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EP0518401B1 - Self-thickened cleaning compositions - Google Patents

Self-thickened cleaning compositions Download PDF

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Publication number
EP0518401B1
EP0518401B1 EP92201412A EP92201412A EP0518401B1 EP 0518401 B1 EP0518401 B1 EP 0518401B1 EP 92201412 A EP92201412 A EP 92201412A EP 92201412 A EP92201412 A EP 92201412A EP 0518401 B1 EP0518401 B1 EP 0518401B1
Authority
EP
European Patent Office
Prior art keywords
composition
weight
composition according
integer
total composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP92201412A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0518401A1 (en
Inventor
Michel Jean Carrie
Stefano Scialla
Peter Geboes
Eddy Vos
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26130362&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0518401(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of EP0518401A1 publication Critical patent/EP0518401A1/en
Application granted granted Critical
Publication of EP0518401B1 publication Critical patent/EP0518401B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C11D1/8305—Mixtures of non-ionic with anionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3715—Polyesters or polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Definitions

  • the present invention relates to cleaning compositions.
  • the compositions according to the present invention are self-thickened, in that they do not require the presence of a thickener compound; furthermore, the compositions according to the present invention are physically stable, even at low temperatures.
  • the compositions according to the present invention are useful for instance as hard surface cleaning compositions or as laundry cleaning compositions.
  • Thickened cleaning compositions are well known in the art, and have found various applications for instance in the context of hard surface or laundry cleaning compositions.
  • compositions which comprise such an anionic surfactant derived from natural coconut oil and an electrolyte.
  • the viscosity of such a composition is of course sensitive to temperature, and a new technical problem has been identified in that such compositions are not physically stable at low temperature, where the product undergoes phase separation; As a result, the product has an aesthetically unacceptable aspect.
  • DE 3 528 843 discloses thickened and sterile cleaning composition
  • fatty acid alkanolamides comprising fatty acid alkanolamides, ammonium salts, hydrogen peroxide and surfactants.
  • FR 2 526 806 discloses cleaning compositions comprising a sulfate or sulfonate anionic surfactant, an amine oxide, and a succinic acid derivative.
  • Canadian patent CA 1 194 381 discloses scouring compositions containing anionic surfactants, an electrolyte and an ethoxylated alcohol surfactant.
  • European patent EP 116 905 teaches the use of an ethoxylated and/or propoxylated alcohol surfactant to reduce the viscosity of industrial-grade synthetic anionic surfactant concentrates.
  • European patent application EP 329 209 discloses scouring compositions comprising a surfactant, an electrolyte and a solvent to build viscosity.
  • compositions according to the present invention are self-thickened aqueous cleaning compositions having a viscosity of from 50 to 700 mPa.s at 60rpm shear rate at 20°C, which comprise from 1% to 25% by weight of the total composition of an alkyl sulphate anionic surfactant derived from natural coconut oil, from 0.1% to 8% by weight of the total composition of ammonium salts and from 0.5% to 25% by weight of the total composition of a compound of the structure: R1-O ⁇ [(R2O) n (R3O) m ] ⁇ R4, wherein :
  • compositions according to the present invention comprise from 1% to 25% by weight of the total composition, preferably from 2% to 8% by weight of the total composition, most preferably 3% to 5% of an alkyl sulphate anionic surfactant derived from natural coconut oil, or mixtures thereof.
  • alkyl sulphate anionic surfactants for use herein can be made by the processes well known to the man skilled in the art. Typically, such surfactants are made from coconut alcohol which is sulfated and possibly ethoxylated. Indeed, ethoxylated alkyl sulfate surfactants are also suitable for use herein, but the average degree of ethoxylation of the anionic surfactants to be used herein should not be more than 2.
  • the neutralizing cation for the alkyl sulfates derived from natural coconut oil to be used herein can be any of the conventional cations used in detergent technology, such as ammonium, potassium or unsubstituted or N-substituted ammonium salts, or mixtures thereof; preferred are the sodium salts.
  • the viscosity of the compositions according to the invention is obtained by using ammonium salts as an electrolyte; suitable ammonium salts for use in the compositions according to the invention include alkanolammonium salts, ammonium chloride, ammonium acetate, ammonium citrate, and ammonium carbonate; it is the electrolyte together with the above described surfactants which builds the viscosity.
  • the viscosity of the composition depends on the proportion of both ingredients, the general rule being that the more electrolyte is added, the more viscosity is obtained.
  • the compositions according to the present invention comprise from 0.1% to 8% by weight of the total composition of ammonium salts, preferably from 0.2% to 6%, most preferably 0.3% to 5%.
  • the ratio of ammonium salts to anionic surfactant is adjusted so as to obtain composition having a viscosity of from 50 to 700 mPa.s at 60rpm shear rate at 20°C, more preferably 80 cps to 350 mPa.s.
  • the viscosity of the compositions according to the invention allows to use said compositions on vertical surfaces.
  • compositions according to the present invention comprise from 0.5% to 25% by weight of the total composition, preferably from 0.6% to 10% , most preferably from 0.7% to 2% of a compound of the formula: R1-O ⁇ [(R2O) n (R3O) m ] ⁇ R4, wherein :
  • R2O and R3O groups may appear in any sequence in the molecule; also, when n and m are greater than 1, different R2O and R3O groups may appear in a same molecule.
  • These surfactant are commercially available from ICI under the trade name UKANIL FM ®, or from BASF under the trade name PLURAFAC LF ®.
  • Preferred surfactant where m is 0 are available from SHELL under the trade name DOBANOL ® or from BASF under the trade name LUTENSOL ®.
  • compositions according to the invention are acidic and have a pH of from 1 to 6, preferably 2.5 to 5.
  • the pH of the compositions according to the invention is partially determined by the amount of electrolyte, but the pH of the final composition can be adjusted by the addition of appropriate acidifiers such as organic or inorganic acids, or acidic salts which buffer pH to an acid value.
  • suitable acidifiers are sulfuric acid, phosphoric acids, although somewhat undesirable from an environmental viewpoint, hydrochloric acid, phosphonic acid, citric acid, acetic acid, tartaric acid, maleic acid, succinic acid and malonic acid, or mixtures thereof.
  • the compositions comprise from 0.5% to 20% by weight of the total composition of citric acid, preferably from 1% to 10%.
  • citric acid it has been found there are many benefits obtainable from the addition of citric acid to the compositions according to the present invention, such as limescale removal performance and improved disinfesting properties.
  • citric acid it is possible to form in situ the ammonium salts described herein above, in this case ammonium citrate by incorporating ammonium hydroxide.
  • the presence of citric acid also helps to build the product's viscosity;
  • compositions according to the invention further comprise from 0.01% to 0.5% by weight of the total composition of a capped 1,2- propylene terephthalate polyoxyethylene polyester of the formula: wherein n is an integer of from about 12 to 43 and u is an integer of from about 2 to 8, and mixtures thereof.
  • the above polymers have a regulating effect on the viscosity of the compositions; indeed, the viscosity of a given product is typically very sensitive to temperature, and the compositions according to the present invention, although they remain phase-stable at all temperatures, tend to become more viscous when temperature drops. It has now been found that the above polymers make the composition's viscosity less sensitive to temperature; thus the compositions have less tendency to become thicker at low temperatures.
  • the compositions according to the present invention further comprise from 1% to 15% by weight of the total composition, preferably from 2% to 10%, most preferably 3% to 8% of hydrogen peroxide.
  • the addition of hydrogen peroxide leads to a severe drop in viscosity;
  • another advantage of the compositions according to the present invention, i.e. comprising the stabilizing nonionic surfactant from the selected class, is that the addition of hydrogen peroxide has little effect on the product's viscosity.
  • bleaching compositions can also be made according to the present invention.
  • compositions according to the present invention may also comprise conventional ingredients such as solvents, chelating agents, fragrance and dyes, provided all these ingredients are compatible with the compositions.
  • compositions according to the present invention can be made by any process where all ingredients are mixed together.
  • the compositions comprise a substantial amount of citric acid
  • the compositions also comprise hydrogen peroxide
  • compositions according to the present invention can be useful in many different contexts where it is desirable to use a viscous product.
  • hard surface cleaning compositions are advantageously formulated as viscous products in order to optimize their application to vertical surfaces, for instance baththubs or toilet bowls. Indeed, the product's viscosity prevents the product from running too quickly down said surface.
  • compositions according to the present invention can also be used in the context of laundry cleaning.
  • a laundry pretreatment composition can be advantageously formulated as a viscous product for a most convenient application to the laundry fabrics.
  • the viscosity of the product allows for a better control of the dispensing of the product and prevents the spreading of the dispensed product beyond the fabric surface being pretreated.
  • compositions which contain the listed ingredients in the listed proportions (weight %).
  • Compositions 1 2 3 4 5 NaCnAS 3.5 3.5 3.5 2.4 3.5 Citric Acid 5.8 6.0 5.8 4.0 5.7 Ukanil R 1.5 1.5 1.0 2.0 - Dobanol R 23-3 - - - - 0.9 Ammonia 0.6 0.6 0.7 - 0.32 Ammonium Chloride - - - 1.0 - Sodium Chloride - - - - - Tri Ethanol Amine - - 1.5 - 2.0 Hydrogen Chloride - - - - - - - Hydrogen Peroxide - 6.0 - - - Sodium Cumene Sulphonate 1.0 - - - - - Perfume 0.5 - 0.5 - 0.4 pH 4.1 4.0 4.5 2.2 3.6 Water & minors up to 100%
  • compositions according to the present invention The following data illustrates the benefits obtained from the compositions according to the present invention.
  • a composition is made which comprises, by weight of the total composition: Sodium coconut alkyl sulfate: 3.5% Ammonia: 0.75% Citric acid: 5.8 pH: 4.3 Water & minors: up to 100%
  • An identical composition is also made, except it comprises in addition 1.5% of Ukanil R .

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  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
EP92201412A 1991-06-14 1992-05-19 Self-thickened cleaning compositions Expired - Lifetime EP0518401B1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP91870095 1991-06-14
EP91870095 1991-06-14
EP92870025 1992-02-14
EP92870025 1992-02-14

Publications (2)

Publication Number Publication Date
EP0518401A1 EP0518401A1 (en) 1992-12-16
EP0518401B1 true EP0518401B1 (en) 1995-11-02

Family

ID=26130362

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92201412A Expired - Lifetime EP0518401B1 (en) 1991-06-14 1992-05-19 Self-thickened cleaning compositions

Country Status (15)

Country Link
EP (1) EP0518401B1 (pt)
JP (1) JPH06508393A (pt)
AT (1) ATE129742T1 (pt)
AU (1) AU667481B2 (pt)
BR (1) BR9206153A (pt)
CA (1) CA2110413C (pt)
DE (1) DE69205730T2 (pt)
DK (1) DK0518401T3 (pt)
ES (1) ES2079138T3 (pt)
GR (1) GR3018145T3 (pt)
IE (1) IE921922A1 (pt)
MX (1) MX9202883A (pt)
NZ (1) NZ243138A (pt)
TR (1) TR25965A (pt)
WO (1) WO1992022628A1 (pt)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994013769A1 (en) * 1992-12-04 1994-06-23 The Procter & Gamble Company Self-thickneded acidic cleaning composition
WO1994026856A1 (en) * 1993-05-06 1994-11-24 The Procter & Gamble Company Mixing order to prepare aqueous detergent compositions
US5573710A (en) * 1993-03-30 1996-11-12 Minnesota Mining And Manufacturing Company Multisurface cleaning composition and method of use
US5656580A (en) * 1992-12-04 1997-08-12 The Procter & Gamble Company Acidic cleaning compositions self-thickened by a mixture of cationic and nonionic surfactants
US5872088A (en) * 1996-11-04 1999-02-16 The Procter & Gamble Company Self-thickened cleaning compositions
AU703727B2 (en) * 1994-05-31 1999-04-01 Procter & Gamble Company, The Cleaning compositions
US6617293B2 (en) 2001-08-06 2003-09-09 3M Innovative Properties Company Thickening on dilution liquid soap

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR970704863A (ko) * 1994-07-21 1997-09-06 테릴 켄트 퀼리 희석시 점도 증가를 나타낼 수 있는 농축 세정제 조성물
EP0875551A1 (en) * 1997-04-30 1998-11-04 The Procter & Gamble Company Self-thickened acidic cleaning compositions
US6849589B2 (en) 2001-10-10 2005-02-01 3M Innovative Properties Company Cleaning composition
CA2584682A1 (en) * 2004-11-19 2006-05-26 The Procter & Gamble Company Acidic laundry detergent compositions
PH12013501439A1 (en) * 2011-01-31 2019-09-02 Unilever Nv Alkaline liquid detergent compositions
BR112013030725A2 (pt) * 2011-06-17 2016-12-06 Reckitt Benckiser Nv composição
EP3004307A1 (en) * 2013-05-24 2016-04-13 The Procter & Gamble Company Low ph detergent composition comprising nonionic surfactants
BR112015028853A2 (pt) 2013-05-24 2017-08-29 Procter & Gamble Composição detergente com ph baixo
US9840681B2 (en) 2013-05-24 2017-12-12 The Procter & Gamble Company Concentrated surfactant composition

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JPS5036646B2 (pt) * 1971-09-09 1975-11-26
US3969282A (en) * 1974-12-23 1976-07-13 Basf Wyandotte Corporation Acidic surfactant composition, stock surfactant solution prepared therefrom, and method of washing soiled substrates employing the same
GB1538747A (en) * 1975-07-17 1979-01-24 Shell Int Research Detergent compositions
BE7T1 (fr) * 1977-06-29 1979-12-07 Procter & Gamble Compositions detergentes
JPS54157110A (en) * 1978-06-01 1979-12-11 Lion Corp Liquid detergent composition having excellent rinsability
ATE14453T1 (de) * 1981-11-13 1985-08-15 Unilever Nv Stabile fluessige detergenssuspensionen.
DE3378637D1 (en) * 1982-07-27 1989-01-12 Procter & Gamble Liquid detergent compositions comprising coacervate mixture of alkylcellulose and carboxymethylcellulose and method for preparing them
US4681704A (en) * 1984-03-19 1987-07-21 The Procter & Gamble Company Detergent composition containing semi-polar nonionic detergent alkaline earth metal anionic detergent and amino alkylbetaine detergent
EP0185427B1 (en) * 1984-12-21 1992-03-04 The Procter & Gamble Company Block polyesters and like compounds useful as soil release agents in detergent compositions
GB8508010D0 (en) * 1985-03-27 1985-05-01 Unilever Plc Liquid bleaching compositions
US4661267A (en) * 1985-10-18 1987-04-28 The Procter & Gamble Company Fabric softener composition
US4671895A (en) * 1985-11-15 1987-06-09 Colgate-Palmolive Company Liquid detergent compositions
DE3541535A1 (de) * 1985-11-25 1987-05-27 Henkel Kgaa Verwendung von polyglykoldialkylethern als viskositaetsregler fuer waessrige aniontensidloesungen
US4711730A (en) * 1986-04-15 1987-12-08 The Procter & Gamble Company Capped 1,2-propylene terephthalate-polyoxyethylene terephthalate polyesters useful as soil release agents
DE3718896A1 (de) * 1987-06-05 1988-12-22 Wintershall Ag Verwendung von alkoxylierten alkoholen als viskositaetsregler fuer hochviskose alkylbenzolsulfonat-konzentrate
DE3726911A1 (de) * 1987-08-13 1989-02-23 Henkel Kgaa Waessrige zubereitungen ionischer tenside mit erhoehter viskositaet
DE3730179A1 (de) * 1987-09-09 1989-03-23 Henkel Kgaa Verdickte waessrige tensidloesungen, insbesondere fuer deren einsatz auf dem gebiet kosmetischer praeparate
DE3817415A1 (de) * 1988-05-21 1989-11-30 Henkel Kgaa Verdickte waessrige tensidloesungen
US4997641A (en) * 1990-04-09 1991-03-05 Colgate-Palmolive Company Hair conditioning shampoo containing C6 -C10 alkyl sulfate or alkyl alkoxy sulfate
JP2602557B2 (ja) * 1989-09-01 1997-04-23 花王株式会社 液体漂白剤組成物
JP2602563B2 (ja) * 1989-12-15 1997-04-23 花王株式会社 液体酸素系漂白剤組成物

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994013769A1 (en) * 1992-12-04 1994-06-23 The Procter & Gamble Company Self-thickneded acidic cleaning composition
US5656580A (en) * 1992-12-04 1997-08-12 The Procter & Gamble Company Acidic cleaning compositions self-thickened by a mixture of cationic and nonionic surfactants
US5573710A (en) * 1993-03-30 1996-11-12 Minnesota Mining And Manufacturing Company Multisurface cleaning composition and method of use
WO1994026856A1 (en) * 1993-05-06 1994-11-24 The Procter & Gamble Company Mixing order to prepare aqueous detergent compositions
AU703727B2 (en) * 1994-05-31 1999-04-01 Procter & Gamble Company, The Cleaning compositions
US5910477A (en) * 1994-05-31 1999-06-08 The Procter & Gamble Company Viscous cleaning compositions with improved foam collapse
US5872088A (en) * 1996-11-04 1999-02-16 The Procter & Gamble Company Self-thickened cleaning compositions
US6617293B2 (en) 2001-08-06 2003-09-09 3M Innovative Properties Company Thickening on dilution liquid soap

Also Published As

Publication number Publication date
CA2110413C (en) 1997-12-09
MX9202883A (es) 1993-03-01
DK0518401T3 (da) 1996-03-04
NZ243138A (en) 1995-07-26
IE921922A1 (en) 1992-12-16
GR3018145T3 (en) 1996-02-29
DE69205730T2 (de) 1996-05-30
ATE129742T1 (de) 1995-11-15
AU2336492A (en) 1993-01-12
TR25965A (tr) 1993-11-01
EP0518401A1 (en) 1992-12-16
BR9206153A (pt) 1994-12-27
DE69205730D1 (de) 1995-12-07
AU667481B2 (en) 1996-03-28
CA2110413A1 (en) 1992-12-23
JPH06508393A (ja) 1994-09-22
WO1992022628A1 (en) 1992-12-23
ES2079138T3 (es) 1996-01-01

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