direction.
- A process according to claim 13 characterised in that at least one peripherally extending crease (20) which is directed towards the carrier body (1) is formed in the tubular casing (10).
- A process according to claim 13 or claim 14 characterised in that the plastic deformation is produced by free shaping.
- A process according to claim 15 characterised in that the plastic deformation is produced by rolling.
- A process according to claim 15 characterised in that the plastic deformation is produced by kneading.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4437718A DE4437718A1 (en) | 1994-10-21 | 1994-10-21 | Catalyst carrier body with an inner insulation |
DE4437718 | 1994-10-21 | ||
PCT/EP1995/004027 WO1996012876A1 (en) | 1994-10-21 | 1995-10-12 | Catalyst carrier element with internal insulation |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0789807A1 EP0789807A1 (en) | 1997-08-20 |
EP0789807B1 true EP0789807B1 (en) | 1998-05-06 |
Family
ID=6531407
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95936484A Expired - Lifetime EP0789807B1 (en) | 1994-10-21 | 1995-10-12 | Catalyst carrier element with internal insulation |
Country Status (7)
Country | Link |
---|---|
US (1) | US6274099B1 (en) |
EP (1) | EP0789807B1 (en) |
JP (1) | JP3801633B2 (en) |
CN (1) | CN1069947C (en) |
DE (2) | DE4437718A1 (en) |
RU (1) | RU2136910C1 (en) |
WO (1) | WO1996012876A1 (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19639633A1 (en) * | 1996-09-26 | 1998-04-02 | Emitec Emissionstechnologie | Honeycomb body with reduced thermal conductivity in the entry and exit area |
DE19646025C2 (en) * | 1996-11-08 | 1999-07-01 | Heinrich Schuermann | Heating arrangement for a catalyst |
GB2325424B (en) * | 1997-05-20 | 2001-01-24 | Emitec Emissionstechnologie | Production of a honeycomb body of twisted sheet layers |
DE19723939C2 (en) * | 1997-06-06 | 2003-02-27 | Leico Werkzeugmaschb Gmbh & Co | Process for producing an exhaust gas catalytic converter |
US6391077B1 (en) * | 1998-04-06 | 2002-05-21 | Lead Industry Company, Ltd. | Apparatus for removing fine particles in exhaust gas and apparatus for cleaning exhaust gas |
DE60027688T3 (en) * | 1999-08-30 | 2012-03-29 | Ngk Insulators, Ltd. | Honeycomb structure with corrugated walling and method of making same |
WO2016153955A1 (en) | 2015-03-23 | 2016-09-29 | Corning Incorporated | Exhaust gas treatment article and methods of manufacturing same |
WO2016182806A1 (en) | 2015-05-08 | 2016-11-17 | Corning Incorporated | Housing, fluid stream treatment article, exhaust system and methods of manufacturing same |
JP2016217305A (en) | 2015-05-25 | 2016-12-22 | 本田技研工業株式会社 | Exhaust emission control device of internal combustion engine |
DE102018214929B4 (en) | 2018-09-03 | 2022-01-27 | Vitesco Technologies GmbH | Catalyst with metallic honeycomb |
CN113232243B (en) * | 2021-01-16 | 2022-12-06 | 温州南冠机械有限公司 | SCR denitration catalyst production mold and production method thereof |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3801289A (en) * | 1972-05-19 | 1974-04-02 | Corning Glass Works | Catalytic converter |
JPS5210491B2 (en) * | 1972-10-20 | 1977-03-24 | ||
DE2312794A1 (en) * | 1973-03-15 | 1974-09-19 | Volkswagenwerk Ag | CATALYST FOR THE CATALYTIC CLEANING OF EXHAUST GASES |
US3904551A (en) * | 1973-12-19 | 1975-09-09 | Grace W R & Co | Process for preparing an auto exhaust catalytic converter |
DE2856030C2 (en) * | 1978-12-23 | 1987-02-12 | Süddeutsche Kühlerfabrik Julius Fr. Behr GmbH & Co KG, 7000 Stuttgart | Method for producing a carrier matrix wound from metal foils for an exhaust gas cartridge |
JPS56162220A (en) * | 1980-05-20 | 1981-12-14 | Ngk Insulators Ltd | Ceramic honeycomb structural body |
US5051241A (en) * | 1988-11-18 | 1991-09-24 | Pfefferle William C | Microlith catalytic reaction system |
US5219667A (en) * | 1991-12-12 | 1993-06-15 | Corning Incorporated | Honeycomb structure and method of forming |
DE9317050U1 (en) * | 1993-11-08 | 1995-03-09 | Emitec Gesellschaft für Emissionstechnologie mbH, 53797 Lohmar | Mechanically stabilized heating catalyst arrangement |
JPH0842333A (en) * | 1994-06-06 | 1996-02-13 | Ford Motor Co | Preparation of catalyst exhaust treating device |
-
1994
- 1994-10-21 DE DE4437718A patent/DE4437718A1/en not_active Withdrawn
-
1995
- 1995-10-12 JP JP51361896A patent/JP3801633B2/en not_active Expired - Fee Related
- 1995-10-12 EP EP95936484A patent/EP0789807B1/en not_active Expired - Lifetime
- 1995-10-12 RU RU97108131A patent/RU2136910C1/en not_active IP Right Cessation
- 1995-10-12 CN CN95195785A patent/CN1069947C/en not_active Expired - Fee Related
- 1995-10-12 DE DE59502127T patent/DE59502127D1/en not_active Expired - Lifetime
- 1995-10-12 WO PCT/EP1995/004027 patent/WO1996012876A1/en active IP Right Grant
-
1997
- 1997-04-21 US US08/843,804 patent/US6274099B1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE59502127D1 (en) | 1998-06-10 |
RU2136910C1 (en) | 1999-09-10 |
CN1069947C (en) | 2001-08-22 |
US6274099B1 (en) | 2001-08-14 |
CN1161727A (en) | 1997-10-08 |
WO1996012876A1 (en) | 1996-05-02 |
DE4437718A1 (en) | 1996-04-25 |
EP0789807A1 (en) | 1997-08-20 |
JP3801633B2 (en) | 2006-07-26 |
JPH10508529A (en) | 1998-08-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0799369B1 (en) | Double-walled housing, especially for catalytic converters in motor vehicles | |
EP0789807B1 (en) | Catalyst carrier element with internal insulation | |
DE3727217A1 (en) | CATALYTIC CONVERTER AND SUBSTRATE SUPPORT | |
DE4434673A1 (en) | Electrically heated catalyst | |
WO2000057039A1 (en) | Method and device for producing a metallic honeycomb body | |
EP0435956A1 (en) | Catalyst with a double casing system. | |
WO2002040838A1 (en) | Radially cross-flowable segmented honeycomb bodies | |
EP0674944B1 (en) | Process for the production of a coated monolithic metal support | |
DE2222663B2 (en) | Process for the production of a device for cleaning the exhaust gases of internal combustion engines | |
EP1967709A1 (en) | Exhaust gas treatment device and method of manufacturing | |
EP0988127B1 (en) | Method for producing a metallic honeycomb element by means of a gas permeable soldering foil | |
WO1996027735A1 (en) | Metal honeycomb element | |
EP1045961B1 (en) | Conical honeycomb body and method for producing same | |
EP0523008A1 (en) | Method of manufacturing a silencer or a catalytic converter for exhaust gases | |
EP0306705B1 (en) | Support structure for producing a catalytic reactor for purifying exhaust gas | |
DE3926072A1 (en) | Catalyser for purifying IC engine exhausts - has circumferential corrugation impressed into jacket surrounding catalyst support matrix | |
EP1157198B1 (en) | Catalytic converter unit with catalyst substrate and device and method for producing same | |
DE19509029C2 (en) | Process for the manufacture of a catalytic treatment device | |
EP0695901B1 (en) | Method for making a pipe coupling of the insertable type | |
WO1999024700A1 (en) | Catalytic converter supported body with open heat radiating areas | |
DE102007036205B4 (en) | A method of manufacturing an air gap insulated pipe unit and exhaust pipe unit | |
DE7401002U (en) | Container for catalytic converter for controlling and monitoring exhaust emissions in internal combustion engines | |
DE3837503A1 (en) | EXHAUST CATALYST FOR MOTOR VEHICLES | |
DE19549603C2 (en) | Catalytic converter for vehicle exhaust gas with a cylindrical substrate | |
EP1551534B1 (en) | Catalyst carrier body comprising a passivation layer, and method for the production thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 19970614 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): DE ES FR GB IT |
|
GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
17Q | First examination report despatched |
Effective date: 19970911 |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): DE ES FR GB IT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: THE PATENT HAS BEEN ANNULLED BY A DECISION OF A NATIONAL AUTHORITY Effective date: 19980506 |
|
REF | Corresponds to: |
Ref document number: 59502127 Country of ref document: DE Date of ref document: 19980610 |
|
GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) |
Effective date: 19980619 |
|
ITF | It: translation for a ep patent filed | ||
ET | Fr: translation filed | ||
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
REG | Reference to a national code |
Ref country code: GB Ref legal event code: IF02 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20101130 Year of fee payment: 16 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20101023 Year of fee payment: 16 Ref country code: GB Payment date: 20101025 Year of fee payment: 16 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20111026 Year of fee payment: 17 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20121012 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST Effective date: 20130628 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20121012 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20130501 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 59502127 Country of ref document: DE Effective date: 20130501 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20121012 Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20121031 |