EP0375701B1 - Ice storage and distribution unit - Google Patents
Ice storage and distribution unit Download PDFInfo
- Publication number
- EP0375701B1 EP0375701B1 EP88906985A EP88906985A EP0375701B1 EP 0375701 B1 EP0375701 B1 EP 0375701B1 EP 88906985 A EP88906985 A EP 88906985A EP 88906985 A EP88906985 A EP 88906985A EP 0375701 B1 EP0375701 B1 EP 0375701B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ice
- vessel
- liquid
- slurry
- bed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000003860 storage Methods 0.000 title claims abstract description 66
- 239000007788 liquid Substances 0.000 claims abstract description 66
- 239000002002 slurry Substances 0.000 claims abstract description 52
- 238000000926 separation method Methods 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- 239000012267 brine Substances 0.000 claims description 37
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 37
- 239000013505 freshwater Substances 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 21
- 238000013019 agitation Methods 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 15
- 150000003839 salts Chemical class 0.000 claims description 14
- 238000007599 discharging Methods 0.000 claims description 4
- 238000012544 monitoring process Methods 0.000 claims description 4
- 238000004891 communication Methods 0.000 claims description 2
- 238000004064 recycling Methods 0.000 claims 2
- 238000010586 diagram Methods 0.000 description 4
- 239000013078 crystal Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 235000012206 bottled water Nutrition 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25C—PRODUCING, WORKING OR HANDLING ICE
- F25C5/00—Working or handling ice
- F25C5/18—Storing ice
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25C—PRODUCING, WORKING OR HANDLING ICE
- F25C2301/00—Special arrangements or features for producing ice
- F25C2301/002—Producing ice slurries
Definitions
- This invention relates to an ice storage and distribution unit and to a method of storing and distributing ice.
- ice is transported in "dry” particle form by blowing it with air through pipes. It is essential that the particles have as low a liquid water content as possible to reduce the weight of the particles and to inhibit conglomeration thereof. It is difficult to obtain perfectly “dry” ice particles, thus the ice particles tend to be heavy and conglomerate to form large ice particles. The energy requirements of transporting the particles are high, and clogging of the transportation pipes can occur.
- the apparatus includes an ice generating unit connected to a vessel by way of an ice inlet so that ice slurry produced by the unit can be fed into the vessel. Once in the vessel, the ice slurry separates so that a relatively thin ice bed forms on top of the liquid bath. Drain tubes located near the top of the vessel are provided for drawing liquid from the bath. An inlet conduit replenishes the drained fluid.
- a motor is mounted on the top of the vessel and rotates scraper blades via a shaft. The scraper blades include water discharge nozzles. Potable water is discharged by the nozzles on to the top of the ice bed so that the scraped ice and water is collected in an annular space surrounding the upper part of the vessel where the ice melts in situ.
- an ice storage and distribution unit comprising: an ice-making machine for producing a slurry of ice particles in solution; an ice-storage and separation vessel for storing said slurry of ice particles in solution and separating the ice from the solution; an ice slurry inlet for introducing said slurry of ice particles in solution from said ice-making machine into said vessel, said slurry separating into a bed of ice and a liquid bath of solution in said vessel; an agitator disposed in said vessel for agitating said ice bed; an ice outlet for discharging said agitated ice from said vessel; a make-up liquid inlet in communication with said vessel; characterised in that said ice storage and distribution unit further comprises level detecting means associated with said vessel for monitoring the level of said bed of ice therein; and valve means responsive to said level detecting means and being associated with said make-up liquid inlet to control liquid flow into said vessel from said make-up liquid inlet to maintain said bed of ice at a
- the present invention provides a method of storing and distributing ice comprising the steps of: introducing an inlet slurry of fine particulate ice in solution into a separation zone; allowing the slurry to separate into an ice bed and a liquid bath in said separation zone; agitating said ice bed in an agitation zone; discharging agitated ice from said agitation zone; characterised by performing the further steps of monitoring the level of said ice bed in said agitation zone and introducing make-up liquid into one of said separation and agitation zones in response to the detected level of the ice bed to maintain the level of said bed at a predetermined level in said agitation zone.
- a slurry of ice and brine can be separated so that the ice can be stored and then readily transported when required.
- the ice can be stored without having to store also a large quantity of water, but can still be transported.
- the present method of storing and distributing ice also enables the ice to be transported using less energy, and with a lower tendency to clog ice transport pipes than prior art methods.
- a storage vessel is also provided which is connected to the ice outlet of the separation vessel by a storage vessel ice inlet. Agitated ice and brine are introduced into the storage vessel through the storage vessel ice inlet. The agitated ice forms a bed of ice in the storage vessel, and entrained brine is at least partially drained from the bed of ice.
- a second storage vessel liquid inlet is provided for introducing liquid into the storage vessel. Agitation means are also provided in the storage vessel for agitating the bed of ice.
- a drain is provided in the base of the storage vessel for draining liquid therefrom.
- a second ice outlet is located adjacent to the agitation means, having ice transportation means located therein.
- the method of the present invention can be advantageously used with the ice making machines disclosed in U.S.-A-4,551,159 and WO-A-8600692. These ice making machines produce a slurry of fine particles of ice in brine.
- an ice storage unit 10 includes a storage and separation vessel 12.
- a slurry inlet 14 is located near the base 16 of the vessel 12 and connects an ice generation unit 18 to the vessel 12.
- Also at the base 16 of the vessel 12 is a pair 20 of liquid outlet lines 21, 22 one of which 21 leads to a drain, and the other of which 22 is connected to a brine inlet 23 and leads to the inlet 24 of the ice generation unit 18.
- a level control device 28 Adjacent to this control device 28 is a blade assembly 30, comprising three blades 32 mounted on a rotatable shaft 34. This shaft 34 extends through the top 36 of the vessel 12 where it is connected to a motor 38. Adjacent to the blades 32 is an ice outlet 40.
- a brine feed pipe 42 Connected at one end to the vessel 12 and at the other end to this ice outlet 40 is a brine feed pipe 42.
- the ice outlet leads to a pump 44, which is connected to a distribution pipe 46.
- a recycle pipe 48 is connected at one end to the distribution pipe 46 and at the other end to the vessel 12.
- a slurry of ice particles and brine solution are generated in the ice generating unit 18, and introduced into the storage and separation vessel 12 through the slurry inlet 14.
- This ice generating unit 18 is disclosed in WO-A-8600692.
- the ice and solution are allowed to separate in the vessel into an ice bed 17 and a liquid bath 19. Liquid from the liquid bath can be recycled back to the ice generating unit 18 to generate additional slurry or can be drained. Ice can be continuously generated and fed into the vessel 12 to build up a bed of ice in the vessel 12.
- the level detector is used to measure the level of ice in the vessel and sufficient makeup water is added to the makeup water inlet 25 to maintain the ice bed at the level of the blades 32.
- the blades 32 are rotated by the motor 38 to scrape the surface of the ice bed.
- the scraped, substantially liquid-free ice is discharged through the ice outlet 40 and is mixed with liquid from the liquid bath through the brine feed pipe 42.
- the resultant slurry is passed through the pump 44 and is recycled to the vessel 12 through the recycle pipe 48.
- the recycled ice tends to fuse with larger ice particles already present in the vessel to create larger, more easily drained ice particles. If ice is required, the ice is not recycled to the vessel through the recycle pipe 48, but is instead sent directly through the distribution pipe 46 to the desired location.
- FIG. 2 shows an alternative embodiment of the ice storage and distribution unit showing in Figure 1. Elements similar to those shown in Figure 1 are indicated by the same reference numeral followed by the suffix "A".
- the apparatus and method of operation are similar to those of Figure 1 except that fresh water is added to the ice in the ice outlet 40A through a fresh water pipe 50 instead of salt water.
- fresh water is also sprayed onto the surface of the ice bed in the vessel through a nozzle to rinse out any salt water entrained in the ice bed.
- FIG 3 shows yet another alternative embodiment of the ice storage and distribution unit shown in Figure 1. Elements similar to those shown in Figure 1 are indicated by the same reference numeral followed by a "′" added for clarity.
- the apparatus and method of operation are similar to those of Figures 1 and 2 except that brine and fresh water are added to the ice in the ice outlet 40′ through the brine feed pipe 42′ and a fresh water pipe 50′ respectively.
- the fresh water pipe 50′ and the brine feed pipe 42′ may be connected at the pump 44′ discharge as opposed to the ice outlet 40′.
- Figure 4 illustrates another alternative embodiment of the unit. Elements similar to those shown in Figure 1 are indicated by the same reference numeral, followed by the suffix "B".
- the apparatus and method of operation are similar to those of Figure 1 except that the outlet 40B discharges directly into a container 52 by gravity, rather than being pumped as a slurry.
- an example of an ice storage and separation vessel 110 is connected to a storage vessel 112, which two form an ice storage and distribution unit.
- the vessel 110 is circular in cross-section while vessel 112 is square in cross-section.
- a drain 114 is located at the base 113 of the ice storage and separation vessel 110 and a pair of diametrically-opposed make-up liquid inlets 116 are located above the drain. These inlets 116 are directed tangentially relative to the vessel 110.
- a make-up water line 115 is connected to the inlets 116 and a prechiller 117 is located in the makeup water line to prechill the makeup water.
- a first ice and brine inlet 118 comprising a horizontal pipe 120 extending across the vessel 110 below the makeup liquid inlet 116 and a pair of risers 122 extending therefrom. These risers have openings 124 in the upper ends 126 thereof, through which ice and brine enter the vessel 110.
- a level control device 128 is associated with the inlet to maintain the level of ice and liquid in the vessel 110 at a preset height.
- a timer control unit 119 can be used to adjust the level.
- This assembly 130 comprises three scraper blades 131 mounted on a rotatable shaft 132.
- This shaft 132 extends through the top 133 of the vessel 110 and is connected to and rotatable by a motor 134 located outside the vessel 110.
- a first ice outlet 136 Adjacent to the blades is located a first ice outlet 136. This outlet 136 is connected to the top 138 of the storage vessel 112.
- a plurality of agitators 142 In the base 140 of the storage vessel 112 is disposed a plurality of agitators 142. These agitators 142 are each rotatable by a respective motor 144 located outside the storage vessel. Torque measuring devices 149 are used to measure the torque on the agitators 142 and when the torque is above a predetermined level, additional makeup water is added through line 152 to raise the level of the ice bed.
- Below the agitators 142 is a second ice outlet 143 with an augur 145 located therein.
- a level detector 146 is located near the base 140 of the storage vessel 112, to detect the level of liquid within the storage vessel 112.
- This level detector is associated with a drain pipe 147. Adjacent to the level detector 146 in the base 140 of the storage vessel 112 is a drain 148. A recycle line 150 is connected to the drain 148 at one end and to the top 158 of the storage vessel 112 at the other end. A pump is located in the recycle line 150 to pump liquid from the drain 148 to the top of the storage vessel 112.
- the operation of the apparatus is as follows. Makeup liquid is continuously fed into the separation vessel 110 through the makeup liquid inlets 116. The tangential orientation of the inlets imparts a vortex on the makeup liquid entering the tank.
- a slurry of fine ice particles and brine generated by an ice generation unit such as that disclosed in WO-A-8600692 is continuously fed into the separation vessel through the first ice and brine inlet 118.
- the ice forms a dense uniform layer in the separation vessel 110, through which only some of the brine can drain.
- the ice layer thereby forms a piston which is held above the makeup water due to the pressure exerted on the ice layer by the makeup water.
- the makeup water and the ice and brine slurry are continuously added to the separation vessel 110 to maintain the ice layer at the level of the blades 131.
- the blades 131 are continuously operated to scrape the top surface of the ice layer.
- the scraped ice and entrained brine are fed into the storage vessel 112 through the first ice outlet 136.
- the crystal structure of the ice is altered by the cutting action of the blades, so that larger, more easily drained ice crystals are obtained in the storage vessel 112.
- the entrained brine drains therefrom.
- the scraped ice particles fuse with other ice particles to form larger ice particles.
- the drained brine from the ice falls into the drain 148 and the ice is stored in the storage vessel 112.
- the drained brine is recycled to the top of the vessel 112 through the recycle line 150. Additional salt water is also fed into the vessel 112 through the salt water inlet 152. The agitators are then actuated. The recycled brine and the additional salt water are added to the ice at the level of the agitators 142 to assist in the agitation of the ice, and to maintain an ice slurry. The auger 145 is then actuated and ice is transported to the outlet 143 and pumped to a desired location.
- FIG 6 shows an alternative embodiment of the ice storage and separation vessel 110A and the storage vessel 112A, wherein an ice and fresh water slurry is provided.
- Elements of the apparatus which are the same as those in Figure 5 are given the same reference numeral, followed by the suffix "A".
- the apparatus and process of the embodiment of Figure 6 are the same as that of Figure 5 except that the recycle line 150A from the drain 148A is connected to the first ice and liquid inlet line 120A, rather than to the top 138A of the storage vessel 112A. Also, fresh makeup water is introduced in the first vessel 110A through line 154 which is first prechilled in prechiller 156. In the storage vessel 112A, fresh water is prechilled in prechiller 157 and is introduced into the vessel through line 158.
- the apparatus of Figure 6 operates as follows.
- the brine is drained from the ice and is recycled to the separation vessel through recycle line 150A.
- the ice in the storage vessel is then sprayed with fresh water from liquid inlet 158 to rinse the ice and remove the remaining salt water therefrom and is drained and recycled to the separation vessel.
- the agitators are actuated.
- a slurry of fresh water and ice is then removed from the storage vessel 112A through the auger 145A.
- FIG 7 shows yet another alternative embodiment of the ice storage and separation vessel 110′ and the storage vessel 112′ wherein an ice, brine and fresh water slurry is provided.
- Elements of the apparatus which are the same as those in Figure 5 are given the same reference numeral, followed by a "′" added for clarity.
- the apparatus and process of the embodiment of Figure 7 are the same as the embodiment of Figure 5 except that fresh water is introduced in the second ice outlet 143′ through line 151 which is first prechilled in a prechiller (not shown).
- the fresh water pipe 151 may be connected to the auger 145′ discharge as opposed to the outlet 143′.
- this embodiment provides an ice, brine and water slurry.
- the embodiment of Figure 6 may also be modified as shown in Figure 8 to provide a brine feed pipe 153 at the outlet 143A′ thereby resulting in an ice, water and brine slurry. Similar to the embodiment in Figure 7, the brine feed pipe 153 may be connected at the auger 145A′ discharge as opposed to the outlet 143A′.
- FIGS 9 and 10 show an alternative embodiment of the blade assembly of Figures 1 to 8. Elements similar to those shown in Figure 1 are indicated by the same reference numeral, followed by the suffix "C".
- the assembly 30C floats on the surface of the ice.
- the assembly 30C is similar to that shown in Figures 1 to 8 except that the shaft 34C is slidably located in bearings 54 of motor 38C.
- the shaft 34C has a groove 56 extending longitudinally over a portion thereof into which is slidably keyed a key 58 connected to the drive shaft 60. Attached to the trailing end 62 of each blade 32C just above the cutting edge 64 is a horizontally extending ski 66.
- skis 66 rest on the surface of the ice bed and the cutting edge 64 of the blade 32C extend into the bed to cut the bed.
- the blade assembly 30C rises or falls within the limits defined by the groove 56 and key 58.
- the assembly 30C will be at its maximum height and a limit switch 68 will be activated by the shaft 32C to drain the vessel.
- FIG 11 shows an alternative design of the blades of a blade assembly suitable for use with the embodiments of the invention illustrated in Figures 1 to 8. Elements similar to those shown in Figure 1 will be given the same reference numeral followed by the letter "D". As can be seen in Figure 11, these blades 32D have serrated cutting edges 70. These blades 32D tend to plow the bed to break up capillaries in the ice bed. The action of the blades leaves peaks and troughs in the ice bed surface, which allow the water to drain more quickly from the ice bed.
- FIG 12 is another alternative embodiment of the invention. Elements similar to those shown in Figure 1 will be given the same reference numerals, followed by the letter "E".
- makeup water is added to the vessel 12E slowly through a central inlet 72.
- makeup water By adding makeup water slowly to the vessel, the solution present in the vessel is maintained in a quiescent state. A concentration gradient is thereby set up in the vessel. Since brine is denser than water, the concentration of salt will be higher at the bottom of the vessel than near the top.
- a liquid distributor is located at the top of the vessel 12E. Fresh water is sprayed onto the surface of the bed by this distributor.
- an auger 76 Also shown in this embodiment is an auger 76.
- An auger or a plurality of augers can be used to replace the blade assembly when a rectangular tank is used instead of a cylindrical tank.
- This agitator can replace the blade assembly used in the embodiments of Figures 1 to 8 if the tanks in these embodiments were rectangular.
- Figure 13 shows an embodiment to the invention suitable for use on board a ship.
- the storage and distribution unit 210 includes a rectangular cross-sectioned vessel 212.
- a slurry inlet 214, leading from an ice generation unit 216 similar to that disclosed in WO-A-8600692 is connected near the top 218 of this vessel 212.
- Beneath this slurry inlet 214 is located a level detector 220, which measures the level of liquid in the vessel 212.
- agitators 224 In the base 222 of the vessel 212 there are located a plurality of agitators 224 which extend across the length of the base 222. These agitators 224 are each operated by a motor 226 located outside of the vessel 212. A torque measuring device 225 is associated with the agitators 224.
- a sump 228 Depending from the base 222 of the vessel is a sump 228.
- a makeup water inlet 230 and two liquid outlets 232, 234 are connected to this sump 228.
- One 232 of the liquid outlets is connected to a drain 236, and to a liquid recycle pipe 238 which is connected to the top 218 of the vessel 212.
- the other 234 of the liquid outlets is connected to the ice generation unit 216.
- Adjacent to the sump 228 is located an ice outlet 240 which has a pump 242 located therein.
- the operation of the unit is as follows. First slurry is generated in the ice generation unit 216, and this slurry is introduced into the vessel 212.
- the water level in the vessel can be kept constant, or brine can be removed from the vessel and a makeup water added through inlet 230 when the brine concentration gets too high.
- the brine concentration can be monitored by a temperature gauge.
- the liquid being removed drains into the sump 228 and can be recycled to the ice generation unit through liquid outlet 234. More slurry from the ice generation unit 216 is fed into the vessel 212, until a bed of ice is built up in the vessel 212.
- the agitators 224 are actuated to agitate the ice, and the ice is discharged through the ice outlet 240 and is pumped to the desired location.
- the torque measuring device 225 measures the torque exerted by the agitators and makeup water is added via line 230 when the torque is increased beyond a predetermined amount.
- the recycle pipe 234 could be removed, and fresh water could be sprayed into the top of the vessel to wash out any entrained salt water in the ice. Fresh water could then be added through the makeup liquid inlet 230 when required. If an ice, brine and fresh water slurry is desired, a fresh water feed pipe can be connected to the outlet 240 or to the auger 242 discharge.
- This embodiment is particularly suitable for use on board a ship to inhibit splashing and spillage of water since the upper portion of the tank is largely empty.
- the tanks of Figures 1 to 8 could be sealed when used on board a ship, however, the expansion of ice would have to be compensated for under certain circumstances.
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Abstract
Description
- This invention relates to an ice storage and distribution unit and to a method of storing and distributing ice.
- In the prior art, ice is transported in "dry" particle form by blowing it with air through pipes. It is essential that the particles have as low a liquid water content as possible to reduce the weight of the particles and to inhibit conglomeration thereof. It is difficult to obtain perfectly "dry" ice particles, thus the ice particles tend to be heavy and conglomerate to form large ice particles. The energy requirements of transporting the particles are high, and clogging of the transportation pipes can occur.
- An apparatus for the continuous concentration of aqueous solutions is known from US-A-4 341 085. The apparatus includes an ice generating unit connected to a vessel by way of an ice inlet so that ice slurry produced by the unit can be fed into the vessel. Once in the vessel, the ice slurry separates so that a relatively thin ice bed forms on top of the liquid bath. Drain tubes located near the top of the vessel are provided for drawing liquid from the bath. An inlet conduit replenishes the drained fluid. A motor is mounted on the top of the vessel and rotates scraper blades via a shaft. The scraper blades include water discharge nozzles. Potable water is discharged by the nozzles on to the top of the ice bed so that the scraped ice and water is collected in an annular space surrounding the upper part of the vessel where the ice melts in situ.
- It is an object of the present invention to obviate or mitigate the above-mentioned disadvantages.
- Accordingly, the present invention provides an ice storage and distribution unit comprising:
an ice-making machine for producing a slurry of ice particles in solution;
an ice-storage and separation vessel for storing said slurry of ice particles in solution and separating the ice from the solution;
an ice slurry inlet for introducing said slurry of ice particles in solution from said ice-making machine into said vessel, said slurry separating into a bed of ice and a liquid bath of solution in said vessel;
an agitator disposed in said vessel for agitating said ice bed;
an ice outlet for discharging said agitated ice from said vessel;
a make-up liquid inlet in communication with said vessel;
characterised in that said ice storage and distribution unit further comprises level detecting means associated with said vessel for monitoring the level of said bed of ice therein; and
valve means responsive to said level detecting means and being associated with said make-up liquid inlet to control liquid flow into said vessel from said make-up liquid inlet to maintain said bed of ice at a predetermined level in said vessel adjacent to said agitator. - In another one of its aspects, the present invention provides a method of storing and distributing ice comprising the steps of:
introducing an inlet slurry of fine particulate ice in solution into a separation zone;
allowing the slurry to separate into an ice bed and a liquid bath in said separation zone;
agitating said ice bed in an agitation zone;
discharging agitated ice from said agitation zone; characterised by performing the further steps of monitoring the level of said ice bed in said agitation zone and introducing make-up liquid into one of said separation and agitation zones in response to the detected level of the ice bed to maintain the level of said bed at a predetermined level in said agitation zone. - With the present invention, a slurry of ice and brine can be separated so that the ice can be stored and then readily transported when required. Also, with the present invention, the ice can be stored without having to store also a large quantity of water, but can still be transported. The present method of storing and distributing ice also enables the ice to be transported using less energy, and with a lower tendency to clog ice transport pipes than prior art methods.
- Preferably, a storage vessel is also provided which is connected to the ice outlet of the separation vessel by a storage vessel ice inlet. Agitated ice and brine are introduced into the storage vessel through the storage vessel ice inlet. The agitated ice forms a bed of ice in the storage vessel, and entrained brine is at least partially drained from the bed of ice. A second storage vessel liquid inlet is provided for introducing liquid into the storage vessel. Agitation means are also provided in the storage vessel for agitating the bed of ice. A drain is provided in the base of the storage vessel for draining liquid therefrom. A second ice outlet is located adjacent to the agitation means, having ice transportation means located therein.
- The method of the present invention can be advantageously used with the ice making machines disclosed in U.S.-A-4,551,159 and WO-A-8600692. These ice making machines produce a slurry of fine particles of ice in brine.
- Preferred embodiments of the invention will now be described, by way of example only, with reference to the following drawings in which:
- Figure 1 is a schematic diagram of an ice storage and distribution unit;
- Figure 2 is a schematic diagram of an alternative embodiment of the ice storage and distribution unit of Figure 1;
- Figure 3 is a schematic diagram of another alternative embodiment of the ice storage and distribution unit of Figure 1;
- Figure 4 is a schematic diagram of another alternative embodiment of the unit of Figure 1;
- Figure 5 is a schematic representation of an apparatus to store and transport an ice and brine slurry;
- Figure 6 is a schematic representation of an alternative embodiment of the apparatus of Figure 5 to store and transport an ice and water slurry;
- Figure 7 is a schematic representation of an alternative embodiment of the apparatus of Figure 5 to store and transport an ice, brine and water slurry;
- Figure 8 is a schematic representation of an alternative embodiment of the apparatus of Figure 6 to store and transport an ice, brine and water slurry;
- Figure 9 is a side view in partial cross-section of a blade assembly to be used in the units of Figures 1 to 8;
- Figure 10 is a view from below of the blade assembly of Figure 9;
- Figure 11 is a side view of an alternative embodiment of a blade assembly to be used with the apparatuses of Figures 1 to 8;
- Figure 12 is an alternative embodiment of an ice storage and distribution unit; and
- Figure 13 is an additional alternative embodiment of an ice storage and distribution unit.
- Referring first to Figure 1, it can be seen that an
ice storage unit 10 includes a storage andseparation vessel 12. Aslurry inlet 14 is located near thebase 16 of thevessel 12 and connects anice generation unit 18 to thevessel 12. Also at thebase 16 of thevessel 12 is apair 20 ofliquid outlet lines brine inlet 23 and leads to theinlet 24 of theice generation unit 18. Above theslurry inlet 14, is amakeup water inlet 25 to allow flow of makeup water into thevessel 12. - At the
upper part 26 of thevessel 12, alevel control device 28 is located. Adjacent to thiscontrol device 28 is ablade assembly 30, comprising threeblades 32 mounted on arotatable shaft 34. Thisshaft 34 extends through thetop 36 of thevessel 12 where it is connected to amotor 38. Adjacent to theblades 32 is anice outlet 40. - Connected at one end to the
vessel 12 and at the other end to thisice outlet 40 is abrine feed pipe 42. The ice outlet leads to apump 44, which is connected to adistribution pipe 46. Arecycle pipe 48 is connected at one end to thedistribution pipe 46 and at the other end to thevessel 12. - The operation of the unit will now be described with reference to Figure 1. A slurry of ice particles and brine solution are generated in the
ice generating unit 18, and introduced into the storage andseparation vessel 12 through theslurry inlet 14. Thisice generating unit 18 is disclosed in WO-A-8600692. - The ice and solution are allowed to separate in the vessel into an
ice bed 17 and aliquid bath 19. Liquid from the liquid bath can be recycled back to theice generating unit 18 to generate additional slurry or can be drained. Ice can be continuously generated and fed into thevessel 12 to build up a bed of ice in thevessel 12. The level detector is used to measure the level of ice in the vessel and sufficient makeup water is added to themakeup water inlet 25 to maintain the ice bed at the level of theblades 32. Theblades 32 are rotated by themotor 38 to scrape the surface of the ice bed. The scraped, substantially liquid-free ice is discharged through theice outlet 40 and is mixed with liquid from the liquid bath through thebrine feed pipe 42. The resultant slurry is passed through thepump 44 and is recycled to thevessel 12 through therecycle pipe 48. The recycled ice tends to fuse with larger ice particles already present in the vessel to create larger, more easily drained ice particles. If ice is required, the ice is not recycled to the vessel through therecycle pipe 48, but is instead sent directly through thedistribution pipe 46 to the desired location. - Figure 2 shows an alternative embodiment of the ice storage and distribution unit showing in Figure 1. Elements similar to those shown in Figure 1 are indicated by the same reference numeral followed by the suffix "A". In this embodiment the apparatus and method of operation are similar to those of Figure 1 except that fresh water is added to the ice in the
ice outlet 40A through afresh water pipe 50 instead of salt water. Optionally, fresh water is also sprayed onto the surface of the ice bed in the vessel through a nozzle to rinse out any salt water entrained in the ice bed. - Figure 3 shows yet another alternative embodiment of the ice storage and distribution unit shown in Figure 1. Elements similar to those shown in Figure 1 are indicated by the same reference numeral followed by a "′" added for clarity. In this embodiment the apparatus and method of operation are similar to those of Figures 1 and 2 except that brine and fresh water are added to the ice in the
ice outlet 40′ through thebrine feed pipe 42′ and afresh water pipe 50′ respectively. Although not shown, thefresh water pipe 50′ and thebrine feed pipe 42′ may be connected at thepump 44′ discharge as opposed to theice outlet 40′. - Figure 4 illustrates another alternative embodiment of the unit. Elements similar to those shown in Figure 1 are indicated by the same reference numeral, followed by the suffix "B". In this embodiment, the apparatus and method of operation are similar to those of Figure 1 except that the
outlet 40B discharges directly into acontainer 52 by gravity, rather than being pumped as a slurry. - Referring to Figure 5, an example of an ice storage and
separation vessel 110 is connected to astorage vessel 112, which two form an ice storage and distribution unit. Thevessel 110 is circular in cross-section whilevessel 112 is square in cross-section. - A
drain 114 is located at thebase 113 of the ice storage andseparation vessel 110 and a pair of diametrically-opposed make-upliquid inlets 116 are located above the drain. Theseinlets 116 are directed tangentially relative to thevessel 110. A make-upwater line 115 is connected to theinlets 116 and aprechiller 117 is located in the makeup water line to prechill the makeup water. - Located inside the
vessel 110 is a first ice andbrine inlet 118 comprising ahorizontal pipe 120 extending across thevessel 110 below themakeup liquid inlet 116 and a pair ofrisers 122 extending therefrom. These risers haveopenings 124 in the upper ends 126 thereof, through which ice and brine enter thevessel 110. Alevel control device 128 is associated with the inlet to maintain the level of ice and liquid in thevessel 110 at a preset height. Atimer control unit 119 can be used to adjust the level. - Above the
risers 122 is located a blade assembly 130. This assembly 130 comprises threescraper blades 131 mounted on arotatable shaft 132. Thisshaft 132 extends through the top 133 of thevessel 110 and is connected to and rotatable by a motor 134 located outside thevessel 110. - Adjacent to the blades is located a
first ice outlet 136. Thisoutlet 136 is connected to the top 138 of thestorage vessel 112. In thebase 140 of thestorage vessel 112 is disposed a plurality ofagitators 142. Theseagitators 142 are each rotatable by a respective motor 144 located outside the storage vessel.Torque measuring devices 149 are used to measure the torque on theagitators 142 and when the torque is above a predetermined level, additional makeup water is added throughline 152 to raise the level of the ice bed. Below theagitators 142 is asecond ice outlet 143 with anaugur 145 located therein. Alevel detector 146 is located near thebase 140 of thestorage vessel 112, to detect the level of liquid within thestorage vessel 112. This level detector is associated with adrain pipe 147. Adjacent to thelevel detector 146 in thebase 140 of thestorage vessel 112 is adrain 148. Arecycle line 150 is connected to thedrain 148 at one end and to the top 158 of thestorage vessel 112 at the other end. A pump is located in therecycle line 150 to pump liquid from thedrain 148 to the top of thestorage vessel 112. - The operation of the apparatus is as follows. Makeup liquid is continuously fed into the
separation vessel 110 through themakeup liquid inlets 116. The tangential orientation of the inlets imparts a vortex on the makeup liquid entering the tank. A slurry of fine ice particles and brine generated by an ice generation unit such as that disclosed in WO-A-8600692, is continuously fed into the separation vessel through the first ice andbrine inlet 118. The ice forms a dense uniform layer in theseparation vessel 110, through which only some of the brine can drain. The ice layer thereby forms a piston which is held above the makeup water due to the pressure exerted on the ice layer by the makeup water. - The makeup water and the ice and brine slurry are continuously added to the
separation vessel 110 to maintain the ice layer at the level of theblades 131. Theblades 131 are continuously operated to scrape the top surface of the ice layer. The scraped ice and entrained brine are fed into thestorage vessel 112 through thefirst ice outlet 136. - The crystal structure of the ice is altered by the cutting action of the blades, so that larger, more easily drained ice crystals are obtained in the
storage vessel 112. As the scraped ice particles fall into thestorage vessel 112, the entrained brine drains therefrom. In the storage vessel, the scraped ice particles fuse with other ice particles to form larger ice particles. The drained brine from the ice falls into thedrain 148 and the ice is stored in thestorage vessel 112. - When it is desired to transport the ice, the drained brine is recycled to the top of the
vessel 112 through therecycle line 150. Additional salt water is also fed into thevessel 112 through thesalt water inlet 152. The agitators are then actuated. The recycled brine and the additional salt water are added to the ice at the level of theagitators 142 to assist in the agitation of the ice, and to maintain an ice slurry. Theauger 145 is then actuated and ice is transported to theoutlet 143 and pumped to a desired location. - Figure 6 shows an alternative embodiment of the ice storage and
separation vessel 110A and thestorage vessel 112A, wherein an ice and fresh water slurry is provided. Elements of the apparatus which are the same as those in Figure 5 are given the same reference numeral, followed by the suffix "A". - The apparatus and process of the embodiment of Figure 6 are the same as that of Figure 5 except that the
recycle line 150A from thedrain 148A is connected to the first ice andliquid inlet line 120A, rather than to the top 138A of thestorage vessel 112A. Also, fresh makeup water is introduced in thefirst vessel 110A throughline 154 which is first prechilled inprechiller 156. In thestorage vessel 112A, fresh water is prechilled inprechiller 157 and is introduced into the vessel throughline 158. - The apparatus of Figure 6 operates as follows. In the storage vessel, the brine is drained from the ice and is recycled to the separation vessel through
recycle line 150A. The ice in the storage vessel is then sprayed with fresh water fromliquid inlet 158 to rinse the ice and remove the remaining salt water therefrom and is drained and recycled to the separation vessel. When ice is required, the agitators are actuated. A slurry of fresh water and ice is then removed from thestorage vessel 112A through theauger 145A. - Figure 7 shows yet another alternative embodiment of the ice storage and
separation vessel 110′ and thestorage vessel 112′ wherein an ice, brine and fresh water slurry is provided. Elements of the apparatus which are the same as those in Figure 5 are given the same reference numeral, followed by a "′" added for clarity. - The apparatus and process of the embodiment of Figure 7 are the same as the embodiment of Figure 5 except that fresh water is introduced in the
second ice outlet 143′ throughline 151 which is first prechilled in a prechiller (not shown). Alternatively, thefresh water pipe 151 may be connected to theauger 145′ discharge as opposed to theoutlet 143′. Thus, this embodiment provides an ice, brine and water slurry. The embodiment of Figure 6 may also be modified as shown in Figure 8 to provide abrine feed pipe 153 at theoutlet 143A′ thereby resulting in an ice, water and brine slurry. Similar to the embodiment in Figure 7, thebrine feed pipe 153 may be connected at theauger 145A′ discharge as opposed to theoutlet 143A′. - Figures 9 and 10 show an alternative embodiment of the blade assembly of Figures 1 to 8. Elements similar to those shown in Figure 1 are indicated by the same reference numeral, followed by the suffix "C". In this embodiment, the
assembly 30C floats on the surface of the ice. Theassembly 30C is similar to that shown in Figures 1 to 8 except that theshaft 34C is slidably located inbearings 54 of motor 38C. Theshaft 34C has agroove 56 extending longitudinally over a portion thereof into which is slidably keyed a key 58 connected to thedrive shaft 60. Attached to the trailingend 62 of eachblade 32C just above thecutting edge 64 is a horizontally extendingski 66. - In operation,
skis 66 rest on the surface of the ice bed and thecutting edge 64 of theblade 32C extend into the bed to cut the bed. When the bed rises or falls, theblade assembly 30C rises or falls within the limits defined by thegroove 56 and key 58. When the vessel is full of ice and liquid, theassembly 30C will be at its maximum height and alimit switch 68 will be activated by theshaft 32C to drain the vessel. - Figure 11 shows an alternative design of the blades of a blade assembly suitable for use with the embodiments of the invention illustrated in Figures 1 to 8. Elements similar to those shown in Figure 1 will be given the same reference numeral followed by the letter "D". As can be seen in Figure 11, these
blades 32D have serrated cutting edges 70. Theseblades 32D tend to plow the bed to break up capillaries in the ice bed. The action of the blades leaves peaks and troughs in the ice bed surface, which allow the water to drain more quickly from the ice bed. - Figure 12 is another alternative embodiment of the invention. Elements similar to those shown in Figure 1 will be given the same reference numerals, followed by the letter "E".
- In this embodiment, makeup water is added to the
vessel 12E slowly through acentral inlet 72. By adding makeup water slowly to the vessel, the solution present in the vessel is maintained in a quiescent state. A concentration gradient is thereby set up in the vessel. Since brine is denser than water, the concentration of salt will be higher at the bottom of the vessel than near the top. At the top of thevessel 12E, a liquid distributor is located. Fresh water is sprayed onto the surface of the bed by this distributor. - With this configuration, fresh, salt-free ice can be obtained relatively quickly.
- Also shown in this embodiment is an
auger 76. An auger or a plurality of augers can be used to replace the blade assembly when a rectangular tank is used instead of a cylindrical tank. This agitator can replace the blade assembly used in the embodiments of Figures 1 to 8 if the tanks in these embodiments were rectangular. - Figure 13 shows an embodiment to the invention suitable for use on board a ship.
- As can be seen in this figure, the storage and
distribution unit 210 includes a rectangularcross-sectioned vessel 212. Aslurry inlet 214, leading from anice generation unit 216 similar to that disclosed in WO-A-8600692 is connected near the top 218 of thisvessel 212. Beneath thisslurry inlet 214 is located alevel detector 220, which measures the level of liquid in thevessel 212. - In the
base 222 of thevessel 212 there are located a plurality ofagitators 224 which extend across the length of thebase 222. Theseagitators 224 are each operated by amotor 226 located outside of thevessel 212. Atorque measuring device 225 is associated with theagitators 224. - Depending from the
base 222 of the vessel is asump 228. Amakeup water inlet 230 and twoliquid outlets sump 228. One 232 of the liquid outlets is connected to adrain 236, and to aliquid recycle pipe 238 which is connected to the top 218 of thevessel 212. The other 234 of the liquid outlets is connected to theice generation unit 216. Adjacent to thesump 228 is located anice outlet 240 which has apump 242 located therein. - The operation of the unit is as follows. First slurry is generated in the
ice generation unit 216, and this slurry is introduced into thevessel 212. The water level in the vessel can be kept constant, or brine can be removed from the vessel and a makeup water added throughinlet 230 when the brine concentration gets too high. The brine concentration can be monitored by a temperature gauge. The liquid being removed drains into thesump 228 and can be recycled to the ice generation unit throughliquid outlet 234. More slurry from theice generation unit 216 is fed into thevessel 212, until a bed of ice is built up in thevessel 212. - When ice is required, the
agitators 224 are actuated to agitate the ice, and the ice is discharged through theice outlet 240 and is pumped to the desired location. - The
torque measuring device 225 measures the torque exerted by the agitators and makeup water is added vialine 230 when the torque is increased beyond a predetermined amount. - If fresh water ice is desired instead of salt water ice, the
recycle pipe 234 could be removed, and fresh water could be sprayed into the top of the vessel to wash out any entrained salt water in the ice. Fresh water could then be added through themakeup liquid inlet 230 when required. If an ice, brine and fresh water slurry is desired, a fresh water feed pipe can be connected to theoutlet 240 or to theauger 242 discharge. - This embodiment is particularly suitable for use on board a ship to inhibit splashing and spillage of water since the upper portion of the tank is largely empty. Alternatively, the tanks of Figures 1 to 8 could be sealed when used on board a ship, however, the expansion of ice would have to be compensated for under certain circumstances.
Claims (18)
- An ice storage and distribution unit (10) comprising:
an ice-making machine (18) for producing a slurry of ice particles in solution;
an ice-storage and separation vessel (12, 110) for storing said slurry of ice particles in solution and separating the ice from the solution;
an ice slurry inlet (14) for introducing said slurry of ice particles in solution from said ice-making machine into said vessel, said slurry separating into a bed of ice (17) and a liquid bath of solution (19) in said vessel;
an agitator (30) disposed in said vessel for agitating said ice bed;
an ice outlet (40, 136) for discharging said agitated ice from said vessel;
a make-up liquid inlet (25) in communication with said vessel;
characterised in that said ice storage and distribution unit further comprises level detecting means (28) associated with said vessel for monitoring the level of said bed of ice therein; and
valve means responsive to said level detecting means and being associated with said make-up liquid inlet to control liquid flow into said vessel (12) from said make-up liquid inlet (25) to maintain said bed of ice (17) at a predetermined level in said vessel adjacent to said agitator (30). - The unit of claim 1 characterised in that said agitator (30) is in the upper portion of the vessel (12) and is in the form of a blade assembly (32).
- The unit of claim 1 characterised in that said unit further comprises:
a storage vessel (112) connected to said ice storage and separation vessel (110) by said ice outlet (136), agitated ice and entrained brine being introduced into said second storage vessel through said ice outlet and forming a bed of ice therein;
a storage vessel liquid inlet (152) for introducing liquid into said storage vessel (112);
agitation means (142) in the base of said storage vessel (112) for agitating said bed of ice; and
a storage vessel ice outlet (143) located adjacent to said agitation means (142). - The unit of claim 3 characterised in that said agitation means (142) has torque measuring means (149) associated therewith, said torque measuring means controlling the amount of liquid introduced into the storage vessel (112) through said liquid inlet (152).
- The unit of claim 3 characterised in that said agitation means (142) has torque measuring means (149) associated therewith, said torque measuring means controlling a valve (158) in said storage vessel liquid inlet (152).
- The unit of claim 1 characterised in that said unit further includes a liquid inlet (42 or 50) for introducing liquid into said agitated ice in said ice outlet to provide an outlet ice slurry.
- The unit of claim 6 characterised in that said liquid is salt or fresh water.
- The unit of claim 6 characterised in that said unit further includes a second liquid inlet (50 or 42) for introducing a second liquid into said agitated ice in said ice outlet to provide an outlet ice slurry.
- The unit of claim 8 characterised in that one of said liquids is salt water and the other of said liquids is fresh water.
- The unit of claim 6 characterised in that said unit further comprises a recycle line (48) to recycle at least a portion of said outlet ice slurry to said vessel (12).
- The unit of claim 1 characterised in that said unit further comprises a recycle line (22) connected to a liquid drain in said vessel (12) for recycling liquid to said ice-making machine (18).
- The unit of claim 1 characterised in that said make-up liquid inlet (25) comprises a pair of tangentially oriented inlets (116).
- A method of storing and distributing ice comprising the steps of:
introducing an inlet slurry of fine particulate ice in solution into a separation zone;
allowing the slurry to separate into an ice bed (17) and a liquid bath (19) in said separation zone;
agitating said ice bed in an agitation zone;
discharging agitated ice from said agitation zone; characterised by performing the further steps of monitoring the level of said ice bed in said agitation zone and introducing make-up liquid into one of said separation and agitation zones in response to the detected level of the ice bed to maintain the level of said bed at a predetermined level in said agitation zone. - The method of claim 13 further including the step of adding liquid to said agitated ice to form an outlet ice slurry.
- The method of claim 14 further including the step of recycling at least a portion of said outlet ice slurry back into said separation zone.
- The method of claim 15 wherein said make-up liquid is introduced into said separation zone.
- The method of any one of claims 14 to 16 wherein the liquid added to said agitated ice is fresh or salt water or both fresh and salt water.
- The method of claim 17 wherein said salt water is obtained from the liquid bath in said separation zone.
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US7483487A | 1987-07-17 | 1987-07-17 | |
US74834 | 1987-07-17 | ||
US9789087A | 1987-09-17 | 1987-09-17 | |
US97890 | 1987-09-17 | ||
US225711 | 1988-06-23 | ||
US07/225,711 US4912935A (en) | 1987-09-17 | 1988-06-23 | Ice storage and distribution unit |
PCT/GB1988/000578 WO1989000668A1 (en) | 1987-07-17 | 1988-07-18 | Ice storage and distribution unit |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0375701A1 EP0375701A1 (en) | 1990-07-04 |
EP0375701B1 true EP0375701B1 (en) | 1995-03-01 |
Family
ID=27372559
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88906985A Expired - Lifetime EP0375701B1 (en) | 1987-07-17 | 1988-07-18 | Ice storage and distribution unit |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP0375701B1 (en) |
JP (1) | JP2736796B2 (en) |
KR (1) | KR970004725B1 (en) |
CN (1) | CN1018671B (en) |
AT (1) | ATE119267T1 (en) |
AU (1) | AU2251788A (en) |
CA (1) | CA1298983C (en) |
DE (1) | DE3853213T2 (en) |
WO (1) | WO1989000668A1 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NO923173L (en) * | 1992-08-13 | 1994-02-14 | Mmc As | Device for ice making |
FR2822226B1 (en) * | 2001-03-19 | 2003-06-27 | Lgl France | METHOD AND DEVICE FOR STORING A DIPHASIC REFRIGERANT FLUID |
KR100451136B1 (en) * | 2001-08-22 | 2004-10-06 | 정순용 | Hydrate heat control method and its apparatus of mass concrete |
WO2004081469A1 (en) * | 2003-03-10 | 2004-09-23 | Skaginn Hf. | A method and apparatus for producing homogenous fluid ice |
JP4692880B2 (en) * | 2005-07-01 | 2011-06-01 | 株式会社マリンリバー | Manufacturing equipment for salt water or seawater microscopic ice |
JP2007040548A (en) * | 2005-07-29 | 2007-02-15 | Kajima Corp | Method and apparatus for producing salt water soft ice |
CN114867975B (en) * | 2019-12-27 | 2024-06-21 | 大金工业株式会社 | Ice supply device and ice making system |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2735591A (en) * | 1956-02-21 | E branchflower | ||
GB480183A (en) * | 1935-09-21 | 1938-02-18 | Erik Oeman | Apparatus for producing cold |
DE668100C (en) * | 1937-04-07 | 1938-11-25 | Julius Pintsch Kom Ges | Device for securing small pieces of ice |
US2419881A (en) * | 1944-06-02 | 1947-04-29 | Int Harvester Co | Sea water fractionator |
US3825158A (en) * | 1973-05-16 | 1974-07-23 | W Morris | Cube ice storage bin with disturber bars |
US4129015A (en) * | 1977-04-22 | 1978-12-12 | Morris Jr William F | Ice storage and dispensing bin |
US4341085A (en) * | 1981-03-04 | 1982-07-27 | Chicago Bridge & Iron Company | Freeze concentration apparatus and method |
US4535942A (en) * | 1981-12-02 | 1985-08-20 | Kyoeizoki Co., Ltd. | Apparatus for containing easily solidifying powder and particles |
US4401449A (en) * | 1982-04-29 | 1983-08-30 | Refrigeration Engineering Corporation | Slush ice maker |
CH659314A5 (en) * | 1982-10-27 | 1987-01-15 | Sulzer Ag | TRAINED ENERGY STORAGE AS A DIRECTLY OPERATING EVAPORATOR. |
DE3484537D1 (en) * | 1984-07-17 | 1991-06-06 | Sunwell Eng Co Ltd | ICE PRODUCTION MACHINE. |
US4584843A (en) * | 1984-11-05 | 1986-04-29 | Chicago Bridge & Iron Company | Method and apparatus of storing ice slurry and its use for cooling purposes |
JPS61282739A (en) * | 1985-06-06 | 1986-12-12 | Yasuo Igarashi | Ice slurry thermal accumulation device |
-
1988
- 1988-07-17 CN CN88106123A patent/CN1018671B/en not_active Expired
- 1988-07-18 KR KR1019890700486A patent/KR970004725B1/en not_active Expired - Fee Related
- 1988-07-18 EP EP88906985A patent/EP0375701B1/en not_active Expired - Lifetime
- 1988-07-18 JP JP63506566A patent/JP2736796B2/en not_active Expired - Fee Related
- 1988-07-18 DE DE3853213T patent/DE3853213T2/en not_active Expired - Fee Related
- 1988-07-18 AU AU22517/88A patent/AU2251788A/en not_active Abandoned
- 1988-07-18 CA CA000572345A patent/CA1298983C/en not_active Expired - Lifetime
- 1988-07-18 WO PCT/GB1988/000578 patent/WO1989000668A1/en active IP Right Grant
- 1988-07-18 AT AT88906985T patent/ATE119267T1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CN1018671B (en) | 1992-10-14 |
DE3853213T2 (en) | 1995-10-26 |
KR900700834A (en) | 1990-08-17 |
EP0375701A1 (en) | 1990-07-04 |
AU2251788A (en) | 1989-02-13 |
KR970004725B1 (en) | 1997-04-02 |
CA1298983C (en) | 1992-04-21 |
CN1032072A (en) | 1989-03-29 |
WO1989000668A1 (en) | 1989-01-26 |
DE3853213D1 (en) | 1995-04-06 |
JPH03500806A (en) | 1991-02-21 |
ATE119267T1 (en) | 1995-03-15 |
JP2736796B2 (en) | 1998-04-02 |
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