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DK1478612T3 - Fischer-Tropsch-fremgangsmåde med forbedret katalysatorregenerering - Google Patents

Fischer-Tropsch-fremgangsmåde med forbedret katalysatorregenerering

Info

Publication number
DK1478612T3
DK1478612T3 DK03700681T DK03700681T DK1478612T3 DK 1478612 T3 DK1478612 T3 DK 1478612T3 DK 03700681 T DK03700681 T DK 03700681T DK 03700681 T DK03700681 T DK 03700681T DK 1478612 T3 DK1478612 T3 DK 1478612T3
Authority
DK
Denmark
Prior art keywords
catalyst
reactor
decreasing
ammonium salts
fischer
Prior art date
Application number
DK03700681T
Other languages
Danish (da)
English (en)
Inventor
Michel Daage
Eric Baochun Shen
Russell John Koveal
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Application granted granted Critical
Publication of DK1478612T3 publication Critical patent/DK1478612T3/da

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/10—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/60—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
    • B01J38/62—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids organic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/64—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using alkaline material; using salts
    • B01J38/66—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using alkaline material; using salts using ammonia or derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/70—Wet oxidation of material submerged in liquid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DK03700681T 2002-01-29 2003-01-03 Fischer-Tropsch-fremgangsmåde med forbedret katalysatorregenerering DK1478612T3 (da)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/059,916 US6753354B2 (en) 2002-01-29 2002-01-29 Fischer-tropsch catalyst enhancement

Publications (1)

Publication Number Publication Date
DK1478612T3 true DK1478612T3 (da) 2006-11-20

Family

ID=27658270

Family Applications (1)

Application Number Title Priority Date Filing Date
DK03700681T DK1478612T3 (da) 2002-01-29 2003-01-03 Fischer-Tropsch-fremgangsmåde med forbedret katalysatorregenerering

Country Status (12)

Country Link
US (1) US6753354B2 (zh)
EP (1) EP1478612B1 (zh)
JP (1) JP4500548B2 (zh)
CN (1) CN100398501C (zh)
AT (1) ATE333936T1 (zh)
AU (1) AU2003201821B8 (zh)
CA (1) CA2471600A1 (zh)
DE (1) DE60307057T2 (zh)
DK (1) DK1478612T3 (zh)
ES (1) ES2269972T3 (zh)
WO (1) WO2003064356A1 (zh)
ZA (1) ZA200404478B (zh)

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AU2005318138B2 (en) * 2004-12-23 2009-08-06 Shell Internationale Research Maatschappij B.V. Process for preparing a catalyst
US7524787B2 (en) * 2005-01-11 2009-04-28 Sasol Technology (Proprietary Limited) Producing supported cobalt catalysts for the Fisher-Tropsch synthesis
RU2412001C2 (ru) * 2005-12-16 2011-02-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ приготовления катализатора синтеза углеводородов
US7825055B2 (en) * 2006-04-21 2010-11-02 Chevron U.S.A. Inc. Regeneration of ionic liquid catalyst using a regeneration metal in the presence of added hydrogen
US8614158B2 (en) * 2008-02-29 2013-12-24 Schlumberger Technology Corporation Fischer-trospch and oxygenate synthesis catalyst activation/regeneration in a micro scale process
US8293805B2 (en) * 2008-05-29 2012-10-23 Schlumberger Technology Corporation Tracking feedstock production with micro scale gas-to-liquid units
US20100152022A1 (en) * 2008-12-17 2010-06-17 Qi Sun Catalyst regeneration method
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BR112012014717B1 (pt) * 2009-12-16 2019-11-12 Shell Int Research processo para regenerar uma ou mais partículas de catalisador de fischer-tropsch que compreendem cobalto
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FR2970187B1 (fr) 2011-01-11 2013-02-08 Eurecat Sa Procede de regeneration hors site de catalyseurs solides.
US8389431B2 (en) * 2011-02-03 2013-03-05 Steag Energy Services Gmbh Method for treating SCR catalysts having accumulated iron compounds
WO2014070857A2 (en) 2012-10-31 2014-05-08 Thermochem Recovery International, Inc. System and method for processing raw gas with in-situ catalyst regeneration
CN107207969B (zh) 2014-11-20 2019-05-07 沙索技术有限公司 费托合成
EP3380234A1 (en) * 2015-11-23 2018-10-03 Clariant Corporation Processes for regenerating catalysts useful in fischer-tropsch processes
CN107952461B (zh) * 2016-10-17 2020-10-27 中国石油化工股份有限公司 一种负载型纳米钴催化剂及其应用
CN111282574B (zh) * 2020-02-03 2020-12-15 中国矿业大学(北京) 一种费托合成铁系催化剂的回收方法
CN114425439A (zh) * 2020-09-18 2022-05-03 中国石油化工股份有限公司 一种废催化裂化催化剂复活方法

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Also Published As

Publication number Publication date
AU2003201821B2 (en) 2008-05-01
US6753354B2 (en) 2004-06-22
DE60307057D1 (de) 2006-09-07
CN100398501C (zh) 2008-07-02
EP1478612B1 (en) 2006-07-26
CA2471600A1 (en) 2003-08-07
ZA200404478B (en) 2006-02-22
WO2003064356A1 (en) 2003-08-07
EP1478612A4 (en) 2005-03-16
EP1478612A1 (en) 2004-11-24
CN1620411A (zh) 2005-05-25
JP2005515893A (ja) 2005-06-02
DE60307057T2 (de) 2006-12-28
US20030166451A1 (en) 2003-09-04
ES2269972T3 (es) 2007-04-01
AU2003201821B8 (en) 2008-06-26
JP4500548B2 (ja) 2010-07-14
ATE333936T1 (de) 2006-08-15

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