EP0275827B1 - Filter for cleaning the exhaust gases from diesel engines - Google Patents
Filter for cleaning the exhaust gases from diesel engines Download PDFInfo
- Publication number
- EP0275827B1 EP0275827B1 EP87810740A EP87810740A EP0275827B1 EP 0275827 B1 EP0275827 B1 EP 0275827B1 EP 87810740 A EP87810740 A EP 87810740A EP 87810740 A EP87810740 A EP 87810740A EP 0275827 B1 EP0275827 B1 EP 0275827B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- soot
- filter
- exhaust gases
- diesel engines
- foamed ceramic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007789 gas Substances 0.000 title claims abstract description 22
- 238000004140 cleaning Methods 0.000 title claims abstract description 5
- 239000000919 ceramic Substances 0.000 claims abstract description 24
- 239000011148 porous material Substances 0.000 claims abstract description 20
- 239000004071 soot Substances 0.000 abstract description 22
- 239000006260 foam Substances 0.000 abstract description 11
- 230000008929 regeneration Effects 0.000 abstract description 6
- 238000011069 regeneration method Methods 0.000 abstract description 6
- 239000002245 particle Substances 0.000 abstract description 2
- 206010061218 Inflammation Diseases 0.000 abstract 3
- 230000004054 inflammatory process Effects 0.000 abstract 3
- 230000000737 periodic effect Effects 0.000 abstract 1
- 210000004027 cell Anatomy 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/033—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
- F01N3/035—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors, e.g. catalysed diesel particulate filters
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2250/00—Combinations of different methods of purification
- F01N2250/02—Combinations of different methods of purification filtering and catalytic conversion
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/06—Ceramic, e.g. monoliths
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B3/00—Engines characterised by air compression and subsequent fuel addition
- F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S55/00—Gas separation
- Y10S55/30—Exhaust treatment
Definitions
- the present invention relates to a filter for cleaning the exhaust gases from diesel engines.
- soot components of the exhaust gases from diesel engines can be reduced in two ways: by optimizing the mixture preparation and the combustion process in the engine and by installing filters in the exhaust gas flow. Depending on the design of the filter, soot separation rates of 50 to 90% are usually achieved.
- the soot filter Since the diesel exhaust soot filter would be clogged with soot within a short period of use, the soot must be burned periodically. The time period from one regeneration phase to another is called the regeneration interval. The filter regenerates itself under certain conditions. The soot deposits are burned at temperatures between 550 and 700 ° C. With catalytically coated filters, the ignition temperature can be reduced to approx. 400 ° C.
- An open-pore foam ceramic is understood to mean a porous ceramic body with a three-dimensional network and cellular structure that contains a large number of continuous cavities.
- the usually cylindrical or multi-disc ceramic body is brought into the exhaust gas flow from diesel engines in such a way that the exhaust gases act on the end face thereof and flow through them parallel to the axis or positively guided. The soot separation is greatest in the part of the filter initially flowed through and decreases rapidly with increasing flow.
- the filter in the area to which the flow first flows has reached its soot deposit capacity and has to be regenerated after a relatively short time, but the remaining area of the filter is still capable of soot absorption, but is also already subjected to the regeneration process.
- EP-PS 0 050 340 describes an exhaust gas filter device which contains such a ceramic body consisting of two clearly delimited areas with different cavities. The area to which the exhaust gases flow first should have 6 to 50 cavities per 2.54 cm, the subsequent area 20 to 150 cavities per 2.54 cm.
- US-A-4 456 457 describes an exhaust gas purification device made of porous material, the exhaust gas stream first having to pass through a zone of higher cell density and then through a zone of low cell density. In the zone of higher cell density, electrical heating ensures that the deposited carbon particles burn off.
- the inventors have therefore set themselves the task of reducing the soot ignition temperature in filters for cleaning the exhaust gases of diesel engines with open-cell foam ceramic.
- the soot will settle more in the area with the denser pore structure and locally lead to a build-up of heat lead to significantly higher temperature peaks.
- These locally occurring temperature peaks in turn locally burn the soot there and thus initiate the regeneration phase of the soot through the entire foam ceramic filter, the ignition temperature of the soot deposited in areas of the foam ceramic which do not have the denser pore structure being considerably lower than that caused by the means mentioned above.
- the filter according to the invention consists of an open-pore foam ceramic which has about 1 to 50% by volume, preferably 10 to 25% by volume, of material with a denser pore structure.
- the coarser ceramic material one with 30 to 80 pores per 2.54 cm is advantageously chosen, for the finer ceramic material one with 40 to 100 pores per 2.54 cm, the difference in the number of pores per 2.54 cm for the two materials being at least 10, preferably 20, is.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Filtering Of Dispersed Particles In Gases (AREA)
- Filtering Materials (AREA)
- Processes For Solid Components From Exhaust (AREA)
- Catalysts (AREA)
Abstract
Description
Die vorliegende Erfindung betrifft ein Filter zur Reinigung der Abgase von Dieselmotoren.The present invention relates to a filter for cleaning the exhaust gases from diesel engines.
Die Russbestandteile der Abgase von Dieselmotoren können grundsätzlich auf zwei Wegen verringert werden: durch Optimierung der Gemischaufbereitung und des Verbrennungsablaufs im Motor und durch Einbau von Filtern in den Abgasstrom. Je nach Ausbildung des Filters werden üblicherweise Russabscheidungsgrade von 50 bis 90% erzielt.The soot components of the exhaust gases from diesel engines can be reduced in two ways: by optimizing the mixture preparation and the combustion process in the engine and by installing filters in the exhaust gas flow. Depending on the design of the filter, soot separation rates of 50 to 90% are usually achieved.
Da das Dieselabgasrussfilter innerhalb kurzer Zeit des Gebrauchs bereits mit Russ verstopft wäre, muss letzterer periodisch verbrannt werden. Die Zeitspanne von einer Regenerierungsphase zur anderen wird als Regenerierungsintervall bezeichnet. Unter bestimmten Bedingungen regeneriert sich das Filter von selbst. Die Russablagerungen werden dabei bei Temperaturen zwischen 550 und 700°C verbrannt. Mit katalytisch beschichteten Filtern kann die Entzündungstemperatur auf ca. 400°C herabgesetzt werden.Since the diesel exhaust soot filter would be clogged with soot within a short period of use, the soot must be burned periodically. The time period from one regeneration phase to another is called the regeneration interval. The filter regenerates itself under certain conditions. The soot deposits are burned at temperatures between 550 and 700 ° C. With catalytically coated filters, the ignition temperature can be reduced to approx. 400 ° C.
Aus der US-PS 4 264 346 ist es bekannt, für obgenannte Zwecke eine offenporige Schaumkeramik als filterwirksames Medium zu verwenden. Als offenporige Schaumkeramik wird dabei ein poröser Keramikkörper mit dreidimensionalem Netzwerk und zellularer Struktur, die eine Vielzahl von durchgehenden Hohlräumen enthält, verstanden. Der meist zylindrische oder aus mehreren Scheiben bestehende Keramikkörper wird derart in den Abgasstrom von Dieselmotoren gebracht, dass die Abgase denselben stirnseitig beaufschlagen und achsparallel oder zwangsgeführt durchströmen. Dabei ist die Russabscheidung im anfänglich durchströmten Teil des Filters am grössten und nimmt mit zunehmender Durchströmung schnell ab. Dies hat zur Folge, dass das Filter im zuerst angeströmten Bereich nach relativ kurzer Zeit seine Russablagerungsaufnahmekapazität erreicht hat und regeneriert werden muss, der restliche Bereich des Filters jedoch noch russaufnahmefähig ist, aber bereits ebenfalls dem Regenerierungsprozess unterworfen wird.From US Pat. No. 4,264,346 it is known to use an open-pore foam ceramic as the filter-effective medium for the above-mentioned purposes. An open-pore foam ceramic is understood to mean a porous ceramic body with a three-dimensional network and cellular structure that contains a large number of continuous cavities. The usually cylindrical or multi-disc ceramic body is brought into the exhaust gas flow from diesel engines in such a way that the exhaust gases act on the end face thereof and flow through them parallel to the axis or positively guided. The soot separation is greatest in the part of the filter initially flowed through and decreases rapidly with increasing flow. The result of this is that the filter in the area to which the flow first flows has reached its soot deposit capacity and has to be regenerated after a relatively short time, but the remaining area of the filter is still capable of soot absorption, but is also already subjected to the regeneration process.
Um die Russaufnahmekapazität des Filters über dem gesamten Querschnitt in Durchströmungsrichtung des Abgases gleichmässiger zu verteilen, wurde bereits vorgeschlagen, den zuerst angeströmten Bereich des Keramikkörpers mit grösseren Hohlräumen zu versehen als den zuletzt angeströmten Bereich, um dadurch zu verhindern, dass das Filter im zuerst angeströmten Bereich vorzeitig verstopft. In der EP-PS 0 050 340 wird eine Abgasfiltereinrichtung beschrieben, die einen derartigen, aus zwei deutlich abgegrenzten Bereichen mit unterschiedlichen Hohlräumen bestehenden Keramikkörper enthält. Der von den Abgasen zuerst angeströmte Bereich soll 6 bis 50 Hohlräume pro 2.54 cm, der nachfolgende Bereich 20 bis 150 Hohlräume pro 2.54 cm aufweisen.In order to distribute the soot absorption capacity of the filter more evenly over the entire cross-section in the direction of flow of the exhaust gas, it has already been proposed to provide the area of the ceramic body with the first inflow area with larger cavities than the area with the last inflow area, in order to prevent the filter from being in the area with the first inflow area clogged prematurely. EP-PS 0 050 340 describes an exhaust gas filter device which contains such a ceramic body consisting of two clearly delimited areas with different cavities. The area to which the exhaust gases flow first should have 6 to 50 cavities per 2.54 cm, the subsequent area 20 to 150 cavities per 2.54 cm.
Die US-A-4 456 457 beschreibt eine Abgasreinigungsvorrichtung aus porösem Material, wobei der Abgasstrom zuerst durch eine Zone höherer Zellendichte und dann durch eine Zone niedriger Zellendichte hindurchtreten muss. In der Zone höherer Zellendichte besorgt eine elektrische Beheizung für den Abbrand der abgeschiedenen Kohlenstoffpartikel.US-A-4 456 457 describes an exhaust gas purification device made of porous material, the exhaust gas stream first having to pass through a zone of higher cell density and then through a zone of low cell density. In the zone of higher cell density, electrical heating ensures that the deposited carbon particles burn off.
Obwohl durch die vorgenannten Massnahmen die Russablagerungsaufnahmekapazität des Keramikfilters verbessert werden kann, ist dem Problem, die Entzündungstemperatur des abgelagerten Russes herabzusetzen, um die Regenerierungsphase so früh als möglich einzuleiten, keine Beachtung geschenkt worden.Although the above measures can improve the soot deposit capacity of the ceramic filter, the problem of lowering the ignition temperature of the deposited soot to start the regeneration phase as early as possible has not been considered.
Die Erfinder haben sich daher die Aufgabe gestellt, bei Filtern zur Reinigung der Abgase von Dieselmotoren mit offenporiger Schaumkeramik die Russentzündungstemperatur zu erniedrigen.The inventors have therefore set themselves the task of reducing the soot ignition temperature in filters for cleaning the exhaust gases of diesel engines with open-cell foam ceramic.
Erfindungsgemäss wird die gestellte Aufgabe durch ein Filter gelöst, welches sich nach dem Wortlaut des Anspruchs 1 auszeichnet. Vorteilhafte Weiterbildungen des erfindungsgemässen Gegenstandes sich durch die Merkmale der Ansprüche 2 und 3 gekennzeichnet.According to the invention, the object is achieved by a filter which is distinguished by the wording of claim 1. Advantageous further developments of the subject matter according to the invention are characterized by the features of claims 2 and 3.
Aufgrund der Tatsache, dass der zuerst vom Abgasstrom angeströmte Bereich der Schaumkeramik bereits teilweise eine dichtere Porenstruktur aufweist, was bedeutet, dass in diesem Bereich die Hohlräume kleiner sind, wird sich im Bereich mit der dichteren Porenstruktur der Russ verstärkt absetzen und lokal zu einem Hitzestau mit wesentlich höheren Temperaturspitzen führen. Diese lokal entstehenden Temperaturspitzen führen wiederum lokal zu einem Abbrand des dortigen Russes und leiten damit durch Flammfortschritt durch das gesamte Schaumkeramikfilter die Regenerierungsphase desselben ein, wobei die Entzündungstemperatur des in Bereichen der Schaumkeramik, die die dichtere Porenstruktur nicht aufweisen, abgelagerten Russes erheblich tiefer liegt als die durch die eingangs genannten Mitteln bewirkte.Due to the fact that the area of the foam ceramic that is initially flown by the exhaust gas flow already partially has a denser pore structure, which means that the cavities are smaller in this area, the soot will settle more in the area with the denser pore structure and locally lead to a build-up of heat lead to significantly higher temperature peaks. These locally occurring temperature peaks in turn locally burn the soot there and thus initiate the regeneration phase of the soot through the entire foam ceramic filter, the ignition temperature of the soot deposited in areas of the foam ceramic which do not have the denser pore structure being considerably lower than that caused by the means mentioned above.
Um den Widerstand des Filters, der einen Gegendruck gegenüber dem Abgas erzeugt, nicht wesentlich zu erhöhen, was eine Herabsetzung der Motorleistung und eine Erhöhung des Treibstoffverbrauchs nach sich ziehen würde, hat es sich als notwendig erwiesen, die zuerst vom Abgasstrom beaufschlagte Fläche zu etwa 20 bis 50% mit einem Material mit dichterer Porenstruktur zu versehen.In order not to significantly increase the resistance of the filter, which creates a back pressure to the exhaust gas, which would result in a reduction in engine performance and an increase in fuel consumption, it has been found necessary to increase the surface area first affected by the exhaust gas flow to approximately 20 up to 50% to be provided with a material with a denser pore structure.
Bei in Personenkraftwagen eingesetzten Dieselmotoren, die mit Abgasfiltern ausgerüstet sind, sollte der Gegendruck bei maximal 0.2 bar liegen. Es hat sich gezeigt, dass solche Bedingunen erfüllt werden, wenn das erfindungsgemässe Filter aus einer offenporigen Schaumkeramik besteht, die etwa 1 bis 50 Vol.%, vorzugsweise 10 bis 25 Vol.%, Material mit dichterer Porenstruktur aufweist. Für das gröbere Keramikmaterial wird vorteilhafterweise eines mit 30 bis 80 Poren pro 2.54 cm, für das feinere Keramikmaterial eines mit 40 bis 100 Poren pro 2.54 cm gewählt, wobei die Differenz der Anzahl Poren pro 2.54 cm bei den beiden Materialien mindestens 10, vorzugsweise 20, beträgt.In diesel engines used in passenger cars, which are equipped with exhaust gas filters, the back pressure should be a maximum of 0.2 bar. It has been shown that such conditions are met if the filter according to the invention consists of an open-pore foam ceramic which has about 1 to 50% by volume, preferably 10 to 25% by volume, of material with a denser pore structure. For the coarser ceramic material, one with 30 to 80 pores per 2.54 cm is advantageously chosen, for the finer ceramic material one with 40 to 100 pores per 2.54 cm, the difference in the number of pores per 2.54 cm for the two materials being at least 10, preferably 20, is.
Des weiteren hat es sich als vorteilhaft erwiesen, in an sich bekannter Weise eine Querschnittsfläche der vom Abgasstrom zuerst angeströmten offenen Schaumkeramik von mindestens 200, vorzugsweise 250 cm2, vorzulegen.Furthermore, it has proven to be advantageous to provide, in a manner known per se, a cross-sectional area of at least 200, preferably 250 cm 2 of the open foam ceramic which is first flown by the exhaust gas flow.
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT87810740T ATE59883T1 (en) | 1986-12-23 | 1987-12-11 | FILTERS FOR PURIFYING THE EXHAUST GASES FROM DIESEL ENGINES. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH512386 | 1986-12-23 | ||
CH5123/86 | 1986-12-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0275827A1 EP0275827A1 (en) | 1988-07-27 |
EP0275827B1 true EP0275827B1 (en) | 1991-01-09 |
Family
ID=4288315
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP87810740A Expired - Lifetime EP0275827B1 (en) | 1986-12-23 | 1987-12-11 | Filter for cleaning the exhaust gases from diesel engines |
Country Status (8)
Country | Link |
---|---|
US (1) | US4857088A (en) |
EP (1) | EP0275827B1 (en) |
JP (1) | JPS63167019A (en) |
AT (1) | ATE59883T1 (en) |
DE (1) | DE3767297D1 (en) |
DK (1) | DK667787A (en) |
ES (1) | ES2020298B3 (en) |
GR (1) | GR3001302T3 (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03258911A (en) * | 1990-03-08 | 1991-11-19 | Ngk Insulators Ltd | Filter for diesel particulate |
WO1993010886A1 (en) * | 1991-11-26 | 1993-06-10 | Engelhard Corporation | Ceria-alumina oxidation catalyst and method of use |
JP4087897B2 (en) | 1991-11-26 | 2008-05-21 | バスフ・カタリスツ・エルエルシー | Improved oxidation catalyst and method of use |
US5250094A (en) | 1992-03-16 | 1993-10-05 | Donaldson Company, Inc. | Ceramic filter construction and method |
US6248684B1 (en) | 1992-11-19 | 2001-06-19 | Englehard Corporation | Zeolite-containing oxidation catalyst and method of use |
US5580535A (en) * | 1994-07-07 | 1996-12-03 | Engelhard Corporation | System and method for abatement of food cooking fumes |
JP4427658B2 (en) | 1998-07-07 | 2010-03-10 | コーニング インコーポレイテッド | Diesel exhaust filter |
DE10151698A1 (en) * | 2001-10-19 | 2003-04-30 | Eberspaecher J Gmbh & Co | Exhaust system with particle filter for an internal combustion engine |
FR2860993B1 (en) * | 2003-10-16 | 2006-06-16 | Sicat | CATALYTIC FILTER BASED ON SILICON CARBIDE (B-SIC) FOR THE COMBUSTION OF SOILS FROM EXHAUST GASES OF A COMBUSTION ENGINE |
CN103785226B (en) * | 2014-03-06 | 2015-12-02 | 云南家润工贸有限公司 | A kind of preparation method of ceramic element |
EP3569528B1 (en) | 2018-05-16 | 2020-07-29 | Schneider Electric Industries SAS | Transport system |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0050340B2 (en) * | 1980-10-17 | 1991-01-16 | Bridgestone Tire Company Limited | Exhaust filter device for collecting particulates in engine exhaust gases and method for its manufacture |
US4451441A (en) * | 1981-01-27 | 1984-05-29 | W. R. Grace & Co. | Method for exhaust gas treatment |
US4456457A (en) * | 1981-04-28 | 1984-06-26 | Nippon Soken, Inc. | Exhaust gas cleaning device for diesel engine |
JPS5893915A (en) * | 1981-11-30 | 1983-06-03 | Nippon Soken Inc | Fine particle purifier of exhaust gas |
JPS61129015A (en) * | 1984-11-24 | 1986-06-17 | Nippon Denso Co Ltd | Filter for purifying exhaust gas and its preparation |
US4600562A (en) * | 1984-12-24 | 1986-07-15 | Texaco Inc. | Method and apparatus for filtering engine exhaust gas |
-
1987
- 1987-12-03 US US07/128,222 patent/US4857088A/en not_active Expired - Fee Related
- 1987-12-11 ES ES87810740T patent/ES2020298B3/en not_active Expired - Lifetime
- 1987-12-11 EP EP87810740A patent/EP0275827B1/en not_active Expired - Lifetime
- 1987-12-11 AT AT87810740T patent/ATE59883T1/en active
- 1987-12-11 DE DE8787810740T patent/DE3767297D1/en not_active Expired - Lifetime
- 1987-12-18 DK DK667787A patent/DK667787A/en not_active Application Discontinuation
- 1987-12-23 JP JP62326620A patent/JPS63167019A/en active Pending
-
1991
- 1991-01-10 GR GR90401154T patent/GR3001302T3/en unknown
Also Published As
Publication number | Publication date |
---|---|
ATE59883T1 (en) | 1991-01-15 |
GR3001302T3 (en) | 1992-08-31 |
ES2020298B3 (en) | 1991-08-01 |
EP0275827A1 (en) | 1988-07-27 |
US4857088A (en) | 1989-08-15 |
DE3767297D1 (en) | 1991-02-14 |
DK667787D0 (en) | 1987-12-18 |
JPS63167019A (en) | 1988-07-11 |
DK667787A (en) | 1988-06-24 |
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