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DE69529230D1 - Trägerkatalysatorkomponent, Trägerkatalysator, ihre Herstellung und Additionspolymerisationsverfahren - Google Patents

Trägerkatalysatorkomponent, Trägerkatalysator, ihre Herstellung und Additionspolymerisationsverfahren

Info

Publication number
DE69529230D1
DE69529230D1 DE69529230T DE69529230T DE69529230D1 DE 69529230 D1 DE69529230 D1 DE 69529230D1 DE 69529230 T DE69529230 T DE 69529230T DE 69529230 T DE69529230 T DE 69529230T DE 69529230 D1 DE69529230 D1 DE 69529230D1
Authority
DE
Germany
Prior art keywords
supported catalyst
preparation
addition polymerization
catalyst component
polymerization process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69529230T
Other languages
English (en)
Other versions
DE69529230T2 (de
Inventor
B Jacobsen
Lee Spencer
L Wauteraerts
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23335790&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE69529230(D1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of DE69529230D1 publication Critical patent/DE69529230D1/de
Application granted granted Critical
Publication of DE69529230T2 publication Critical patent/DE69529230T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
DE69529230T 1994-11-17 1995-11-02 Trägerkatalysatorkomponent, Trägerkatalysator, ihre Herstellung und Additionspolymerisationsverfahren Expired - Lifetime DE69529230T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US34098994A 1994-11-17 1994-11-17
PCT/US1995/014192 WO1996016092A1 (en) 1994-11-17 1995-11-02 Supported catalyst component, supported catalyst, their preparation, and addition polymerization process

Publications (2)

Publication Number Publication Date
DE69529230D1 true DE69529230D1 (de) 2003-01-30
DE69529230T2 DE69529230T2 (de) 2003-09-04

Family

ID=23335790

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69529230T Expired - Lifetime DE69529230T2 (de) 1994-11-17 1995-11-02 Trägerkatalysatorkomponent, Trägerkatalysator, ihre Herstellung und Additionspolymerisationsverfahren

Country Status (19)

Country Link
EP (1) EP0792297B1 (de)
JP (1) JPH10512902A (de)
CN (1) CN1127524C (de)
AT (1) ATE229987T1 (de)
AU (1) AU699285B2 (de)
BR (1) BR9510354A (de)
CZ (1) CZ293261B6 (de)
DE (1) DE69529230T2 (de)
ES (1) ES2184811T3 (de)
FI (1) FI972110L (de)
MX (1) MX9703592A (de)
MY (1) MY113329A (de)
NO (1) NO315612B1 (de)
NZ (1) NZ296399A (de)
PL (1) PL320255A1 (de)
RU (1) RU2166513C2 (de)
TW (1) TW353083B (de)
WO (1) WO1996016092A1 (de)
ZA (1) ZA959800B (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7153909B2 (en) 1994-11-17 2006-12-26 Dow Global Technologies Inc. High density ethylene homopolymers and blend compositions
US6506866B2 (en) 1994-11-17 2003-01-14 Dow Global Technologies Inc. Ethylene copolymer compositions
US6034024A (en) * 1996-05-10 2000-03-07 Albemarle Corporation Heat treated alumoxanes
WO2000014129A1 (en) * 1998-09-04 2000-03-16 The Dow Chemical Company Long chain branched ethylene homopolymer made by a slurry process and blends thereof
GB9822123D0 (en) 1998-10-09 1998-12-02 Borealis As Catalyst
KR20010033872A (ko) 1998-11-04 2001-04-25 간디 지오프레이 에이치. 올레핀의 중합을 위한 성분 및 촉매
US6432860B1 (en) * 1999-03-22 2002-08-13 Fina Technology, Inc. Supported metallocene catalysts
ES2286890T3 (es) * 1999-07-15 2007-12-01 Dow Global Technologies Inc. Homopolimeros de etileno de alta densidad y composiciones de mezcla.
KR20020012346A (ko) * 2000-08-07 2002-02-16 유현식 신디오탁틱 폴리스티렌을 고수율로 제조하고 반응기부착물을 감소시키는 담지촉매
US7220804B1 (en) 2000-10-13 2007-05-22 Univation Technologies, Llc Method for preparing a catalyst system and its use in a polymerization process
DE60205387T2 (de) 2001-08-17 2006-06-01 Dow Global Technologies, Inc., Midland Bimodale polyethylenzusammensetzung und gegenstände daraus
US7084220B2 (en) * 2003-02-05 2006-08-01 Lg Chem, Ltd. Catalyst system for preparing styrene polymer and method for preparing of styrene polymer using the same
DE10348624A1 (de) * 2003-10-15 2005-05-25 Basell Polyolefine Gmbh Geträgerte Metallalkylverbindung und Verfahren zu deren Herstellung
US7619047B2 (en) * 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
DE102006020486A1 (de) * 2006-04-28 2007-10-31 Basell Polyolefine Gmbh Geträgerte Metallalkylverbindung und Verfahren zur Polymerisation von Olefinen in deren Gegenwart
EP2119732A1 (de) 2008-05-16 2009-11-18 Borealis Technology Oy Metallocen-Katalysator-Zusammensetzungen mit verbesserten Eigenschaften, Verfahren zu ihrer Herstellung und ihre Verwendung zur Herstellung von Polyolefin-Homo- oder Copolymeren
SG173101A1 (en) 2009-01-23 2011-08-29 Evonik Oxeno Gmbh Film
JP5787769B2 (ja) 2009-01-23 2015-09-30 エボニック デグサ ゲーエムベーハーＥｖｏｎｉｋ Ｄｅｇｕｓｓａ ＧｍｂＨ ３置換ｃ４−１０アルケンとのポリオレフィン気相重合
US20120142882A1 (en) 2009-01-23 2012-06-07 Evonik Oxeno Gmbh Pe mib slurry polymerisation
WO2011078923A1 (en) 2009-12-23 2011-06-30 Univation Technologies, Llc Methods for producing catalyst systems
US8975209B2 (en) 2010-05-11 2015-03-10 Tosoh Finechem Corporation Solid support-polymethylaluminoxane complex, method for producing same, olefin polymerization catalyst, and method for producing polyolefin
GB2498936A (en) 2012-01-31 2013-08-07 Norner Innovation As Polyethylene with multi-modal molecular weight distribution

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2538588B2 (ja) * 1987-04-03 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒の製法
DE4139262A1 (de) * 1991-11-29 1993-06-03 Basf Ag Getraegerte katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen
DE4207899A1 (de) * 1992-03-12 1993-09-16 Basf Ag Feststoff, enthaltend chemisch gebundene metallalkylgruppen, und seine verwendung
JPH06100614A (ja) * 1992-08-06 1994-04-12 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびこれを用いるオレフィンの重合方法
TW298593B (de) * 1993-02-12 1997-02-21 Hoechst Ag
DE4336659A1 (de) * 1993-10-27 1995-05-04 Witco Gmbh Verfahren zur Herstellung von Alkylaluminoxanen auf inerten Trägermaterialien
DE59503827D1 (de) * 1994-06-03 1998-11-12 Pcd Polymere Ag Katalysatorträger, geträgerte Metallocenkatalysatoren und deren Verwendung für die Herstellung von Polyolefinen

Also Published As

Publication number Publication date
MX9703592A (es) 1997-08-30
CN1127524C (zh) 2003-11-12
AU699285B2 (en) 1998-11-26
NO315612B1 (no) 2003-09-29
ATE229987T1 (de) 2003-01-15
MY113329A (en) 2002-01-31
EP0792297A1 (de) 1997-09-03
CZ152297A3 (en) 1997-08-13
FI972110A0 (fi) 1997-05-16
CN1164241A (zh) 1997-11-05
RU2166513C2 (ru) 2001-05-10
CZ293261B6 (cs) 2004-03-17
PL320255A1 (en) 1997-09-15
AU4019795A (en) 1996-06-17
EP0792297B1 (de) 2002-12-18
JPH10512902A (ja) 1998-12-08
NO972260D0 (no) 1997-05-16
WO1996016092A1 (en) 1996-05-30
FI972110L (fi) 1997-05-16
BR9510354A (pt) 1997-12-23
NO972260L (no) 1997-07-16
DE69529230T2 (de) 2003-09-04
ES2184811T3 (es) 2003-04-16
ZA959800B (en) 1997-05-19
TW353083B (en) 1999-02-21
NZ296399A (en) 1999-02-25

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Legal Events

Date Code Title Description
8327 Change in the person/name/address of the patent owner

Owner name: DOW GLOBAL TECHNOLOGIES, INC., MIDLAND, MICH., US

8363 Opposition against the patent
8365 Fully valid after opposition proceedings