DE69726821T2 - Katalysatorsysteme für die Polymerisation und die Copolymerisation von Alpha-Olefinen - Google Patents
Katalysatorsysteme für die Polymerisation und die Copolymerisation von Alpha-Olefinen Download PDFInfo
- Publication number
- DE69726821T2 DE69726821T2 DE69726821T DE69726821T DE69726821T2 DE 69726821 T2 DE69726821 T2 DE 69726821T2 DE 69726821 T DE69726821 T DE 69726821T DE 69726821 T DE69726821 T DE 69726821T DE 69726821 T2 DE69726821 T2 DE 69726821T2
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- Germany
- Prior art keywords
- sup
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- group
- copolymerization
- polymerization
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- 239000003054 catalyst Substances 0.000 title abstract 2
- 239000004711 α-olefin Substances 0.000 title abstract 2
- 238000007334 copolymerization reaction Methods 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 239000002879 Lewis base Substances 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052768 actinide Inorganic materials 0.000 abstract 1
- 150000001255 actinides Chemical class 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000005018 aryl alkenyl group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052747 lanthanoid Inorganic materials 0.000 abstract 1
- 150000002602 lanthanoids Chemical class 0.000 abstract 1
- 150000007527 lewis bases Chemical class 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/146—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of boron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1608—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/49—Hafnium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES9602302 | 1996-10-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69726821D1 DE69726821D1 (de) | 2004-01-29 |
| DE69726821T2 true DE69726821T2 (de) | 2004-10-21 |
Family
ID=8296545
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69726821T Expired - Fee Related DE69726821T2 (de) | 1996-10-30 | 1997-10-30 | Katalysatorsysteme für die Polymerisation und die Copolymerisation von Alpha-Olefinen |
| DE69701306T Expired - Fee Related DE69701306T2 (de) | 1996-10-30 | 1997-10-30 | Organometallische Katalysatoren für die Polymerisation und die Copolymerisation von Alpha-Olefinen |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69701306T Expired - Fee Related DE69701306T2 (de) | 1996-10-30 | 1997-10-30 | Organometallische Katalysatoren für die Polymerisation und die Copolymerisation von Alpha-Olefinen |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5977392A (de) |
| EP (2) | EP0839833B1 (de) |
| JP (3) | JP3340064B2 (de) |
| AT (3) | ATE202121T1 (de) |
| DE (2) | DE69726821T2 (de) |
| ES (2) | ES2142140T3 (de) |
| NO (3) | NO316699B1 (de) |
| PT (3) | PT839833E (de) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3955140B2 (ja) | 1996-10-31 | 2007-08-08 | レプソル・ケミカ・ソシエダ・アノニマ | アルフアオレフインの重合及び共重合用触媒系 |
| EP0856524A1 (de) * | 1997-02-01 | 1998-08-05 | Repsol Quimica S.A. | Heterogene Katalysatorzusammensetzungen zur Polymerisation von Olefinen, Verfahren zu deren Herstellung und deren Verwendung |
| US6489261B1 (en) * | 1997-12-01 | 2002-12-03 | Dsm N.V. | Catalyst composition comprising a reduced transition metal complex and a cocatalyst |
| DE69914012T2 (de) | 1998-04-27 | 2004-12-09 | Repsol Quimica S.A. | Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen |
| DE69916358T2 (de) * | 1998-04-29 | 2005-04-21 | Repsol Quimica Sa | Verfahren und Verwendung von heterogenen Katalysatorbestandteilen für die Olefinpolymerisation |
| WO2002024769A2 (en) * | 2000-09-25 | 2002-03-28 | Basell Technology Company B.V. | Process for the preparation of ethylene polymers with a bis-amido titanium compound |
| GB0102440D0 (en) | 2001-01-31 | 2001-03-14 | Borealis Tech Oy | Catalyst |
| JP2003020416A (ja) | 2001-07-06 | 2003-01-24 | Fuji Photo Film Co Ltd | テトラシアノキノジメタン化合物を対アニオンとした特定構造のシアニン色素化合物及び該シアニン色素化合物を含む光情報記録媒体 |
| KR100690345B1 (ko) * | 2004-09-03 | 2007-03-09 | 주식회사 엘지화학 | 담지 메탈로센 촉매, 그 제조방법 및 이를 이용한폴리올레핀의 제조방법 |
| KR101959519B1 (ko) * | 2016-04-12 | 2019-03-18 | (주)디엔에프 | 전이금속 화합물, 이의 제조방법 및 이를 포함하는 전이금속함유 박막증착용 조성물 |
| CN116410223A (zh) * | 2021-12-31 | 2023-07-11 | 中国石油天然气股份有限公司 | 四芳基乙氧基侧链单茂金属化合物、包含其的催化剂体系及应用进行的聚烯烃合成方法 |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1022382B (de) * | 1956-04-12 | 1958-01-09 | Hoechst Ag | Verfahren zur Polymerisation von niederen Olefinen |
| US3440237A (en) * | 1958-05-22 | 1969-04-22 | Monsanto Co | Production of polyethylene with water-modified ziegler catalyst |
| US3184416A (en) * | 1958-05-22 | 1965-05-18 | Monsanto Co | Production of ziegler polymerization catalysts |
| US4172945A (en) * | 1976-01-14 | 1979-10-30 | E. R. Squibb & Sons, Inc. | Precursors of indanpentol derivatives |
| DE3127133A1 (de) * | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polyolefinen und deren copolymerisaten |
| IL85097A (en) * | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
| US5055438A (en) * | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
| US5064797A (en) * | 1987-04-03 | 1991-11-12 | Phillips Petroleum Company | Process for producing polyolefins and polyolefin catalysts |
| US4939217A (en) * | 1987-04-03 | 1990-07-03 | Phillips Petroleum Company | Process for producing polyolefins and polyolefin catalysts |
| DE3718888A1 (de) * | 1987-06-05 | 1988-12-22 | Hoechst Ag | Verfahren zur herstellung eines 1-olefinpolymers |
| US4925821A (en) * | 1987-12-17 | 1990-05-15 | Exxon Chemical Patents Inc. | Method for utilizing triethyaluminum to prepare an alumoxane support for an active metallocene catalyst |
| US4912075A (en) * | 1987-12-17 | 1990-03-27 | Exxon Chemical Patents Inc. | Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization |
| US4937217A (en) * | 1987-12-17 | 1990-06-26 | Exxon Chemical Patents Inc. | Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst |
| US5008228A (en) * | 1988-03-29 | 1991-04-16 | Exxon Chemical Patents Inc. | Method for preparing a silica gel supported metallocene-alumoxane catalyst |
| US4935397A (en) * | 1988-09-28 | 1990-06-19 | Exxon Chemical Patents Inc. | Supported metallocene-alumoxane catalyst for high pressure polymerization of olefins and a method of preparing and using the same |
| NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| US5057475A (en) * | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
| CA2027123C (en) * | 1989-10-30 | 2001-09-04 | Michael J. Elder | Metallocene catalysts for polymerization of olefins |
| EP1110974B1 (de) * | 1992-08-05 | 2007-11-28 | ExxonMobil Chemical Patents Inc. | Verfahren zur Herstellung von einem geträgertem Aktivatorkomponenten |
| WO1994007928A1 (en) * | 1992-10-02 | 1994-04-14 | The Dow Chemical Company | Supported homogeneous catalyst complexes for olefin polymerization |
| IT1264680B1 (it) * | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori supportati per la polimerizzazione delle olefine |
| MX9500982A (es) * | 1994-02-17 | 1997-02-28 | Union Carbide Chem Plastic | Composicion catalizadora cargada con metaloceno, secada por rociadura para usarse en la fabricacion de poliolefina. |
| US5486632A (en) * | 1994-06-28 | 1996-01-23 | The Dow Chemical Company | Group 4 metal diene complexes and addition polymerization catalysts therefrom |
| DE69502028T2 (de) * | 1994-10-31 | 1998-12-10 | Dsm N.V., Heerlen | Katalytische zusammensetzung und verfahren zur olefinpolymerisation |
| ES2120868B1 (es) * | 1995-08-03 | 2000-09-16 | Repsol Quimica Sa | Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas. |
| US5688880A (en) * | 1995-12-11 | 1997-11-18 | The Dow Chemical Company | Readily supportable metal complexes |
| WO1998016311A1 (en) * | 1996-10-15 | 1998-04-23 | Northwestern University | Phenolate constrained geometry metallocene olefin polymerization catalyst, method of making, and method of using |
-
1997
- 1997-10-30 NO NO19975008A patent/NO316699B1/no unknown
- 1997-10-30 EP EP97500184A patent/EP0839833B1/de not_active Expired - Lifetime
- 1997-10-30 PT PT97500184T patent/PT839833E/pt unknown
- 1997-10-30 EP EP97500186A patent/EP0839835B1/de not_active Expired - Lifetime
- 1997-10-30 ES ES97500186T patent/ES2142140T3/es not_active Expired - Lifetime
- 1997-10-30 JP JP33626397A patent/JP3340064B2/ja not_active Expired - Fee Related
- 1997-10-30 US US08/961,349 patent/US5977392A/en not_active Expired - Fee Related
- 1997-10-30 JP JP9336262A patent/JPH10182716A/ja active Pending
- 1997-10-30 PT PT97500186T patent/PT839835E/pt unknown
- 1997-10-30 DE DE69726821T patent/DE69726821T2/de not_active Expired - Fee Related
- 1997-10-30 PT PT97500185T patent/PT839834E/pt unknown
- 1997-10-30 NO NO19974998A patent/NO317950B1/no not_active IP Right Cessation
- 1997-10-30 AT AT97500185T patent/ATE202121T1/de not_active IP Right Cessation
- 1997-10-30 ES ES97500184T patent/ES2210479T3/es not_active Expired - Lifetime
- 1997-10-30 AT AT97500186T patent/ATE189822T1/de not_active IP Right Cessation
- 1997-10-30 NO NO19975007A patent/NO319295B1/no unknown
- 1997-10-30 JP JP33626197A patent/JP3352374B2/ja not_active Expired - Fee Related
- 1997-10-30 DE DE69701306T patent/DE69701306T2/de not_active Expired - Fee Related
- 1997-10-30 AT AT97500184T patent/ATE256706T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP0839833A3 (de) | 1998-09-02 |
| JPH10182716A (ja) | 1998-07-07 |
| JPH10226710A (ja) | 1998-08-25 |
| EP0839835A1 (de) | 1998-05-06 |
| PT839834E (pt) | 2001-11-30 |
| NO975007L (no) | 1998-05-04 |
| ES2142140T3 (es) | 2000-04-01 |
| DE69701306T2 (de) | 2000-09-14 |
| ES2210479T3 (es) | 2004-07-01 |
| US5977392A (en) | 1999-11-02 |
| JP3340064B2 (ja) | 2002-10-28 |
| PT839835E (pt) | 2000-08-31 |
| EP0839833B1 (de) | 2003-12-17 |
| EP0839835B1 (de) | 2000-02-16 |
| PT839833E (pt) | 2004-05-31 |
| NO974998L (no) | 1998-05-04 |
| NO316699B1 (no) | 2004-03-26 |
| ATE189822T1 (de) | 2000-03-15 |
| NO319295B1 (no) | 2005-07-11 |
| NO975008D0 (no) | 1997-10-30 |
| JPH10226711A (ja) | 1998-08-25 |
| ATE202121T1 (de) | 2001-06-15 |
| EP0839833A2 (de) | 1998-05-06 |
| NO317950B1 (no) | 2005-01-10 |
| NO975007D0 (no) | 1997-10-30 |
| NO975008L (no) | 1998-05-04 |
| JP3352374B2 (ja) | 2002-12-03 |
| DE69726821D1 (de) | 2004-01-29 |
| DE69701306D1 (de) | 2000-03-23 |
| NO974998D0 (no) | 1997-10-30 |
| ATE256706T1 (de) | 2004-01-15 |
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