DK3035428T3 - Fastoxidbrændselscelle - Google Patents
Fastoxidbrændselscelle Download PDFInfo
- Publication number
- DK3035428T3 DK3035428T3 DK16154313.7T DK16154313T DK3035428T3 DK 3035428 T3 DK3035428 T3 DK 3035428T3 DK 16154313 T DK16154313 T DK 16154313T DK 3035428 T3 DK3035428 T3 DK 3035428T3
- Authority
- DK
- Denmark
- Prior art keywords
- layer
- fuel cell
- gas
- cathode layer
- solid oxide
- Prior art date
Links
- 239000000446 fuel Substances 0.000 title claims description 75
- 239000007787 solid Substances 0.000 title claims description 27
- 239000007789 gas Substances 0.000 claims description 76
- 239000000463 material Substances 0.000 claims description 36
- 239000002737 fuel gas Substances 0.000 claims description 22
- 239000007784 solid electrolyte Substances 0.000 claims description 22
- 230000001590 oxidative effect Effects 0.000 claims description 17
- 230000015572 biosynthetic process Effects 0.000 description 31
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 10
- 238000010304 firing Methods 0.000 description 10
- 238000007788 roughening Methods 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 239000000919 ceramic Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 6
- 238000007639 printing Methods 0.000 description 6
- 230000014509 gene expression Effects 0.000 description 5
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 238000004049 embossing Methods 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000005488 sandblasting Methods 0.000 description 4
- 238000007650 screen-printing Methods 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 238000009826 distribution Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000011195 cermet Substances 0.000 description 2
- 229910021526 gadolinium-doped ceria Inorganic materials 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 238000007645 offset printing Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- -1 naphtha Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0258—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
- H01M8/026—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant characterised by grooves, e.g. their pitch or depth
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0241—Composites
- H01M8/0245—Composites in the form of layered or coated products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
- H01M8/0273—Sealing or supporting means around electrodes, matrices or membranes with sealing or supporting means in the form of a frame
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
- H01M8/2425—High-temperature cells with solid electrolytes
- H01M8/2432—Grouping of unit cells of planar configuration
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2457—Grouping of fuel cells, e.g. stacking of fuel cells with both reactants being gaseous or vaporised
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/2483—Details of groupings of fuel cells characterised by internal manifolds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/2484—Details of groupings of fuel cells characterised by external manifolds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/2484—Details of groupings of fuel cells characterised by external manifolds
- H01M8/2485—Arrangements for sealing external manifolds; Arrangements for mounting external manifolds around a stack
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M2008/1293—Fuel cells with solid oxide electrolytes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Composite Materials (AREA)
- Fuel Cell (AREA)
- Inert Electrodes (AREA)
Claims (6)
1. Fastoxidbrændselscelle (10), der omfatter: et brændselscellehovedlegeme, der indbefatter et katodelag (141), et fastelektrolytlag (143) og et anodelag (144), og som har en strømgenereringsfunktion; en konnektor (110), der er placeret til at vende ind mod ét elektrodelag af katodelaget (141) og anodelaget (144); strømaftagere (147), der er placeret mellem det ene elektrodelag (141, 144) og konnektoren (110), og som er i kontakt med en overflade af det ene elektrodelag (141, 144) og en overflade af konnektoren (110), hvilke overflader vender ind mod hinanden for derved elektrisk at forbinde det ene elektrodelag (141, 144) og konnektoren (110); og riller (145) tilvejebragt i en del af en overflade af det ene elektrodelag (141, 144), hvilken overflade er placeret på siden, hvor det ene elektrodelag (141, 144) er i kontakt med strømaftagerne (147), hvor delen af overfladen ikke er i kontakt med strømaftagerne (147), hvor rillerne (145) strækker sig i to retninger, der hælder i forhold til en retning for en strømningsbane af en oxiderende gas tilført katodelaget (141) eller en retning for en strømningsbane for en brændselsgas tilført anodelaget (144), kendetegnet ved, at strømaftagerne (147) er anbragt i et gitter set fra oven.
2. Fastoxidbrændselscelle (10) ifølge krav 1, hvor overfladen af det ene elektrodelag (141, 144), der er i kontakt med strømaftagerne (147), har en aritmetisk middel ruhed Ra, der er større end 0,3 pm.
3. Fastoxidbrændselscelle (10) ifølge krav 1 eller 2, hvor overfladen af det ene elektrodelag (141, 144), der er i kontakt med strømaftagerne (147), har en aritmetisk middel bølgethed Wa, der er mindre end 0,3 pm.
4. Fastoxidbrændselscelle (10) ifølge et hvilket som helst af kravene 1 til 3, hvor hver strømaftager (147) er fremstillet af et materiale, der er det samme som konnektorens (110) materiale, således at hver strømaftager (147) er forenet med konnektoren (110).
5. Fastoxidbrændselscelle (10) ifølge et hvilket som helst af kravene 1 til 4, hvor rillernes (145) to udstrækkende retninger har hældningsvinkler på ±45° i forhold til retningen af strømningsbanen for den oxiderende gas eller brændselsgassen.
6. Fastoxidbrændselscelle (10) ifølge et hvilket som helst af kravene 1 til 5, hvor, set fra oven, strømningsbaner af den oxiderende gas tilført katodelaget (141) eller strømningsbaner af brændselsgassen tilført oxidlaget (144) strækker sig i to strømningsbaneretninger mellem de strømaftagerne (147), der er anbragt i gitteret.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011105827A JP5819099B2 (ja) | 2011-05-11 | 2011-05-11 | 固体酸化物形燃料電池 |
EP12782274.0A EP2709197B1 (en) | 2011-05-11 | 2012-02-21 | Solid oxide fuel cell |
Publications (1)
Publication Number | Publication Date |
---|---|
DK3035428T3 true DK3035428T3 (da) | 2018-09-17 |
Family
ID=47138940
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DK12782274.0T DK2709197T3 (da) | 2011-05-11 | 2012-02-21 | Fastoxidbrændselscelle |
DK16154313.7T DK3035428T3 (da) | 2011-05-11 | 2012-02-21 | Fastoxidbrændselscelle |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DK12782274.0T DK2709197T3 (da) | 2011-05-11 | 2012-02-21 | Fastoxidbrændselscelle |
Country Status (8)
Country | Link |
---|---|
US (1) | US9853308B2 (da) |
EP (2) | EP2709197B1 (da) |
JP (1) | JP5819099B2 (da) |
KR (3) | KR101713464B1 (da) |
CN (1) | CN103534855B (da) |
CA (2) | CA2832329C (da) |
DK (2) | DK2709197T3 (da) |
WO (1) | WO2012153446A1 (da) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DK2955777T3 (da) | 2013-02-07 | 2020-04-20 | Morimura Sofc Tech Co Ltd | Brændselscelle og fremgangsmåde til fremstilling af samme |
DK3046171T3 (da) * | 2013-09-10 | 2019-03-18 | Ngk Spark Plug Co | Brændselscelle og brændselscellestak. |
KR101674259B1 (ko) * | 2013-09-27 | 2016-11-08 | 주식회사 엘지화학 | 고체 산화물 연료전지의 연료극 지지체 제조방법 및 고체 산화물 연료전지의 연료극 지지체 |
JP6465546B2 (ja) * | 2013-12-24 | 2019-02-06 | 日本特殊陶業株式会社 | 固体酸化物形燃料電池及びその製造方法 |
CN105917507B (zh) * | 2014-01-15 | 2018-06-19 | 日本特殊陶业株式会社 | 燃料电池盒及燃料电池堆 |
EP3605686A1 (en) * | 2015-06-15 | 2020-02-05 | Ngk Spark Plug Co., Ltd. | Fuel cell stack and method for manufacturing fuel cell stack |
JP6060300B1 (ja) * | 2015-06-30 | 2017-01-11 | 日本碍子株式会社 | 燃料電池 |
CN105470529B (zh) * | 2015-12-03 | 2018-12-14 | 苏州攀特电陶科技股份有限公司 | 一种固体氧化物燃料电池电极及其制备方法和基于其的固体氧化物燃料电池 |
WO2018096971A1 (ja) | 2016-11-22 | 2018-05-31 | カルソニックカンセイ株式会社 | 燃料電池の製造方法及び燃料電池 |
JP6472842B2 (ja) * | 2016-11-22 | 2019-02-20 | カルソニックカンセイ株式会社 | 固体電解質層と電極との接合方法、及び、燃料電池の製造方法 |
JP6621541B2 (ja) * | 2017-06-06 | 2019-12-18 | 日本特殊陶業株式会社 | 電気化学反応セルスタック、インターコネクタ−電気化学反応単セル複合体および電気化学反応セルスタックの製造方法 |
WO2019189915A1 (ja) * | 2018-03-30 | 2019-10-03 | 大阪瓦斯株式会社 | 電気化学素子積層体、電気化学素子、電気化学モジュール、電気化学装置およびエネルギーシステム |
CN113097552B (zh) * | 2021-04-06 | 2023-05-05 | 广东省科学院新材料研究所 | 一种连接板及固体氧化物燃料电池/电解池电堆 |
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2011
- 2011-05-11 JP JP2011105827A patent/JP5819099B2/ja active Active
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2012
- 2012-02-21 KR KR1020157014251A patent/KR101713464B1/ko active Active
- 2012-02-21 CN CN201280022529.2A patent/CN103534855B/zh active Active
- 2012-02-21 CA CA2832329A patent/CA2832329C/en active Active
- 2012-02-21 EP EP12782274.0A patent/EP2709197B1/en active Active
- 2012-02-21 EP EP16154313.7A patent/EP3035428B1/en active Active
- 2012-02-21 DK DK12782274.0T patent/DK2709197T3/da active
- 2012-02-21 KR KR1020157037017A patent/KR20160008246A/ko not_active Ceased
- 2012-02-21 US US14/114,571 patent/US9853308B2/en active Active
- 2012-02-21 DK DK16154313.7T patent/DK3035428T3/da active
- 2012-02-21 WO PCT/JP2012/001136 patent/WO2012153446A1/ja active Application Filing
- 2012-02-21 CA CA2898511A patent/CA2898511C/en active Active
- 2012-02-21 KR KR1020137032313A patent/KR20140020326A/ko not_active Withdrawn
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CA2898511C (en) | 2019-09-03 |
US9853308B2 (en) | 2017-12-26 |
EP3035428B1 (en) | 2018-06-13 |
CA2898511A1 (en) | 2012-11-15 |
KR20160008246A (ko) | 2016-01-21 |
WO2012153446A1 (ja) | 2012-11-15 |
CA2832329C (en) | 2018-09-18 |
EP3035428A1 (en) | 2016-06-22 |
CA2832329A1 (en) | 2012-11-15 |
EP2709197A4 (en) | 2015-08-05 |
EP2709197A1 (en) | 2014-03-19 |
CN103534855B (zh) | 2016-10-12 |
KR20150065949A (ko) | 2015-06-15 |
JP2012238439A (ja) | 2012-12-06 |
KR20140020326A (ko) | 2014-02-18 |
EP2709197B1 (en) | 2019-11-06 |
KR101713464B1 (ko) | 2017-03-07 |
US20140051009A1 (en) | 2014-02-20 |
CN103534855A (zh) | 2014-01-22 |
DK2709197T3 (da) | 2020-01-20 |
JP5819099B2 (ja) | 2015-11-18 |
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