EP0703292A1 - Verfahren zur Verringerung der Ausbildung von Inkrustationen auf Textilien und Waschmittel für das Verfahren - Google Patents

Verfahren zur Verringerung der Ausbildung von Inkrustationen auf Textilien und Waschmittel für das Verfahren Download PDF

Info

Publication number: EP0703292A1
Authority: EP; European Patent Office
Prior art keywords: builder; carbohydrate; detergent; build; washing
Prior art date: 1994-09-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP95306663A

Other languages

English (en)

French (fr)

Other versions

EP0703292B1 (de

Inventor

Roland Herwig Friedrick Dr. Beck

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Cerestar Holding BV

Original Assignee

Cerestar Holding BV

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1994-09-22

Filing date

1995-09-21

Publication date

1996-03-27

1995-09-21 Application filed by Cerestar Holding BV filed Critical Cerestar Holding BV

1996-03-27 Publication of EP0703292A1 publication Critical patent/EP0703292A1/de

2001-04-18 Application granted granted Critical

2001-04-18 Publication of EP0703292B1 publication Critical patent/EP0703292B1/de

2015-09-21 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000003599 detergent Substances 0.000 title claims abstract description 22
239000000203 mixture Substances 0.000 title claims abstract description 18
238000000034 method Methods 0.000 title claims abstract description 15
230000003247 decreasing effect Effects 0.000 title claims abstract description 7
239000004753 textile Substances 0.000 title abstract 2
238000005406 washing Methods 0.000 claims abstract description 27
150000001720 carbohydrates Chemical class 0.000 claims abstract description 12
150000001719 carbohydrate derivatives Chemical class 0.000 claims abstract description 11
239000004744 fabric Substances 0.000 claims description 9
239000000126 substance Substances 0.000 claims description 6
239000010457 zeolite Substances 0.000 claims description 6
229920002774 Maltodextrin Polymers 0.000 claims description 4
239000005913 Maltodextrin Substances 0.000 claims description 4
229940035034 maltodextrin Drugs 0.000 claims description 4
229910021536 Zeolite Inorganic materials 0.000 claims description 3
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
235000014633 carbohydrates Nutrition 0.000 description 8
230000001603 reducing effect Effects 0.000 description 8
239000000243 solution Substances 0.000 description 7
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 4
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
230000000694 effects Effects 0.000 description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 2
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
229930195725 Mannitol Natural products 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
DLRVVLDZNNYCBX-UHFFFAOYSA-N Polydextrose Polymers OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(O)O1 DLRVVLDZNNYCBX-UHFFFAOYSA-N 0.000 description 2
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
-1 alkali metal salts Chemical class 0.000 description 2
229910021538 borax Inorganic materials 0.000 description 2
VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 2
239000001639 calcium acetate Substances 0.000 description 2
235000011092 calcium acetate Nutrition 0.000 description 2
229960005147 calcium acetate Drugs 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
239000000845 maltitol Substances 0.000 description 2
235000010449 maltitol Nutrition 0.000 description 2
VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 2
229940035436 maltitol Drugs 0.000 description 2
239000000594 mannitol Substances 0.000 description 2
235000010355 mannitol Nutrition 0.000 description 2
239000000178 monomer Substances 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
239000010452 phosphate Substances 0.000 description 2
229910000029 sodium carbonate Inorganic materials 0.000 description 2
239000004328 sodium tetraborate Substances 0.000 description 2
235000010339 sodium tetraborate Nutrition 0.000 description 2
150000005846 sugar alcohols Chemical class 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
229920002245 Dextrose equivalent Polymers 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
229920001202 Inulin Polymers 0.000 description 1
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
229920001100 Polydextrose Polymers 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
239000012190 activator Substances 0.000 description 1
230000002411 adverse Effects 0.000 description 1
230000005791 algae growth Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
125000000746 allylic group Chemical group 0.000 description 1
239000002280 amphoteric surfactant Substances 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
238000004061 bleaching Methods 0.000 description 1
239000007844 bleaching agent Substances 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
230000007423 decrease Effects 0.000 description 1
239000008121 dextrose Substances 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
238000012851 eutrophication Methods 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229940029339 inulin Drugs 0.000 description 1
JYJIGFIDKWBXDU-MNNPPOADSA-N inulin Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)OC[C@]1(OC[C@]2(OC[C@]3(OC[C@]4(OC[C@]5(OC[C@]6(OC[C@]7(OC[C@]8(OC[C@]9(OC[C@]%10(OC[C@]%11(OC[C@]%12(OC[C@]%13(OC[C@]%14(OC[C@]%15(OC[C@]%16(OC[C@]%17(OC[C@]%18(OC[C@]%19(OC[C@]%20(OC[C@]%21(OC[C@]%22(OC[C@]%23(OC[C@]%24(OC[C@]%25(OC[C@]%26(OC[C@]%27(OC[C@]%28(OC[C@]%29(OC[C@]%30(OC[C@]%31(OC[C@]%32(OC[C@]%33(OC[C@]%34(OC[C@]%35(OC[C@]%36(O[C@@H]%37[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O%37)O)[C@H]([C@H](O)[C@@H](CO)O%36)O)[C@H]([C@H](O)[C@@H](CO)O%35)O)[C@H]([C@H](O)[C@@H](CO)O%34)O)[C@H]([C@H](O)[C@@H](CO)O%33)O)[C@H]([C@H](O)[C@@H](CO)O%32)O)[C@H]([C@H](O)[C@@H](CO)O%31)O)[C@H]([C@H](O)[C@@H](CO)O%30)O)[C@H]([C@H](O)[C@@H](CO)O%29)O)[C@H]([C@H](O)[C@@H](CO)O%28)O)[C@H]([C@H](O)[C@@H](CO)O%27)O)[C@H]([C@H](O)[C@@H](CO)O%26)O)[C@H]([C@H](O)[C@@H](CO)O%25)O)[C@H]([C@H](O)[C@@H](CO)O%24)O)[C@H]([C@H](O)[C@@H](CO)O%23)O)[C@H]([C@H](O)[C@@H](CO)O%22)O)[C@H]([C@H](O)[C@@H](CO)O%21)O)[C@H]([C@H](O)[C@@H](CO)O%20)O)[C@H]([C@H](O)[C@@H](CO)O%19)O)[C@H]([C@H](O)[C@@H](CO)O%18)O)[C@H]([C@H](O)[C@@H](CO)O%17)O)[C@H]([C@H](O)[C@@H](CO)O%16)O)[C@H]([C@H](O)[C@@H](CO)O%15)O)[C@H]([C@H](O)[C@@H](CO)O%14)O)[C@H]([C@H](O)[C@@H](CO)O%13)O)[C@H]([C@H](O)[C@@H](CO)O%12)O)[C@H]([C@H](O)[C@@H](CO)O%11)O)[C@H]([C@H](O)[C@@H](CO)O%10)O)[C@H]([C@H](O)[C@@H](CO)O9)O)[C@H]([C@H](O)[C@@H](CO)O8)O)[C@H]([C@H](O)[C@@H](CO)O7)O)[C@H]([C@H](O)[C@@H](CO)O6)O)[C@H]([C@H](O)[C@@H](CO)O5)O)[C@H]([C@H](O)[C@@H](CO)O4)O)[C@H]([C@H](O)[C@@H](CO)O3)O)[C@H]([C@H](O)[C@@H](CO)O2)O)[C@@H](O)[C@H](O)[C@@H](CO)O1 JYJIGFIDKWBXDU-MNNPPOADSA-N 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910001425 magnesium ion Inorganic materials 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
150000002763 monocarboxylic acids Chemical class 0.000 description 1
150000004682 monohydrates Chemical class 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
238000010979 pH adjustment Methods 0.000 description 1
239000001259 polydextrose Substances 0.000 description 1
235000013856 polydextrose Nutrition 0.000 description 1
229940035035 polydextrose Drugs 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
235000019832 sodium triphosphate Nutrition 0.000 description 1
HLWRUJAIJJEZDL-UHFFFAOYSA-M sodium;2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetate Chemical compound [Na+].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC([O-])=O HLWRUJAIJJEZDL-UHFFFAOYSA-M 0.000 description 1
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000002352 surface water Substances 0.000 description 1
229920001059 synthetic polymer Polymers 0.000 description 1
238000004448 titration Methods 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
125000002348 vinylic group Chemical group 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/40—Products in which the composition is not well defined
- C11D7/44—Vegetable products

Definitions

the present invention relates to a process for decreasing the build-up of inorganic incrustations on fabrics caused by water hardness and repeated washing cycles with detergent compositions.
the present invention relates to a process for decreasing the build-up of inorganic incrustations wherein a co-builder is added to the washing cycle, and to detergent and/or anti-incrustation compositions containing said co-builder.
detergents contain builders in order to support detergent action and to eliminate calcium and magnesium ions (hardness ions), which arise partly from the water and sometimes also from soil and fabrics.
a well known builder is sodium tripolyphosphate which has excellent properties in the washing process even at low concentrations. Despite its many advantageous properties however, it causes serious ecological problems, namely eutrophication of stationary or slowly flowing surface waters leading to extreme algal growth which adversely influences marine organisms. As a result, the use of phosphate free detergents is of great importance.
zeolites Some substitutes of phosphate builders such as zeolites have been adopted. However, zeolites alone in water softening have poor efficiency. Therefore, good anti-incrustation effects are achieved only in the presence of auxiliary compounds called co-builders.
co-builders are synthetic polymers and/or co-polymers of olefinic mono- or dicarboxylic acids such as acrylic and maleic acid and copolymers of said monomers with other allylic or vinylic monomers.
a common characteristic of these polymeric materials is their minimal biodegradability which leads to ecological problems.
non-polymeric co-builders such as EDTA (ethylenediaminetetraacetic acid sodium salt), NTA (nitrilotriacetic acid sodium salt) and phosphonates. As with the polymeric co-builders these substances too are non-biodegradable.
Another object of the present invention is to provide detergent and/or anti-incrustation compositions containing said biodegrable co-builders.
a range of carbohydrates or carbohydrate derivatives having a DE of 0.5 to 20 inclusive may be used in the process of the invention eg. polydextrose or partially degraded inulin but preferably the carbohydrate or carbohydrate derivative is a maltodextrin having a DE of 0.5 to 20 inclusive, particularly a DE of 8 to 17 inclusive.
DE dextrose equivalent
the co-builders based on such carbohydrates and carbohydrate derivatives having a DE of 0.5 to 20 inclusive can be incorporated into the detergent compositions or added as such directly to the washing bath.
detergent and/or anti-incrustation compositions containing the hereinbefore defined co-builders. These compositions may also contain other conventional components such as anionic, non-ionic, cationic or amphoteric surfactants, alkali metal salts (e.g. sodium carbonate, sodium silicate), neutral salts (e.g. sodium sulphate), zeolites, bleaching agents, bleaching activators and other minor ingredients.
alkali metal salts e.g. sodium carbonate, sodium silicate
neutral salts e.g. sodium sulphate
zeolites zeolites
bleaching agents bleaching activators and other minor ingredients.
novel co-builders are used in combination with zeolite-based detergents.
co-builders used according to the present invention are particularly efficacious in the presence of inorganic persalts, such as sodium perborate tetrahydrate or monohydrate.
the amount of the co-builders used in the process can vary from 1 g/washing cycle to 40 g/washing cycle, and preferably from 2 g/washing cycle to 20 g/washing cycle. This amount is achieved by a range of from 0.5 % to 20 % and preferably by a range of from 1 % to 10 %, expressed as 100 % dry substance of co-builder in the detergent or anti-incrustation compositions.
the co-builders used according to the present invention are naturally derived, biodegradable compounds. In combination with detergents they reduce the build up of inorganic incrustations on fabrics and on washing machine components. Such activity is more significant at high temperatures e.g. at 90°C.
the co-builder activities of the following compositions were evaluated on a laboratory scale using the so-called "Hampshire" test which measures the Ca++ sequestering capacity of the composition.
the test was carried out as follows :- 1 gram of the substance under test is dissolved in 100 ml of demineralised water, the solution filtered and the filtrate made up to 100 ml with demineralised water. 10 ml of a 2 % by weight aqueous solution of sodium carbonate is then added, the pH adjusted to 11 with sodium hydroxide solution (0.1 N or more concentrated for a large pH adjustment) and the temperature regulated at 20°C.
the solution is then titrated with a calcium acetate solution (39.59 g/l) at a rate of 1 ml/min until a permanent turbidity becomes apparent.
the quantity of Ca++ in the calcium acetate solution determined by a preliminary titration with EDTA, is 10.03 mg Ca++/ml.

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Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Health & Medical Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Molecular Biology (AREA)
Emergency Medicine (AREA)
Detergent Compositions (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

EP95306663A 1994-09-22 1995-09-21 Verfahren zur Verringerung der Ausbildung von Inkrustationen auf Textilien und Waschmittel für das Verfahren Expired - Lifetime EP0703292B1 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB9419091		1994-09-22
GB9419091A GB9419091D0 (en)	1994-09-22	1994-09-22	Process for decreasing the build up of inorganic incrustations on textiles and detergent composition used in such process

Publications (2)

Publication Number	Publication Date
EP0703292A1 true EP0703292A1 (de)	1996-03-27
EP0703292B1 EP0703292B1 (de)	2001-04-18

Family

ID=10761731

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP95306663A Expired - Lifetime EP0703292B1 (de)	1994-09-22	1995-09-21	Verfahren zur Verringerung der Ausbildung von Inkrustationen auf Textilien und Waschmittel für das Verfahren

Country Status (9)

Country	Link
EP (1)	EP0703292B1 (de)
JP (1)	JPH08176593A (de)
AT (1)	ATE200692T1 (de)
CA (1)	CA2158714A1 (de)
DE (1)	DE69520720T2 (de)
ES (1)	ES2155500T3 (de)
FI (1)	FI113664B (de)
GB (1)	GB9419091D0 (de)
MX (1)	MX9504068A (de)

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Publication number	Priority date	Publication date	Assignee	Title
WO1997020904A1 (de) *	1995-12-07	1997-06-12	Henkel Kommanditgesellschaft Auf Aktien	Verfahren zur herstellung schmutzlösender granulate mit dextrin-träger und mittel, welche diese enthalten
WO1997020905A1 (de) *	1995-12-07	1997-06-12	Henkel Kommanditgesellschaft Auf Aktien	Waschmittel mit carbonathaltigem buildersystem und/oder percarbonathaltigem bleichmittel
US6225276B1 (en)	1997-02-07	2001-05-01	Henkel Kommanditgesellschaft Auf Aktien	pH-controlled release of detergent components
US6329335B1 (en)	1997-03-07	2001-12-11	Henkel Kommanditgesellschaft Auf Aktien	Detergent tablets
DE10112136A1 (de) *	2001-03-14	2002-10-02	Henkel Kgaa	Verhinderung von Textilschäden beim Waschen
US6528474B1 (en)	1999-08-04	2003-03-04	Henkel Kommanditgesellschaft Auf Aktien	Method of manufacturing a detergent with soluble builder
US6610752B1 (en)	1999-10-09	2003-08-26	Cognis Deutschland Gmbh	Defoamer granules and processes for producing the same
US6616705B2 (en)	2000-09-08	2003-09-09	Cognis Deutschland Gmbh & Co. Kg	Laundry detergent compositions
US6620209B2 (en)	2000-09-08	2003-09-16	Cognis Deutschland Gmbh & Co. Kg	Laundry detergent compositions
WO2004053042A1 (de)	2002-12-06	2004-06-24	Henkel Kommanditgesellschaft Auf Aktien	Mehrkomponenten-flüssigwaschmittel
US6756351B2 (en)	2000-04-18	2004-06-29	Cognis Deutschland Gmbh & Co. Kg	Detergents and cleaning agents
US6841614B1 (en)	1998-10-29	2005-01-11	Henkel Kommanditgesellschaft Auf Aktien	Polymer granules produced by fluidized bed granulation
US6951838B1 (en)	1999-09-15	2005-10-04	Cognis Deutschland Gmbh & Co. Kg	Detergent tablets
US6977239B1 (en)	1999-11-25	2005-12-20	Cognis Deutschland Gmbh & Co. Kg	Detergent tablets
US7049279B1 (en)	1999-11-25	2006-05-23	Cognis Deutschland Gmbh & Co. Kg	Process for preparing detergent granules with an improved dissolution rate
US7091168B2 (en)	2000-06-29	2006-08-15	Cognis Deutschland Gmbh & Co. Kg	Liquid detergents
US7199096B1 (en)	1999-11-09	2007-04-03	Cognis Deutschland Gmbh & Co. Kg	Detergent tablets
US7601679B2 (en)	2000-07-14	2009-10-13	Henkel Ag & Co. Kgaa	Process for producing a hollow body with a compartment, containing a portion of a washing, cleaning or rinsing agent
US7601678B2 (en)	2001-02-07	2009-10-13	Henkel Ag & Co. Kgaa	Washing and cleaning agents comprising fine microparticles with cleaning agent components
DE102008053884A1 (de)	2008-10-30	2010-05-06	Henkel Ag & Co. Kgaa	Anti Pickel Hautbehandlungsmittel
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US7807616B2 (en)	2004-11-11	2010-10-05	Henkel Ag & Co. Kgaa	Geranonitrile substitute
US7897556B2 (en)	2004-04-15	2011-03-01	Henkel Ag & Co. Kgaa	Phthalimidoperoxyhexanoic acid particles encapsulated in a water soluble material
DE102014226010A1 (de)	2014-12-16	2016-06-16	Henkel Ag & Co. Kgaa	Verfahren zur Herstellung von wasserlöslichen Wasch- und Reinigungsmittelschäumen
US11155771B2 (en)	2018-11-09	2021-10-26	Henkel Ag & Co. Kgaa	Method for preparing a liquid washing or cleaning agent using a preservative-free dye solution

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US6686327B1 (en)	1999-10-09	2004-02-03	Cognis Deutschland Gmbh & Co. Kg	Shaped bodies with improved solubility in water
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Cited By (26)

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WO1997020904A1 (de) *	1995-12-07	1997-06-12	Henkel Kommanditgesellschaft Auf Aktien	Verfahren zur herstellung schmutzlösender granulate mit dextrin-träger und mittel, welche diese enthalten
WO1997020905A1 (de) *	1995-12-07	1997-06-12	Henkel Kommanditgesellschaft Auf Aktien	Waschmittel mit carbonathaltigem buildersystem und/oder percarbonathaltigem bleichmittel
US6225276B1 (en)	1997-02-07	2001-05-01	Henkel Kommanditgesellschaft Auf Aktien	pH-controlled release of detergent components
US6407052B2 (en)	1997-02-07	2002-06-18	Henkel Kommanditgesellschaft Auf Aktien	pH-controlled release of detergent components
US6329335B1 (en)	1997-03-07	2001-12-11	Henkel Kommanditgesellschaft Auf Aktien	Detergent tablets
US6841614B1 (en)	1998-10-29	2005-01-11	Henkel Kommanditgesellschaft Auf Aktien	Polymer granules produced by fluidized bed granulation
US6528474B1 (en)	1999-08-04	2003-03-04	Henkel Kommanditgesellschaft Auf Aktien	Method of manufacturing a detergent with soluble builder
US6951838B1 (en)	1999-09-15	2005-10-04	Cognis Deutschland Gmbh & Co. Kg	Detergent tablets
US6610752B1 (en)	1999-10-09	2003-08-26	Cognis Deutschland Gmbh	Defoamer granules and processes for producing the same
US7199096B1 (en)	1999-11-09	2007-04-03	Cognis Deutschland Gmbh & Co. Kg	Detergent tablets
US7049279B1 (en)	1999-11-25	2006-05-23	Cognis Deutschland Gmbh & Co. Kg	Process for preparing detergent granules with an improved dissolution rate
US6977239B1 (en)	1999-11-25	2005-12-20	Cognis Deutschland Gmbh & Co. Kg	Detergent tablets
US6756351B2 (en)	2000-04-18	2004-06-29	Cognis Deutschland Gmbh & Co. Kg	Detergents and cleaning agents
US7091168B2 (en)	2000-06-29	2006-08-15	Cognis Deutschland Gmbh & Co. Kg	Liquid detergents
US7601679B2 (en)	2000-07-14	2009-10-13	Henkel Ag & Co. Kgaa	Process for producing a hollow body with a compartment, containing a portion of a washing, cleaning or rinsing agent
US6616705B2 (en)	2000-09-08	2003-09-09	Cognis Deutschland Gmbh & Co. Kg	Laundry detergent compositions
US6620209B2 (en)	2000-09-08	2003-09-16	Cognis Deutschland Gmbh & Co. Kg	Laundry detergent compositions
US7601678B2 (en)	2001-02-07	2009-10-13	Henkel Ag & Co. Kgaa	Washing and cleaning agents comprising fine microparticles with cleaning agent components
DE10112136A1 (de) *	2001-03-14	2002-10-02	Henkel Kgaa	Verhinderung von Textilschäden beim Waschen
WO2004053042A1 (de)	2002-12-06	2004-06-24	Henkel Kommanditgesellschaft Auf Aktien	Mehrkomponenten-flüssigwaschmittel
US7897556B2 (en)	2004-04-15	2011-03-01	Henkel Ag & Co. Kgaa	Phthalimidoperoxyhexanoic acid particles encapsulated in a water soluble material
US7807616B2 (en)	2004-11-11	2010-10-05	Henkel Ag & Co. Kgaa	Geranonitrile substitute
DE102008053884A1 (de)	2008-10-30	2010-05-06	Henkel Ag & Co. Kgaa	Anti Pickel Hautbehandlungsmittel
DE102008053883A1 (de)	2008-10-30	2010-05-06	Henkel Ag & Co. Kgaa	neues Verdickungssystem
DE102014226010A1 (de)	2014-12-16	2016-06-16	Henkel Ag & Co. Kgaa	Verfahren zur Herstellung von wasserlöslichen Wasch- und Reinigungsmittelschäumen
US11155771B2 (en)	2018-11-09	2021-10-26	Henkel Ag & Co. Kgaa	Method for preparing a liquid washing or cleaning agent using a preservative-free dye solution

Also Published As

Publication number	Publication date
EP0703292B1 (de)	2001-04-18
DE69520720D1 (de)	2001-05-23
FI954506A0 (fi)	1995-09-22
JPH08176593A (ja)	1996-07-09
FI113664B (fi)	2004-05-31
ES2155500T3 (es)	2001-05-16
GB9419091D0 (en)	1994-11-09
ATE200692T1 (de)	2001-05-15
MX9504068A (es)	1997-02-28
DE69520720T2 (de)	2001-08-02
CA2158714A1 (en)	1996-03-23
FI954506L (fi)	1996-03-23

Publication	Publication Date	Title
EP0703292B1 (de)	2001-04-18	Verfahren zur Verringerung der Ausbildung von Inkrustationen auf Textilien und Waschmittel für das Verfahren
KR100226309B1 (ko)	1999-10-15	선택된 빌더계를 함유하는 세정제 및 클리닝제제
US6187055B1 (en)	2001-02-13	Washing agents with specific oxidized oligosaccharides
US4999129A (en)	1991-03-12	Process and composition for washing soiled polyester fabrics
EP0525239B1 (de)	1997-07-09	Verfahren zur Erhöhung der Bleichwirksamkeit eines inorganischen Persalzes
US4470919A (en)	1984-09-11	Oxygen-bleach-containing liquid detergent compositions
RU2609417C2 (ru)	2017-02-01	Связывающая кальций композиция
US4623357A (en)	1986-11-18	Bleach compositions
RU2606123C2 (ru)	2017-01-10	Связывающая кальций композиция
US20110034364A1 (en)	2011-02-10	Color-Protecting Detergent or Cleanser
JP7292309B2 (ja)	2023-06-16	ポリアスパラギン酸並びにオリゴ糖及び多糖をベースとするグラフトポリマーをフィルム抑制添加剤として含む食器洗い用洗剤製剤
KR920002085B1 (ko)	1992-03-10	무린세제 표백조성물
US5496494A (en)	1996-03-05	Process for decreasing the build up of inorganic incrustations on textiles and detergent composition used in such process
EP0612842A2 (de)	1994-08-31	Wäschewaschmittel
AU2003299288B2 (en)	2011-07-07	Detergent composition exhibiting enhanced stain removal
JPH05214367A (ja)	1993-08-24	洗剤
US20230183613A1 (en)	2023-06-15	Use of carboxymethylated polymer of lysines as dispersing agent and compositions comprising the same
US5520842A (en)	1996-05-28	Solid detergent compositions comprising at least one storage-stable, biodegradable and non-hygroscopic derivative of a polycarboxylic polymer
EP0058444A1 (de)	1982-08-25	Waschmittelzusammensetzung
US4617139A (en)	1986-10-14	Detergent compositions containing polymers
JPH0354159B2 (de)	1991-08-19
KR900004537B1 (ko)	1990-06-29	세제 조성물
EP0608642A2 (de)	1994-08-03	Hemmung des Kristzallwachstums von Kalziumkorbonat
US4189396A (en)	1980-02-19	Detergent compositions
JPS61108697A (ja)	1986-05-27	重合体含有洗剤組成物

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