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DE8533598U1 - Membrane for electro-acoustic transducers - Google Patents

Membrane for electro-acoustic transducers

Info

Publication number
DE8533598U1
DE8533598U1 DE8533598U DE8533598U DE8533598U1 DE 8533598 U1 DE8533598 U1 DE 8533598U1 DE 8533598 U DE8533598 U DE 8533598U DE 8533598 U DE8533598 U DE 8533598U DE 8533598 U1 DE8533598 U1 DE 8533598U1
Authority
DE
Germany
Prior art keywords
molded part
membrane
electro
acoustic transducers
igr
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE8533598U
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German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of DE8533598U1 publication Critical patent/DE8533598U1/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • C04B35/111Fine ceramics
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04RLOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
    • H04R31/00Apparatus or processes specially adapted for the manufacture of transducers or diaphragms therefor
    • H04R31/003Apparatus or processes specially adapted for the manufacture of transducers or diaphragms therefor for diaphragms or their outer suspension
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04RLOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
    • H04R7/00Diaphragms for electromechanical transducers; Cones
    • H04R7/02Diaphragms for electromechanical transducers; Cones characterised by the construction
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04RLOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
    • H04R2307/00Details of diaphragms or cones for electromechanical transducers, their suspension or their manufacture covered by H04R7/00 or H04R31/003, not provided for in any of its subgroups
    • H04R2307/023Diaphragms comprising ceramic-like materials, e.g. pure ceramic, glass, boride, nitride, carbide, mica and carbon materials
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04RLOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
    • H04R2307/00Details of diaphragms or cones for electromechanical transducers, their suspension or their manufacture covered by H04R7/00 or H04R31/003, not provided for in any of its subgroups
    • H04R2307/027Diaphragms comprising metallic materials

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Signal Processing (AREA)
  • Ceramic Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Acoustics & Sound (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Multimedia (AREA)
  • Diaphragms For Electromechanical Transducers (AREA)
  • ing And Chemical Polishing (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Description

PATENTANWALT DR.-ING. KLAUS DURM KARLSRUHE FELIX-MOTTL-STRASS.EJ a TELEFON 853355 N VERTfIETEfI BeJi/I EUROPÄISCHEN PATENTAMTPATENT ATTORNEY DR.-ING. KLAUS DURM KARLSRUHE FELIX-MOTTL-STRASSE PHONE 853355 AT THE EUROPEAN PATENT OFFICE

• · ■ ■ ·· ■ ■ ·

B 3337/85 Gbm 21. November 1985B 3337/85 Gbm 21 November 1985

Bernhard Thielf technischer Angestellter JahnstraßeBernhard Thiel f technical employee Jahnstraße

6653 Blieskastei 5 15 6653 Blieskastel 5 15

Membran für elektro-akustische WandlerMembrane for electro-acoustic transducers

&igr; 20 &igr; 20

j Die Neuerung betrifft eine Membran aus einem wenig j The innovation concerns a membrane made of a little

' dehn- und stauchbaren Material für elektro-akusfcische' stretchable and compressible material for electro-acoustic

Wandler.converter.

Anwendung findet die Neuerung insbesondere bei Membranen für Lautsprecher.The innovation is particularly used in membranes for loudspeakers.

Eine schwingfähige Membran für elektro-akustische Wandler sollte möglichst wenig dehn- und stauchbar sein und darüber hinaus ein extrem geringes Gewicht aufweisen. Die bisher bekannten Lautsprechermembranen genügen diesen Forderungen nur teilweise.A vibrating membrane for electro-acoustic transducers should be as stretchable and compressible as possible and should also be extremely lightweight. The loudspeaker membranes known to date only partially meet these requirements.

Es ist bekannt, Membranen für Lautsprecher aus Pappen» 35It is known to make membranes for loudspeakers out of cardboard» 35

guß, aus Kunststoff sowie aus Metall herzustellen. Membranen aus Pappenguß oder Kunststoff sind zwar kostengünstig herzustellen und haben eine große innere Dämpfung, neigen aber wegen ihrer geringen Festigkeit zu Partialschwingungen, deren Frequenzen mitten im Hörbereich liegen und daher sehr störend wahrgenommen werden« Die innere Dämpfung des Materials kann diese Partialschwingungen zwar mildern, führt aber äü änderen Fehlern wie Z. &Xgr;. &Kgr;&igr;&igr;&Ggr;&Ggr;&bgr;&Pgr;cast, plastic and metal. Membranes made of cast cardboard or plastic are inexpensive to produce and have a high level of internal damping, but due to their low strength they tend to produce partial vibrations whose frequencies are in the middle of the hearing range and are therefore perceived as very disturbing. The internal damping of the material can mitigate these partial vibrations, but leads to other errors such as Z. &Xgr;. &Kgr;&igr;&igr;&Ggr;&Ggr;&bgr;&Pgr;

Q oder schlechtem Impulsverhalten. Bei Membranen aus Metall (Aluminium, Titan, ganz selten Beryllium) liegen wegen der höheren Festigkeit die Partialschwingungen im Frequenzbereich höher. Sie befinden sich aber immer noch im Arbeitsbereich des jeweiligen Lautsprechers und sind sehr laut hörbar, da die innere Dämpfung nur gering ist.Q or poor impulse response. With membranes made of metal (aluminium, titanium, very rarely beryllium), the partial vibrations in the frequency range are higher due to their greater strength. However, they are still in the working range of the respective loudspeaker and are very loudly audible because the internal damping is only minimal.

Die Aufgabe der Neuerung besteht in der Konzeption einer Membran für elektro-akustische Wandler aus einem Material möglichst geringer Dehn- und Stauchbarkeit, welches die Nachteile bekannter Membranen nicht aufweist.The aim of the innovation is to design a membrane for electro-acoustic transducers made of a material with the lowest possible stretchability and compressibility, which does not have the disadvantages of known membranes.

Als Lösung der gestellten Aufgabe schlägt die Neuerung vor, als Material für die Membranen elektro-akustische Wandler Aluminium-Oxid in kristalliner Form, also Korund, zu verwenden.As a solution to the problem, the innovation proposes using aluminum oxide in crystalline form, i.e. corundum, as the material for the membranes of electro-acoustic transducers.

Aluminium-Oxid in kristalliner Form besitzt nur eine ganz geringe Dehn- und Stauchbarkeit, was bedeutet, daß Membranen mit sehr hoher Steifigkeit hergestellt werden können, darüber hinaus hat sich gezeigt, daßAluminium oxide in crystalline form has only a very low stretchability and compressibility, which means that membranes with very high stiffness can be produced. In addition, it has been shown that

tt (11*1 ····*(11*1 ····*

es möglich ist, beliebig geformte, sehr dünne und damit außerordentlich leichte Membranen herzustellen, deren kleine Masse nur geringe Trägheitskräfte hervorruft. Da hierbei von einem der endgültigen Form der Membran genau entsprechenden Formkörper aus Reinaluminium-Blech ausgegangen werden kann, gibt es hinsichtlich der teilweise recht komplizierten Formgebungen der Membranen keine Schwierigkeiten.it is possible to produce membranes of any shape, very thin and therefore extremely light, whose small mass causes only small inertial forces. As a molded body made of pure aluminum sheet that corresponds exactly to the final shape of the membrane can be used, there are no difficulties with regard to the sometimes very complicated shapes of the membranes.

Die Herstellung einer neuerungsgemaßen Membran geschieht dadurch, daß zunächst ein Formteil aus Reinaluminium zu bilden ist, welches einer anodischen Oxidation unterworfen wird. Durch Brennen bei Temperaturen oberhalt 600 Grad Celsius wandelt sich das Aluminium-Oxid in eine kristalline Modifikation um, das heißt, es entsteht Korund, ein Material, welches dem Formteil die angestrebten Eigenschaften verleiht. The manufacture of a membrane according to the innovation is carried out by first forming a molded part from pure aluminum, which is then subjected to anodic oxidation. By firing at temperatures above 600 degrees Celsius, the aluminum oxide is converted into a crystalline modification, i.e. corundum is created, a material which gives the molded part the desired properties.

Die Neuerung wird nachstehend anhand der beigefügten Zeichnung näher erläutert. In dieser Zeichnung zeigen in vereinfachter schematischer Darstellung:The innovation is explained in more detail below using the attached drawing. This drawing shows a simplified schematic representation:

Fig. 1 ein dünnwandiges Formteil in Gestalt einer Membran für elektro-akustische Wandler in einem Querschnitt;Fig. 1 a thin-walled molded part in the form of a membrane for electro-acoustic transducers in a cross-section;

Fig. 2 die Herstellung des Formteiles gemäß Fig. 1 durch Tiefziehen aus Reinaluminium-Blech; Fig. 2 the production of the molded part according to Fig. 1 by deep drawing from pure aluminum sheet;

t tt t

t i'i iir »lii- int i'i iir »lii- in

Flg. 3 das Entfetten und Abspülen des durchFlg. 3 Degreasing and rinsing of the

Tiefziehen gebildeten Formteiles;deep drawing formed part;

Fig. 4 die Reinigung und das Anätzen des entfetteten Formteiles;Fig. 4 the cleaning and etching of the degreased molded part;

Fig. 5 die Neutralisierung des gereinigtenFig. 5 the neutralization of the purified

Formteiles JMoulded part J

Fig. 6 die anodische Oxidation des FormteilesFig. 6 the anodic oxidation of the molded part

mit Gleichstrom;with direct current;

Fig. 7 das Brennen des anodisch oxidierten Formteiles bei Temperaturen über 600 Grad Celsius.Fig. 7 the firing of the anodically oxidized molded part at temperatures above 600 degrees Celsius.

Bei dem in Figur 1 beispielhaft dargestellten, dünnwandigen Formteil 1 handelt es sich um eine Membran für einen eiektro-akustischen Wandler, nämlich eine Lautsprechermembran. Das Formteil 1 ist nahtlos aus einem dünnen Reinaluminium-Blech (Reinheit 99,95 %) mit einer Dicke von 0,1 Millimeter gebildet und besteht aus einem kreisringförmigön Einspannrand 2, einem flachkegeligen Trichter 3 sowie einem zylindrischen Schwingspulenhalter 4. Der Einspannrand 2 kann Sicken aufweisen, die in der Zeichnung aber nicht dargestellt sind.The thin-walled molded part 1 shown as an example in Figure 1 is a membrane for an electro-acoustic transducer, namely a loudspeaker membrane. The molded part 1 is seamlessly formed from a thin pure aluminum sheet (purity 99.95 %) with a thickness of 0.1 millimeters and consists of a circular clamping edge 2, a flat-conical funnel 3 and a cylindrical voice coil holder 4. The clamping edge 2 can have beads, which are not shown in the drawing.

Das Formteil 1 wird - wie Figur 2 verdeutlicht - durch Tiefziehen hergestellt. Hierzu wird die leicht einge-QQ fettete Platine aus Reinaluminium-Blech auf die Form 5 gelegt und am späteren Einspannrand 2 durch den Niederhalter 6 festgehalten. Mit dem Stempel 7 findet die Verformung der Platine zu dem Formteil 1 statt»The molded part 1 is produced by deep drawing, as shown in Figure 2. To do this, the lightly greased plate made of pure aluminum sheet is placed on the mold 5 and held in place at the later clamping edge 2 by the hold-down device 6. The plate is deformed into the molded part 1 using the stamp 7.

gg Das solchermaßen durch Tiefziehen aus Reinaluminium ge-gg The thus formed by deep drawing from pure aluminium

&ngr; &igr; &igr;&ngr;&igr;&igr;

bildete Formteil 1 wird - vgl. Figur 3 - in einer Tetrachlorkohlenstoff (CCI4) enthaltenden Wanne 8 durch mehrmaliges Gintauchen entfettet und abgespült.The molded part 1 formed is degreased and rinsed by repeated immersion in a tank 8 containing carbon tetrachloride (CCl4) - see Figure 3.

Das entfettete Formteil 1 wird anschließend durch Einbringen in ein Gefäß 9 mit Natronlauge (NaOH) von anhaftenden Oxidschichten und Schmutz gereinigt und zugleich angeätzt - siehe Figur 4.The degreased molded part 1 is then cleaned of adhering oxide layers and dirt by placing it in a vessel 9 with sodium hydroxide solution (NaOH) and at the same time etched - see Figure 4.

Die Reste der am Formteil 1 noch anhaftenden Natronlauge werden durch Einbringen in das mit verdünnter Salpetersäure (NO3H) gefüllte Becken 10 neutralisierteThe residues of the caustic soda still adhering to the molded part 1 are neutralized by introducing them into the tank 10 filled with diluted nitric acid (NO3H).

Das wie beschrieben vorbereitete Formteil 1 wird jetzt einer anodischen Oxidation unterworfen - vgl. Figur 6. &bgr; In einem Trog 11 befindet sich Oxalsäure oder B · Ameisensäure in welche das Formteil 1 gehängt wird.The molded part 1 prepared as described is now subjected to anodic oxidation - see Figure 6. In a trough 11 there is oxalic acid or B formic acid in which the molded part 1 is suspended.

Im Trog 11 befindet sich eine als Kathode dienende Reinaluminium-Platte 12. Das die Anode bildende Formteil 1 sowie die Reinaluminium-Platte 12 sind mittels elektrischer Leitungen 13 über ein Amperemeter 14 mit einer Gleichstromquelle 15 verbunden.In the trough 11 there is a pure aluminum plate 12 serving as a cathode. The molded part 1 forming the anode and the pure aluminum plate 12 are connected to a direct current source 15 by means of electrical lines 13 via an ammeter 14.

Die Elektrolyse (bei welcher sich Wasserstoff (H) entwickelt) wird im Trog 11 bei einer Stromstärke von etwa 1 Ampere je Quadratdezimeter der Oberfläche des Formteiles 1 solange durchgeführt, bis letzteres durchscheinend geworden ist - dies ist leicht zu beobachten - und die am Amperemeter 14 angezeigte Stromstärke auf den hundertsten Teil , auf etwa IO Milliampere pro Quadratdezimeter, gefallen ist. Aus dem ursprünglichen Reinaluminium (Al) des Formteiles 1 ist dann Aluminium-Oxid (AI2O3) in überwiegena amorpher Modifikation (mit einge·= lagertem Kristallwasser und Verunreinigungen durch die vorangegangenen Behandlungen mit den Säuren) entstanden.The electrolysis (during which hydrogen (H) is developed) is carried out in the trough 11 at a current of about 1 ampere per square decimetre of the surface of the moulded part 1 until the latter has become transparent - this is easy to observe - and the current indicated on the ammeter 14 has fallen to a hundredth, to about 10 milliamperes per square decimetre. The original pure aluminium (Al) of the moulded part 1 then becomes aluminium oxide (AI2O3) in a predominantly amorphous modification (with embedded water of crystallisation and impurities from the previous treatments with the acids).

Il ItIl It

&igr; &igr; &igr;&igr;&igr;&igr;

.+ 6 V I.+ 6 V I

Als letzter Schritt wird nun das aus amorphem Aluminium- i Oxid bestehende Formteil 1 in einen Brennofen einge- ?As a final step, the molded part 1 consisting of amorphous aluminum oxide is placed in a kiln.

setzt und dort solange Temperaturen von wenigstens 600 | Grad Celsius ausgesetzt, bis das (amorphe) Aluminium- [·and exposed to temperatures of at least 600 | degrees Celsius until the (amorphous) aluminium [·

5 Oxid (AI2O3) des Formteiles 1 sich in eine kri- j5 oxide (AI2O3) of the molded part 1 into a kri- j

stalline Modifikation umgewandelt hat. Durch das Brennen ; ist dann der harte und spröde, chemisch beständige und hoch isolierende Stoff Korund mit einem spezifischen Gewicht von etwa 3,9 entstanden. Bis auf das durch das Brennen unvermeidliche Schwinden ist das nunmehr aus Korund bestehende Formteil 1 mit demjenigen aus Reinaluminium gebildeten identisch.stalline modification. The firing process then produced the hard and brittle, chemically resistant and highly insulating material corundum with a specific weight of about 3.9. Except for the shrinkage that is inevitable due to the firing, the molded part 1 now made of corundum is identical to the one made of pure aluminum.

Ct(I &iacgr; CCt(I Î C

[ t &iacgr; &iacgr;[ t &iacgr;&iacgr;

1 B 3337/85 Gbm1 B 3337/85 Gbm

21. November 198521 November 1985

Zusammenstellung der benutzten Bezuqsziffern List of reference numbers used

1010 11 Formteilmolded part •• 22 EinspannrandClamping edge 33 Trichterfunnel 44 SchwingspulenhalterVoice coil holder 55 Formshape 2525 55 NiederhalterHold-down clamp 77 StempelRubber stamp 88th WanneTub 99 Gefäßvessel 1010 Beckenpool 2020 1111 Trogtrough 1212 Reinaluminium-PlattePure aluminum plate 1313 Leitungencables 1414 Amperemeterammeter 1515 GleichstromquelleDC source 2525 1616 Brennofenkiln

« ■ »ttt t t I t If(I '« ■ »ttt t t I t If(I '

* · * I Ii* · * I Ii

Claims (1)

. I 1 i I H ·'·. I 1 i IH ·'· &igr; * a &igr;&igr; * a &igr; i I · ■ 1 Il I I ·i I · ■ 1 Il I I · 1 B 3337/85 Gbm1 B 3337/85 Gbm 21. November 198521 November 1985 10 Schutzanspruch 10 Right to protection Membran für elektro-akustische Wandler aus einem wenig dehn- und stauchbaren Material, bestehend aus 15 Aluminium-Oxid in kristalliner Form.Membrane for electro-acoustic transducers made of a material with low stretch and compression, consisting of 15 aluminum oxide in crystalline form. im it·in it·
DE8533598U 1985-11-29 1985-11-29 Membrane for electro-acoustic transducers Expired DE8533598U1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19853542202 DE3542202A1 (en) 1985-11-29 1985-11-29 METHOD FOR PRODUCING SINGLE-WALLED MOLDED PARTS FROM CERAMIC AND MEMBRANE FOR SOUND TRANSDUCER RECEIVED BY THE METHOD
DE19853546548 DE3546548A1 (en) 1985-11-29 1985-11-29 Membrane for sound converters (transducers)

Publications (1)

Publication Number Publication Date
DE8533598U1 true DE8533598U1 (en) 1987-04-02

Family

ID=25838313

Family Applications (3)

Application Number Title Priority Date Filing Date
DE19853542202 Granted DE3542202A1 (en) 1985-11-29 1985-11-29 METHOD FOR PRODUCING SINGLE-WALLED MOLDED PARTS FROM CERAMIC AND MEMBRANE FOR SOUND TRANSDUCER RECEIVED BY THE METHOD
DE8533598U Expired DE8533598U1 (en) 1985-11-29 1985-11-29 Membrane for electro-acoustic transducers
DE19853546548 Granted DE3546548A1 (en) 1985-11-29 1985-11-29 Membrane for sound converters (transducers)

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE19853542202 Granted DE3542202A1 (en) 1985-11-29 1985-11-29 METHOD FOR PRODUCING SINGLE-WALLED MOLDED PARTS FROM CERAMIC AND MEMBRANE FOR SOUND TRANSDUCER RECEIVED BY THE METHOD

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE19853546548 Granted DE3546548A1 (en) 1985-11-29 1985-11-29 Membrane for sound converters (transducers)

Country Status (3)

Country Link
EP (1) EP0224087A3 (en)
JP (1) JPS62153161A (en)
DE (3) DE3542202A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19504453C1 (en) * 1995-02-10 1996-01-25 Maxs Ag Prodn. of membrane for electro-acoustic converter

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE463816B (en) * 1988-03-25 1991-01-28 Erik Sundstroem METHOD FOR THE PREPARATION OF THE LIQUID DIVISION BODY FOR HEAT GAS consisting of a body of ALFA corundum, and the corresponding LIQUID DIVISION BODY
DE4419251A1 (en) * 1994-06-01 1995-12-07 Nokia Deutschland Gmbh speaker
ATE383638T1 (en) * 2003-09-26 2008-01-15 Bocingo S L HORN
DE102006005474A1 (en) * 2006-01-27 2007-08-02 Michael Loos Making ceramic loudspeaker cone for medium and low frequencies, casts slip optionally aided by electrophoretic precipitation, extracts green cone, fires then sinters
DE102016220845B4 (en) 2016-10-24 2022-12-08 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Process for forming ceramic and/or powder-metallurgical green sheets

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Publication number Priority date Publication date Assignee Title
DE1095622B (en) * 1955-12-02 1960-12-22 Vaw Ver Aluminium Werke Ag Process for pretreatment of workpieces made of aluminum or aluminum alloys for the production of high-gloss, anodically oxidized surfaces
JPS544920B2 (en) * 1971-12-09 1979-03-12
GB1460622A (en) * 1974-05-07 1977-01-06 Rikagaku Kenkyusho Production of moisture sensitive elements
GB1557690A (en) * 1976-01-01 1979-12-12 Riken Keikinzoku Kogyo Kk Electrolytically produced coloured aluminium oxide
DE2742637A1 (en) * 1977-09-22 1979-04-05 Oberflaechenveredelung Uhl Gmb Pretreatment of aluminium profiles and sheets before anodising - by sand blasting and etching with sodium hydroxide soln.
JPS5916814A (en) * 1982-07-16 1984-01-28 Lion Corp Composition for oral cavity
JPS5978986A (en) * 1982-10-28 1984-05-08 日産自動車株式会社 Manufacture of ceramic parts
JPS59218096A (en) * 1983-05-26 1984-12-08 Mitsubishi Electric Corp Manufacture of diaphragm for speaker
JPS60159195A (en) * 1984-01-30 1985-08-20 Pentel Kk Thin film body of aluminum oxide
JPS60171262A (en) * 1984-02-16 1985-09-04 ダイセル化学工業株式会社 Manufacture of inorganic sheet material
JPS60235609A (en) * 1984-05-08 1985-11-22 Nippon Koki Kk Preparation of ion permselective membrane
JPS61266343A (en) * 1985-05-20 1986-11-26 三菱レイヨン株式会社 Manufacture of ceramic sintered body

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19504453C1 (en) * 1995-02-10 1996-01-25 Maxs Ag Prodn. of membrane for electro-acoustic converter

Also Published As

Publication number Publication date
JPS62153161A (en) 1987-07-08
EP0224087A3 (en) 1989-05-31
DE3542202A1 (en) 1987-06-04
DE3546548C2 (en) 1988-07-07
DE3546548A1 (en) 1987-08-13
EP0224087A2 (en) 1987-06-03
DE3542202C2 (en) 1988-12-15

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