[go: up one dir, main page]

EA200802105A1 - Система и способ для превращения биомассы в этанол через сингаз - Google Patents

Система и способ для превращения биомассы в этанол через сингаз

Info

Publication number
EA200802105A1
EA200802105A1 EA200802105A EA200802105A EA200802105A1 EA 200802105 A1 EA200802105 A1 EA 200802105A1 EA 200802105 A EA200802105 A EA 200802105A EA 200802105 A EA200802105 A EA 200802105A EA 200802105 A1 EA200802105 A1 EA 200802105A1
Authority
EA
Eurasian Patent Office
Prior art keywords
ethanol
biomass
syngas
singas
conversing
Prior art date
Application number
EA200802105A
Other languages
English (en)
Other versions
EA013194B1 (ru
Inventor
Лэрри Джек Мельничук
Кэрен Венита Келли
Роберт С. Дейвис
Original Assignee
Вудлэнд Байофьюэлс Инк.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Вудлэнд Байофьюэлс Инк. filed Critical Вудлэнд Байофьюэлс Инк.
Publication of EA200802105A1 publication Critical patent/EA200802105A1/ru
Publication of EA013194B1 publication Critical patent/EA013194B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/44—Fluidisation grids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
    • C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/08—Ethanol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/482—Gasifiers with stationary fluidised bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C10K1/026—Dust removal by centrifugal forces
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/12—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C10J2300/0909—Drying
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/12—Heating the gasifier
    • C10J2300/1246—Heating the gasifier by external or indirect heating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1606—Combustion processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1621—Compression of synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1665—Conversion of synthesis gas to chemicals to alcohols, e.g. methanol or ethanol
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1853—Steam reforming, i.e. injection of steam only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861—Heat exchange between at least two process streams
    • C10J2300/1876—Heat exchange between at least two process streams with one stream being combustion gas
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Раскрыты способ и установка для синтеза этанола, производимого посредством методов синтеза с промежуточным производством сингаза. Кроме того, описаны способ и установка для газификации биомассы, например, в паровом газификаторе, в котором используется псевдоожиженный слой и нагревание с помощью горячих топочных газов, полученных при сжигании сингаза. Описаны также способы и установка для превращения сингаза в этанол с постадийным проведением каталитических реакций с превращением монооксида углерода и водорода в этанол, используя катализатор, включающий ацетат иридия.
EA200802105A 2006-04-05 2007-04-05 Способ получения этанола EA013194B1 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US78906706P 2006-04-05 2006-04-05
US88118907P 2007-01-19 2007-01-19
PCT/US2007/008560 WO2007117590A2 (en) 2006-04-05 2007-04-05 System and method for converting biomass to ethanol via syngas

Publications (2)

Publication Number Publication Date
EA200802105A1 true EA200802105A1 (ru) 2009-04-28
EA013194B1 EA013194B1 (ru) 2010-02-26

Family

ID=38473088

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200802105A EA013194B1 (ru) 2006-04-05 2007-04-05 Способ получения этанола

Country Status (10)

Country Link
US (3) US8088832B2 (ru)
EP (1) EP2004583B1 (ru)
JP (1) JP2009532483A (ru)
KR (1) KR20080108605A (ru)
AU (1) AU2007235322A1 (ru)
BR (1) BRPI0710578B1 (ru)
CA (1) CA2682778C (ru)
EA (1) EA013194B1 (ru)
ES (1) ES2539761T3 (ru)
WO (1) WO2007117590A2 (ru)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2571425C2 (ru) * 2010-02-02 2015-12-20 Селаниз Интернэшнл Корпорейшн Способ испарения уксусной кислоты в процессах гидрирования для производства этанола
RU2577987C2 (ru) * 2010-11-09 2016-03-20 Инеос Коммершиал Сервисиз Юк Лимитед Способ и устройство для получения спиртов

Families Citing this family (208)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8088832B2 (en) 2006-04-05 2012-01-03 Woodland Biofuels Inc. System and method for converting biomass to ethanol via syngas
WO2008141204A2 (en) * 2007-05-11 2008-11-20 The Texas A & M University System Biofuel processing system
FI122786B (fi) * 2007-07-20 2012-06-29 Upm Kymmene Oyj Synteettisten hiilivetyketjujen valmistuksessa syntyvän hiilidioksidin käyttö
EP2072490A1 (en) * 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbons to alcohols
EP2072491A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of alcohol(s) into alcohol(s) with increased carbon-chain
EP2072492A1 (en) * 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbons to ethanol
US20090221725A1 (en) * 2008-02-28 2009-09-03 Enerkem, Inc. Production of ethanol from methanol
EP2382021A4 (en) * 2008-07-07 2014-03-26 Christopher J Brown USE OF HOT STEAM DRYERS IN AN ALCOHOL STILLING SYSTEM
DE102008032166A1 (de) * 2008-07-08 2010-01-14 Karl-Heinz Tetzlaff Verfahren und Vorrichtung zur Herstellung von teerfreiem Synthesgas aus Biomasse
US8680317B2 (en) 2008-07-31 2014-03-25 Celanese International Corporation Processes for making ethyl acetate from acetic acid
US8501652B2 (en) 2008-07-31 2013-08-06 Celanese International Corporation Catalysts for making ethanol from acetic acid
US7816565B2 (en) 2008-07-31 2010-10-19 Celanese International Corporation Direct and selective production of acetaldehyde from acetic acid utilizing a supported metal catalyst
US8309773B2 (en) 2010-02-02 2012-11-13 Calanese International Corporation Process for recovering ethanol
US8309772B2 (en) 2008-07-31 2012-11-13 Celanese International Corporation Tunable catalyst gas phase hydrogenation of carboxylic acids
US8304586B2 (en) 2010-02-02 2012-11-06 Celanese International Corporation Process for purifying ethanol
US8637714B2 (en) 2008-07-31 2014-01-28 Celanese International Corporation Process for producing ethanol over catalysts containing platinum and palladium
US8471075B2 (en) 2008-07-31 2013-06-25 Celanese International Corporation Processes for making ethanol from acetic acid
US8338650B2 (en) 2008-07-31 2012-12-25 Celanese International Corporation Palladium catalysts for making ethanol from acetic acid
US7863489B2 (en) 2008-07-31 2011-01-04 Celanese International Corporation Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst
US8546622B2 (en) 2008-07-31 2013-10-01 Celanese International Corporation Process for making ethanol from acetic acid using acidic catalysts
US7608744B1 (en) 2008-07-31 2009-10-27 Celanese International Corporation Ethanol production from acetic acid utilizing a cobalt catalyst
US7884253B2 (en) * 2008-12-11 2011-02-08 Range Fuels, Inc. Methods and apparatus for selectively producing ethanol from synthesis gas
US8192854B2 (en) * 2009-02-06 2012-06-05 Ut-Battelle, Llc Microbial fuel cell treatment of ethanol fermentation process water
US8927781B2 (en) * 2009-02-12 2015-01-06 Ichikawa Office Inc. Method for producing ethanol
US20100275823A1 (en) * 2009-05-04 2010-11-04 I Power Energy Systems, Llc Special Pyrogen Waste treatment and electrical generation combination of systems
US8450535B2 (en) 2009-07-20 2013-05-28 Celanese International Corporation Ethanol production from acetic acid utilizing a cobalt catalyst
KR101588057B1 (ko) * 2009-07-29 2016-01-22 에스케이이노베이션 주식회사 바이오 디젤의 생산 방법
US8680321B2 (en) 2009-10-26 2014-03-25 Celanese International Corporation Processes for making ethanol from acetic acid using bimetallic catalysts
US8710277B2 (en) 2009-10-26 2014-04-29 Celanese International Corporation Process for making diethyl ether from acetic acid
US8394984B2 (en) 2010-02-02 2013-03-12 Celanese International Corporation Process for producing an ethyl acetate solvent and co-production of ethanol
US8541633B2 (en) 2010-02-02 2013-09-24 Celanese International Corporation Processes for producing anhydrous ethanol compositions
US8222466B2 (en) 2010-02-02 2012-07-17 Celanese International Corporation Process for producing a water stream from ethanol production
US8680343B2 (en) 2010-02-02 2014-03-25 Celanese International Corporation Process for purifying ethanol
US8394985B2 (en) 2010-02-02 2013-03-12 Celanese International Corporation Process for producing an ester feed stream for esters production and co-production of ethanol
US8460405B2 (en) 2010-02-02 2013-06-11 Celanese International Corporation Ethanol compositions
US8932372B2 (en) 2010-02-02 2015-01-13 Celanese International Corporation Integrated process for producing alcohols from a mixed acid feed
US8552226B2 (en) 2010-02-02 2013-10-08 Celanese International Corporation Process for heat integration for ethanol production and purification process
US8728179B2 (en) 2010-02-02 2014-05-20 Celanese International Corporation Ethanol compositions
US8575403B2 (en) 2010-05-07 2013-11-05 Celanese International Corporation Hydrolysis of ethyl acetate in ethanol separation process
US8858659B2 (en) 2010-02-02 2014-10-14 Celanese International Corporation Processes for producing denatured ethanol
US8344186B2 (en) 2010-02-02 2013-01-01 Celanese International Corporation Processes for producing ethanol from acetaldehyde
US8318988B2 (en) 2010-05-07 2012-11-27 Celanese International Corporation Process for purifying a crude ethanol product
US8314272B2 (en) 2010-02-02 2012-11-20 Celanese International Corporation Process for recovering ethanol with vapor separation
US8668750B2 (en) 2010-02-02 2014-03-11 Celanese International Corporation Denatured fuel ethanol compositions for blending with gasoline or diesel fuel for use as motor fuels
US8747492B2 (en) 2010-02-02 2014-06-10 Celanese International Corporation Ethanol/fuel blends for use as motor fuels
US8552224B2 (en) 2010-05-07 2013-10-08 Celanese International Corporation Processes for maximizing ethanol formation in the hydrogenation of acetic acid
US8912239B2 (en) * 2010-02-13 2014-12-16 Mcalister Technologies, Llc Carbon recycling and reinvestment using thermochemical regeneration
DE102010009936A1 (de) * 2010-03-02 2011-09-08 Heinz Spliethoff Verfahren zur allothermen Vergasung von kohlenstoffhaltigen Vergasungsbrennstoffen
US8575404B2 (en) 2010-05-07 2013-11-05 Celanese International Corporation Process for recycling gas from acetic acid hydrogenation
US8680342B2 (en) 2010-05-07 2014-03-25 Celanese International Corporation Process for recovering alcohol produced by hydrogenating an acetic acid feed stream comprising water
US8754267B2 (en) 2010-05-07 2014-06-17 Celanese International Corporation Process for separating acetaldehyde from ethanol-containing mixtures
US8704011B2 (en) 2010-05-07 2014-04-22 Celanese International Corporation Separating ethanol and ethyl acetate under low pressure conditions
US8604255B2 (en) 2010-05-07 2013-12-10 Celanese International Corporation Process for recovering ethanol with sidedraws to regulate C3+ alcohols concentrations
US8704010B2 (en) 2010-05-07 2014-04-22 Celanese International Corporation Alcohol production process with impurity removal
US8569551B2 (en) 2010-05-07 2013-10-29 Celanese International Corporation Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process
JP2012001441A (ja) * 2010-06-14 2012-01-05 Sekisui Chem Co Ltd エタノール製造方法、およびエタノール製造システム
US8846988B2 (en) 2010-07-09 2014-09-30 Celanese International Corporation Liquid esterification for the production of alcohols
US9150474B2 (en) 2010-07-09 2015-10-06 Celanese International Corporation Reduction of acid within column through esterification during the production of alcohols
US8884080B2 (en) 2010-07-09 2014-11-11 Celanese International Corporation Reduced energy alcohol separation process
US8710280B2 (en) 2010-07-09 2014-04-29 Celanese International Corporation Weak acid recovery system for ethanol separation processes
US9126125B2 (en) 2010-07-09 2015-09-08 Celanese International Corporation Reduced energy alcohol separation process having water removal
US8859827B2 (en) 2011-11-18 2014-10-14 Celanese International Corporation Esterifying acetic acid to produce ester feed for hydrogenolysis
US8809597B2 (en) 2010-07-09 2014-08-19 Celanese International Corporation Separation of vapor crude alcohol product
US8901358B2 (en) 2010-07-09 2014-12-02 Celanese International Corporation Esterification of vapor crude product in the production of alcohols
US9024083B2 (en) 2010-07-09 2015-05-05 Celanese International Corporation Process for the production of ethanol from an acetic acid feed and a recycled ethyl acetate feed
US9272970B2 (en) 2010-07-09 2016-03-01 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US8846986B2 (en) 2011-04-26 2014-09-30 Celanese International Corporation Water separation from crude alcohol product
AU2011274524A1 (en) 2010-07-09 2012-11-15 Celanese International Corporation Finishing reactor for purifying ethanol
US8710279B2 (en) 2010-07-09 2014-04-29 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US8536384B2 (en) 2010-07-09 2013-09-17 Celanese International Corporation Recovering ethanol sidedraw by separating crude product from hydrogenation process
US8664454B2 (en) 2010-07-09 2014-03-04 Celanese International Corporation Process for production of ethanol using a mixed feed using copper containing catalyst
US8704008B2 (en) 2010-07-09 2014-04-22 Celanese International Corporation Process for producing ethanol using a stacked bed reactor
EP2635369B1 (en) 2010-11-05 2016-03-02 Thermochem Recovery International, Inc. Solids circulation system and method for capture and conversion of reactive solids
NL2006535C2 (en) * 2011-04-04 2012-10-08 Btg Biomass Technology Group B V Method for the manufacture of methanol.
US8350098B2 (en) 2011-04-04 2013-01-08 Celanese International Corporation Ethanol production from acetic acid utilizing a molybdenum carbide catalyst
US8907141B2 (en) 2011-04-26 2014-12-09 Celanese International Corporation Process to recover alcohol with secondary reactors for esterification of acid
US8927780B2 (en) 2011-04-26 2015-01-06 Celanese International Corporation Process for removing aldehydes from ethanol reaction mixture
US9024082B2 (en) 2011-04-26 2015-05-05 Celanese International Corporation Using a dilute acid stream as an extractive agent
US8686199B2 (en) 2011-04-26 2014-04-01 Celanese International Corporation Process for reducing the concentration of acetic acid in a crude alcohol product
US8686200B2 (en) 2011-04-26 2014-04-01 Celanese International Corporation Process to recover alcohol from an acidic residue stream
US8927788B2 (en) 2011-04-26 2015-01-06 Celanese International Corporation Process to recover alcohol with reduced water from overhead of acid column
US8461399B2 (en) 2011-04-26 2013-06-11 Celanese International Corporation Separation process having an alcohol sidestream
US8927784B2 (en) 2011-04-26 2015-01-06 Celanese International Corporation Process to recover alcohol from an ethyl acetate residue stream
US9073816B2 (en) 2011-04-26 2015-07-07 Celanese International Corporation Reducing ethyl acetate concentration in recycle streams for ethanol production processes
US9000232B2 (en) 2011-04-26 2015-04-07 Celanese International Corporation Extractive distillation of crude alcohol product
US8748675B2 (en) 2011-06-16 2014-06-10 Celanese International Corporation Extractive distillation of crude alcohol product
US8927787B2 (en) 2011-04-26 2015-01-06 Celanese International Corporation Process for controlling a reboiler during alcohol recovery and reduced ester formation
US8927783B2 (en) 2011-04-26 2015-01-06 Celanese International Corporation Recovering ethanol with sidestreams to regulate C3+ alcohols concentrations
US8592635B2 (en) 2011-04-26 2013-11-26 Celanese International Corporation Integrated ethanol production by extracting halides from acetic acid
US9024085B2 (en) 2011-04-26 2015-05-05 Celanese International Corporation Process to reduce ethanol recycled to hydrogenation reactor
US20120277482A1 (en) * 2011-04-26 2012-11-01 Celanese International Corporation Removing Water from an Acetic Acid Stream in the Production of Alcohols
US8933278B2 (en) 2011-04-26 2015-01-13 Celanese International Corporation Process for producing ethanol and reducing acetic acid concentration
US8884081B2 (en) 2011-04-26 2014-11-11 Celanese International Corporation Integrated process for producing acetic acid and alcohol
US9024084B2 (en) 2011-04-26 2015-05-05 Celanese International Corporation Reduced energy alcohol separation process having controlled pressure
US9000233B2 (en) 2011-04-26 2015-04-07 Celanese International Corporation Process to recover alcohol with secondary reactors for hydrolysis of acetal
US8754268B2 (en) 2011-04-26 2014-06-17 Celanese International Corporation Process for removing water from alcohol mixtures
US8704012B2 (en) 2011-06-16 2014-04-22 Celanese International Corporation Distillation of crude alcohol product using entrainer
US8927782B2 (en) 2011-08-03 2015-01-06 Celanese International Corporation Vapor separation in alcohol production
US8877986B2 (en) 2011-08-03 2014-11-04 Celanese International Corporation Process for recovering alcohol
US8884079B2 (en) 2011-08-03 2014-11-11 Celanese International Corporation Reducing impurities in hydrogenation processes with multiple reaction zones
US8440866B2 (en) 2011-08-03 2013-05-14 Celanese International Corporation Process for separating ethanol having low acid
US8877987B2 (en) 2011-08-03 2014-11-04 Celanese International Corportation Process for producing anhydrous ethanol using extractive distillation column
US8895786B2 (en) 2011-08-03 2014-11-25 Celanese International Corporation Processes for increasing alcohol production
US8748676B2 (en) 2011-08-03 2014-06-10 Celanese International Corporation Process for purifying a crude ethanol product
US8575405B2 (en) 2011-08-03 2013-11-05 Celanese International Corporation Reducing acetals during ethanol separation process
US8829253B2 (en) 2011-08-19 2014-09-09 Celanese International Corporation Integrated process for producing ethanol from methanol
US8853466B2 (en) 2011-08-19 2014-10-07 Celanese International Corporation Integrated process for producing ethanol from methanol
US8853467B2 (en) 2011-08-19 2014-10-07 Celanese International Corporation Integrated process for producing ethanol
CN103958398B (zh) 2011-09-27 2016-01-06 国际热化学恢复股份有限公司 合成气净化系统和方法
US8536382B2 (en) 2011-10-06 2013-09-17 Celanese International Corporation Processes for hydrogenating alkanoic acids using catalyst comprising tungsten
US8658843B2 (en) 2011-10-06 2014-02-25 Celanese International Corporation Hydrogenation catalysts prepared from polyoxometalate precursors and process for using same to produce ethanol while minimizing diethyl ether formation
US9168500B2 (en) 2011-10-26 2015-10-27 Res Usa, Llc Gasifier fluidization
US8614359B2 (en) 2011-11-09 2013-12-24 Celanese International Corporation Integrated acid and alcohol production process
US8809598B2 (en) 2011-11-09 2014-08-19 Celanese International Corporation Producing ethanol using two different streams from acetic acid carbonylation process
WO2013070211A1 (en) * 2011-11-09 2013-05-16 Celanese International Corporation Integrated process for producing ethanol from methanol
US8704013B2 (en) 2011-11-09 2014-04-22 Celanese International Corporation Integrated process for producing ethanol
US8809599B2 (en) 2011-11-09 2014-08-19 Celanese International Corporation Integrated process for producing ethanol and water balance control
US8686201B2 (en) 2011-11-09 2014-04-01 Celanese International Corporation Integrated acid and alcohol production process having flashing to recover acid production catalyst
WO2013070213A1 (en) * 2011-11-09 2013-05-16 Celanese International Corporation Iintegrated process for producing ethanol from methanol with water balance control
US8853468B2 (en) 2011-11-18 2014-10-07 Celanese International Corporation Vapor esterification method to produce ester feed for hydrogenolysis
US8829249B2 (en) 2011-11-18 2014-09-09 Celanese International Corporation Integrated esterification and hydrogenolysis process for producing ethanol
US8748673B2 (en) 2011-11-18 2014-06-10 Celanese International Corporation Process of recovery of ethanol from hydrogenolysis process
US9024089B2 (en) 2011-11-18 2015-05-05 Celanese International Corporation Esterification process using extractive separation to produce feed for hydrogenolysis
US8829251B2 (en) 2011-11-18 2014-09-09 Celanese International Corporation Liquid esterification method to produce ester feed for hydrogenolysis
US8802901B2 (en) 2011-11-18 2014-08-12 Celanese International Corporation Continuous ethyl acetate production and hydrogenolysis thereof
EP2782890A1 (en) 2011-11-22 2014-10-01 Celanese International Corporation Esterifying an ethanol and acetic acid mixture to produce an ester feed for hydrogenolysis
US8703868B2 (en) 2011-11-28 2014-04-22 Celanese International Corporation Integrated process for producing polyvinyl alcohol or a copolymer thereof and ethanol
US20130133222A1 (en) * 2011-11-30 2013-05-30 General Electric Company Particulate fluidization system
US20130143973A1 (en) * 2011-12-02 2013-06-06 Celanese International Corporation Biomass gasification and integrated processes for making industrial chemicals through an ester intermediate
US9029614B2 (en) 2011-12-14 2015-05-12 Celanese International Corporation Phasing reactor product from hydrogenating acetic acid into ethyl acetate feed to produce ethanol
US8927790B2 (en) 2011-12-15 2015-01-06 Celanese International Corporation Multiple vapor feeds for hydrogenation process to produce alcohol
US8575406B2 (en) 2011-12-22 2013-11-05 Celanese International Corporation Catalysts having promoter metals and process for producing ethanol
US8907139B2 (en) 2011-12-28 2014-12-09 Celanese International Corporation Process for acetal removal in the purification of a crude ethanol product
US9333496B2 (en) 2012-02-29 2016-05-10 Celanese International Corporation Cobalt/tin catalyst for producing ethanol
US8455702B1 (en) 2011-12-29 2013-06-04 Celanese International Corporation Cobalt and tin catalysts for producing ethanol
US8907142B2 (en) 2011-12-29 2014-12-09 Celanese International Corporation Process for promoting catalyst activity for ethyl acetate conversion
US9079172B2 (en) 2012-03-13 2015-07-14 Celanese International Corporation Promoters for cobalt-tin catalysts for reducing alkanoic acids
CN103282334B (zh) 2011-12-30 2015-11-25 国际人造丝公司 用于从加氢方法进行乙醇生产和回收的压力驱动蒸馏
EP2800625A1 (en) 2012-01-06 2014-11-12 Celanese International Corporation Hydrogenation catalysts with cobalt-modified supports
US9024086B2 (en) 2012-01-06 2015-05-05 Celanese International Corporation Hydrogenation catalysts with acidic sites
US8802588B2 (en) 2012-01-23 2014-08-12 Celanese International Corporation Bismuth catalyst composition and process for manufacturing ethanol mixture
US9242219B2 (en) * 2012-01-30 2016-01-26 PHG Energy, LLC Fluidized bed biogasifier and method for gasifying biosolids
US10738249B2 (en) 2012-01-30 2020-08-11 Aries Gasification, Llc Universal feeder for gasification reactors
US9051235B2 (en) 2012-02-07 2015-06-09 Celanese International Corporation Process for producing ethanol using a molar excess of hydrogen
US9353034B2 (en) 2012-02-07 2016-05-31 Celanese International Corporation Hydrogenation process with reduced residence time for vapor phase reactants
EA024718B1 (ru) * 2012-02-09 2016-10-31 Ланцатек Нью Зилэнд Лимитед Усовершенствованное улавливание углерода при брожении
US8729311B2 (en) 2012-02-10 2014-05-20 Celanese International Corporaton Catalysts for converting acetic acid to acetone
US20140223908A1 (en) * 2012-02-14 2014-08-14 Coldunell Limited Waste Management System
US8729317B2 (en) 2012-02-15 2014-05-20 Celanese International Corporation Ethanol manufacturing process over catalyst with cesium and support comprising tungsten or oxides thereof
US9126194B2 (en) 2012-02-29 2015-09-08 Celanese International Corporation Catalyst having support containing tin and process for manufacturing ethanol
US8802903B2 (en) 2012-03-13 2014-08-12 Celanese International Corporation Stacked bed reactor with diluents for producing ethanol
US8927786B2 (en) 2012-03-13 2015-01-06 Celanese International Corporation Ethanol manufacturing process over catalyst having improved radial crush strength
US8536383B1 (en) 2012-03-14 2013-09-17 Celanese International Corporation Rhodium/tin catalysts and processes for producing ethanol
US9073042B2 (en) 2012-03-14 2015-07-07 Celanese International Corporation Acetic acid hydrogenation over a group VIII metal calcined catalyst having a secondary promoter
US9126173B2 (en) * 2012-03-26 2015-09-08 Sundrop Fuels, Inc. Pretreatment of biomass using thermo mechanical methods before gasification
CN103974903B (zh) * 2012-05-02 2016-05-25 上原春男 活性炭制造系统
WO2013186886A1 (ja) * 2012-06-13 2013-12-19 三井造船株式会社 エタノール製造方法およびエタノール製造装置
EP2876100B1 (en) 2012-07-23 2025-07-23 Renaissance Energy Research Corporation Oxygenated product production method
US9279365B2 (en) * 2012-09-04 2016-03-08 General Electric Company Power augmentation systems and methods for grid frequency control
US10005963B2 (en) 2012-09-20 2018-06-26 University Of South Florida Systems and methods for producing liquid fuels from landfill gases
KR101407979B1 (ko) 2012-10-10 2014-06-17 한국에너지기술연구원 알코올 제조용 금속 촉매의 제조방법 및 이에 따라 제조된 금속 촉매
US8772553B2 (en) 2012-10-26 2014-07-08 Celanese International Corporation Hydrogenation reaction conditions for producing ethanol
US8957262B2 (en) 2012-11-20 2015-02-17 Celanese International Corporation Olefin hydration for hydrogenation processes
US8729318B1 (en) 2012-11-20 2014-05-20 Celanese International Corporation Process for producing ethanol from methyl acetate
CN102942446B (zh) * 2012-12-03 2015-09-23 大唐国际化工技术研究院有限公司 一种回收氢再循环的醋酸酯加氢制乙醇的方法
JP6594206B2 (ja) * 2012-12-10 2019-10-23 サザン カンパニー 段階的ガス化における第２段ガス化装置
US9000237B2 (en) 2012-12-20 2015-04-07 Celanese International Corporation Ethanol refining process using intermediate reboiler
KR101890952B1 (ko) * 2012-12-26 2018-08-22 에스케이이노베이션 주식회사 기류 건조기를 포함하는 탄소 연료의 가스화 복합 설비
US8926718B2 (en) 2013-03-15 2015-01-06 Celanese International Corporation Thermochemically produced ethanol compositions
US8975451B2 (en) 2013-03-15 2015-03-10 Celanese International Corporation Single phase ester feed for hydrogenolysis
US9409846B2 (en) 2013-03-15 2016-08-09 Celanese International Corporation Process for separating product gas using carbonylation processes
JP6567510B2 (ja) * 2013-06-26 2019-08-28 レール・リキード−ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード 直接燃焼される加熱方法、及びその実施のための設備
US10370539B2 (en) 2014-01-30 2019-08-06 Monolith Materials, Inc. System for high temperature chemical processing
US10100200B2 (en) 2014-01-30 2018-10-16 Monolith Materials, Inc. Use of feedstock in carbon black plasma process
US11939477B2 (en) 2014-01-30 2024-03-26 Monolith Materials, Inc. High temperature heat integration method of making carbon black
US10138378B2 (en) 2014-01-30 2018-11-27 Monolith Materials, Inc. Plasma gas throat assembly and method
US20150211378A1 (en) * 2014-01-30 2015-07-30 Boxer Industries, Inc. Integration of plasma and hydrogen process with combined cycle power plant, simple cycle power plant and steam reformers
WO2015116943A2 (en) 2014-01-31 2015-08-06 Monolith Materials, Inc. Plasma torch design
CN103897743B (zh) * 2014-03-28 2016-02-03 上海锅炉厂有限公司 固体燃料分级气化-燃烧双床多联产系统与方法
US10619173B2 (en) 2014-07-22 2020-04-14 Iogen Corporation Process for using biogenic carbon dioxide derived from non-fossil organic material
US9108894B1 (en) 2014-07-22 2015-08-18 Iogen Corporation Process for using biogenic carbon dioxide derived from non-fossil organic material
CA2953164C (en) 2014-07-22 2023-04-11 Iogen Corporation Process for producing fuel using two fermentations
EP3018094A1 (en) 2014-11-06 2016-05-11 Casale SA Process for producing a synthesis gas
US11434509B2 (en) 2014-12-08 2022-09-06 Iogen Corporation Process for using biogenic carbon dioxide derived from non-fossil organic material
EP3246302A4 (en) * 2015-01-13 2018-07-04 Sekisui Chemical Co., Ltd. Butadiene production system and butadiene production method
WO2016126599A1 (en) 2015-02-03 2016-08-11 Monolith Materials, Inc. Carbon black generating system
BR112017016692A2 (pt) 2015-02-03 2018-04-10 Monolith Materials, Inc. método e aparelho para resfriamento regenerativo
CN111601447A (zh) 2015-07-29 2020-08-28 巨石材料公司 Dc等离子体焰炬电力设计方法和设备
US20170066923A1 (en) 2015-09-09 2017-03-09 Monolith Materials, Inc. Circular few layer graphene
EP3350855A4 (en) 2015-09-14 2019-08-07 Monolith Materials, Inc. Soot from natural gas
CN106807367A (zh) * 2015-12-02 2017-06-09 中国科学院大连化学物理研究所 一种碳基材料负载的铱基催化剂及其制备方法和应用
EP3416757B1 (en) 2016-02-16 2023-01-11 ThermoChem Recovery International, Inc. Two-stage energy-integrated product gas generation system and method
MX2018011589A (es) 2016-03-25 2019-09-18 Thermochem Recovery Int Inc Sistema y metodo de generacion de gas producto de energia ntegrada de tres etapas.
CA3211318A1 (en) 2016-04-29 2017-11-02 Monolith Materials, Inc. Torch stinger method and apparatus
CN109562347A (zh) 2016-04-29 2019-04-02 巨石材料公司 颗粒生产工艺和设备的二次热添加
US10364398B2 (en) 2016-08-30 2019-07-30 Thermochem Recovery International, Inc. Method of producing product gas from multiple carbonaceous feedstock streams mixed with a reduced-pressure mixing gas
CN110603297A (zh) 2017-03-08 2019-12-20 巨石材料公司 用热传递气体制备碳颗粒的系统和方法
JP2020517562A (ja) 2017-04-20 2020-06-18 モノリス マテリアルズ インコーポレイテッド 粒子システムと方法
US9920926B1 (en) 2017-07-10 2018-03-20 Thermochem Recovery International, Inc. Pulse combustion heat exchanger system and method
EP3676220A4 (en) 2017-08-28 2021-03-31 Monolith Materials, Inc. PARTICLE GENERATION SYSTEMS AND METHODS
CA3116989C (en) 2017-10-24 2024-04-02 Monolith Materials, Inc. Particle systems and methods
US10099200B1 (en) 2017-10-24 2018-10-16 Thermochem Recovery International, Inc. Liquid fuel production system having parallel product gas generation
CN109812832A (zh) * 2017-11-21 2019-05-28 吴鲜家 高效能燃烧控制系统及其方法
US11512260B2 (en) 2018-06-11 2022-11-29 Donald Gene Taylor Pulse detonation shockwave gasifier
US11555157B2 (en) 2020-03-10 2023-01-17 Thermochem Recovery International, Inc. System and method for liquid fuel production from carbonaceous materials using recycled conditioned syngas
US11466223B2 (en) * 2020-09-04 2022-10-11 Thermochem Recovery International, Inc. Two-stage syngas production with separate char and product gas inputs into the second stage
CN112169712A (zh) * 2020-10-29 2021-01-05 北京石油化工工程有限公司 二甲醚羰基化合成乙酸甲酯的反应器
CN115747263B (zh) * 2022-12-05 2023-10-20 华南农业大学 一种通过混合纤维素发酵提升乙醇产率的方法

Family Cites Families (179)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3153091B2 (ja) * 1994-03-10 2001-04-03 株式会社荏原製作所 廃棄物の処理方法及びガス化及び熔融燃焼装置
US3972952A (en) * 1975-03-14 1976-08-03 Celanese Corporation Vapor-phase conversion of methanol and ethanol to higher linear primary alcohols by heterogeneous catalysis
NZ194405A (en) * 1979-08-02 1982-05-25 Dut Pty Ltd Producing liquid hydrocarbon streams by hydrogenation of fossil-based feedstock
EP0036724A1 (en) 1980-03-18 1981-09-30 The British Petroleum Company p.l.c. Process for the production of ethanol by the liquid phase hydrocarbonylation of methanol
DE3101750A1 (de) * 1981-01-21 1982-08-26 Basf Ag, 6700 Ludwigshafen Verfahren zur kontinuierlichen herstellung von ethanol
US4498909A (en) * 1982-11-02 1985-02-12 Dm International, Inc. Process for the gasification of fuels
EP0167300A1 (en) * 1984-06-06 1986-01-08 Humphreys & Glasgow Limited Process for the production of alcohols
GB2162172B (en) * 1984-07-26 1988-10-12 Davy Mckee Process
US4971599A (en) 1985-06-11 1990-11-20 Cordell Henry L Apparatus for gasifying solid organic materials
US4954665A (en) * 1985-11-07 1990-09-04 Union Carbide Chemicals And Plastics Company Inc. Methanol homologation
US5138982A (en) * 1986-01-21 1992-08-18 Ebara Corporation Internal circulating fluidized bed type boiler and method of controlling the same
CA1285375C (en) * 1986-01-21 1991-07-02 Takahiro Ohshita Thermal reactor
US4628066A (en) * 1986-02-12 1986-12-09 Air Products And Chemicals, Inc. Process for the production of methanol
US4747355A (en) * 1986-02-14 1988-05-31 Berkum Robert A Van Combustion apparatus and method of generating gas
US4767543A (en) 1986-11-13 1988-08-30 Universite De Sherbrooke Oxidation of wastewaters
US4761185A (en) 1986-11-14 1988-08-02 Universite De Sherbrooke Rapid starch depolymerization via spray reactors
US4766154A (en) * 1987-02-06 1988-08-23 Air Products And Chemicals, Inc. Liquid phase methanol reactor staging process for the production of methanol
DK158221C (da) * 1987-06-30 1990-09-10 Haldor Topsoe As Fremgangsmaade til fremstilling af eddikesyre, metylacetat, eddikesyreanhydrid eller blandinger deraf
CA1300884C (en) 1987-08-24 1992-05-19 John W. Black Fluidized bed gasifier
US4848249A (en) * 1987-11-30 1989-07-18 Texas A&M University System and process for conversion of biomass into usable energy
GB8807284D0 (en) * 1988-03-26 1988-04-27 Bp Chem Int Ltd Chemical process
DE3828534A1 (de) * 1988-08-23 1990-03-08 Gottfried Dipl Ing Roessle Verfahren zur verwertung von energiehaltiger masse, vorrichtung zur durchfuehrung des verfahrens und verwendung eines bei der verwertung anfallenden produkts
US5059404A (en) 1989-02-14 1991-10-22 Manufacturing And Technology Conversion International, Inc. Indirectly heated thermochemical reactor apparatus and processes
US4929254A (en) * 1989-07-13 1990-05-29 Set Technology B.V. Down-draft fixed bed gasifier system
US5079267A (en) * 1989-09-16 1992-01-07 Xytel Technologies Partnership Methanol production
HU9201539D0 (en) 1990-09-11 1992-08-28 Kortec Ag Method and device for gasifying gasifiable materials and/or transforming gas as well as heat exchanger of high temperature for executing said method
US5120885A (en) * 1990-09-21 1992-06-09 Kao Corporation Process for producing alcohol
MY107920A (en) * 1990-12-27 1996-06-29 Kao Corp Process for producing alcohol
JPH0699337B2 (ja) * 1990-12-27 1994-12-07 花王株式会社 アルコールの製造方法
US5226927A (en) * 1991-02-13 1993-07-13 Southern California Edison Wood gasifier
FI89535C (fi) 1991-04-11 1997-07-22 Tampella Power Oy Foerbraenningsanlaeggning
US5218931A (en) * 1991-11-15 1993-06-15 Foster Wheeler Energy Corporation Fluidized bed steam reactor including two horizontal cyclone separators and an integral recycle heat exchanger
EP0555060B1 (en) * 1992-02-04 1996-07-17 Air Products And Chemicals, Inc. Liquid phase methanol process with co-rich recycle
US5334755A (en) 1992-04-24 1994-08-02 Chiyoda Corporation Process for the production of acetic acid from methanol and carbon monoxide using supported rhodium catalyst
US5695532A (en) 1992-05-08 1997-12-09 State Electricity Commission Of Victoria Integrated carbonaceous fuel drying and gasification process and apparatus
US5488143A (en) * 1992-06-30 1996-01-30 Korea Institute Of Science And Technology Processes for the carbonylation of methanol to form acetic acid, methyl acetate and acetic anhydride
US5414161A (en) * 1992-06-30 1995-05-09 Korea Institute Of Science And Technology Process for the preparation of ethanol from methanol
PT100794B (pt) * 1992-08-20 1999-12-31 Ineti Inst Nac Engenh E Tecnol Gaseificador em leito fluidizado
US5279234A (en) * 1992-10-05 1994-01-18 Chiptec Wood Energy Systems Controlled clean-emission biomass gasification heating system/method
US5607487A (en) * 1993-03-17 1997-03-04 Taylor; Leland T. Bottom feed - updraft gasification system
GB9306409D0 (en) * 1993-03-26 1993-05-19 Bp Chem Int Ltd Process
FR2703351A1 (fr) * 1993-03-31 1994-10-07 Rhone Poulenc Chimie Procédé de préparation d'acides carboxyliques ou des esters correspondants en présence d'un catalyseur à base de rhodium et d'iridium.
US5334848A (en) * 1993-04-09 1994-08-02 Trw Inc. Spacecraft docking sensor system
US5344848A (en) 1993-05-27 1994-09-06 Meyer Steinberg Process and apparatus for the production of methanol from condensed carbonaceous material
KR960006546B1 (ko) * 1993-07-28 1996-05-17 한국과학기술연구원 초산에스테르의 제조 방법
US5484465A (en) 1993-08-02 1996-01-16 Emery Recycling Corporation Apparatus for municipal waste gasification
CA2114965C (fr) 1994-02-04 2004-07-27 Denis Ngoy Bangala Catalyseur de reformage a la vapeur et sa methode de preparation
US5922090A (en) * 1994-03-10 1999-07-13 Ebara Corporation Method and apparatus for treating wastes by gasification
AU2571095A (en) * 1994-05-13 1995-12-05 Pardies Acetiques Method for the preparation of carboxylic acids or corresponding esters in the presence of a soluble iridium-based catalyst
US5589599A (en) 1994-06-07 1996-12-31 Mcmullen; Frederick G. Pyrolytic conversion of organic feedstock and waste
US5666890A (en) * 1994-06-22 1997-09-16 Craig; Joe D. Biomass gasification system and method
FR2725443B1 (fr) * 1994-10-05 1996-12-20 Rhone Poulenc Chimie Preparation d'acides carboxyliques ou des esters correspondants par carbonylation en presence d'iridium
GB9503385D0 (en) * 1995-02-21 1995-04-12 Bp Chem Int Ltd Process
CA2146192C (en) 1995-04-03 1999-04-06 Universite De Sherbrooke Polyionic insoluble hydrogels comprising xanthan
US5599976A (en) * 1995-04-07 1997-02-04 Hoechst Celanese Corporation Recovery of acetic acid from dilute aqueous streams formed during a carbonylation process
JP3927237B2 (ja) * 1995-04-27 2007-06-06 ダイセル化学工業株式会社 酢酸の製造法
US6683224B1 (en) * 1995-05-03 2004-01-27 Cognis Deutschland Gmbh & Co. Kg Process for the production of fatty alcohols
WO1997000841A1 (en) 1995-06-20 1997-01-09 Kao Corporation Method for producing alcohol
US5696284A (en) 1995-06-21 1997-12-09 Bp Chemicals Limited Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof
GB9517184D0 (en) * 1995-08-22 1995-10-25 Bp Chem Int Ltd Process
FR2746795B1 (fr) * 1996-03-27 1998-06-19 Rhone Poulenc Chimie Procede de preparation d'acide acetique et/ou d'acetate de methyle par isomerisation et carbonylation
DK40796A (da) * 1996-04-10 1997-10-11 Haldor Topsoe As Fremgangsmåde til fremstilling af eddikesyre
US5900224A (en) * 1996-04-23 1999-05-04 Ebara Corporation Method for treating wastes by gasification
US5980858A (en) 1996-04-23 1999-11-09 Ebara Corporation Method for treating wastes by gasification
ES2188974T3 (es) * 1996-09-04 2003-07-01 Ebara Corp Procedimiento de gasificacion de desechos utilizando un horno de fusion rotativo.
DK136196A (da) 1996-11-29 1998-05-30 Haldor Topsoe As Fremgangsmåde til fremstilling af eddikesyre
GB9625335D0 (en) * 1996-12-05 1997-01-22 Bp Chem Int Ltd Process
GB9626429D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
GB9626428D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
US5900505A (en) * 1997-02-04 1999-05-04 Eastman Chemical Company Heterogeneous vapor phase carbonylation process
US6028119A (en) * 1997-02-27 2000-02-22 Mitsui Chemicals, Inc. Process for methanol production
DE69808983T2 (de) * 1997-03-31 2003-08-07 Director General Of Agency Of Industrial Science And Technology, Tokio/Tokyo Methanolsynthese- und Reformierungskatalysator bestehend aus Kupfer, Zink und Aluminium
DE19730939A1 (de) * 1997-07-18 1999-01-21 Basf Ag Verfahren zur Hydrierung von Carbonylverbindungen
US6048374A (en) 1997-08-18 2000-04-11 Green; Alex E. S. Process and device for pyrolysis of feedstock
CA2215251C (en) 1997-10-01 2003-02-25 Kemestrie Inc. Industrial preparation of high purity gallic acid
AU734203B2 (en) 1997-12-18 2001-06-07 Ebara Corporation Fuel gasification system
US6521783B1 (en) * 1998-01-29 2003-02-18 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates
US6127432A (en) 1998-01-29 2000-10-03 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates and catalysts therefor
CA2259481A1 (en) 1998-02-09 1999-08-09 Kemestrie Inc. Direct extraction and/or purification of high purity maltol and essential oils by sublimation process
WO1999060027A1 (en) 1998-05-14 1999-11-25 Kemestrie Inc. Process for preparing a high purity chemical-free microcrystalline cellulose from a chemically produced cellulose
US5993751A (en) 1998-06-02 1999-11-30 Moriarty; Jack Pyrolizer
CA2243619A1 (fr) 1998-07-17 2000-01-17 Universite De Sherbrooke Hydrogels polyioniques a base de xanthane et chitosane pour stabilisation et relargage controle des vitamines
US20010027737A1 (en) 1998-08-21 2001-10-11 Stan E. Abrams Gasifier system and method
US6211405B1 (en) * 1998-10-23 2001-04-03 Celanese International Corporation Addition of iridium to the rhodium/inorganic iodide catalyst system
FR2785606B1 (fr) * 1998-11-05 2001-01-26 Acetex Chimie Preparation d'acide acetique et/ou d'acetate de methyle en presence d'iridium et de platine
FI105499B (fi) 1998-11-20 2000-08-31 Foster Wheeler Energia Oy Menetelmä ja laite leijupetireaktorissa
GC0000088A (en) 1999-02-15 2004-06-30 Shell Int Research Process for the preparation of hydrocarbons from carbon monoxide and hydrogen.
EP2011879B1 (en) * 1999-03-11 2012-11-28 Zeachem, Inc. Process for producing ethanol
CA2367534C (en) 1999-04-07 2006-12-05 Kemestrie Inc. Mobile granular bed filtration apparatus for hot gas conditioning
AU3799700A (en) 1999-04-07 2000-11-14 Kemestrie Inc. Mobile granular bed filtration apparatus for hot gas conditioning
ES2172367B1 (es) 1999-04-07 2003-10-16 Kemestrie Inc Aparato de filtracion de lecho granular movil para el acondicionado de gases calientes
DE1198541T1 (de) 1999-05-14 2003-02-06 Kemestrie Inc., Sherbrooke Verfahren und vorrichtung zur vergasung von abfällen
ES2183662B1 (es) 1999-05-14 2003-12-16 Kemestrie Inc Recipiente de reaccion de gasificacion y procedimiento correspondiente
CA2372111A1 (en) 1999-05-14 2000-11-23 Kemestrie Inc. Process and apparatus for gasification of refuse
CA2376483C (en) * 1999-06-09 2010-01-12 Technische Universitat Munchen Lehrstuhl Fur Thermische Kraftanlagen Facility for the gasification of carbon-containing feed materials
US6353132B1 (en) * 1999-08-25 2002-03-05 Eastman Chemical Company Vapor phase carbonylation process using group 5 metal promoted iridium catalyst
US6355595B1 (en) * 1999-08-25 2002-03-12 Eastman Chemical Company Group 5 metal promoted iridium carbonylation catalyst
US6355837B1 (en) * 1999-08-25 2002-03-12 Eastman Chemical Company Vapor phase carbonylation process using group 4 metal promoted iridium catalyst
TWI241392B (en) * 1999-09-20 2005-10-11 Japan Science & Tech Agency Apparatus and method for gasifying solid or liquid fuel
DE19948332B4 (de) * 1999-10-07 2005-09-22 Steer, Thomas, Dr.-Ing. Verfahren und Vorrichtung zum Gewinnen heizwertreicher Brennstoffe
US6723886B2 (en) * 1999-11-17 2004-04-20 Conocophillips Company Use of catalytic distillation reactor for methanol synthesis
KR20010062259A (ko) 1999-12-24 2001-07-07 추후제출 폐기물, 특히 산업 폐기물, 바이오매스 또는 이와 유사한가스화 물질의 가스화를 위한 방법 및 가스화 플랜트
US6133328A (en) 2000-02-22 2000-10-17 Lightner; Gene E. Production of syngas from a biomass
KR100590973B1 (ko) * 2000-02-29 2006-06-19 미츠비시 쥬고교 가부시키가이샤 바이오매스 가스화 가스를 이용한 메탄올 합성 장치 및 이의 사용방법
PT1263698E (pt) 2000-03-06 2008-08-28 Woodland Biofuels Inc Processo para converter material celulósico em hidrocarbonetos líquidos
FI114289B (fi) 2000-04-07 2004-09-30 Foster Wheeler Energia Oy Laite hiukkasten erottamiseksi kuumista kaasuista
US20030157171A1 (en) 2000-07-07 2003-08-21 Esteban Chornet Drug delivery system for poorly water soluble drugs
AT409413B (de) * 2000-08-11 2002-08-26 Rotec Engineering Gmbh & Co Kg Verfahren zum vergasen von abfall
US6647903B2 (en) 2000-09-14 2003-11-18 Charles W. Aguadas Ellis Method and apparatus for generating and utilizing combustible gas
US6986828B2 (en) 2000-11-03 2006-01-17 Kemestrie Inc. Process for producing low DP microcrystalline cellulose
CN1226093C (zh) * 2000-11-08 2005-11-09 出光兴产株式会社 烃重整用催化剂以及用该催化剂重整烃的方法
AU1671702A (en) 2000-11-17 2002-05-27 Future Energy Resources Corp Small scale high throughput biomass gasification system and method
US6680137B2 (en) * 2000-11-17 2004-01-20 Future Energy Resources Corporation Integrated biomass gasification and fuel cell system
CN1255515C (zh) * 2000-12-04 2006-05-10 埃默瑞能源有限公司 多面体气化器
EP2302017A3 (en) 2000-12-21 2012-05-09 Rentech, Inc. Biomass gasification system and method
US6486366B1 (en) 2000-12-23 2002-11-26 Degussa Ag Method for producing alcohols by hydrogenation of carbonyl compounds
JP2002193858A (ja) 2000-12-28 2002-07-10 Mitsubishi Heavy Ind Ltd バイオマス原料によるメタノール製造方法及びその装置
JP3973840B2 (ja) * 2001-01-18 2007-09-12 独立行政法人科学技術振興機構 固形燃料ガス化装置
FR2820422B1 (fr) * 2001-02-08 2003-04-25 Acetex Chimie Modification du systeme catalytique dans un procede industriel de fabrication d'acide acetique et/ou d'acetate de methyle
US6972114B2 (en) 2001-02-16 2005-12-06 Pope Leroy B Biomass gasifier apparatus and method
US6617471B2 (en) * 2001-06-20 2003-09-09 Eastman Chemical Company Method for carbonylation of lower aliphatic alcohols using tin promoted iridium catalyst
FR2826960B1 (fr) 2001-07-03 2005-10-21 Acetex Chimie Procede de controle d'une production d'acide acetique et/ou d'acetate de methyle en continu
US6863878B2 (en) * 2001-07-05 2005-03-08 Robert E. Klepper Method and apparatus for producing synthesis gas from carbonaceous materials
JP4959074B2 (ja) * 2001-07-19 2012-06-20 三菱重工業株式会社 メタノールの製造方法
JP4259777B2 (ja) 2001-07-31 2009-04-30 井上 斉 バイオマスのガス化方法
AU2002356086B2 (en) 2001-08-24 2007-11-29 Shell Internationale Research Maatschappij B.V. Process for the preparation of hydrocarbons
CA2357527C (en) * 2001-10-01 2009-12-01 Technology Convergence Inc. Methanol recycle stream
EP1308671A1 (en) * 2001-10-30 2003-05-07 Alstom (Switzerland) Ltd A circulating fluidized bed reactor device
CA2469653C (en) * 2001-12-18 2011-10-25 Jerrel Dale Branson System and method for extracting energy from agricultural waste
US20030115800A1 (en) * 2001-12-18 2003-06-26 Muneyoshi Yamada Method for gasifying biomass and catalyst used for said method
CA2365785A1 (en) * 2001-12-19 2003-06-19 Louis Obidniak Pyrolysis system
FI112952B (fi) * 2001-12-21 2004-02-13 Foster Wheeler Energia Oy Menetelmä ja laitteisto hiilipitoisen materiaalin kaasuttamiseksi
JP4224240B2 (ja) 2002-02-07 2009-02-12 株式会社荏原製作所 液体燃料合成システム
JP3980382B2 (ja) 2002-03-13 2007-09-26 新日本製鐵株式会社 バイオマス熱分解方法及びその装置
DE10214003B4 (de) * 2002-03-27 2005-12-22 Lurgi Ag Verfahren zur Erzeugung von Kohlenmonoxid und Methanol
US7244399B2 (en) 2002-04-26 2007-07-17 Foster Wheeler Energia Oy Grid construction for a fluidized bed reactor
US6596781B1 (en) * 2002-05-02 2003-07-22 Chevron U.S.A. Inc. Integrated process for preparing Fischer-Tropsch products and acetic acid from synthesis gas
CA2383279A1 (fr) 2002-05-06 2003-11-06 Sylvain Cloutier Reacteur
CA2484850A1 (en) 2002-05-06 2003-11-13 Kemestrie Inc. Apparatus for treating lignocellulose material and method associated thereto
CN1315771C (zh) * 2002-05-06 2007-05-16 伊斯曼化学公司 连续羰基化工艺
CA2486873A1 (en) * 2002-05-22 2003-12-04 Manufacturing And Technology Conversion International, Inc. Pulse gasification and hot gas cleanup apparatus and process
US8317886B2 (en) * 2002-05-22 2012-11-27 Nexterra Systems Corp. Apparatus and method for gasifying solid organic materials
FR2839972B1 (fr) 2002-05-23 2005-08-19 Inst Francais Du Petrole Procede de carbonylation des alcools utilisant un catalyseur a base de rhodium ou d'iridium dans un liquide ionique non-aqueux,avec un recyclage efficace du catalyseur
JP4227771B2 (ja) 2002-07-17 2009-02-18 三菱重工業株式会社 バイオマスのガス化方法
JP2004149556A (ja) 2002-10-28 2004-05-27 Nishinippon Environmental Energy Co Inc バイオマスのガス化方法及びそのガス化装置
CN1308225C (zh) 2002-10-28 2007-04-04 萨索尔技术(控股)有限公司 合成气及合成气衍生产品的制备
EP1613553A1 (en) * 2003-04-01 2006-01-11 Haldor Tops E A/S Process for the preparation of a hydrogen-rich stream
FI114115B (fi) * 2003-04-15 2004-08-13 Foster Wheeler Energia Oy Menetelmä ja laite lämmön talteenottamiseksi leijupetireaktorissa
EP1631374A2 (en) 2003-04-30 2006-03-08 Ebara Corporation A supplying apparatus for supplying combustible material, a gasification apparatus for gasifying combustible material and method for gasifying combustible material
CN1477090A (zh) 2003-05-16 2004-02-25 中国科学院广州能源研究所 生物质间接液化一步法合成二甲醚的方法
US20040265158A1 (en) * 2003-06-30 2004-12-30 Boyapati Krishna Rao Co-producing hydrogen and power by biomass gasification
US8394863B2 (en) * 2003-08-21 2013-03-12 Pearson Technologies, Inc. Process and apparatus for the production of useful products from carbonaceous feedstock
TW200519073A (en) * 2003-08-21 2005-06-16 Pearson Technologies Inc Process and apparatus for the production of useful products from carbonaceous feedstock
JP4085160B2 (ja) * 2003-08-27 2008-05-14 独立行政法人産業技術総合研究所 バイオマスの自己触媒作用を利用したガス化法
JP2005112956A (ja) 2003-10-06 2005-04-28 Nippon Steel Corp バイオマスのガス化方法
US6846951B1 (en) * 2003-10-09 2005-01-25 Acetex (Cyprus) Limited Integrated process for acetic acid and methanol
JP4487175B2 (ja) 2003-10-28 2010-06-23 正康 坂井 バイオマスからのメタノール製造方法
US20050095183A1 (en) * 2003-11-05 2005-05-05 Biomass Energy Solutions, Inc. Process and apparatus for biomass gasification
US7196239B2 (en) * 2003-11-19 2007-03-27 Exxonmobil Chemical Patents Inc. Methanol and ethanol production for an oxygenate to olefin reaction system
US7241322B2 (en) 2003-11-21 2007-07-10 Graham Robert G Pyrolyzing gasification system and method of use
US7244400B2 (en) * 2003-11-25 2007-07-17 Foster Wheeler Energy Corporation Fluidized bed reactor system having an exhaust gas plenum
CN1279311C (zh) 2004-04-06 2006-10-11 东南大学 多喷嘴喷动流化床气化炉
US7384987B2 (en) * 2004-06-01 2008-06-10 Syntec Biofuel, Inc. Catalysts and processes for the manufacture of lower aliphatic alcohols from syngas
CN2745924Y (zh) 2004-08-06 2005-12-14 中国林业科学研究院林产化学工业研究所 生物质细颗粒物料气化炉
JP2006083293A (ja) 2004-09-16 2006-03-30 Fuji Electric Systems Co Ltd バイオマス燃料のガス化装置
US7287477B2 (en) * 2004-10-13 2007-10-30 Foster Wheeler Energy Corporation Cyclone bypass for a circulating fluidized bed reactor
JP2006131820A (ja) 2004-11-09 2006-05-25 Ishikawajima Harima Heavy Ind Co Ltd 流動層ガス化方法及び装置
CN2789258Y (zh) 2005-05-31 2006-06-21 董颖 生物质气化炉
CN2813616Y (zh) 2005-07-15 2006-09-06 合肥天焱绿色能源开发有限公司 组合生物质气化炉
EP2172568A1 (en) 2005-07-19 2010-04-07 Inbicon A/S Method and apparatus for conversion of cellulosic material to enthanol
US7579383B2 (en) * 2005-07-27 2009-08-25 Exxonmobil Chemical Patents Inc. Fluid bed methanol synthesis
CN100345940C (zh) 2005-08-24 2007-10-31 南京工业大学 利用热管供热的流化床生物质气化炉
US8088832B2 (en) 2006-04-05 2012-01-03 Woodland Biofuels Inc. System and method for converting biomass to ethanol via syngas
US9428706B2 (en) 2006-12-22 2016-08-30 Afina Energy Inc. Method for low-severity gasification of heavy petroleum residues
US8080693B2 (en) 2008-02-28 2011-12-20 Enerkem, Inc. Production of ethanol from methanol
US20090221725A1 (en) 2008-02-28 2009-09-03 Enerkem, Inc. Production of ethanol from methanol
US8137655B2 (en) 2008-04-29 2012-03-20 Enerkem Inc. Production and conditioning of synthesis gas obtained from biomass
US8192647B2 (en) 2008-12-19 2012-06-05 Enerkem Inc. Production of synthesis gas through controlled oxidation of biomass
US9353042B2 (en) 2010-08-20 2016-05-31 Enerkem, Inc. Production of acetates from acetic acid and alcohols

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2571425C2 (ru) * 2010-02-02 2015-12-20 Селаниз Интернэшнл Корпорейшн Способ испарения уксусной кислоты в процессах гидрирования для производства этанола
RU2577987C2 (ru) * 2010-11-09 2016-03-20 Инеос Коммершиал Сервисиз Юк Лимитед Способ и устройство для получения спиртов

Also Published As

Publication number Publication date
ES2539761T3 (es) 2015-07-03
US8710107B2 (en) 2014-04-29
BRPI0710578B1 (pt) 2016-11-29
EP2004583B1 (en) 2015-06-03
AU2007235322A2 (en) 2009-01-08
EA013194B1 (ru) 2010-02-26
WO2007117590A3 (en) 2008-06-19
US20070270511A1 (en) 2007-11-22
KR20080108605A (ko) 2008-12-15
WO2007117590A2 (en) 2007-10-18
BRPI0710578A2 (pt) 2011-08-16
CA2682778A1 (en) 2007-10-18
JP2009532483A (ja) 2009-09-10
EP2004583A2 (en) 2008-12-24
US20140256993A1 (en) 2014-09-11
US8088832B2 (en) 2012-01-03
CA2682778C (en) 2017-03-07
WO2007117590A9 (en) 2008-11-06
AU2007235322A1 (en) 2007-10-18
US20120283341A1 (en) 2012-11-08

Similar Documents

Publication Publication Date Title
EA200802105A1 (ru) Система и способ для превращения биомассы в этанол через сингаз
WO2009111331A3 (en) Gasification using steam generated utilizing biomass feedstocks
Yang et al. Biogas and syngas upgrading
UA109765C2 (uk) Спосіб виробництва чистого гарячого газа на основі твердих палив
WO2010124077A3 (en) Integrated, high-efficiency processes for biomass conversion to synthesis gas
WO2009111332A3 (en) Reduced carbon footprint steam generation processes
WO2009086407A3 (en) Steam generating slurry gasifier for the catalytic gasification of a carbonaceous feedstock
WO2011026630A3 (de) Verfahren und vorrichtung zur nutzung von sauerstoff bei der dampfreformierung von biomasse
EA200870484A1 (ru) Способ получения жидких углеводородов
NZ587568A (en) Method and device for converting carbonaceous raw materials
CN103930523A (zh) 使碳基原料热化学转化为主要含有h2和co的合成气体的方法
Song et al. Simulation of air-steam gasification of pine sawdust in an updraft gasification system for production of hydrogen-rich producer gas
EA201490089A1 (ru) Способ регулирования отношения водорода к монооксиду углерода в синтез-газе
MY161114A (en) Method and device for producing process vapor and boiler feed steam in a heatable reforming reactor for producing synthesis gas
Asih et al. Techno-enviro-economic analysis of integrated direct chemical looping coal-based power generation and methanol synthesis using renewable hydrogen
Moneti et al. Simulations of a plant with a fluidized bed gasifier WGS and PSA
DK2706103T3 (en) Process for gasifying a charge of carbonaceous material with improved efficiency
Adnan et al. Gasification of various biomasses including microalgae using CO2–A thermodynamic study
CA2849794A1 (en) Carbon neutral natural gas to liquids plant with biomass co-feed
Kaniyal et al. Dynamic modeling of the coproduction of liquid fuels and electricity from a hybrid solar gasifier with various fuel blends
Yin et al. Novel calcium-looping-based biomass-integrated gasification combined cycle: Thermodynamic modeling and experimental study
MY178682A (en) Method and device for producing synthetic gas and method and device for synthesizing liquid fuel
PL413518A1 (pl) Skojarzony system wytwarzania paliwa i energii cieplnej oraz sposób wytwarzania paliwa i energii cieplnej
EA201000973A1 (ru) Способ и установка для производства полукокса и горючего газа
Shabani et al. Investigation of biomass gasification hydrogen and electricity co-production with carbon dioxide capture and storage