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EP0703292A1 - Process for decreasing the build up of inorganic incrustations on textiles and detergent composition used in such a process - Google Patents

Process for decreasing the build up of inorganic incrustations on textiles and detergent composition used in such a process Download PDF

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Publication number
EP0703292A1
EP0703292A1 EP95306663A EP95306663A EP0703292A1 EP 0703292 A1 EP0703292 A1 EP 0703292A1 EP 95306663 A EP95306663 A EP 95306663A EP 95306663 A EP95306663 A EP 95306663A EP 0703292 A1 EP0703292 A1 EP 0703292A1
Authority
EP
European Patent Office
Prior art keywords
builder
carbohydrate
detergent
build
washing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP95306663A
Other languages
German (de)
French (fr)
Other versions
EP0703292B1 (en
Inventor
Roland Herwig Friedrick Dr. Beck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cerestar Holding BV
Original Assignee
Cerestar Holding BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cerestar Holding BV filed Critical Cerestar Holding BV
Publication of EP0703292A1 publication Critical patent/EP0703292A1/en
Application granted granted Critical
Publication of EP0703292B1 publication Critical patent/EP0703292B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/40—Products in which the composition is not well defined
    • C11D7/44—Vegetable products

Definitions

  • the present invention relates to a process for decreasing the build-up of inorganic incrustations on fabrics caused by water hardness and repeated washing cycles with detergent compositions.
  • the present invention relates to a process for decreasing the build-up of inorganic incrustations wherein a co-builder is added to the washing cycle, and to detergent and/or anti-incrustation compositions containing said co-builder.
  • detergents contain builders in order to support detergent action and to eliminate calcium and magnesium ions (hardness ions), which arise partly from the water and sometimes also from soil and fabrics.
  • a well known builder is sodium tripolyphosphate which has excellent properties in the washing process even at low concentrations. Despite its many advantageous properties however, it causes serious ecological problems, namely eutrophication of stationary or slowly flowing surface waters leading to extreme algal growth which adversely influences marine organisms. As a result, the use of phosphate free detergents is of great importance.
  • zeolites Some substitutes of phosphate builders such as zeolites have been adopted. However, zeolites alone in water softening have poor efficiency. Therefore, good anti-incrustation effects are achieved only in the presence of auxiliary compounds called co-builders.
  • co-builders are synthetic polymers and/or co-polymers of olefinic mono- or dicarboxylic acids such as acrylic and maleic acid and copolymers of said monomers with other allylic or vinylic monomers.
  • a common characteristic of these polymeric materials is their minimal biodegradability which leads to ecological problems.
  • non-polymeric co-builders such as EDTA (ethylenediaminetetraacetic acid sodium salt), NTA (nitrilotriacetic acid sodium salt) and phosphonates. As with the polymeric co-builders these substances too are non-biodegradable.
  • Another object of the present invention is to provide detergent and/or anti-incrustation compositions containing said biodegrable co-builders.
  • a range of carbohydrates or carbohydrate derivatives having a DE of 0.5 to 20 inclusive may be used in the process of the invention eg. polydextrose or partially degraded inulin but preferably the carbohydrate or carbohydrate derivative is a maltodextrin having a DE of 0.5 to 20 inclusive, particularly a DE of 8 to 17 inclusive.
  • DE dextrose equivalent
  • the co-builders based on such carbohydrates and carbohydrate derivatives having a DE of 0.5 to 20 inclusive can be incorporated into the detergent compositions or added as such directly to the washing bath.
  • detergent and/or anti-incrustation compositions containing the hereinbefore defined co-builders. These compositions may also contain other conventional components such as anionic, non-ionic, cationic or amphoteric surfactants, alkali metal salts (e.g. sodium carbonate, sodium silicate), neutral salts (e.g. sodium sulphate), zeolites, bleaching agents, bleaching activators and other minor ingredients.
  • alkali metal salts e.g. sodium carbonate, sodium silicate
  • neutral salts e.g. sodium sulphate
  • zeolites zeolites
  • bleaching agents bleaching activators and other minor ingredients.
  • novel co-builders are used in combination with zeolite-based detergents.
  • co-builders used according to the present invention are particularly efficacious in the presence of inorganic persalts, such as sodium perborate tetrahydrate or monohydrate.
  • the amount of the co-builders used in the process can vary from 1 g/washing cycle to 40 g/washing cycle, and preferably from 2 g/washing cycle to 20 g/washing cycle. This amount is achieved by a range of from 0.5 % to 20 % and preferably by a range of from 1 % to 10 %, expressed as 100 % dry substance of co-builder in the detergent or anti-incrustation compositions.
  • the co-builders used according to the present invention are naturally derived, biodegradable compounds. In combination with detergents they reduce the build up of inorganic incrustations on fabrics and on washing machine components. Such activity is more significant at high temperatures e.g. at 90°C.
  • the co-builder activities of the following compositions were evaluated on a laboratory scale using the so-called "Hampshire" test which measures the Ca++ sequestering capacity of the composition.
  • the test was carried out as follows :- 1 gram of the substance under test is dissolved in 100 ml of demineralised water, the solution filtered and the filtrate made up to 100 ml with demineralised water. 10 ml of a 2 % by weight aqueous solution of sodium carbonate is then added, the pH adjusted to 11 with sodium hydroxide solution (0.1 N or more concentrated for a large pH adjustment) and the temperature regulated at 20°C.
  • the solution is then titrated with a calcium acetate solution (39.59 g/l) at a rate of 1 ml/min until a permanent turbidity becomes apparent.
  • the quantity of Ca++ in the calcium acetate solution determined by a preliminary titration with EDTA, is 10.03 mg Ca++/ml.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

A process for decreasing the build-up of inorganic incrustations on textiles deriving from water hardness and due to repeated washing cycles with detergent compositions comprises the addition to the washing batch of a carbohydrate or carbohydrate derivative having a DE of 0.5 to 20 inclusive as co-builder.

Description

  • The present invention relates to a process for decreasing the build-up of inorganic incrustations on fabrics caused by water hardness and repeated washing cycles with detergent compositions.
  • More particularly, the present invention relates to a process for decreasing the build-up of inorganic incrustations wherein a co-builder is added to the washing cycle, and to detergent and/or anti-incrustation compositions containing said co-builder.
  • It is well known that detergents contain builders in order to support detergent action and to eliminate calcium and magnesium ions (hardness ions), which arise partly from the water and sometimes also from soil and fabrics.
  • In case of multiple washing cycles the washing performance is significantly reduced because of the build up of inorganic incrustations on fabrics and on washing machine components. Such build up of inorganic incrustations on fabrics decreases the flexibility of fibres and consequently shortens the fabric life, in addition to greying the tissue.
  • A well known builder is sodium tripolyphosphate which has excellent properties in the washing process even at low concentrations. Despite its many advantageous properties however, it causes serious ecological problems, namely eutrophication of stationary or slowly flowing surface waters leading to extreme algal growth which adversely influences marine organisms. As a result, the use of phosphate free detergents is of great importance.
  • Some substitutes of phosphate builders such as zeolites have been adopted. However, zeolites alone in water softening have poor efficiency. Therefore, good anti-incrustation effects are achieved only in the presence of auxiliary compounds called co-builders.
  • The most widely used co-builders are synthetic polymers and/or co-polymers of olefinic mono- or dicarboxylic acids such as acrylic and maleic acid and copolymers of said monomers with other allylic or vinylic monomers. A common characteristic of these polymeric materials is their minimal biodegradability which leads to ecological problems.
  • There are known other non-polymeric co-builders, such as EDTA (ethylenediaminetetraacetic acid sodium salt), NTA (nitrilotriacetic acid sodium salt) and phosphonates. As with the polymeric co-builders these substances too are non-biodegradable.
  • It is therefore an object of the present invention to provide a process for decreasing the build-up of inorganic incrustations on fabrics and on washing machine components by using co-builders which are very efficient in reducing incrustation build up during washing cycles and which are cheap and biodegradable.
  • Another object of the present invention is to provide detergent and/or anti-incrustation compositions containing said biodegrable co-builders.
  • It has now surprisingly been found that certain carbohydrates show a high efficiency in reducing incrustation build up when combined with detergents, particularly with zeolite-based detergents.
  • In European patent application 0 618 286 there is described a co-builder based upon a non-reducing carbohydrate or a non-reducing carbohydrate derivative. Preferred among the non-reducing carbohydrate derivatives are certain sugar alcohols exemplified by maltitol and, especially, by mannitol. It has now been found however that the carbohydrate or carbohydrate derivative need not be fully non-reducing but that some reducing activity is tolerable and that certain compounds showing such activity are as effective co-builders as the sugar alcohols referred to above.
  • In accordance with one aspect of the present invention therefore there is provided a process for decreasing the build-up of inorganic incrustations on fabrics and on washing machine components during multiple washing cycles with detergent compositions characterized by the addition to the washing cycle of a co-builder based on a carbohydrate or carbohydrate derivative having a DE of 0.5 to 20 inclusive.
  • A range of carbohydrates or carbohydrate derivatives having a DE of 0.5 to 20 inclusive may be used in the process of the invention eg. polydextrose or partially degraded inulin but preferably the carbohydrate or carbohydrate derivative is a maltodextrin having a DE of 0.5 to 20 inclusive, particularly a DE of 8 to 17 inclusive.
  • "DE" or dextrose equivalent is a measure of the reducing activity of a carbohydrate measured by comparison with dextrose which has a DE of 100.
  • The co-builders based on such carbohydrates and carbohydrate derivatives having a DE of 0.5 to 20 inclusive can be incorporated into the detergent compositions or added as such directly to the washing bath.
  • In accordance with another aspect of the present invention, there are provided detergent and/or anti-incrustation compositions containing the hereinbefore defined co-builders. These compositions may also contain other conventional components such as anionic, non-ionic, cationic or amphoteric surfactants, alkali metal salts (e.g. sodium carbonate, sodium silicate), neutral salts (e.g. sodium sulphate), zeolites, bleaching agents, bleaching activators and other minor ingredients.
  • In accordance with one preferred embodiment of the present invention the novel co-builders are used in combination with zeolite-based detergents.
  • The co-builders used according to the present invention are particularly efficacious in the presence of inorganic persalts, such as sodium perborate tetrahydrate or monohydrate.
  • The amount of the co-builders used in the process can vary from 1 g/washing cycle to 40 g/washing cycle, and preferably from 2 g/washing cycle to 20 g/washing cycle. This amount is achieved by a range of from 0.5 % to 20 % and preferably by a range of from 1 % to 10 %, expressed as 100 % dry substance of co-builder in the detergent or anti-incrustation compositions.
  • The co-builders used according to the present invention are naturally derived, biodegradable compounds. In combination with detergents they reduce the build up of inorganic incrustations on fabrics and on washing machine components. Such activity is more significant at high temperatures e.g. at 90°C.
  • The present invention is disclosed in still further detail in the following Example, which is supplied for purely illustrative and not limiting purposes.
    • Example
  • The co-builder activities of the following compositions were evaluated on a laboratory scale using the so-called "Hampshire" test which measures the Ca⁺⁺ sequestering capacity of the composition. The test was carried out as follows :-
    1 gram of the substance under test is dissolved in 100 ml of demineralised water, the solution filtered and the filtrate made up to 100 ml with demineralised water. 10 ml of a 2 % by weight aqueous solution of sodium carbonate is then added, the pH adjusted to 11 with sodium hydroxide solution (0.1 N or more concentrated for a large pH adjustment) and the temperature regulated at 20°C. The solution is then titrated with a calcium acetate solution (39.59 g/l) at a rate of 1 ml/min until a permanent turbidity becomes apparent. The quantity of Ca⁺⁺ in the calcium acetate solution, determined by a preliminary titration with EDTA, is 10.03 mg Ca⁺⁺/ml.
  • The results of the determinations in mg Ca⁺⁺/g of test substance were as follows : -
    Substance Solution with borax (2g/50 ml) Solution without borax
    Maltodextrin (DE = 12) 40.7 9.7
    Mannitol 46.9 7.9
    Maltitol 47.8 9.2

Claims (10)

  1. A process for decreasing the build up of inorganic incrustations on fabrics and on washing machine components during multiple washing cycles characterized by the addition to the washing cycle of a co-builder based on a carbohydrate or carbohydrate derivative having a DE of 0.5 to 20 inclusive.
  2. The process according to Claim 1, characterized in that the carbohydrate or carbohydrate derivative is a maltodextrin.
  3. The process according to Claim 2 characterized in that the maltodextrin has a DE of 8 to 17 inclusive.
  4. The process according to Claim 1, characterized in that the co-builder as such is added directly to the washing bath.
  5. The process according to Claim 4, characterized in that the co-builder is added in amount ranging from 1 g/washing cycle to 40 g/washing cycle, preferably from 2 g/washing cycle to 20 g/washing cycle.
  6. The process according to Claim 1, characterized in that the co-builder is incorporated in the detergent composition.
  7. Detergent and/or anti-incrustation composition containing a co-builder based on a carbohydrate or carbohydrate derivative having a DE of 0.5 to 20.
  8. Detergent and/or anti-incrustation composition according to Claim 7, characterized in that it contains a zeolite.
  9. Detergent and/or anti-incrustation composition according to Claim 7, characterized in that it contains the co-builder in an amount ranging from 0.5 % to 20 %, preferably from 1 % to 10 %, expressed as 100 % dry substance of the detergent or anti-incrustation composition.
  10. Detergent and/or anti-incrustation composition according to Claim 7, characterized in that it contains an inorganic persalt.
EP95306663A 1994-09-22 1995-09-21 Process for decreasing the build up of inorganic incrustations on textiles and detergent composition used in such a process Expired - Lifetime EP0703292B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9419091A GB9419091D0 (en) 1994-09-22 1994-09-22 Process for decreasing the build up of inorganic incrustations on textiles and detergent composition used in such process
GB9419091 1994-09-22

Publications (2)

Publication Number Publication Date
EP0703292A1 true EP0703292A1 (en) 1996-03-27
EP0703292B1 EP0703292B1 (en) 2001-04-18

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EP95306663A Expired - Lifetime EP0703292B1 (en) 1994-09-22 1995-09-21 Process for decreasing the build up of inorganic incrustations on textiles and detergent composition used in such a process

Country Status (9)

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EP (1) EP0703292B1 (en)
JP (1) JPH08176593A (en)
AT (1) ATE200692T1 (en)
CA (1) CA2158714A1 (en)
DE (1) DE69520720T2 (en)
ES (1) ES2155500T3 (en)
FI (1) FI113664B (en)
GB (1) GB9419091D0 (en)
MX (1) MX9504068A (en)

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WO1997020904A1 (en) * 1995-12-07 1997-06-12 Henkel Kommanditgesellschaft Auf Aktien Process for the preparation of soil-release granules with dextrin carrier, and agents which contain them
WO1997020905A1 (en) * 1995-12-07 1997-06-12 Henkel Kommanditgesellschaft Auf Aktien Washing agent comprising a carbonate-containing builder system and/or percarbonate-containing bleach
US6225276B1 (en) 1997-02-07 2001-05-01 Henkel Kommanditgesellschaft Auf Aktien pH-controlled release of detergent components
US6329335B1 (en) 1997-03-07 2001-12-11 Henkel Kommanditgesellschaft Auf Aktien Detergent tablets
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US6528474B1 (en) 1999-08-04 2003-03-04 Henkel Kommanditgesellschaft Auf Aktien Method of manufacturing a detergent with soluble builder
US6610752B1 (en) 1999-10-09 2003-08-26 Cognis Deutschland Gmbh Defoamer granules and processes for producing the same
US6616705B2 (en) 2000-09-08 2003-09-09 Cognis Deutschland Gmbh & Co. Kg Laundry detergent compositions
US6620209B2 (en) 2000-09-08 2003-09-16 Cognis Deutschland Gmbh & Co. Kg Laundry detergent compositions
WO2004053042A1 (en) 2002-12-06 2004-06-24 Henkel Kommanditgesellschaft Auf Aktien Multicomponent liquid detergent
US6756351B2 (en) 2000-04-18 2004-06-29 Cognis Deutschland Gmbh & Co. Kg Detergents and cleaning agents
US6841614B1 (en) 1998-10-29 2005-01-11 Henkel Kommanditgesellschaft Auf Aktien Polymer granules produced by fluidized bed granulation
US6951838B1 (en) 1999-09-15 2005-10-04 Cognis Deutschland Gmbh & Co. Kg Detergent tablets
US6977239B1 (en) 1999-11-25 2005-12-20 Cognis Deutschland Gmbh & Co. Kg Detergent tablets
US7049279B1 (en) 1999-11-25 2006-05-23 Cognis Deutschland Gmbh & Co. Kg Process for preparing detergent granules with an improved dissolution rate
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US7199096B1 (en) 1999-11-09 2007-04-03 Cognis Deutschland Gmbh & Co. Kg Detergent tablets
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US7807616B2 (en) 2004-11-11 2010-10-05 Henkel Ag & Co. Kgaa Geranonitrile substitute
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US11155771B2 (en) 2018-11-09 2021-10-26 Henkel Ag & Co. Kgaa Method for preparing a liquid washing or cleaning agent using a preservative-free dye solution

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DE19962886A1 (en) 1999-12-24 2001-07-05 Cognis Deutschland Gmbh Surfactant granules with an improved dissolution rate
DE19962883A1 (en) 1999-12-24 2001-07-12 Cognis Deutschland Gmbh Detergent tablets
DE10003124A1 (en) 2000-01-26 2001-08-09 Cognis Deutschland Gmbh Process for the preparation of surfactant granules
DE10012949A1 (en) 2000-03-16 2001-09-27 Henkel Kgaa Mixtures of cyclic and linear silicic esters of lower alcohols and fragrance and/or biocide alcohols are used as fragrance and/or biocide in liquid or solid laundry and other detergents and in skin and hair cosmetics
DE10019405A1 (en) 2000-04-19 2001-10-25 Cognis Deutschland Gmbh Dry detergent granulate production comprises reducing fatty alcohol content in technical mixture of alkyl and/or alkenyl-oligoglycosides and mixing resultant melt with detergent additives in mixer or extruder
DE10046251A1 (en) 2000-09-19 2002-03-28 Cognis Deutschland Gmbh Detergents and cleaning agents based on alkyl and / or alkenyl oligoglycosides and fatty alcohols
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JPS5259605A (en) * 1975-11-11 1977-05-17 Kao Corp Detergent composition
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DATABASE WPI Section Ch Week 2677, Derwent World Patents Index; Class A97, AN 77-45788Y *

Cited By (26)

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US6329335B1 (en) 1997-03-07 2001-12-11 Henkel Kommanditgesellschaft Auf Aktien Detergent tablets
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US7601679B2 (en) 2000-07-14 2009-10-13 Henkel Ag & Co. Kgaa Process for producing a hollow body with a compartment, containing a portion of a washing, cleaning or rinsing agent
US6616705B2 (en) 2000-09-08 2003-09-09 Cognis Deutschland Gmbh & Co. Kg Laundry detergent compositions
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US7601678B2 (en) 2001-02-07 2009-10-13 Henkel Ag & Co. Kgaa Washing and cleaning agents comprising fine microparticles with cleaning agent components
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US7897556B2 (en) 2004-04-15 2011-03-01 Henkel Ag & Co. Kgaa Phthalimidoperoxyhexanoic acid particles encapsulated in a water soluble material
US7807616B2 (en) 2004-11-11 2010-10-05 Henkel Ag & Co. Kgaa Geranonitrile substitute
DE102008053883A1 (en) 2008-10-30 2010-05-06 Henkel Ag & Co. Kgaa new thickening system
DE102008053884A1 (en) 2008-10-30 2010-05-06 Henkel Ag & Co. Kgaa Anti pimple skin treatment
DE102014226010A1 (en) 2014-12-16 2016-06-16 Henkel Ag & Co. Kgaa Process for the preparation of water-soluble detergent and cleaner foams
US11155771B2 (en) 2018-11-09 2021-10-26 Henkel Ag & Co. Kgaa Method for preparing a liquid washing or cleaning agent using a preservative-free dye solution

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FI954506L (en) 1996-03-23
ATE200692T1 (en) 2001-05-15
FI113664B (en) 2004-05-31
ES2155500T3 (en) 2001-05-16
CA2158714A1 (en) 1996-03-23
EP0703292B1 (en) 2001-04-18
FI954506A0 (en) 1995-09-22
JPH08176593A (en) 1996-07-09
MX9504068A (en) 1997-02-28
GB9419091D0 (en) 1994-11-09
DE69520720D1 (en) 2001-05-23

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