DE69812616T2 - Vinylacetatverfahren mit anwendung eines palladium-gold-kupfer katalysators - Google Patents

Vinylacetatverfahren mit anwendung eines palladium-gold-kupfer katalysators Download PDF

Info

Publication number: DE69812616T2
Authority: DE; Germany
Prior art keywords: vinyl acetate; copper catalyst; gold copper; palladium gold; acetate process
Prior art date: 1997-06-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

DE69812616T

Other languages

English (en)

Other versions

DE69812616D1 (de

Inventor

Ioan Nicolau

Jerry A Broussard

M Colling

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Celanese International Corp

Original Assignee

Celanese International Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1997-06-03

Filing date

1998-05-15

Publication date

2004-01-15

1998-05-15 Application filed by Celanese International Corp filed Critical Celanese International Corp

2003-04-30 Application granted granted Critical

2003-04-30 Publication of DE69812616D1 publication Critical patent/DE69812616D1/de

2004-01-15 Publication of DE69812616T2 publication Critical patent/DE69812616T2/de

2018-05-16 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Catalysts (AREA)

DE69812616T 1997-06-03 1998-05-15 Vinylacetatverfahren mit anwendung eines palladium-gold-kupfer katalysators Expired - Lifetime DE69812616T2 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US08/870,120 US5731457A (en)	1997-06-03	1997-06-03	Vinyl acetate process utilizing a palladium-gold-copper catalyst
PCT/US1998/009984 WO1998055443A1 (en)	1997-06-03	1998-05-15	Vinyl acetate process utilizing a palladium-gold-copper catalyst

Publications (2)

Publication Number	Publication Date
DE69812616D1 DE69812616D1 (de)	2003-04-30
DE69812616T2 true DE69812616T2 (de)	2004-01-15

Family

ID=25354822

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE69812616T Expired - Lifetime DE69812616T2 (de)	1997-06-03	1998-05-15	Vinylacetatverfahren mit anwendung eines palladium-gold-kupfer katalysators

Country Status (28)

Country	Link
US (1)	US5731457A (de)
EP (1)	EP0988275B1 (de)
JP (1)	JP4377458B2 (de)
KR (1)	KR100556010B1 (de)
CN (1)	CN1127472C (de)
AR (1)	AR015845A1 (de)
AT (1)	ATE235454T1 (de)
AU (1)	AU731821B2 (de)
BR (1)	BR9809190A (de)
CA (1)	CA2292651C (de)
CZ (1)	CZ295009B6 (de)
DE (1)	DE69812616T2 (de)
ES (1)	ES2195336T3 (de)
HU (1)	HUP0004244A1 (de)
ID (1)	ID23033A (de)
MY (1)	MY117131A (de)
NO (1)	NO312719B1 (de)
NZ (1)	NZ501496A (de)
PE (1)	PE94699A1 (de)
PL (1)	PL337163A1 (de)
RU (1)	RU2194036C2 (de)
SK (1)	SK164699A3 (de)
TR (1)	TR199903008T2 (de)
TW (1)	TW389753B (de)
UA (1)	UA56239C2 (de)
WO (1)	WO1998055443A1 (de)
YU (1)	YU49182B (de)
ZA (1)	ZA984726B (de)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6034030A (en) *	1994-02-22	2000-03-07	Celanese International Corporation	Vinyl acetate catalyst preparation method
US5968869A (en) *	1997-06-03	1999-10-19	Celanese International Corporation	Vinyl acetate catalyst comprising palladium and gold deposited on a copper containing carrier
US5948724A (en) *	1997-10-28	1999-09-07	Celanese International Corporation	Vinyl acetate catalyst comprising metallic palladium and gold and cupric acetate
US6072078A (en) *	1997-12-12	2000-06-06	Celanese International Corporation	Vinyl acetate production using a catalyst comprising palladium, gold, copper and any of certain fourth metals
US6017847A (en) *	1998-06-02	2000-01-25	Celanese International Corporation	Vinyl acetate catalyst prepared with potassium aurate and comprising metallic palladium and gold on a carrier precoated with copper
US6015769A (en) *	1998-06-02	2000-01-18	Celanese International Corporation	Vinyl acetate catalyst comprising metallic palladium, gold and copper supported on a carrier and prepared with potassium aurate
TW487598B (en) *	1999-08-30	2002-05-21	Dairen Chemical Corp	Catalyst for oxacylation and process for producing the same
US6303537B1 (en) *	1999-11-17	2001-10-16	Celanese International Corporation	Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication
TW200539941A (en)	2003-12-19	2005-12-16	Celanese Int Corp	Methods of making alkenyl alkanoates
US7468455B2 (en) *	2004-11-03	2008-12-23	Velocys, Inc.	Process and apparatus for improved methods for making vinyl acetate monomer (VAM)
AU2005319574B2 (en)	2004-12-20	2009-09-24	Celanese International Corporation	Modified support materials for catalysts
TW202204039A (zh)	2020-06-11	2022-02-01	美商瑟蘭斯國際股份有限公司	用於乙酸乙烯酯製造之催化劑的製備方法
JP7517468B2 (ja) *	2020-11-27	2024-07-17	株式会社レゾナック	酢酸ビニル製造用触媒の製造方法及び酢酸ビニルの製造方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1296138B (de) *	1967-03-03	1969-05-29	Hoechst Ag	Verfahren zur Herstellung von Carbonsaeurevinylestern
NL167680C (nl) *	1968-07-19	1982-01-18	Hoechst Ag	Werkwijze voor het bereiden van allylesters van carbonzuren uit propeen, zuurstof en carbonzuur.
US5274181A (en) *	1991-05-06	1993-12-28	Bp Chemicals Limited	Catalysts and processes for the manufacture of vinyl acetate
US5185308A (en) *	1991-05-06	1993-02-09	Bp Chemicals Limited	Catalysts and processes for the manufacture of vinyl acetate
DE4120492A1 (de) *	1991-06-21	1992-12-24	Hoechst Ag	Verfahren zur herstellung von vinylacetat
TW330160B (en) *	1992-04-08	1998-04-21	Hoechst Ag	Supported catalyst, process for its preparation and its use for the preparation of vinyl acetate
US5332710A (en) *	1992-10-14	1994-07-26	Hoechst Celanese Corporation	Vinyl acetate catalyst preparation method
US5347046A (en) *	1993-05-25	1994-09-13	Engelhard Corporation	Catalyst and process for using same for the preparation of unsaturated carboxylic acid esters
EP0685449B1 (de) *	1994-06-02	1999-08-18	The Standard Oil Company	Fliessbett-Verfahren zur Acetoxylierung von Äthylen zur Herstellung von Vinylacetat
US5550281A (en) *	1994-06-02	1996-08-27	Cirjak; Larry M.	Fluid bed process for the acetoxylation of ethylene in the production of vinyl acetate
US5688993A (en) *	1995-12-22	1997-11-18	E. I. Du Pont De Nemours And Company	Method for modifying catalyst performance during the gas phase synthesis of vinyl acetate

1997
- 1997-06-03 US US08/870,120 patent/US5731457A/en not_active Expired - Lifetime
1998
- 1998-05-15 KR KR1019997011265A patent/KR100556010B1/ko not_active IP Right Cessation
- 1998-05-15 EP EP98922335A patent/EP0988275B1/de not_active Expired - Lifetime
- 1998-05-15 PL PL98337163A patent/PL337163A1/xx unknown
- 1998-05-15 AT AT98922335T patent/ATE235454T1/de active
- 1998-05-15 ES ES98922335T patent/ES2195336T3/es not_active Expired - Lifetime
- 1998-05-15 CZ CZ19994366A patent/CZ295009B6/cs not_active IP Right Cessation
- 1998-05-15 JP JP50246299A patent/JP4377458B2/ja not_active Expired - Fee Related
- 1998-05-15 CN CN98805739A patent/CN1127472C/zh not_active Expired - Fee Related
- 1998-05-15 RU RU2000100323/04A patent/RU2194036C2/ru not_active IP Right Cessation
- 1998-05-15 WO PCT/US1998/009984 patent/WO1998055443A1/en active IP Right Grant
- 1998-05-15 ID IDW991451A patent/ID23033A/id unknown
- 1998-05-15 HU HU0004244A patent/HUP0004244A1/hu unknown
- 1998-05-15 UA UA99126570A patent/UA56239C2/uk unknown
- 1998-05-15 DE DE69812616T patent/DE69812616T2/de not_active Expired - Lifetime
- 1998-05-15 BR BR9809190-5A patent/BR9809190A/pt not_active IP Right Cessation
- 1998-05-15 TR TR1999/03008T patent/TR199903008T2/xx unknown
- 1998-05-15 NZ NZ501496A patent/NZ501496A/en not_active IP Right Cessation
- 1998-05-15 AU AU74908/98A patent/AU731821B2/en not_active Ceased
- 1998-05-15 SK SK1646-99A patent/SK164699A3/sk unknown
- 1998-05-15 CA CA002292651A patent/CA2292651C/en not_active Expired - Fee Related
- 1998-05-20 TW TW087107819A patent/TW389753B/zh not_active IP Right Cessation
- 1998-06-02 AR ARP980102573A patent/AR015845A1/es active IP Right Grant
- 1998-06-02 ZA ZA9804726A patent/ZA984726B/xx unknown
- 1998-06-02 PE PE1998000444A patent/PE94699A1/es not_active Application Discontinuation
- 1998-06-02 MY MYPI98002468A patent/MY117131A/en unknown
- 1998-06-03 YU YU24598A patent/YU49182B/sh unknown
1999
- 1999-12-01 NO NO19995874A patent/NO312719B1/no not_active IP Right Cessation

Also Published As

Publication number	Publication date
SK164699A3 (en)	2000-06-12
CZ436699A3 (cs)	2000-06-14
NZ501496A (en)	2001-11-30
EP0988275B1 (de)	2003-03-26
AR015845A1 (es)	2001-05-30
AU731821B2 (en)	2001-04-05
UA56239C2 (uk)	2003-05-15
WO1998055443A1 (en)	1998-12-10
NO312719B1 (no)	2002-06-24
ES2195336T3 (es)	2003-12-01
TW389753B (en)	2000-05-11
NO995874L (no)	1999-12-01
BR9809190A (pt)	2000-08-01
JP2002502420A (ja)	2002-01-22
MY117131A (en)	2004-05-31
PE94699A1 (es)	1999-10-05
CN1259115A (zh)	2000-07-05
ATE235454T1 (de)	2003-04-15
US5731457A (en)	1998-03-24
CA2292651A1 (en)	1998-12-10
CA2292651C (en)	2006-06-13
JP4377458B2 (ja)	2009-12-02
YU49182B (sh)	2004-07-15
NO995874D0 (no)	1999-12-01
AU7490898A (en)	1998-12-21
EP0988275A1 (de)	2000-03-29
RU2194036C2 (ru)	2002-12-10
KR100556010B1 (ko)	2006-03-03
ID23033A (id)	2000-01-06
PL337163A1 (en)	2000-07-31
TR199903008T2 (en)	2000-07-21
ZA984726B (en)	1999-12-02
DE69812616D1 (de)	2003-04-30
KR20010013272A (ko)	2001-02-26
CZ295009B6 (cs)	2005-05-18
CN1127472C (zh)	2003-11-12
YU24598A (en)	1999-11-22
HUP0004244A1 (en)	2001-03-28

Publication	Publication Date	Title
ID19559A (id)	1998-07-23	Metode penambahan emas dua tahap untuk pembuatan katalis vinil asetat
ATE283112T1 (de)	2004-12-15	Herstellung eines metallisches palladium, kupfer und gold enthaltenden vinylacetatkatalysators
DE69812616T2 (de)	2004-01-15	Vinylacetatverfahren mit anwendung eines palladium-gold-kupfer katalysators
DE69612127D1 (de)	2001-04-26	Vorrichtung zum verbinden der Abschnitte eines Perforationsstranges
ATE272443T1 (de)	2004-08-15	Vinylacetatkatalysator mit metallischem palladium und gold mit kaliumaurat bereitet
PL340765A1 (en)	2001-02-26	Vinyl acetate catalyst containing palladium, gold, copper and some fourth metals
PL340627A1 (en)	2001-02-12	Method of obtained vinyl acetate using a catalyst containing palladium, gold and predetermined third metals
ID21457A (id)	1999-06-17	Katalis, proses untuk menghasilkan katalis dan proses untuk pembuatan vinil asetat memakai katalis
ZA984729B (en)	1999-12-02	Vinyl acetate catalyst comprising palladium and gold deposited on a copper containing carrier.
ATE284271T1 (de)	2004-12-15	Herstellung eines metallisches palladium, kupfer und gold enthaltenden vinylacetatkatalysators
NO20002147D0 (no)	2000-04-27	FremgangsmÕte for fremstilling av vinylacetat ved anvendelse av katalysator omfattende metallisk palladium og gull samt kupriacetat
PL323489A1 (en)	1998-03-30	Catalyst for use in vinyl acetate production processes
AU2156899A (en)	1999-06-28	Catalyst based on palladium, gold, alkali metal and lanthanoid and process for preparing vinyl acetate
BR9708288A (pt)	1999-08-03	Catalisador de liga coloidal de paládio/ouro para produç o de acetado de vinila
ID22194A (id)	1999-09-16	Metode untuk menghasilkan vinil asetat
ID19959A (id)	1998-08-27	Suatu proses untuk memproduksi polimer-polimer vinil
HUP9902716A3 (en)	2000-05-29	A two step gold compounds addition method for preparing a vinyl acetate catalyst
KR970019415U (ko)	1997-05-26	금속와이어 흡착노즐
ID18355A (id)	1998-04-02	Katalis koloid logam campuran paladium emas untuk memproduksi vinil asetat

Legal Events

Date	Code	Title	Description
2004-04-22	8364	No opposition during term of opposition