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DE69933558D1 - Zusammensetzung und verfahren zur vermeidung der polymerisation von aromatischen vinyl polymeren - Google Patents

Zusammensetzung und verfahren zur vermeidung der polymerisation von aromatischen vinyl polymeren

Info

Publication number
DE69933558D1
DE69933558D1 DE69933558T DE69933558T DE69933558D1 DE 69933558 D1 DE69933558 D1 DE 69933558D1 DE 69933558 T DE69933558 T DE 69933558T DE 69933558 T DE69933558 T DE 69933558T DE 69933558 D1 DE69933558 D1 DE 69933558D1
Authority
DE
Germany
Prior art keywords
polymerization
avoiding
composition
aromatic vinyl
vinyl polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69933558T
Other languages
English (en)
Other versions
DE69933558T2 (de
Inventor
B Arhancet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Veolia WTS USA Inc
Original Assignee
BetzDearborn Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BetzDearborn Inc filed Critical BetzDearborn Inc
Publication of DE69933558D1 publication Critical patent/DE69933558D1/de
Application granted granted Critical
Publication of DE69933558T2 publication Critical patent/DE69933558T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02—Monomers containing only one unsaturated aliphatic radical
    • C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06—Hydrocarbons
    • C08F112/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B63/00—Purification; Separation; Stabilisation; Use of additives
    • C07B63/04—Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • C07C15/46—Styrene; Ring-alkylated styrenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/38—Separation; Purification; Stabilisation; Use of additives
    • C07C17/42—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/24—Halogenated aromatic hydrocarbons with unsaturated side chains
    • C07C25/28—Halogenated styrenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
    • C07C49/683—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings having unsaturation outside the aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/12—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing sulfur and oxygen
    • C09K15/14—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing sulfur and oxygen containing a phenol or quinone moiety
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/20—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerisation Methods In General (AREA)
DE69933558T 1998-03-25 1999-02-10 Zusammensetzung und verfahren zur vermeidung der polymerisation von aromatischen vinylpolymeren Expired - Lifetime DE69933558T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/047,551 US6024894A (en) 1998-03-25 1998-03-25 Compositions and methods for inhibiting vinyl aromatic monomer polymerization
US47551 1998-03-25
PCT/US1999/002926 WO1999048996A1 (en) 1998-03-25 1999-02-10 Compositions and methods for inhibiting vinyl aromatic monomer polymerization

Publications (2)

Publication Number Publication Date
DE69933558D1 true DE69933558D1 (de) 2006-11-23
DE69933558T2 DE69933558T2 (de) 2007-06-21

Family

ID=21949626

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69933558T Expired - Lifetime DE69933558T2 (de) 1998-03-25 1999-02-10 Zusammensetzung und verfahren zur vermeidung der polymerisation von aromatischen vinylpolymeren

Country Status (10)

Country Link
US (1) US6024894A (de)
EP (1) EP1086192B1 (de)
KR (1) KR100713764B1 (de)
AR (1) AR017985A1 (de)
BR (1) BR9909042B1 (de)
CA (1) CA2323870C (de)
DE (1) DE69933558T2 (de)
ES (1) ES2270584T3 (de)
TW (1) TW539681B (de)
WO (1) WO1999048996A1 (de)

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CA2343022A1 (en) * 1998-09-09 2000-03-16 Baker Hughes Incorporated Vinyl monomer polymerization inhibition using hindered hydroxylamines
WO2000042079A1 (en) * 1999-01-19 2000-07-20 Angus Chemical Company Sterically-hindered alkyl hydroxylamines for scavenging of free radicals
US6685823B2 (en) * 2000-10-16 2004-02-03 Uniroyal Chemical Company, Inc. C-nitrosoaniline compounds and their blends as polymerization inhibitors
US6689926B2 (en) 2002-02-12 2004-02-10 Fina Technology, Inc. Process for purifying styrene monomer feedstock prior to polymerization
US6960279B2 (en) * 2002-05-06 2005-11-01 Fina Technology, Inc. Method for stabilizing vinyl aromatic monomers using selected polymerization inhibitors and polymers prepared therewith
US6926820B2 (en) * 2002-09-20 2005-08-09 G.E. Betz, Inc. Inhibition of viscosity increase and fouling in hydrocarbon streams including unsaturation
JP4790414B2 (ja) * 2003-03-17 2011-10-12 伯東株式会社 芳香族ビニル化合物の重合抑制剤および重合抑制方法
US7128826B2 (en) * 2003-07-31 2006-10-31 General Electric Company Polymerization inhibitor for styrene dehydrogenation units
US7651635B1 (en) 2009-02-05 2010-01-26 Nalco Company Polymer inhibition of vinyl aromatic monomers using a quinone methide/alkyl hydroxylamine combination
US8298440B2 (en) 2010-06-03 2012-10-30 General Electric Company Methods and compositions for inhibiting vinyl aromatic monomer polymerization
US9090526B2 (en) * 2011-06-13 2015-07-28 Nalco Company Synergistic combination for inhibiting polymerization of vinyl monomers
US8884038B2 (en) 2011-06-13 2014-11-11 Nalco Company Synthesis of 7-acetyleno quinone methide derivatives and their application as vinylic polymerization retarders
US9206268B2 (en) 2011-09-16 2015-12-08 General Electric Company Methods and compositions for inhibiting polystyrene formation during styrene production
US8901362B2 (en) 2012-02-02 2014-12-02 General Electric Company Methods and compositions for styrene inhibition via in situ generation of quinone methides
JP6043937B2 (ja) * 2012-08-16 2016-12-14 株式会社片山化学工業研究所 ビニル芳香族モノマーの重合を抑制するための組成物
WO2014030131A1 (en) 2012-08-24 2014-02-27 Dorf Ketal Chemicals (India) Private Limited Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof
US10869444B2 (en) * 2018-07-13 2020-12-22 Ecolab Usa Inc. Compositions of oxygenated amines and quinone methides as antifoulants for vinylic monomers
ES2971105T3 (es) 2018-07-13 2024-06-03 Ecolab Usa Inc Composición para inhibir la polimerización de monómeros que comprende un inhibidor de nitróxido, un retardante de metida de quinona y un estabilizador de amina
KR20210068020A (ko) 2018-09-28 2021-06-08 에코랍 유에스에이 인코퍼레이티드 아미노-퀴논 중합방지제 및 이의 사용 방법
TW202114976A (zh) * 2019-10-11 2021-04-16 美商藝康美國公司 醌甲基化物及銨鹽抗聚合劑組合物及方法
WO2022182612A1 (en) * 2021-02-26 2022-09-01 Bl Technologies, Inc. Composition and method for inhibiting the formation and growth of popcorn polymers

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2965685A (en) * 1958-06-24 1960-12-20 Monsanto Chemicals Polymerization inhibitor
DE2028183B2 (de) * 1969-06-10 1975-09-11 Rohm And Haas Co., Philadelphia, Pa. (V.St.A.) Verfahren zur Inhibierung der Polymerisation von Acrylsäure bei der Destillation
GB1346774A (en) * 1970-10-05 1974-02-13 Bp Chem Int Ltd Stabilisation of acrylonitrile
US3733326A (en) * 1971-03-10 1973-05-15 Sankyo Co Inhibition of the polymerization of vinyl monomers
US4040911A (en) * 1976-01-02 1977-08-09 Gulf Research & Development Company Process for inhibiting the polymerization of styrene
US4003800A (en) * 1976-01-02 1977-01-18 Gulf Research & Development Company Styrene purification process
US4105506A (en) * 1977-02-24 1978-08-08 Cosden Technology, Inc. Polymerization inhibitor for vinyl aromatic compounds
US4237326A (en) * 1979-05-30 1980-12-02 Mitsubishi Petrochemical Company Limited Method of inhibiting polymerization of styrene
US4376678A (en) * 1982-07-29 1983-03-15 American Hoechst Corporation Method of inhibiting polymerization of vinyl aromatic compounds
US4409408A (en) * 1982-09-24 1983-10-11 Atlantic Richfield Company Inhibiting polymerization of vinyl aromatic monomers
US4434307A (en) * 1982-12-27 1984-02-28 Atlantic Richfield Company Inhibiting polymerization of vinyl aromatic monomers
US4466905A (en) * 1983-04-11 1984-08-21 Cosden Technology, Inc. Polymerization inhibition process for vinyl aromatic compounds
US4670131A (en) * 1986-01-13 1987-06-02 Exxon Chemical Patents Inc. Method for controlling fouling of hydrocarbon compositions containing olefinic compounds
DE3611764A1 (de) * 1986-04-08 1987-10-15 Bernd Kellner Vakuum-sonnenkollektor
US4720566A (en) * 1986-10-23 1988-01-19 Betz Laboratories, Inc. Method and composition for inhibiting acrylonitrile polymerization
US4885413A (en) * 1987-05-20 1989-12-05 Borg-Warner Chemicals, Inc. Process and composition for stabilization of ar-brominated styrenic monmer against premature stabilization
US4774374A (en) * 1987-06-12 1988-09-27 Uniroyal Chemical Company, Inc. Stabilized vinyl aromatic composition
US4956020A (en) * 1989-04-28 1990-09-11 Hakuto Chemical Co., Ltd. Inhibiting popcorn polymer growth
US5312952A (en) * 1992-04-23 1994-05-17 Uniroyal Chemical Company, Inc. Polymerization inhibitor for vinyl aromatics
US5254760A (en) * 1992-07-29 1993-10-19 Ciba-Geigy Corporation Inhibiting polymerization of vinyl aromatic monomers
US5282957A (en) * 1992-08-19 1994-02-01 Betz Laboratories, Inc. Methods for inhibiting polymerization of hydrocarbons utilizing a hydroxyalkylhydroxylamine
CA2099168A1 (en) * 1992-10-21 1994-04-22 Betzdearborn Inc. Compositions and methods for inhibiting styrene polymerization
ES2096220T3 (es) * 1992-10-21 1997-03-01 Betz Europ Inc Composiciones y metodos para inhibir la polimerizacion de monomeros vinil-aromaticos.
US5470440A (en) * 1994-04-19 1995-11-28 Betz Laboratories, Inc. Method for inhibiting vinyl aromatic monomer polymerization
US5426257A (en) * 1994-06-30 1995-06-20 Betz Laboratories, Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
US5446220A (en) * 1994-08-24 1995-08-29 Betz Laboratories, Inc. Methods for inhibiting vinyl aromatic monomer polymerization
US5489720A (en) * 1994-06-30 1996-02-06 Betz Laboratories, Inc. Methods for inhibiting vinyl aromatic monomer polymerization
US5545786C1 (en) * 1994-11-28 2001-10-16 Ciba Geigy Corp Method for inhibiting premature polymerization of vinyl aromatic monomers
US5583247A (en) * 1995-04-14 1996-12-10 Ciba-Geigy Corporation 7-substituted quinone methides as inhibitors for unsaturated monomers
US5616774A (en) * 1995-04-14 1997-04-01 Ciba-Geigy Corporation Inhibition of unsaturated monomers with 7-aryl quinone methides
US5648573A (en) * 1995-06-12 1997-07-15 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
US5627248A (en) * 1995-09-26 1997-05-06 The Dow Chemical Company Difunctional living free radical polymerization initiators

Also Published As

Publication number Publication date
EP1086192B1 (de) 2006-10-11
EP1086192A1 (de) 2001-03-28
CA2323870A1 (en) 1999-09-30
BR9909042A (pt) 2000-12-05
EP1086192A4 (de) 2005-02-09
US6024894A (en) 2000-02-15
TW539681B (en) 2003-07-01
AR017985A1 (es) 2001-10-24
ES2270584T3 (es) 2007-04-01
CA2323870C (en) 2005-11-08
KR20010034636A (ko) 2001-04-25
BR9909042B1 (pt) 2009-05-05
WO1999048996A1 (en) 1999-09-30
DE69933558T2 (de) 2007-06-21
KR100713764B1 (ko) 2007-05-07

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