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DE69501720D1 - Katalysatoren und verfahren zur polymerisierung von olefinen - Google Patents

Katalysatoren und verfahren zur polymerisierung von olefinen

Info

Publication number
DE69501720D1
DE69501720D1 DE69501720T DE69501720T DE69501720D1 DE 69501720 D1 DE69501720 D1 DE 69501720D1 DE 69501720 T DE69501720 T DE 69501720T DE 69501720 T DE69501720 T DE 69501720T DE 69501720 D1 DE69501720 D1 DE 69501720D1
Authority
DE
Germany
Prior art keywords
carbon atoms
alkenyl
alkyl
catalysts
arylalkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69501720T
Other languages
English (en)
Other versions
DE69501720T2 (de
Inventor
Occo Tiziano Dall
Maurizio Galimberti
Luigi Resconi
Enrico Albizzati
Gianni Pennini
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Montell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montell Technology Co BV filed Critical Montell Technology Co BV
Publication of DE69501720D1 publication Critical patent/DE69501720D1/de
Application granted granted Critical
Publication of DE69501720T2 publication Critical patent/DE69501720T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE69501720T 1994-07-20 1995-07-18 Katalysatoren und verfahren zur polymerisierung von olefinen Expired - Fee Related DE69501720T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI941516A IT1273661B (it) 1994-07-20 1994-07-20 Catalizzatori per la polimerizzazione delle olefine
PCT/EP1995/002813 WO1996002580A1 (en) 1994-07-20 1995-07-18 Catalysts and processes for the polymerization of olefins

Publications (2)

Publication Number Publication Date
DE69501720D1 true DE69501720D1 (de) 1998-04-09
DE69501720T2 DE69501720T2 (de) 1998-09-10

Family

ID=11369317

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69501720T Expired - Fee Related DE69501720T2 (de) 1994-07-20 1995-07-18 Katalysatoren und verfahren zur polymerisierung von olefinen

Country Status (25)

Country Link
US (2) US5849653A (de)
EP (1) EP0720627B1 (de)
JP (1) JP3714678B2 (de)
KR (1) KR100356549B1 (de)
CN (1) CN1113899C (de)
AT (1) ATE163653T1 (de)
AU (1) AU695214B2 (de)
BG (1) BG100514A (de)
BR (1) BR9506295A (de)
CA (1) CA2171834A1 (de)
CZ (1) CZ112796A3 (de)
DE (1) DE69501720T2 (de)
ES (1) ES2115391T3 (de)
FI (1) FI961269A (de)
HU (1) HU215264B (de)
IL (1) IL114659A (de)
IT (1) IT1273661B (de)
MX (1) MX9601040A (de)
NO (1) NO308904B1 (de)
PL (1) PL313588A1 (de)
RU (1) RU2155774C2 (de)
SK (1) SK49496A3 (de)
TR (1) TR199500876A2 (de)
WO (1) WO1996002580A1 (de)
ZA (1) ZA955988B (de)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1276752B1 (it) 1995-06-20 1997-11-03 Spherilene S P A Ora Montell I Catalizzatori e procedimenti per la polimerizzazione di olefine
IT1277696B1 (it) * 1995-12-22 1997-11-11 Enichem Spa Catalizzatori per la polimerizzazione di alfa-olefine
JPH10101727A (ja) * 1996-09-24 1998-04-21 Shell Internatl Res Maatschappij Bv オレフィン又はポリマーを水素化するための触媒及び方法
ATE260304T1 (de) * 1996-10-09 2004-03-15 Atofina Res Verfahren zur herstellung und verwendung von meso-racemisch bis(indenyl)ethan-zirconium- dichloridverbindungen
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
ZA989699B (en) * 1997-10-29 1999-04-25 Montell Technology Company Bv Catalysts for the polymerization of olefins and process for the preparation thereof
US6015766A (en) * 1997-12-18 2000-01-18 Mobil Oil Corporation Catalyst systems for olefin polymerization based on metallocene complexes and oligoalkylaluminates with sterically hindered alkyl groups as cocatalysts
US6001766A (en) * 1997-12-24 1999-12-14 Mobil Oil Corporation Bimetallic catalysts for ethylene polymerization reactions activated with paraffin-soluble alkylalumoxanes
DE69907785T2 (de) 1998-03-09 2004-02-12 Basell Poliolefine Italia S.P.A. Mehrstufiges Verfahren zur Olefinpolymerisation
EP1073521A1 (de) * 1998-04-15 2001-02-07 Shell Internationale Researchmaatschappij B.V. Katalysatorsystem zur oligomerisierung von alpha-olefinen
EP0953582A1 (de) * 1998-04-27 1999-11-03 Fina Research S.A. Herstellung von Polyolefin
US6812182B2 (en) 1998-10-23 2004-11-02 Albemarle Corporation Compositions formed from hydroxyaluminoxane and their use as catalyst components
US6555494B2 (en) 1998-10-23 2003-04-29 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions, their preparation and their use as catalyst components
US6492292B2 (en) 1998-10-23 2002-12-10 Albemarle Corporation Gelatinous compositions formed from hydroxyaluminoxane, solid compositions formed therefrom, and the use of such compositions as catalyst components
US6462212B1 (en) 1998-10-23 2002-10-08 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components
US6160145A (en) * 1998-10-23 2000-12-12 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components
EP1860127B1 (de) * 1998-10-27 2011-01-12 Westlake Longview Corporation Verfahren zur Olefinpolymerisation, Polyethylene und daraus hergestellte Folien und Artikel
CA2350542A1 (en) 1998-11-18 2000-05-25 Basell Technology Company B.V. Methylene bridged metallocenes as olefin-polymerization-catalyst components
AU1658600A (en) * 1998-12-15 2000-07-03 Basell Technology Company B.V. Catalyst system for olefin polymerization
ATE252605T1 (de) 1999-03-09 2003-11-15 Basell Polyolefine Gmbh Mehrstufiges verfahren zur (co)polymersation von olefinen
DE60001902T2 (de) 1999-06-04 2003-11-13 Basell Polyolefine Gmbh Verfahren zur herstellung titankomplexen
US6441211B1 (en) 1999-06-07 2002-08-27 Basell Technology Company Bv Preparation of transition-metal-alkyl-complexes carrying a bidentate, dianionic ligand
US6420298B1 (en) 1999-08-31 2002-07-16 Exxonmobil Oil Corporation Metallocene catalyst compositions, processes for making polyolefin resins using such catalyst compositions, and products produced thereby
EP1214364B1 (de) * 1999-09-22 2003-07-16 Basell Polyolefine GmbH Katalysatorsystem unf verfahren zur polymerisierung von olefine
ES2239665T3 (es) 2000-01-18 2005-10-01 Basell Polyolefine Gmbh Procedimiento para producir polimeros aa base de propileno, substancialmente amorfos.
EP1222216B1 (de) 2000-05-24 2004-12-29 Basell Polyolefine GmbH Propylenpolymere und verfahren zur ihrer herstellung
US6673869B2 (en) 2000-07-27 2004-01-06 Basell Poliolefine Italia S.P.A. Transparent elastomeric thermoplastic polyolefin compositions
WO2002024769A2 (en) 2000-09-25 2002-03-28 Basell Technology Company B.V. Process for the preparation of ethylene polymers with a bis-amido titanium compound
EP1265933B1 (de) 2000-12-22 2008-08-13 Basell Polyolefine GmbH Katalysatorkomponente fur die polymerisation von olefinen
CA2451121A1 (en) * 2001-06-20 2003-01-03 Shell Internationale Research Maatschappij B.V. Process for the preparation of oligomers
EP1428840A4 (de) * 2001-08-07 2005-04-06 Denki Kagaku Kogyo Kk Polymerherstellungsverfahren
KR20030087670A (ko) * 2002-05-09 2003-11-15 (주)다사테크 회전기계의 비접촉식 전원공급장치
JP2004149761A (ja) * 2002-09-02 2004-05-27 Sumitomo Chem Co Ltd エチレン重合体
TWI555574B (zh) 2011-03-09 2016-11-01 亞比馬利股份有限公司 含有碳陽離子劑之鋁氧烷催化活性劑及其於聚烯烴催化劑中之用途
RU2510646C2 (ru) * 2012-06-26 2014-04-10 Дэлим Индастриал Ко, Лтд. Металлоценовое соединение, включающая его композиция катализатора и использующий его способ полимеризации олефина
KR102165484B1 (ko) * 2018-05-10 2020-10-14 한화솔루션 주식회사 올레핀 중합 촉매용 전이금속 화합물 및 이를 포함하는 올레핀 중합 촉매
KR20220049731A (ko) 2020-10-15 2022-04-22 에스케이이노베이션 주식회사 폴리프로필렌의 제조방법

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DE2608863A1 (de) * 1976-03-04 1977-09-08 Basf Ag Verfahren zum herstellen von polyaethylen
DE2608933A1 (de) * 1976-03-04 1977-09-08 Basf Ag Verfahren zum herstellen von polyaethylen
DE3127133A1 (de) * 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von polyolefinen und deren copolymerisaten
DE3424697C2 (de) * 1984-07-05 1999-07-08 Targor Gmbh Verfahren zur Polymerisation von Ethylen oder von Mischungen von Ethylen mit anderen 1-Olefinen
MY103812A (en) * 1988-02-12 1993-09-30 Mitsui Chemicals Inc Olefin polymerization catalyst and process for the polymerization of olefins.
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IT1237398B (it) * 1989-01-31 1993-06-01 Ausimont Srl Catalizzatori per la polimerizzazione di olefine.
US5321107A (en) * 1989-01-31 1994-06-14 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
DE3922546A1 (de) * 1989-07-08 1991-01-17 Hoechst Ag Verfahren zur herstellung von cycloolefinpolymeren
ATE173746T1 (de) * 1991-02-27 1998-12-15 Ticona Gmbh Verfahren zur herstellung von cycloolefin(co)polymeren mit enger molekulargewichtsverteilung
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IT1264680B1 (it) * 1993-07-07 1996-10-04 Spherilene Srl Catalizzatori supportati per la polimerizzazione delle olefine

Also Published As

Publication number Publication date
BR9506295A (pt) 1997-08-12
ZA955988B (en) 1996-06-18
KR960704940A (ko) 1996-10-09
DE69501720T2 (de) 1998-09-10
AU3113595A (en) 1996-02-16
KR100356549B1 (ko) 2003-02-11
JPH09503251A (ja) 1997-03-31
IL114659A (en) 2000-06-01
WO1996002580A1 (en) 1996-02-01
HU9601038D0 (en) 1996-06-28
FI961269A (fi) 1996-05-02
NO961109L (no) 1996-05-15
FI961269A0 (fi) 1996-03-19
HUT74321A (en) 1996-12-30
ES2115391T3 (es) 1998-06-16
BG100514A (en) 1997-01-31
CN1135761A (zh) 1996-11-13
AU695214B2 (en) 1998-08-06
SK49496A3 (en) 1997-03-05
NO961109D0 (no) 1996-03-19
CA2171834A1 (en) 1996-02-01
IL114659A0 (en) 1995-11-27
ATE163653T1 (de) 1998-03-15
PL313588A1 (en) 1996-07-08
IT1273661B (it) 1997-07-09
EP0720627A1 (de) 1996-07-10
JP3714678B2 (ja) 2005-11-09
US5849653A (en) 1998-12-15
RU2155774C2 (ru) 2000-09-10
ITMI941516A0 (it) 1994-07-20
HU215264B (hu) 1998-11-30
US6136932A (en) 2000-10-24
MX9601040A (es) 1997-06-28
CN1113899C (zh) 2003-07-09
CZ112796A3 (en) 1996-12-11
ITMI941516A1 (it) 1996-01-20
NO308904B1 (no) 2000-11-13
EP0720627B1 (de) 1998-03-04
TR199500876A2 (tr) 1996-06-21

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Representative=s name: PFENNING MEINIG & PARTNER GBR, 80339 MUENCHEN

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